JOURNAL OF POLYMER RESEARCH
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2015
·Vol. 22
·期 2
·1-14
·
IF 1.92
Li Hongbin,Shi Wenying,Zhang Yufeng,Zhou Rong
Poly( p -phenylene terephtalamide) (PPTA) reinforcing blends are of great scientific interest, however the thermodynamic difference of the components make them incompatible with inferior physical-chemical properties. In this work, with the aim of exploring novel separation membrane materials, PPTA/poly(vinylidene fluoride) (PVDF) reinforcing blends were prepared by a novel reactive blending technique of in situ polymerization (method І), and the conventional solution blending (method Π), respectively. The effects of these two methods on polymers compatibility were investigated and compared through ATR-FTIR, XRD, XPS and FESEM characterization. Thermal stability, surface hydrophilicity and mechanical properties were measured through TG, water contact angle (WCA) and tensile measurements. It was found that stronger intermolecular interaction especially hydrogen bonds between polymer components in in-situ blends prevented PVDF from crystallization and a continuous phase configuration appeared. However, slution blends showed an obvious two-phase structure in FESEM observation which varied from a spherical crystallization of PVDF at low PPTA content to a fibrous-like crystallization of PPTA at high PPTA concentration. Solution blends showed lower hydrophilicity which was attributed to the PPTA crystallization and its perpendicular uniplanar orientation along blend film surface. In-situ blends exhibited higher tensile strength which was due to the better polymers compatibility between the rigid reinforced PPTA molecules and flexible PVDF matrix. The PPTA/PVDF in-situ blend is a promising candidate for the high-performance separation membrane material.
研究领域:
材料科学
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高分子化学
·
膜技术
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产品关联
DOI
高影响因子
RSC Advances
·
2023
·Vol. 13
·期 28
·19002-19010
·
IF 3.9
Han Runlin,Wang Chaoyue,Bi Congcong,Wang Hanli
Polyvinylidene fluoride (PVDF) has been widely studied and applied in separation membranes due to its high thermal and chemical stability and mechanical strength. However, PVDF has strong hydrophobicity, resulting in easy contamination of the membrane surface and fast flux attenuation, so it is necessary to modify the membrane surface to improve its separation selectivity and service life. In this paper, PVDF microporous membrane was used as the matrix material and graphene oxide (GO) as the separation layer material. The GO/Mn3O4/PVDF composite membrane was prepared by layer self-assembly of GO nanosheets, and the functional layer spacing was adjusted by nanometer Mn3O4 intercalation. The prepared composite membrane showed high flux and separation selectivity in the filtration of organic compounds. The results showed that the rejection of methylene blue increased from 34% to 99.5%, and the flux decreased from 3000 L m−2 h−1 to 95 L m−2 h−1 when GO nanosheets covered the PVDF supporting membrane. After the introduction of Mn3O4 nanowires in the GO interlayer, the dye rejection reached 99.9% and the flux reached 612 L m−2 h−1. Compared with the unintercalated composite membranes, the flux of the prepared composite membranes showed good stability in the treatment of methylene blue, and the rejection remained unchanged.
研究领域:
材料科学
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环境工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ACS Applied Materials & Interfaces
·
2020
·
IF 8.758
Yutang Kang,Shihui Jiao,Boran Wang,Xinyan Lv,Wenwen Wang,Wen Yin,Zhenwei Zhang,Qi zhang,Yumei Tan,Guangsheng Pang
Separation membranes with underliquid dual superlyophobicity have recently caused widespread concern due to their switchable separation of oil–water mixtures and emulsions. However, the fabrication of the reported underliquid dual superlyophobic membranes is difficult, and the design of the underliquid dual superlyophobic surface of these membranes is challenging because of their complex surface composition. Theoretically, underliquid dual superlyophobicity is an underliquid Cassie state attainable by the synergy of the underliquid dual lyophobic surface and the construction of a high-roughness surface. Herein, we fabricated an underliquid dual superlyophobic membrane by combining underliquid dual lyophobic polyvinylidene fluoride (PVDF) and TiO2 nanowires. PVDF-modified TiO2 nanowire membranes with underliquid dual superlyophobicity were prepared via a simple adsorption and filtration approach. PVDF was coated onto TiO2 nanowires to form a PVDF layer with a thickness of 6 nm. The PVDF modification provided flexibility to the fragile TiO2 nanowires membrane and changed its wettability from underwater superoleophobicity/underoil superhydrophilicity to underliquid dual superlyophobicity. The PVDF-modified TiO2 nanowires membrane efficiently separated both oil-in-water and water-in-oil emulsions. The binary cooperative effect between the TiO2 nanowires and the coated PVDF layer was responsible for the underliquid dual superlyophobicity.
研究领域:
材料科学
·
界面化学
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DOI
PubMed
高影响因子
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2024
·Vol. 31
·期 19
·28695-28705
·
IF 0
Liu Hongyu,Ye Wei,Zhang Huan,Wang Huicai,Wei Junfu
Here, polyaniline/polyvinylidene fluoride (PANI/PVDF) nanofiber composite membrane was fabricated using electrostatic spinning technology to remove hexavalent chromium Cr(VI). The employment of PANI not only extremely enhanced the hydrophilic property of the nanofiber membrane, but also facilitated the transfer of Cr 2 O 7 2− from water to the membrane. The PANI/PVDF membrane had an extremely excellent performance in getting rid of Cr(VI) and a quite large flux (250 L/m 2 h). The maximum adsorption quantity of the membrane could reach 334.5 mg/g in which adsorption played 52.12% part and reduction played 47.87% part. The removal rate could reach nearly 100% immediately in the permeate solution under filtration while it needed 240 min to reach 100% only by static adsorption. Therefore, the interception of the membrane and the adsorption reduction of PANI had synergistic effect on removal of Cr(VI). Furthermore, the removal rate of Cr(VI) could still reach 95.97% after reused 8 times. The membrane showed a very good reusability and application prospect. Graphical Abstract
研究领域:
环境科学
·
材料科学
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产品关联
DOI
PubMed
SEPARATION AND PURIFICATION TECHNOLOGY
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2019
·
IF 5.107
Anran Zhou,Ruibao Jia,Yonglei Wang,Shaohua Sun,Xiaodong Xin,Mingquan Wang,Qinghua Zhao,Huanhuan Zhu
The technique of coupling photocatalysis and membrane filtration was applied to the abatement of sulfonamide antibiotics in water. TiO 2 photocatalyst has been aroused widespread concern in recent years due to its low price and easy availability. A PVDF-PVP-TiO 2 -Dopamine blend ultrafiltration membrane (PPTD) was first fabricated in this study and removal of sulfadiazine (SD) in water using a PPTD membrane filtration-photocatalysis system was realized. The addition of PVP-TiO 2 -Dopamine increased the porosity and average pore size of membranes, resulting in improved hydrophilicity, flux of modified membranes. In pure water, the SD removal efficiency was 91.4% with a first-order rate constant k 0.0216 min −1 under the optimum conditions ([SD] 0 = 0.4 µmol/L, UV = 125 µW/cm 2 , pH = 7.5 ± 0.1, t = 2 h). Water quality parameters (NO 3 − , Cl − , SO 4 2− , humic acid (HA)) showed quite different effects on SD decontamination. Simulated degradation experiments using real samples demonstrated that PPTD membrane filtration-photocatalysis system has significant potential with regard to controlling SD as pollutants in water. The photocatalytic mechanism characterized using ESR indicated that OH was largely responsible for SD decontamination. The mechanism of the PPTD membrane filtration-photocatalysis system suggests that TiO 2 -Dopamine could exist synergistically through the bidentate structure or the chelated structure, and that OH, O 2 − , HO 2 , H 2 O 2 and 1 O 2 may be produced in the PPTD membrane filtration-photocatalysis system.
研究领域:
环境科学
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材料科学
·
生物学
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产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2022
·
IF 16.744
Ru Wang,Xiaoyu Xie,Chunxiang Xu,Yi Lin,Daotong You,Jinping Chen,Zhuxin Li,Zengliang Shi,Qiannan Cui,Mingliang Wang
Piezoelectric field engineering has been recently proved to restrain the photogenerated carrier recombination both in the bulk and on the surface of photocatalyst. Herein, we proposed a bi-piezoelectric ZnO nanorods (NR)/PVDF-HFP spongy film that can utilize water flow vibration to boost the photocatalytic degradation of organic dye. The composite photocatalyst can be deformed by water flow to generate an integrated piezoelectric field from PVDF-HFP and ZnO NR , which can considerably drive the separation and transfer of photogenerated charge carriers in ZnO NR. As a result, the ZnO NR/PVDF-HFP spongy film shows a ∼ 3 fold increase in reaction rate constant of degrading methyl orange (MO) with irradiation as flow speed increases from 200 rpm to 1000 rpm. A model about the bi-piezoelectric effect of ZnO NR/PVDF-HFP was configurated according to a series of characterization by piezoelectric force microscopy (PFM) and photoluminescence (PL). This work demonstrates the contribution of the bi-piezoelectric effect to photocatalytic water decontamination and provides a promising strategy to use dual-sustainable energy— solar and water energy.
研究领域:
材料科学
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环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THERMOPLASTIC COMPOSITE MATERIALS
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2022
·
IF 3.027
Hua Jiao,Jiechen Jin,Kang Zhao,Xue R Zhou,Xinyuan Zhang,Sen Song,Jia Wang,Yufei Tang,Guodong Cui
Barium titanate (BaTiO3) is a typical perovskite-type oxide with high dielectric constant, low dielectric loss, and excellent ferroelectric, piezoelectric, pyroelectric, and other properties. In view of the low photogenerated electron-hole separation efficiency of T-BT itself, it is proposed to prepare nanocomposites with good catalytic performance by compound modification with Ag. Considering repeated use, on the basis of powder catalysis, a porous block is prepared by compounding powder and organic polymer PVDF. In this study, the t-BaTiO3/Ag/β-PVDF composite material with porosity of ∼70.4% was prepared with the raw material of PVDF and piezoelectric t-BaTiO3/Ag. The mechanical and piezoelectric photocatalytic properties of the composite material was studied systematically. The piezoelectric coefficient d33 is 1.44 pC/N which can be explained by COMSOL simulation calculation. Moreover, the compressive strength is 1.76 MPa. The degradation MO and RhB results indicated that t-BaTiO3/Ag/β-PVDF composite material had good degradation and cycle stability.
研究领域:
材料科学
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催化化学
·
物理学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Jiangchao Chen,Guisheng Zhu,Kunpeng Jiang,Huarui Xu,Yunyun Zhao,Hu Wang,Pengfei Pang,Yiran Bai,Peipei Wang,Haining Wu
Safety concerns such as lithium dendrite growth, leakage and volatilization regularly plague conventional liquid lithium metal batteries. However, solid polymer electrolytes can mitigate these issues due to their chemical and electrochemical stability. In this paper, we show that the construction of porous structures gives PVDF-HFP based polymers excellent solution retention, quick Li + transport channels, and ultra-long Li-symmetric cycle stability. PVDF-HFP based electrolyte membrane with porous structure exhibits excellent electrolyte retention (129.5 %) and superior ionic conductivity (2.4 × 10 -3 S cm −1 at 20 ℃). In addition, Lithium-symmetric half battery uses the DPH250 porous electrolyte film to stably last more than 2000 h during the lithium plating/stripping process. DI regulation of PVDF-HFP electrolyte membrane is beneficial to achieve uniform lithium deposition, and better solve the interface problems existing in solid state batteries. LiFePO 4 /DPH250-LiPF 6 /Li batteries exhibit stable cycling performance and reversible specific discharge capacity, suggesting a potential strategy for stabilizing lithium metal batteries.
研究领域:
材料科学
·
能源存储
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MEMBRANE SCIENCE
·
2024
·
IF 8.4
Yazhen Jiang,Binghui Wang,Hongyu Liu,Junbin Liao,Shuaijun Yu,Edison Huixiang Ang,Jiangnan Shen
Electrically-driven membrane technology plays a crucial role in water treatment and purification, finding applications in various fields like saline water and wastewater desalination, saline concentration and wastewater recycling. The content of this study is based on dually cross-linking and hot-pressing on a PVDF blend, to fabricate a kind of anion exchange membranes (AEMs) having semi-interpenetrating network and thus improve the defect of the traditional heterogeneous AEMs. The research explores the impact of vinyl imidazole (VIM) and dimethylaminoethyl methacrylate (DMAEMA) monomers, primarily or dually cross-linking, and optimizes the membrane properties through a hot-pressing process. Under these optimized conditions, the resulting membranes exhibit robust mechanical properties and outstanding desalination capabilities, achieving an area resistance of 2.56 Ω cm 2 (comparable to standard homogeneous membranes), a desalination rate of 97.26% (outperforming the Neosepta AMX: 76.90%), and a salt limiting concentration of 3.1 M (surpassing the heterogeneous AEM and Neosepta AMX). Notably, this synthesis method is characterized by its cheap raw material and low energy consumption. This research offers valuable insights for the advancement and large-scale implementation of anion exchange membrane desalination.
研究领域:
材料科学
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环境工程
·
水处理技术
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产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2024
·Vol. 59
·期 20
·9165-9181
·
IF 3.5
Zhao Chen,Yang Gang,Luo Qianxue
The PDA/PEI modification technology is commonly employed to improve the resistance to membrane fouling of polymeric membranes used in the treatment of oily wastewater. Nevertheless, the surface characteristics of membrane materials frequently restrict the implementation of the modification technique in terms of both the amount and speed of deposition. The hydrophobic membranes, such as PVDF and PTFE, have a surface with very low surface free energy and only inert functional groups. This surface is not suitable for the deposition of PDA/PEI. This study utilized plasma etching treatment to break the C–H and C–F bonds on the surface of the PVDF membrane, resulting in the introduction of oxygen-containing functional groups. During the deposition process, the PDA/PEI exhibited a tendency to chemically connect to material surfaces that included oxygen-containing functional groups, such as –OH, by processes such as hydrogen bonding. During the modification procedure, the etched membrane experienced an increase in the mass of PDA/PEI deposition and the strength of interfacial bonding. As a result, the modified membrane acquired improved hydrophilicity and anti-fouling performance. In summary, this study offers useful insights for improving the surface properties of hydrophobic polymeric membranes to prevent membrane fouling.
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
ACS ES&T Water
·
2025
·
IF 4.3
Zihao Hong,Ziyi Yuan,Zhiyu Liu,Raphael Semiat,J. Paul Chen
Membrane distillation (MD) is a thermal-based membrane separation process driven by vapor pressure differences generated by temperature differences, and has great potential for applications in desalination, wastewater treatment, and resource recovery. However, during long-term operation, wetting and fouling lead to deteriorated permeate quality and treatment efficiency. Herein, we developed a surface modification method for the polyvinylidene difluoride (PVDF) membrane to improve the antifouling and antiwetting ability without sacrificing permeability. This method imparts superhydrophobic properties to the PVDF membrane by depositing fluorinated TiO2 nanoparticles (NPs) on its surface. The modified PVDF membrane exhibited a higher water contact angle (WCA, 157.4°) and an ultralow water sliding angle (WSA, 2.1°), indicating successful superhydrophobic modification. The modified PVDF membrane possessed superior resistance against fouling and wetting. In 150-h operation of direct contact membrane distillation, it exhibited robust performance in treating a hypersaline solution (100 g/L NaCl) containing foulants (50 mg/L humic acid). The results also verified that the TiO2 layer was firmly attached to the membrane surface. Our study demonstrates that this surface modification approach can effectively improve the membrane performance of the MD process for treatment of high-salinity solution containing foulants.
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MEMBRANE SCIENCE
·
2017
·
IF 6.035
Xuan Zhang,Liang Shen,Wan-Zhong Lang,Yan Wang
In this work, a small amount of hydrophilic perfluorosulfonic acid (PFSA) is incorporated into the polyvinylidene fluoride (PVDF) substrate to develop the high-performance thin-film composite (TFC) membrane for forward osmosis applications. Because of the hydrophilicity and excellent compatibility with PVDF, PFSA not only significantly improves the wettability of the modified membrane substrate, but also well optimizes the pore size by changing the membrane morphology of PVDF/PFSA substrate. These two factors effectively mitigate the water transport resistance and favor the better formation of the polyamide (PA) layer during the interfacial polymerization, thus improving both the water flux and membrane selectivity of the resultant TFC membranes simultaneously. Effects of the PFSA concentration on the overall properties of the modified substrates and corresponding PVDF/PFSA TFC membranes are systematically investigated via various characterizations. Consequently, the PVDF/PFSA TFC membrane achieves a best water flux ( J V ) of 54.4 LMH and a reverse salt flux ( J S ) of 10.9 gMH in AL-DS mode, and a J V of 27.0 LMH with J S of 8.4 gMH in AL-FS mode using deionized (DI) water and 1 M NaCl aqueous solution as the feed and draw solutions respectively. This work may provide a new orientation in developing TFC membranes on the hydrophobic substrate with its intrinsic advantages maximized.
研究领域:
材料科学
·
环境工程
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）