CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Yingkui Yan,Ye Wang,Zhenxin Zhang,Songtao Zhang,Jinhua Ye,Li Shi
The exploration of low-cost and efficient cocatalysts is vitally important for attaining reliable and affordable photocatalytic CO 2 conversion. Here, it is found that post-transition metal ions (Sn 4+ ) doped CdSe/S colloidal crystal can serve as effective photocatalyst for CO 2 reduction under visible light, in which Sn 4+ serves as an ionized cocatalyst. Specifically, Sn 4+ doped CdSe/S colloidal crystal shows an improved and stable photocatalytic CO 2 reduction performance with CO generation rate of 50.3 μmol h −1 and H 2 generation rate of 7.8 μmol h −1 in the presence of triethanolamine as sacrificial agent. The improved photocatalytic activity can be ascribed to the increased light harvesting ability, enhanced CO 2 adsorption capability and the improved surface charge transfer efficiency induced by Sn 4+ dopant.
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高影响因子
Materials Advances
·
2021
·Vol. 3
·期 1
·682-688
·
IF 0
Xin Wen,Huahua Fan,Lihong Jing,Ming Deng,Xiaodan Huang,Tifeng Jiao,Li Zhang,Minghua Liu
The design and fabrication of chiral inorganic materials with circularly polarized luminescence (CPL) have attracted great interest. Herein, achiral fluorescent quantum dots (QDs) were found to show CPL activity upon doping into the two-component hydrogels composed of N-[(9H-fluoren-9-ylmethoxy) carbonyl]-glutamic acid (Fmoc-Glu) and deoxyguanosine (dG). It was found that the helical structures could be formed in the two-component hydrogels, and the helicity was dependent on the absolute configuration of Fmoc-Glu. Upon introduction of water-soluble achiral CdSe/ZnS QDs into the hydrogel, the hydrogel could transmit chirality to QDs and make achiral QDs show obvious CPL signals. The mirrored CPL spectra of QDs were obtained when the enantiomeric Fmoc-Glu was used, i.e., negative and positive CPL signals appeared in the L-Fmoc-Glu/dG and D-Fmoc-Glu/dG hydrogels, respectively, which indicated that the CPL signal followed the molecular chirality of Fmoc-Glu. However, when K+ ions were added into the co-assembly of Fmoc-Glu/dG/QDs, only negative CPL signals of QDs could be obtained regardless of whether the L-Fmoc-Glu or D-Fmoc-Glu was used. It was suggested that the G-quadruplex (G4) was formed when K+ ions were introduced into the gel, which is more competitive in inducing the supramolecular chirality of achiral QDs than Fmoc-Glu. This study provides not only a convenient way to fabricate CPL-active QDs via gelation, but also a deep understanding on the competitive chirality transfer in the multi-component supramolecular hybrid system.
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APPLIED SURFACE SCIENCE
·
2019
·
IF 5.155
Di Zhang,Pin Ma,Shuo Wang,Mingpeng Xia,Sidong Zhang,Dongmei Xie,Xiaowen Zhou,Yuan Lin
Recently, the pre-synthesized oil-soluble quantum dots (QDs) have triggered great interests due to advantages of monodispersity, stability and easy synthesis. Aggregation of QDs is the reason for low loading and poor efficiency during the in situ ligand exchange linker-assisted assembly process of preparing photovoltaic devices. In this work, we modify TiO 2 films with 4-mercaptobenzoic acid (MBA) as linkers and adjust modification time (MT) of MBA on the surface of TiO 2 films. As the MT increases from 0 to 6 min, even 360 min, loading amount of QDs and photovoltaic performance improve first and then decrease. The results of line scan in cross-sectional view of photoanodes show that QDs uniformly distribute throughout the short-MT films thickness, while obvious aggregation occur in the surface of long-MT films. The best device with 3 min of MBA modification exhibits an optimal efficiency of 5.58%.
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高影响因子
SENSORS
·
2018
·Vol. 18
·期 9
·2980
·
IF 2.475
Zhizhong Han,Qinghua Weng,Chaofan Lin,Jinquan Yi,Jie Kang
In this work, the CdSe–ZnO flower-rod core-shell structure (CSZFRs) was prepared by ion-exchange method. The surface of CSZFRs was modified by 3-mercaptopropionic acid (MPA), and then the DNA probe was immobilized on the surface via chemical bond between -NH2of DNA probe and -COOH of MPA. Finally, the target norovirous (NV) RNA was combined with the probe according to the principle of complementary base pairing, resulting in a decrease of the photocurrent. The results show that the absorbance spectrum of visible light is enhanced for CSZFRs compared with pure ZnO. Under visible light irradiation, the photocurrent of CSZFRs is up to 0.1 mA, which can improve the sensitivity of the photoelectrochemical (PEC) biosensor. In the measurement range of 0–5.10 nM, the measured concentrations (c) have a good linear relationship with the output photocurrent of the biosensor. The linear regression equation is expressed asI= 0.03256 − 0.0033c(R2= 0.99, S/N = 3) with a detection limit of 0.50 nM. Therefore, this work realizes a rapid and sensitive method for the detection of NV RNA.Keywords:CdSe–ZnO flower-rod;photoelectrochemical biosensor;norovirous RNA;ion-exchange method
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PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2018
·Vol. 42
·期 7
·4811-4817
·
IF 3.201
Weiwei Chen,Shan Yu,Yunqian Zhong,Xiang-Bing Fan,Li-Zhu Wu,Ying Zhou
Quantum dot (QD)/TiO2 composites are widely used materials in the field of photocatalysis. However, the influence of different exposed facets of TiO2 in composites on photocatalytic hydrogen evolution is rarely reported. In this work, CdSe QD–TiO2 composites with dominant {001} or {101} faceted anatase were synthesized and specifically characterized using X-ray powder diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. Photocatalytic hydrogen evolution tests reveal that {001}-TiO2/CdSe QDs exhibit a 213.1- and 9.0-fold increase in photocatalytic activity compared to {001}-TiO2 and CdSe QDs, respectively. Notably, the photocatalytic activity of {001}-TiO2/CdSe QDs is 2.2 times higher than that of {101}-TiO2/CdSe QDs. Based on the results from UV-Vis diffuse reflectance spectroscopy, Brunauer–Emmett–Teller surface area testing, Mott–Schottky testing and steady-state and time-resolved emission spectroscopy, the main reason for enhanced photocatalytic activity is the faster electron transfer from CdSe QDs to {001}-TiO2 compared with to {101}-TiO2. This research on tailored facets in QD/TiO2 composites provides primary insights for the design of effective photocatalysts.
研究领域:
材料科学
·
光催化
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高影响因子
MICROCHIMICA ACTA
·
2015
·Vol. 182
·期 9
·1661-1668
·
IF 3.741
Wang Lin,Mei Ling,Liu Xiang,Shi Jiankai,Li Yahong,Gu Ning,Cui Rongjing
A nanocomposite consisting of helical carbon nanotubes, polyallylamine hydrochloride and CdSe quantum dots was synthesized and used for the electrochemiluminescent determination of dopamine in presence of peroxodisulfate. The nanocomposite was characterized by transmission electron microscopy, UV-absorption and photoluminescence spectroscopy. The electrochemical process was characterized by cyclic voltammetry and electrochemical impedance spectroscopy. Under optimized conditions, the ECL intensity decreases linearly with the concentration of dopamine in the 1.0 × 10 -9 mol · L -1 to 2.0 × 10 -5 mol · L -1 range, with a 0.2 × 10 -9 mol · L -1 detection limit. The method represents a rapid, simple and sensitive protocol for the determination of dopamine.
A glassy carbon electrode was modified with a nanocomposite prepared from helical carbon nanotubes, polyallylamine hydrochloride and CdSe quantum dots, and used for electrochemiluminescent determination of of dopamine.
研究领域:
纳米技术
·
电化学
·
分析化学
·
材料科学
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高影响因子
COLLOIDS AND SURFACES B-BIOINTERFACES
·
2013
·
IF 3.554
Moyuan Cao,Lin Yu,Ping Zhang,Han Xiong,Yucun Jin,Yi Lu,Li-Qun Wang
In this research, soft-binding aminopropanol (APP) was employed as an efficient ligand, for the transfer of as-prepared hydrophobic CdSe/ZnS quantum dots (QDs) into polar solvents. It was found that the ligands at the surface of the original QDs could be completely replaced by APP after a phase-transferring process which successfully maintained fluorescence properties and original morphology of the QDs. The resulting intermediate QDs were soluble in common polar organic solvents, such as dimethyl sulfoxide (DMSO), dimethyl formamide (DMF) and tetrahydrofuran (THF), and the soft-binding ligand could be easily removed by exposure to water. Taking advantage of the excellent solubility of the APP-capped QDs and the soft-binding characteristics of APP, a novel reaction-free method was investigated for the fluorescent labeling of polysaccharide-based micelles via encapsulation of the intermediate QDs. The incorporation of QDs had little effect on the size of the micelles and did not elevate their cytotoxicity. A photo-induced fluorescence enhancement effect was observed for the incorporated QDs, and the QD-labeled micelles could be used for cell imaging. The concept of soft-binding ligand capped QDs and the reaction-free fluorescent labeling method can be applied to a wide range of QD studies.
研究领域:
材料科学
·
生物医学工程
·
纳米技术
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高影响因子
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING
·
2017
·Vol. 123
·期 3
·189
·
IF 1.455
Lin Yibing,Lin Yu,Wu Jihuai,Zhang Xiaolong,Fang Biaopeng
The composite photoanodes based on the ZnO/SnO 2 hierarchical structures with high photoelectricity properties have been successfully synthesized, and used in the CdS and CdSe quantum dots co-sensitized solar cells (QDSSCs). In this experiment, the ZnO/SnO 2 nanoparticles (ZS-NP) and hierarchical nanosheets-based microflowers (ZS-MF) were prepared by the one-step hydrothermal route and the morphologies of the products were controlled by the solvent variation. An improved power conversion efficiency of 4.98% was achieved for the cell based on the ZS-MF composite photoanodes, which showed an increase of 21.8% compared to the ZS-NP photoanodes (4.09%). This result is mainly connected to the unique superiority of the three-dimensional hierarchical microflower nanostructures for light scattering and quantum dots loading, which is responsible for the increase of photocurrent values and eventual PCE.
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高影响因子
DALTON TRANSACTIONS
·
2018
·Vol. 47
·期 7
·2214-2221
·
IF 4.099
Qiang Wu,Juan Hou,Haifeng Zhao,Zhiyong Liu,Xuanyu Yue,Shanglong Peng,Haibin Cao
ZnS as an inorganic passivation agent has been proven to be effective in suppressing charge recombination and enhancing power conversion efficiency (PCE) in quantum dot-sensitized solar cells (QDSCs). In the present study, we constructed a novel TiO2/ZnS/CdS/ZnCdS/CdSe/ZnS photoelectrode via successive ionic layer adsorption and reaction (SILAR) and chemical bath deposition (CBD). The complementary effects of multi-ZnS layers on the optical and electrochemical performance of the QDSCs were systematically investigated. The multi-ZnS can not only facilitate the growth and distribution of QDs, but also suppress the different interface charge recombination effectively. We suggest that the formation of the ZnCdS intermediate layers via ion-exchange route during CBD process contributes to the higher photoelectrochemical cell performance of the QDSCs with the middle ZnS layer. When the three-layer ZnS was employed in CdS/CdSe co-sensitized system, the PCE reached 6.05%, which is much higher than that observed for solar cells with the conventional single ZnS treatments and the two layers inserted at the interface between CdS QDs and CdSe QDs and electrolyte (4.80% and 5.42%, respectively).
研究领域:
材料科学
·
纳米科技
·
光电子学
·
能源化学
·
半导体器件
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高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2020
·
IF 7.489
Changlin Li,Shangrong Chen,Xiangxiang Gao,Wei Zhang,Yanfang Wang
The photoelectrochemical (PEC) performance of ZnO is restricted by its low light absorption ability and high recombination rate of photogenerated carriers. In order to overcome these drawbacks, ZnO/CdS/CdSe heterostructures are prepared on Zn foil substrate using facile three-step methods containing hydrothermal growth, successive ionic layer adsorption reaction (SILAR) and modified chemical bath deposition (CBD). The effects of process parameters containing the number of SILAR cycles of CdS, sensitization sequence of CdS and CdSe, and precursors of CdSe on PEC performance of ZnO/CdS/CdSe heterostructures, and ZnO NRAs on PEC performance of CdS/CdSe co-sensitizer have been scrutinized. Through CdS and CdSe co-sensitization, a layer of CdS/CdSe nanofilm is conformally deposited on ZnO nanorod arrays (NRAs) observed by transmission electron microscopy (TEM). Both the visible-light absorption ability and separation efficiency of photogenerated carriers of ZnO NRAs are significantly enhanced evidenced by UV–vis diffuse reflectance absorption spectra , photoluminescence (PL) spectra and electrochemical impedance spectra. Due to the synergistic effect of ZnO NRAs and CdS/CdSe co-sensitizer, the ZnO/CdS/CdSe heterostructures with five SILAR cycles and one modified CBD cycle (ZnO-CdS5-CdSe) show efficient PEC properties with photocurrent density of 6.244 mA/cm 2 at −0.2 V vs Ag/AgCl under light illumination of 100 mW/cm 2 , which are 57.28 and 4.73 times higher than those of pristine ZnO NRAs and CdS/CdSe clusters, respectively. Moreover, the photoconversion efficiency and incident photon to current conversion efficiency (IPCE) of the ZnO-CdS5-CdSe photoanode reach 4.381% and 80.92%, respectively. The heterostructures based on Zn foil substrate in this study can be a promising candidate for practical PEC application and other applications such as photocatalytic degradation and solar cell due to its low manufacturing cost, large-scale production and efficient PEC ability.
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PubMed
高影响因子
RSC Advances
·
2015
·Vol. 5
·期 23
·17905-17914
·
IF 3.84
Jin Wang,Chenchen Guo,Yongqiang Yu,Huabing Yin,Xueting Liu,Yang Jiang
A new self-doped 3-hexylthiophene-b-sodium styrene sulfonate block copolymer (P3HT-b-PSSNa) was obtained via solution copolymerization of sodium styrene sulfonate (SSNa) with vinyl end-group poly(3-hexylthiophene) (v-P3HT), which was synthesized under Grignard metathesis (GRIM) reaction conditions. The self-doping structure can be controlled by altering the feed amounts of SSNa monomer, and it exhibited tunable properties. In comparison with v-P3HT, P3HT-b-PSSNa shows good solubility, broad absorption, higher electrical conductivity and good donor/acceptor (D/A) interface binding with CdSe quantum dots (QDs). Composites of P3HT-b-PSSNa and CdSe exhibit uniform dispersion, good compatibility and highly efficient fluorescence quenching, and surface chemical state analysis confirmed the chemical bonding between copolymer and QDs. This is helpful for rapid charge transfer of different semiconductors in the two-phase D/A interface. Here, we developed a strategy for producing a conjugated polymer with both doped stability during repeated electric cycles and compatibility with inorganic semiconductor materials.
研究领域:
材料科学
·
化学
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高影响因子
ACS Applied Nano Materials
·
2025
·
IF 5.5
Xiaoxia Kang,Jige Yuan,Xijuan Gu,Xiaoyan Li,Tao Wen,Miao He,Yue He,Xiaoxiao Yang,Yuechen Li,Conglin Guo,Haiwei Ji,Yuling Qin,Li Wu
The agriculture and environmental industries have employed organophosphorus pesticides (OPs) chemicals as insecticides extensively in previous decades, leading to persistent life-threatening issues. Therefore, developing a platform for the efficient identification of OPs is significant for environmental protection and human health. In this study, a strategy for the colorimetric and fluorescence detection of OPs by combining quantum dots (QDs) with DNA-templated silver nanoclusters (DNA-AgNCs) was proposed. Technically, the fluorescence of DNA-AgNCs will be enhanced once guanine (G)-rich sequences get close to the DNA-AgNCs to form hybrid complexes DNA-AgNCs/G, while quenching of fluorescence can be attributed to the hydrolysate (thiocholine) of acetylthiocholine (ATch) that was caused by acetylcholinesterase (AchE). Based on the fact that OPs can irreversibly inhibit the catalytic activity of AchE and slow down the fluorescence quenching of DNA-AgNCs/G, thus, OPs detection can be achieved by evaluating the fluorescence intensity of DNA-AgNCs/G. Additionally, a dual-mode detection system (colorimetric and fluorescent) is achieved through an ion-exchange reaction between QDs and DNA-AgNCs/G. The concentration of OPs is quantified by monitoring fluorescence changes in the QDs and poly(9,9-dioctylfluorene) (PFO) polymer dots (Pdots) system, with PFO Pdots serving as a stable internal reference. Using trichlorfon as a model, the limit of detection (LOD) was 2.55 pg/mL, while an excellent linear relationship with the trichlorfon concentrations in the range of 5 × 100–5 × 105 pg/mL was obtained. Additionally, visual detection (as low as 1.06 pg/mL) can be realized readily, taking advantage of the ion-exchange reaction between DNA-AgNCs and QDs.
研究领域:
环境科学
·
生物化学
·
纳米技术
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高影响因子
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