CORROSION SCIENCE
·
2021
·
IF 7.205
Jinlong Chen,Jianxin He,Lingjie Li
To gain insights into the effect of sodium dodecylbenzene sulfonate (SDBS) on Mg corrosion in NaCl medium, in-situ Raman spectroscopy was employed to monitor the interface evolutions of Mg surface in NaCl and NaCl+SDBS solutions. Accompanied by ex-situ Raman, SEM and XPS results, the evolution models during Mg corrosion in corrosive media were established to reveal the influence of DBS − . Competitive adsorption models about the interface of Mg/NaCl+SDBS between DBS − and Cl − were also presented to explain the inhibition effect of SDBS. These models guide the optimal usage of SDBS in Mg alloy corrosion inhibition.
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DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2020
·
IF 5.162
Kegui Zhang,Wenzhong Yang,Feng Ge,Bin Xu,Yun Chen,Xiaoshuang Yin,Ying Liu,Huanzhen Zuo
A composite coating containing konjac glucomannan (KGM) and CaCO 3 was fabricated on AA5052 alloy through a self-curing process, and its surface morphology and component were characterized by scanning electron microscope (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and thermogravimetric analysis (TGA). The effect of Ca(OH) 2 content on the protective property of the composite coating for aluminum alloy in 3.5 wt% NaCl solution was evaluated by electrochemical impedance spectroscopy measurements. Moreover, the inhibitory performance of the coating on the pitting corrosion of metal was examined by potentiodynamic polarization curves and atomic force microscopy (AFM). The images of scanning electron microscope show the composite coating with a thickness of 50 μm has well-defined branch-shaped structure. The FT-IR spectra confirm the successful fabrication of the polymer coating through the formation of CaCO 3 . The results of electrochemical impedance spectroscopy suggest that the resistance of the aluminum alloy sample coated with such protective layer is improved by six orders of magnitude, compared with the bare metal. After 60 d of immersion, the polarization curve data and AFM analysis show the pitting corrosion occurring on AA5052 surface is prevented due to the barrier property of coating.
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DOI
PubMed
高影响因子
SOLAR ENERGY MATERIALS AND SOLAR CELLS
·
2020
·
IF 6.984
Xuejiao Li,Na Li,Weihua Liu,Zhongfeng Tang,Jianqiang Wang
The first principle molecular dynamics (FPMD) simulations in combination with experimental measurements are applied to investigate the thermophysical properties and structural evolution of MgCl 2 –NaCl–KCl (MNK) eutectic . The densities, melting point, and enthalpy of fusion simulated by FPMD within NPT ensemble are consistent with experimental results. Besides, the thermal conductivity of molten MNK eutectic evaluated from FPMD simulations with NVT ensemble gives satisfactory result. Furthermore, the shear viscosities of MNK eutectic are deduced based on ion self-diffusion coefficients and solvodynamic radius, similar to the data estimated by additive contribution method. Eventually, the change rules of radial and angular distribution functions and structural factor of MNK eutectic during melting are revealed, and the melting mechanism is proposed from the evolution of polyhedral coordination structures. These results are heuristic in structure-activity relationship of MNK eutectic, which sheds insight for further development of efficient heat transfer and storage media through microstructure engineering.
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高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2020
·
IF 3.99
Xin Liu,Jihui Wang,Wenbin Hu
The superparamagnetic Fe 3 O 4 /CS/inhibitor nanocomposite was synthesized by using ionic gel method with Fe 3 O 4 as superparamagnetic core, chitosan as nanocarrier and molybdate (MoO 4 2− ) and benzoate (C 6 H 5 COO − ) working as loaded inhibitors. The morphology, structure and magnetic property of nanocomposite were characterized by transmission electron microscopy , X-ray diffraction, Fourier transform infrared spectroscopy and vibrating sample magnetometer . The release behavior of nanocomposite with and without external magnetic field (“no MF” mode and “MF ON” mode) was conducted by UV–vis spectroscopy, and the corrosion inhibition performance of nanocomposite for carbon in 3.5% NaCl solution was investigated by polarization curve and electrochemical impedance spectrum methods. The results show that the obtained Fe 3 O 4 /CS/inhibitors was in a well-defined core-shell structure with MoO 4 2− and C 6 H 5 COO- loaded flake-like chitosan shell stacking closely to Fe 3 O 4 surface. Under no MF mode, the release behavior of nanocomposite was mainly ion exchange and Fickian diffusion mechanism. Under MF ON mode, the swelling of polymer chains and diffusion between magnetic nanoparticles were involved apart from the ion exchange and Fickian diffusion mechanism. With the addition of nanocomposite inhibitors in NaCl solution, the charge transfer resistance and inhibition efficiency of steel increased firstly and then decreased with the prolonging of immersion time. The highest inhibition efficiency of nanocomposite inhibitors in NaCl solution under on MF and MF ON mode was located in 30 min and 90 min respectively. The inhibition of nanocomposite for carbon steel in NaCl solution is resulting from the reduction of aggressive Cl- concentration in the solution due to the ion exchange between Cl- ions in solution and MoO 4 2− and C 6 H 5 COO- ions in the nanocomposite, and the formation of ferric/ferrous molybdate, ferric/ferrous benzoate and basic ferric benzoate inhibition films on steel. This novel as-prepared composite owns superior loading capacity of inhibitors and its preparation process is especially simple relative to other nanocomposites in previous reported works.
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高影响因子
CELLULOSE
·
2019
·Vol. 26
·期 15
·8313-8323
·
IF 3.917
Wang Chao,Yang Guihua,Zhang Xueming,Shao Lupeng,Lyu Gaojin,Mao Jianzhen,Liu Shijie,Xu Feng
Levulinic acid (LA) production from corncob acid hydrolysis residues (CAHR) using FeCl 3 as Lewis acid catalyst in green solutions of salt was investigated. The reaction kinetic relationships were determined in the temperature range of 160–180 °C, with FeCl 3 concentrations of 0.12–0.36 M, and a reaction time of 0–60 min. The maximum LA concentration of 59.0 mol% (24.5 g/L) was achieved at 170 °C in a 30% NaCl solution containing 0.24 M FeCl 3 . A pseudo first-order kinetic model was proposed to describe the cellulose deconstruction to LA. The model agreed perfectly with the evolution in the concentrations of the major compounds such as glucose, 5-hydroxymethylfurfural and LA during the CAHR hydrolysis. The kinetic model developed for CAHR was in good agreement with that previously developed for other lignocellulosic systems. Based on our kinetic model and reaction system, the LA yield is increased at the lower end of the temperature range with the higher acid concentrations. The results indicated that the concentrated seawater after desalination could be a green solvent in the biorefinery.
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DOI
高影响因子
Green Chemistry Letters and Reviews
·
2019
·
IF 2.754
Jinchang Wang,Yuanhua Lin,Zhipeng Sun,Xi Luo,Wanying Liu,Xuefeng Deng
In this study, Corydalis yanhusuo extract acts as a green inhibitor for J55 steel in 3.5% NaCl solution saturated with CO2. Rapid resolution liquid chromatography shows the concentrations of Palmatine to be 0.6358 g/L, Tetrahydropalmatine 0.7715 g/L, and Corydaline 0.3755 g/L. Potentiodynamic polarization results suggest that Corydalis yanhusuo extract is a mixed-type inhibitor. The inhibition efficiency of Corydalis yanhusuo extract increases with the increase of concentration and reaches 92.36% at 5%v/v but decrease with the increased temperature. The inhibition efficiency is 69% at 80°C. The protective film formed on the metal surface was confirmed by Fourier transforms infrared spectroscopy, UV–visible, scanning electrochemical microscope and scanning electron microscope methods. The quantum chemical calculations predicate that Palmatine acts as the major component for inhibition performance.
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DOI
高影响因子
KEY ENGINEERING MATERIALS
·
2022
·
IF 0
Shuai Ren,Xiao Hua Lv,Guo Feng Liu,Xiao Yuan Zhang
Insulators covered with superhydrophobic coatings have better anti-pollution flashover performance. In high-pollution areas, the superhydrophobic coating gets covered with a contamination layer. The droplets are in contact with the contamination layer instead of the superhydrophobic coating. However, there is still a lack of relevant research on the hydrophobicity of the contamination layer. It is not conducive to evaluating the functional performance of superhydrophobic insulators in high-pollution areas. Choose diatomite to simulate contamination. The effects of fouling time, environment temperature, diatomite density, and impurity (NaCl) on the hydrophobicity of the contamination layer are analyzed experimentally. The experiment results show that the diatomite layer becomes hydrophobic over time. The higher the temperature is, the faster the hydrophobicity of the contamination layer will increase, and the higher the peak value of the static contact angle will be. However, the diatomite density and the exitance of NaCl have little influence on the hydrophobicity of the diatomite layer. Furtherly, the composition of the superhydrophobic coating is found in the diatomite layer, which proves the existence of hydrophobicity transfer. According to theoretical analysis, the appearance of transfer will enhance the hydrophobicity of diatomite particles. When the angular coordinate of the liquid-protrusions-gas triple line is greater than 90°, the mechanical conditions for the diatomite particles carried away by the droplet can be satisfied. As a result, hydrophobic diatomite is attached to the droplets’ surface.
研究领域:
电气工程
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材料科学
·
环境科学
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DOI
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
·
2025
·
IF 8.3
Mengqi Xiao,Jibao Zhang,Yang Li,Yan Li,Xuejian Liu,Xiaolin Wang,Zhenyuan Yin
Hydrate-based H 2 storage has emerged as a promising solution for offshore wind-to-hydrogen applications. Seawater is widely accessible on offshore platforms and can be directly used as a hydrate former. However, effects of salt in seawater on the kinetics of hydrogen hydrate are less understood and warrants investigation. This study systematically examines the influence of NaCl on the H 2 hydrates formation in the presence of a thermodynamic promoter, 1,3-dioxolane (DIOX). Effects of NaCl on the thermodynamics, kinetics, and morphology of H 2 -DIOX hydrates were investigated. The thermodynamic inhibition on DIOX hydrates is more pronounced than that on H 2 -DIOX hydrates in simulated seawater, resulting in a slurry-like hydrate morphology that improves gas-liquid contact. H 2 final gas uptake achieved in simulated seawater is seven-fold that of pure water with H 2 only occupying 5 12 cages of sII hydrate. Our study provides insights into the direct use of seawater for offshore hydrate-based H 2 storage.
研究领域:
储能技术
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化学工程
·
海洋技术
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氢能
·
物理化学
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高影响因子
INORGANIC CHEMISTRY
·
2022
·
IF 5.436
Jinhua Feng,Junnan Chen,Shuchang Wang,Miaomiao Jia,Zhiyu Zhang,Tongwen Yu,Ming Xue
Searching for the efficient and sustainable inhibitors to defend metal corrosion in the marine environment has received a great deal attention in both academia and industry. In this work, a new strategy was developed to encapsulate benzimidazole (BI) inhibitor guest molecules into the micropores of bio-MOF-1, which was constructed with the other natural adenine inhibitor. Electrochemical characterizations revealed that the slowly sustained release of BI and adenine inhibitors from the BI@bio-MOF-1 composite presented excellent anti-corrosion durability in the whole mild steel corrosion process. The impedance arc value attained approximately 5000 Ω·cm2 at initially 2 h and further increased to 6000 Ω·cm2 after 5 days immersion in 0.5 M NaCl solution, and the inhibition efficiency reached 85.36% due to the synergistic dual inhibitive effect of BI@bio-MOF-1 composite. The dual inhibition-based bio-MOF-1 composite equipped strong metal-chelating capability and response durability, exhibiting high potentiality for metal anti-corrosion applications.
研究领域:
材料科学
·
腐蚀工程
·
化学工程
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2024
·Vol. 141
·期 22
·e55447
·
IF 2.7
Huawei Huang,Yiwen Hu,Xiuduo Song,Jian Kang,Dandan Chen
The development of thin-film nanocomposite (TFN) membranes with high performance is conducive to efficient desalination and wastewater treatment. In this work, dendritic mesoporous silica nanoparticles (DLSiO 2 ) were synthesized by a dual-templating strategy. Afterward, they were introduced into the aqueous phase to fabricate TFN membranes via in situ interfacial polymerization (IP) reaction. Powerful techniques as scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, Nano zetasizer-DLS, x-ray photoelectron microscopy, electrokinetic analyzer, and contact angle were used in the characterization of dendritic structures and nanocomposite membranes. Results revealed that DLSiO 2 with special structural characteristics can effectively regulate the IP process, promoting the enhancement of the crosslinking degree, surface hydrophilicity, and surface negative charge of polyaimde (PA) selective layers. It is also beneficial for constructing extra water channels within the PA selective layer to boost the transport of water molecules. As a consequence, the prepared TFN membrane with 0.3 mg/mL DLSiO 2 exhibits optimal separation performance and good pressure resistance, acid–base resistance, and anti-fouling properties. It also exhibited a water permeability of 4.17 L m −2 h −1 bar −1 (increased by 61.7% compared with thin film composites (TFC) membrane) and a NaCl rejection of 99.0%, which were better than those of TFN membranes prepared by introducing other types of silica in other studies.
研究领域:
材料科学
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环境工程
·
化学工程
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DOI
高影响因子
SOLAR ENERGY MATERIALS AND SOLAR CELLS
·
2022
·
IF 7.305
Xiangyang Liu,Zeyang Kang,Jiahao Zhao,Shaoxuan Huang,Ying Zhang,Maogang He
Coupling with supercritical power cycle can improve the thermal efficiency of the concentrated solar system. Design the suitable thermal storage medium is critical to the new coupling system. A new ternary eutectic salt with low cost was developed composed of NaCl , Na 2 CO 3 , and Na 2 SO 4 based on the calculation method of phase diagram , meeting the requirements of solar energy storage over 873 K. The eutectic point and composition of the designed salt were predicted to be 900 K and 50 mol% NaCl-35 mol% Na 2 CO 3 -15 mol% Na 2 SO 4 . The designed salt shows high specific heat capacity and phase-change enthalpy, and low cost, which indicates it has good thermal storage capacity. Composite phase change materials with multi-walled carbon nanotubes and graphene nanosheets which can enhance the thermal conductivity and heat capacity of designed salt were prepared. The effects of preparation methods on the thermophysical properties of the composite phase change materials were analyzed.
研究领域:
材料科学
·
能源工程
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高影响因子
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
·
2021
·Vol. 26
·期 2
·449-456
·
IF 2.647
Liu Shanshan,Li Chenyao,Wang Dongxin,Li Junyi,Yuan Rui,Che Yusi,He Jilin,Song Jianxun
In this research, the reduction mechanism of Nb(V) under various [F − ]/[Nb n+ ] ratios ( α ) was investigated by a series of electrochemical techniques, such as square wave voltammetry (SWV) and chronopotentiometry (CP). We previously studied the electrode reduction process of Nb(V) and revealed that was Nb(V) → Nb(III) → Nb(I) → Nb in NaCl-KCl molten salt. It was found in this research that the electrode reduction process of Nb(V) ion was shortened to Nb(V) → Nb(III) → Nb when α was equal to 1.0; furthermore, the electrode reduction process of Nb(V) ion transforms to Nb(V) → Nb(IV) → Nb when α was greater than or equal to 5.0. Moreover, the reaction mechanism was also discussed in this work. Metallic niobium was collected on a molybdenum electrode under the condition of higher fluoride content after electrolysis in the melt.
研究领域:
材料科学
·
电化学
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高影响因子
危险品化学品经营许可证（带存储）