CERAMICS INTERNATIONAL
·
2022
·
IF 5.532
Jie Zhang,Kang-Bo Yu,Jia-Min Wu,Chun-Sheng Ye,Wen Zheng,Heng Liu,Shi-Feng Wen,Chun-Ze Yan,Yu-Sheng Shi
SiO 2 -based ceramic cores are widely used in the preparation of gas turbine engine hollow blades due to their excellent chemical stability and easy removal after casting. In this paper, ZrSiO 4 reinforced SiO 2 -based ceramics were fabricated using digital light processing (DLP) technology. The results showed that the addition of ZrSiO 4 reduced the cure depth due to its high UV light absorptivity and refractive index . When the content of ZrSiO 4 increased to 15 wt%, the cristobalite content reached the maximum, and radial shrinkage reached the minimum of 1.4%. ZrSiO 4 grains could hinder the propagation of cracks, enhancing the room-temperature flexural strength . At 1550 °C, fracturing across SiO 2 grains in SiO 2 -based ceramics led to the great improvement of high-temperature flexural strength. When the content of ZrSiO 4 reached 15 wt%, the flexural strength at room temperature and high temperature was 11.5 MPa and 36.7 MPa, respectively. Therefore, the SiO 2 -based ceramics prepared using DLP technology have good room temperature and high temperature properties, and are expected to be used for hollow blade casting.
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CHEMOSPHERE
·
2022
·
IF 8.943
Jinhua Luo,Yaohui Wu,Mengzhu Jiang,Aihua Zhang,Xiaoyong Chen,Yelin Zeng,Yonghong Wang,Yunlin Zhao,Guangjun Wang
Developing broad-spectrum light reactions, effective charge separation, and easily recoverable photocatalysts were considered cost-effective pollution remediation methods. The ZnFe 2 O 4 /BC/ZnO composite was prepared to achieve these objectives, where biochar (BC) was used as a conductive channel and ZnFe 2 O 4 as a magnetic substance. Among them, the 0.6-ZBO composite performed the best, with photocatalytic removal of tetracycline (TC) reaching 85.6%. The photocatalytic degradation rated constant of 0.6-ZBO composite was 23.36 × 10 −3 min −1 , which was 7.6, 4.1, and 2.5 times higher than that of ZnFe 2 O 4 /BC, ZnO, and ZnFe 2 O 4 /ZnO samples, respectively. According to several characterization data, it was demonstrated that successful Z-scheme heterojunctions were constructed between ZnFe 2 O 4 and ZnO. The 0.6-ZBO complex increased the range of light absorption and strengthened the separation of electron-hole pairs, thus improving the redox ability of the complex. In the different water matrices, the stability of 0.6-ZBO was excellent and its ability to remove TC decreased slightly to about 11% after 5 cycles. This work provided a valuable approach to design a novel and efficient system for degrading organic pollutants in wastewater using magnetic biochar.
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JOURNAL OF ALLOYS AND COMPOUNDS
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2022
·
IF 6.371
Junhui Yi,Haoxian Zeng,Hai Lin,Minghao Li,Runkun Xie,Beifang Chen,Runsi Ding,Zhenghui Liu,Dehao Li,Ning Li
Rational design of Z-scheme heterojunction is known to be a good strategy for promoting photogenerated charge efficient separation. In this paper, a direct Z-scheme Ag 2 O/Bi 2 MoO 6 heterostructured microspheres with good interfacial properties were successfully prepared by hydrothermal synthesis-coprecipitation-calcination decomposition. Various techniques such as Transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), and powder X-ray diffraction (PXRD) were used to reveal the structure, morphology, composition, electrochemical and optical properties of the target product. The catalytic activity of the as-prepared composite was evaluated by visible light degradation of Rhodamine B (RhB) and transient photocurrent. As expected, the results showed that 1:5 Ag 2 O/Bi 2 MoO 6 exhibited the optimal catalytic performance. And the visible degradation efficiency is up to 86% in 90 min, which was 2.69 times higher than that of Bi 2 MoO 6 (32%). And 1:5 Ag 2 O/Bi 2 MoO 6 exhibited the highest photocurrent efficiency (0.8 μA/cm 2 ). Meanwhile, the efficiency of 1:5Ag 2 O/Bi 2 MoO 6 keep 90% after four cycles. The enhanced activity can be attributed to the formation of a good interfacial contact between Ag 2 O and Bi 2 MoO 6 . In addition, hole and superoxide were identified as the main active species. Eventually a possible direct Z-scheme mechanism was proposed to explain enhanced performance. This work may provide a new perspective for the rational design of excellent Bi 2 MoO 6 -based Z-scheme heterojunctions for environmental remediation.
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Electronic Materials Letters
·
2022
·Vol. 19
·期 1
·94-107
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IF 3.151
Luo Menghao,Feng Hange,Hu Yuechuan,Chen Keke,Dong Zibo,Xue Shaolin
Abstract Photocatalytic degradation has received considerable emphasis since it shows significant possibilities in environmental pollution. In this work, ternary Z-scheme heterojunction g-C 3 N 4 /TiO 2 /Ti 3 C 2 photocatalysts are designed and fabricated. The Z-scheme heterojunctions formed on the surfaces of g-C 3 N 4 and TiO 2 dramatically modify the photocatalytic performances of the compound under illumination. Meanwhile, in this process, multilayer Ti 3 C 2 , as the transport medium of Z-scheme heterojunction, is tightly bonded to TiO 2 generated by hydrothermal oxidation and g-C 3 N 4 with large specific surface area, which effectively facilitates the space charge separation and depresses the charge recombination. When the addition amount of TiO 2 /Ti 3 C 2 is 80 mg and calcined at 450 ℃ for 4 h, g-C 3 N 4 /TiO 2 /Ti 3 C 2 has the greatest photocatalytic performance, and the kinetic constant for degradation methyl orange (MO) was about 3.62 times that of g-C 3 N 4 and 14.55 times that of Ti 3 C 2 , respectively. This work illustrates that g-C 3 N 4 /TiO 2 /Ti 3 C 2 has outstanding potential and offers novel insights for designing and synthesizing new ternary heterojunction materials. Graphical Abstract
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高影响因子
APPLIED SURFACE SCIENCE
·
2022
·
IF 7.392
Jingxuan Pei,Zhenfei Tian,Xiang Yu,Shuting Zhang,Shiqing Ma,Yibo Sun,Rabah Boukherroub
Antibiotic residues in wastewater cause a serious threat to aquatic environment and human safety. Therefore, the development of robust strategies for detecting antibiotic residues becomes critical. In this work, a surface-enhanced Raman scattering (SERS) substrate, consisting of gold nanoparticles/nano diamond/carbon nitride (Au/ND/C 3 N 4 ) hybrid, which features enhanced light utilization and self-cleaning properties, is developed for sensitive sensing of tetracycline. The fabricated Au/ND/C 3 N 4 substrate effectively captures target molecules and enhances Raman activity, owing to abundant functional groups and light scattering effect of ND. Moreover, the heterostructure formed by Au NPs, ND and C 3 N 4 endows this SERS substrate with superior self-cleaning capability, enabling its reusability. The Au/ND/C 3 N 4 substrate exhibits high sensitivity (10 -14 M), desirable reproducibility (RSD = 13.29 %, n = 238) and favourable stability (84.8 % of initial intensity after 30 days) for crystal violet probe. Also, no significant loss of SERS or catalytic activity is observed during cyclic SERS detection. Likewise, the detection of tetracycline at nanomolar level is achieved with good recyclability. This work proposes a distinctive strategy for enhancing SERS activity, and the developed self-cleaning Au/ND/C 3 N 4 substrate represents a potential candidate for highly sensitive detection of antibiotic residues in wastewater.
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ECS Journal of Solid State Science and Technology
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2022
·Vol. 11
·期 10
·107001
·
IF 2.483
Jiaqi Luo,Weijiu Huang,Bitao Liu,Bing Liu
Zirconia slurry aimed to apply in digital light process (DLP) printing technology were made of the 3 mol% yttrium oxide (Y2O3) stabilized micro-nano zirconium dioxide (3YSZ) powders. An overall mechanical strength can be obtained via a precise control of two-step sintering process. The results show that Y2O3 in 3YSZ would diffuses into the ceramic lattice, further stabilizing the metastable tetragonal zirconia (t-ZrO2) toughening phase in sub-micro sized grains with nearly 100% crystal phase transition ratio. The Vickers hardness of sintered ceramic parts reaches 12.94 ± 0.186 GPa. The fracture toughness (KIC) of sintered ceramics is 5.63 ± 0.015 MPa·m1/2. The propagation law of Vickers crack reveals the mechanism of strengthening and toughening of fine grains on matrix fracture toughness. Due to the uniform crystals also can make the corrosion better to construct a three-phase boundary sensitive process, the response of the T-ZrO2-SnO2 to 30 ppm NH3 is 15.7 mV which is 2 times more than the commercial ZrO2. A relative short response and recovery times of 6 s and 33 s can achieve with a good reproducibility of continuous response and recovery transients.
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ACS Omega
·
2022
·
IF 4.132
Weiwei Tie,Surjya Sarathi Bhattacharyya,Cancan Han,Shuaibiao Qiu,Weiwei He,Seung Hee Lee
A novel high-performance BiOBr@graphene (BiOBr@G) photocatalyst with a new assembly structure had been demonstrated using a facile hydrothermal method through chemical bonding of reduced graphene oxide and structure-defined BiOBr flakes for improving charge separation and transfer performance, which were first synthesized at room temperature in immiscible solvents without corrosive acids. The prepared samples were characterized, and the BiOBr@G composite realized an efficient assembly portfolio of graphene and BiOBr flakes with defined structures, verified by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman and X-ray photoelectron spectroscopy (XPS), in which BiOBr flakes were covalently linked with the assembled graphene sheets through the Bi–C bond. This composite exhibited remarkable visible light absorbance and efficient photoinduced charge splitting characteristics in comparison with those of pure BiOBr, as established by DRS absorption, photoluminescence radiation, and photocurrent study. Hence, a very small amount (5 mg) of the BiOBr@G composite displayed a complete photodegradation effect on the rhodamine B dye under only 15 min of visible light excitation, which was three times faster than that of pure BiOBr and extremely superior to that of commercial P25. This was probably ascribed to the well-defined BiOBr structure itself, elevated light absorbance, and Bi–C chemical bond inducing quick charge separation and transfer in the BiOBr@G composite. Additionally, investigations on the photocatalytic mechanism displayed that the photogenerated holes in the BiOBr valence band and derivative superoxide radicals played vital roles in the photodegradation of RhB dyes, as reinforced by the electron spin resonance method, where the covalent linking of BiOBr and graphene served as an effective pathway for charge transportation.
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高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2022
·
IF 16.744
Yunxiong Zeng,Xingyu Zhan,Bo Hong,Yingchun Xia,Yangbin Ding,Tao Cai,Kai Yin,Xingqin Wang,Liming Yang,Shenglian Luo
Recently, antibiotic pollution has aroused great concern due to its toxicity to living organisms and the risk of drug-resistance gene generation in the ecosystem. Carbon nitride (CN) photodegradation towards antibiotics is a promising technology for water purification. However, CN possesses a low activity due to the fast recombination of electron-hole pairs and slow reaction kinetics. Herein, we report the fabrication of nitrogen-vacancy and oxygen-substitution modified carbon nitride ((Nv, Os)–CN) with a rearranged surface via a low-temperature thermal oxidation strategy. The (Nv, Os)–CN can degrade tetracycline (TC), ciprofloxacin (CIP) and sulfadiazine (SZO) than CN under visible light irradiation efficiently. The first-order kinetic constant of (Nv, Os)–CN for TC, CIP and SZO was 2.1, 2.24 and 1.38 folds higher than those of CN, respectively. This high performance benefits from the rearranged surface atoms by forming an active surface with rich Nv and Os, thus promoting interfacial charge transfer and building robust water-(Nv, Os)–CN interface. In addition, the possible photodegraded pathways, resulting intermediates and risks of TC photodegradation were analyzed by the LC-MS and QSAR methods. Our proposed low-temperature thermal oxidation strategy to achieve surface atom rearrangement endows CN with an enhanced photoactivity toward antibiotics degradation.
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高影响因子
Journal of Materials Chemistry C
·
2022
·Vol. 10
·期 48
·18234-18240
·
IF 8.067
Chuan-Jun Tang,Bo-Mei Liu,Lin Huang,Jing Wang,Qiang Tang
The rapid development of minimized near-infrared (NIR) phosphor-converted LEDs (pc-LEDs) has evoked a large demand for broadband NIR phosphors and will enable breakthrough NIR spectroscopy applications. Consequently, the search for NIR pc-LEDs which can emit in the NIR-II window (1000–1700 nm) has become increasingly urgent. Herein, an unprecedented long-wavelength NIR MgTi2O5:Ni2+ phosphor that exhibits broadband NIR emission covering 1200 to 1700 nm with a full width at half maximum (FWHM) of 245 nm is successfully synthesized. By combining the MgTi2O5:Ni2+ phosphor with an ultraviolet LED chip, a high-performance NIR pc-LED is fabricated, which has a NIR output power of 3.6 mW at 300 mA driving current. These results indicate that the fabricated NIR-II pc-LED device is a promising candidate as a broadband light source for NIR spectroscopy applications including night vision, high-penetrating imaging, and information restoration. For instance, the secret information covered by ink can be recovered with the aid of an NIR-II pc-LED. This work not only provides a new material that has great potential as a NIR light source, but also demonstrates a set of approaches to expand the application of NIR spectroscopy and imaging technology.
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ACS Applied Materials & Interfaces
·
2022
·
IF 10.383
Fanghao Ye,Huibo Yan,Siyang Liu,Baoxing Liu,Zhiqing Zhang,Mengyao Tian,Ting Zheng,Xi Lan,Jincheng Huang,Chunfeng Meng,Ping Xu,Guijun Li
Perovskite light-emitting diodes (PeLEDs) have become a hot research topic in recent years and can now achieve an external quantum efficiency (EQE) of over 22% for green and red devices. However, the efficiency of blue PeLEDs, which are essential for display applications, lags far behind their green and red counterparts. The interface of the PeLEDs has a critical influence on the carrier transport and exciton recombination dynamics, and interface engineering is considered to be an effective strategy to improve the device performance. Herein, quaternary ammonium-based ionic liquids serve as an interfacial modification layer to significantly improve the device efficiency and stability. The interaction of quaternary ammonium cations with Pb(Br/Cl)6 octahedra promotes nucleation sites, which significantly improves the morphology of perovskite films and reduces the formation of defects in films. In addition, ion migration is also effectively suppressed in the device. As a result, with tributylmethylammonium bromide (TMAB) used as the interface layer, the EQE of the device is successfully increased from 3.5 to 6.7%, and the operational stability with a half-lifetime (T50) is increased by over 12 times. Our work provides a new class of interface modification materials toward high-performance blue PeLEDs.
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高影响因子
NEW JOURNAL OF CHEMISTRY
·
2022
·Vol. 46
·期 47
·22639-22649
·
IF 3.925
Doudou Wang,Haiyan Zhang,Ye Zhang,Zhixuan Huang,Lili Li
The design of organic photocatalysts with visible-light-response is an important way to solve energy crisis and environmental pollution. Polypyrrole (PPy) as one of the conjugated polymers is a prospective photocatalyst material due to its excellent optical properties, easy synthesis and high environmental stability. In this work, polyacrylonitrile (PAN) and g-C3N4 were electrospun as a fiber membrane matrix. PPy was coated on the matrix by in situ polymerization of a pyrrole monomer using doped Fe3+ as an oxidant. PPy exhibited a broadband visible light absorption region and a narrow band gap which was conducive to improve visible light utilization. The separation efficiency of photogenerated e−–h+ pairs was improved by constructing a heterojunction between PPy and g-C3N4. The doping of Fe3+ as an electron scavenger further prevented the recombination of carriers. The PAN/g-C3N4-PPy-Fe3+ membrane showed highly efficient removal performance for both cationic and anionic dyes. Moreover, PAN/g-C3N4-PPy-Fe3+ exhibited excellent recyclability and stability. This work outlined an approach for designing a novel conjugated polymer based multi-component composite photocatalyst with visible light response.
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PLoS One
·
2022
·Vol. 17
·期 8
·e0273169
·
IF 3.752
Chu-Ya Wang,Xin Fang,Qi Zeng,Heng-Deng Zhou,Yongze Lu
Bismuth(III) oxybromide (BiOBr) is a typical photocatalyst with a unique layered structure. However, the response of BiOBr to visible light is not strong enough for practical application. Moreover, the charge separation efficiency of BiOBr still needs to be improved. In this study, series of Au-doped BiOBr photocatalysts was prepared through a facile one-step hydrothermal method. The as-prepared Au 0.3 -BiOBr nanosheets exhibited an excellent electrochemical performance. The charge separation efficiency of Au 0.3 -BiOBr nanosheets was enhanced by 18.5 times compared with that of BiOBr. The intrinsic photocatalytic activity of Au 0.3 -BiOBr nanosheets in the degradation of tetracycline hydrochloride was approximately twice higher than that of BiOBr under visible light irradiation. In addition, three pathways were identified for the photocatalytic degradation and mineralization of tetracycline hydrochloride, which involve four reactions: hydroxylation, demethylation, ring opening and mineralization. Accordingly, this study proposes a feasible and effective Au-doped BiOBr photocatalyst, and describes a promising strategy for the design and synthesis of high-performance photocatalysts.
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