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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2018 ·Vol. 30 ·期 2 ·1699-1705 · IF 2.324

Electrical and optical responses of composite films based on N,N-dimethylamino-4′-N′-methylstilbazolium 2,4,6-trimethylbenzenesulfonate (DSTMS)-graphene

Teng Fei,Chen Dong,Ma Yuzhe,Ji Shaohua,Liu Jiaojiao,Wang Tianhua,Tang Jie,Cao Lifeng,Teng Bing

N,N -dimethylamino-4′-N′-methylstilbazolium 2,4,6-trimethylbenzenesulfonate (DSTMS)-graphene ex-situ and in-situ composite films with 2% concentration of graphene were first prepared and systematically investigated. The crystallinity of DSTMS-based composite films were confirmed by XRD analysis, and the functional groups of composite films can be obtained by FT-IR. Optical absorptions were recorded using UV–Vis-NIR spectral analysis, and the band gap and extinction coefficient of the films were calculated. The thermal stability of the composite films were analyzed by TG/DSC. The pressure sensitive resistance test showed that the pressure sensitive signal of the composite films were significantly increased after graphene added, while the signal of DSTMS film eventually disappears. This work expands the application of organic nonlinear crystal DSTMS in optics and electricity by doping graphene.

研究领域: 材料科学 · 凝聚态物理 · 功能材料 · 非线性光学 · 纳米复合材料 · 电学性能 · 光学性能 · 热分析
✓ 已验证 DOI 高影响因子
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH · 2021 ·Vol. 28 ·期 46 ·65243-65254 · IF 4.223

Construction safety: an analysis of the cross-influence of economic, construction, and accident death factors

Chen Tao,Cao Zhonghong

To explore the relations between the number of accident deaths (NCD) and various factors in construction safety, a multiple linear regression model was established, based on the panel data of economy, construction labor, and the number of accident deaths in 31 provinces (regions) of China from 2009 to 2018. The results show that the average total profits and taxes (TPAT), and the death rate of ten thousand people (DR) are positively correlated with NCD, while the labor productivity (LP) is negatively correlated with it. Under the condition that other factors remain unchanged, NCD increases by 0.02 per a hundred million CNY. However, if DR increases by one ten thousand, NCD will increase by 8.66 on average. On the contrary, when LP increases by a hundred million CNY per ten thousand people, NCD decreases by 0.19. The model also predicts NCD in different provinces and cities from 2019 to 2020 with the method of quadratic exponential smoothing. As well, practice results show that the model is effective and practical.

研究领域: 安全工程 · 建筑工程 · 应用统计学 · 公共安全 · 劳动经济学
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IONICS · 2016 ·Vol. 22 ·期 11 ·2225-2233 · IF 2.119

Construction of a highly sensitive NADH sensing platform based on PDDA-rGO nanocomposite modified electrode

Lu Juanjuan,Liu Yuelin,Liu Xinhe,Lu Xiaoquan,Liu Xiuhui

In this article, we constructed an electrochemical sensor for highly sensitive determination of β-nicotinamide adenine dinucleotide (NADH) using the poly(diallyldimethylammonium chloride)-functionalized reduced graphene oxide nanocomposite modified electrode (PDDA-rGO/GCE). The nanocomposite was characterized by transmission electron microscopy, Fourier transform-infrared spectrometry, ultraviolet-visible absorption spectrometry, cyclic voltammetry, and electrochemical impedance spectroscopy. The experimental results demonstrated that the fabricated sensor exhibited excellent electrocatalytic activity on the oxidation of NADH with a decreased about 200 mV in overpotential and 5.0-fold increment in the oxidation peak current compared to a bare GCE. Applying cyclic voltammetry, a wide linear range from 1.0 × 10 −7 to 2.9 × 10 −3  M with low limit of detection (LOD) of 3.4 × 10 −8  M and high sensitivity of 463.3 μA mM −1  cm −2 were obtained, which was superior to other NADH electrochemical sensors reported previously. Furthermore, the fabricated NADH sensor possessed excellent selectivity, reproducibility, and stability. The oxidation mechanism of NADH at the PDDA-rGO/GCE was also discussed in detail. A simple NADH sensing platform based on PDDA-rGO composite is constructed, which exhibits an ultra-low detection limit ( 3.4×10-8 M) towards the oxidation of NADH, and the electrochemical reaction mechanism of NADH is discussed in detail.

研究领域: 生物电化学 · 生物传感器 · 纳米生物技术 · 分子诊断 · 转化医学 · 电分析化学
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JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY · 2019 ·Vol. 19 ·期 1 ·57-65 · IF 1.093

Effects of Emulsifier Dosage and Curing Time on Self-Healing Microcapsules Containing Rejuvenator and Optimal Dosage in Asphalt Binders

Liu Wolong,Zhang Jiupeng,Liu Qi,Pei Jianzhong,Zhu Cunzhen,Liu Peng

Micro-damages always occur and accumulate in asphalt pavement materials under the effects of temperature, vehicle loads and other factors during service. Accordingly, self-healing microcapsules could be added into asphalt binder and repair micro-damages to prevent damage extension in time. In this study, the emulsified rejuvenator and melamine-urea-formaldehyde resin (MUF) were selected as the core and cyst wall materials, respectively, and in-situ polymerization method was applied to synthesize the novel microcapsules. The effects of emulsifier dosage and curing time were revealed on the particle size, dispersion, surface morphology and coating properties, and the optimum process parameters were determined for microcapsules. Then, the micro morphology, molecular structure, and thermal stability were further investigated to determine the optimal preparation of the microcapsules. Finally, the linear amplitude sweep (LAS) test was performed to evaluate the self-healing efficiency of the asphalt binder with different dosages of prepared microcapsule, and the optimal dosage of microcapsules was determined as 0.5%.

CAS / MDL: 25155-30-0
研究领域: 材料科学 · 土木工程 · 化学工程
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