PHYSICAL CHEMISTRY CHEMICAL PHYSICS
·
2014
·Vol. 16
·期 23
·11584-11589
·
IF 4.198
Yunyun Huang,Wensheng Lin,Kan Chen,Wenkai Zhang,Xudong Chen,Ming Qiu Zhang
A water-processable blue fluorescent silver nanoparticle@graphene–polymer composite (Ag@G–pNIPAM) consisting of graphene coated with a thermally responsive poly-(N-isopropylacrylamide) (pNIPAM) shell is prepared. The pNIPAM shell swells or collapses as a function of temperature, serving as a means to trap silver nanoparticles in solution and get them sufficiently close to the graphene core to provide fluorescence enhancement based on the local surface plasmon resonance (LSPR) effect. The unique thermoresponsive properties and high enhancement ratio of the material should find application in solution fluorescence enhancers and a variety of biomedical applications, such as cellular uptake, sensing and imaging.
研究领域:
纳米医学
·
生物材料
·
分子影像学
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生物传感
·
药物递送系统
✓ 已验证
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2019
·Vol. 30
·期 7
·6832-6837
·
IF 2.195
Li Chunzhe
A series of Ca 3 La 6 (SiO 4 ) 6 :Eu 2+ and Ca 3 La 6 (SiO 4 ) 6 :Eu 2+ /Mn 2+ phosphors were fabricated by a solid state reaction. The phase composition and luminescent properties of the fabricated phosphors were investigated. The XRD patterns show that Eu 2+ and Mn 2+ were doped into the Ca 3 La 6 (SiO 4 ) 6 host in the present experiment. The Ca 3 La 6 (SiO 4 ) 6 :Eu 2+ phosphors show the emission band in blue region and the Ca 3 La 6 (SiO 4 ) 6 :Mn 2+ phosphors exhibit the emission band in yellow region. The excitation band of Ca 3 La 6 (SiO 4 ) 6 :Mn 2+ overlaps with the emission band of Ca 3 La 6 (SiO 4 ) 6 :Eu 2+ that means a possibility for the energy transfer process from Eu 2+ to Mn 2+ in the Ca 3 La 6 (SiO 4 ) 6 :Eu 2+ /Mn 2+ phosphors. Tunable luminescence was obtained due to this energy transfer process and warm white light was emitted by Ca 3 La 6 (SiO 4 ) 6 :0.05Eu 2+ /0.04Mn 2+ and Ca 3 La 6 (SiO 4 ) 6 :0.05Eu 2+ /0.05Mn 2+ phosphors.
研究领域:
材料科学
·
无机化学
·
固体物理
·
发光材料
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光学材料
✓ 已验证
DOI
高影响因子
Materials Today Chemistry
·
2022
·
IF 7.613
S. Wu,Y. Fu,Q. Liu,P. Xiong,D. Wang,G. Zhang,S. Yuan,Y. Chen
Developing highly efficient cyan-emitting fluorescent materials is essential to bridge the cyan gap in phosphor-converted white light-emitting diodes for full-spectrum white illumination. Here, a Bi-doped cyan phosphor has been reported to solve this gap. The phase purity, photoluminescence emission/excitation spectra, concentration quenching, lifetime decay curves, and temperature-dependent photoluminescence emission spectra were systematically investigated. SrLaGaO 4 :Bi 3+ exhibits a broad excitation band (250–400 nm), which matches with the emission of a commercial near-ultraviolet light-emitting diode chip. The cyan light peaked at 475 nm is observed, which is attributed to the 3 P 1 → 1 S 0 transition of Bi 3+ . The thermal quenching experiment was performed, and the activation energy was calculated as 0.36 eV. Finally, full-spectrum white light-emitting diode devices were fabricated using SrLaGaO 4 :Bi 3+ phosphors, commercial blue BaMgAl 10 O 17 :Eu 2+ phosphor, green (Ba, Sr) 2 SiO 4 :Eu 2+ phosphor, and red CaAlSiN 3 :Eu 2+ phosphor, which displayed an International Commission on an illumination coordinate of (0.3732, 0.3850), a correlated color temperature of 4290 K, and a color rendering index of 93.2 at a drive current of 20 mA. This result indicates that SrLaGaO 4 :Bi 3+ plays an essential role in bridging the cyan gap, providing new inspiration for applying cyan-emitting phosphors in full-spectrum white lighting.
研究领域:
材料科学
·
光学工程
·
固态照明
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发光材料
·
无机化学
✓ 已验证
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2023
·
IF 4.8
Menghua Liu,Shuangying Li,Zhi Li,Yanhui Li,Yue Zhang,Jingwen Niu,Linchun Nie,Chunmao Chen,Qingxiang Zhou
Amoxicillin is one of the most important semi-synthetic penicillin broad-spectrum β-lactam antibiotics and has achieved many applications. There are few reports on its application for synthesizing carbon dots (CDs). Present work explored the possibility of amoxicillin converted into CDs with sodium carbonate used as the co-reactant employing facile hydrothermal method. The obtained CDs exhibited good selectivity and sensitivity to benzidine and could be explored as an effective fluorescence probe for monitoring benzidine. The fluorescence intensity of CDs was quenched based on the principle of static quenching due to the formation of a non-fluorescent complex between CD and benzidine. Within the range of 0.2–2 μM and 2–16 μM, CDs possessed good linear characteristics, high sensitivity, and a low detection limit of 0.08 μM. The results demonstrated that the fluorescence probe possessed the merits of simplicity, rapidity, low cost, short analytical time, high selectivity and sensitivity, and good stability. According to the verification results from the real water samples, the fluorescence probe had high reliability and feasibility, and could be employed for monitoring benzidine in waters.
研究领域:
分析化学
·
环境监测
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纳米材料
·
荧光传感
·
药物化学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2014
·Vol. 4
·期 48
·25183-25188
·
IF 3.708
Meihua Wang,Weifen Niu,Xin Wu,Lixia Li,Jun Yang,Shaomin Shuang,Chuan Dong
3-Mercaptopropionic acid (MPA)-capped ZnS:Cu/ZnS core/shell quantum dots (QDs) have been synthesized via a facile aqueous coprecipitation method and characterized by fluorescence, UV-Vis absorption, infrared spectroscopy and transmission electron microscopy. The fluorescence of ZnS:Cu/ZnS could be increased in the presence of uric acid (UA). The affecting factors for the fluorescence of ZnS:Cu/ZnS were examined including pH, temperature and reacting time. Under the optimized conditions, the fluorescence intensity of the ZnS:Cu/ZnS QDs against the UA concentration showed a linear response in the range of 0.66 μM to 3.3 μM with the correlation coefficient (R2) 0.9973 and the limit of detection 0.044 μM. Most relevant molecules and physiological ions had no effect on the detection of UA. The feasibility of the developed method was further demonstrated by determining the concentration of uric acid in human urine samples and the recoveries were 95% ∼ 103%. Our work provides a sensitive, selective and convenient fluorescence method to determine UA in real samples.
研究领域:
分析化学
·
纳米医学
·
生物传感器
·
临床检验
·
分子诊断
✓ 已验证
DOI
高影响因子
JOURNAL OF RARE EARTHS
·
2021
·Vol. 40
·期 11
·1691-1698
·
IF 3.712
Qingsong Hu,Zaifa Pan,Guijie Liang
White light-emitting diodes (WLEDs) fabricated by single-phase full color emitting phosphor are an emerging solution for health lighting. The crystallographic site occupation of activators in a proper host lattice is crucial for sophisticated design of such phosphor. Here, we report a high quality white light-emitting phosphor Ba 2 Ca(BO 3 ) 2 :Ce 3+ (K + ),Eu 2+ ,Mn 2+ with spectral distribution covering whole visible region. Blue light emission originates from Ce 3+ ions occupying preferentially Ba 2+ site by controlling synthesis conditions. Green and red lights are obtained from Eu 2+ occupying Ba 2+ (and Ca 2+ ) site and Mn 2+ occupying Ca 2+ site, respectively. In this triple-doped phosphor, strong red emission with a low concentration of Mn 2+ is realized by the efficient energy transfer from Ce 3+ and Eu 2+ to Mn 2+ . Furthermore, high quality white light is accomplished by properly tuning the relative doping amount of Ce 3+ (K + )/Eu 2+ /Mn 2+ based on efficient simultaneous energy transfer. The results indicate that Ba 2 Ca(BO 3 ) 2 :Ce 3+ (K + ),Eu 2+ ,Mn 2+ is a promising white light-emitting phosphor in WLEDs application.
研究领域:
材料科学
·
无机化学
·
发光材料
·
固态照明
·
能源材料
✓ 已验证
DOI
高影响因子
JOURNAL OF LUMINESCENCE
·
2021
·
IF 3.599
Chenwei Xu,Chenxia Li,Degang Deng,Hua Yu,Le Wang,Changyu Shen,Xufeng Jing,Shiqing Xu
A series of new double perovskite structure CaLaMgTaO 6 : Bi 3+ , Eu 3+ phosphors were synthesized by high-temperature solid-phase method. The crystal structure, luminescence characteristics and temperature sensing performance have been systematically studied. The substitution rule of Bi 3+ in CLMT and its luminescence characteristics are described. The decay curve of Bi 3+ further proves the existence of an energy transfer from Bi 3+ to Eu 3+ . They have different thermal quenching behaviors, and their fluorescence intensity ratio (FIR) parameter has tremendous temperature sensing performance. Under 329 nm ultraviolet excitation, the emission peaks at 408 nm and 614 nm are used as the reference signal, the largest absolute sensitivity is 0.0127 K −1 at 573 K, and the maximum relative sensitivity is 1.33%K −1 at 483 K. This indicates that CaLaMgTaO 6 : Bi 3+ , Eu 3+ is a material with excellent temperature measurement performance and applicability in non-contact optical thermometers.
研究领域:
材料科学
·
发光材料
·
光学传感
·
无机化学
·
功能材料
✓ 已验证
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2021
·
IF 4.821
Zhihao Wu,Ruchun Chen,Shuang Pan,Hui Liu,Xiaoli Hu
Herein, a convenient method is developed for ratiometric fluorescence detection of ATP (adenosine triphosphate) based on CDs-OPD (carbon dots- o-phenylenediamine). In the absence of ATP, oxOPD, the colored oxidation product of OPD fabricated by a redox reaction occurred between OPD and Cu 2+ , not only quenches the fluorescence of CDs, but also emits a yellow fluorescence which acts as another signal element. However, ATP will compete with OPD to chelate Cu 2+ inhibiting the redox reaction, which hampers the formation of oxOPD resulting in the diminution of IFE (inner filter effect) between CDs and oxOPD, then the fluorescence of CDs restores. ATP-induced dual-signal response of the CDs-OPD/Cu 2+ system makes ratiometric assay possible. The method exhibits high sensitivity toward ATP with a detection limit of 0.43 μmol L −1 . Furthermore, the semi-quantitative measurement of ATP is available by naked eyes through the color of fluorescence and solution. Finally, the developed method is employed for the quantification of ATP in practical samples with satisfactory results.
研究领域:
分析化学
·
生物传感
·
纳米材料
·
分子生物学
·
临床检验
✓ 已验证
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2022
·
IF 6.371
Yonghui Xu,Liang Zhang,Shuwen Yin,Xiudi Wu,Hongpeng You
Despite significant progress has been made in the luminescent materials for white light emitting diodes (WLEDs), it is still desirable to develop novel highly efficient phosphors with appropriate excitation and high visible emission for high color rendering WLEDs. In this study, we report a novel phosphor BaGa 2 Si 2 O 7 :Ce 3+ ,Tb 3+ (BGSO:Ce 3+ ,Tb 3+ ) with highly effective green luminescence. BGSO:Ce 3+ ,Tb 3+ phosphor represents a broad excitation band in the range of 300–400 nm and intense emission at approximately 542 nm with a high photoluminescence quantum efficiency of 76.4%. The structure, luminescence, and energy transfer from the Ce 3+ and Tb 3+ ions were investigated in detail. Moreover, the incorporation of Na + or K + ions into BGSO:Ce 3+ ,Tb 3+ for charge compensation can improve the emission intensity and thermal stability. Moreover, a near ultraviolet (n-UV) pumped prototype WLED device was fabricated and it exhibited bright warm-white light with CIE chromaticity coordinates of (0.3561, 0.3344), high color-rendering index (Ra=90.4), and low CCT (3330 K) upon 20 mA driving current. This work provides a new strategy to develop high-quality solid-state LED phosphors.
研究领域:
材料科学
·
光学工程
·
固体物理
·
发光材料
·
半导体器件
✓ 已验证
DOI
高影响因子
OPTICAL MATERIALS
·
2016
·
IF 2.183
Renping Cao,Xiangfeng Ceng,Jijun Huang,Hui Ao,Guotai Zheng,Xiaoguang Yu,Xinqin Zhang
A double perovskite Sr 2 ZnMoO 6 :Mn 4+ (SZM:Mn 4+ ) phosphor is synthesized by high-temperature solid-state reaction method in air. Emission band peaking at ∼705 nm of SZM:Mn 4+ phosphor in the range of 650–790 nm is attributed to the 2 E → 4 A 2 transition of Mn 4+ ion with activated different lattice vibration modes. Three excitation bands in the range of 210–610 nm are assigned to the O 2− → Mn 4+ charge transfer and the 4 A 2 → ( 4 T 1 , 2 T 2 , and 4 T 2 ) transition of Mn 4+ ion. The optimal Mn 4+ ion concentration is ∼0.8 mol% in SZM:Mn 4+ phosphor. Fluorescence lifetime of SZM:Mn 4+ phosphor decreases from ∼132 μs to 108 μs with increasing Mn 4+ ion concentration in the range of 0.2–1.0 mol%. Time-resolved spectra and fluorescence lifetime data indicate that luminescent center is caused by Mn 4+ ion. The luminous mechanism of SZM:Mn 4+ phosphor is explained by Tanabe-Sugano energy level diagram of Mn 4+ ion. The results are useful to understand the influences of the neighboring coordination environment around Mn 4+ and host crystal structure to the luminescence properties of Mn 4+ ion and develop other novel Mn 4+ -doped materials.
研究领域:
材料科学
·
无机化学
·
固体物理
·
发光材料
·
光电功能材料
✓ 已验证
DOI
高影响因子
Science China-Materials
·
2018
·Vol. 61
·期 7
·1001-1006
·
IF 4.318
Zhang Guo-Qiang,Ou Wei,Xu Yang-Sen
氢能源是未来最理想的清洁能源, 可以利用太阳能和光催化材料分解水获得. 开发廉价、 资源丰富、 环境友好的光催化材料, 成为近年来能源和环境领域的研究热点. 基于此, 我们报道了一种新型有机光催化材料-不含金属的荧光素超分子纳米片, 其在可见光下显示出高效的光催化分解水产氢活性, 产氢速率接近341 μmol g −1 h −1 , 在420±10 nm的波段下表观量子效率达到1.2%. 这是荧光素超分子晶体首次被报道并应用于可见光下分解水产氢, 这一发现丰富了有机和超分子光催化剂的种类.
研究领域:
光催化
·
能源材料
·
超分子化学
·
清洁能源
·
光化学
✓ 已验证
DOI
高影响因子
DALTON TRANSACTIONS
·
2015
·Vol. 44
·期 17
·8278-8283
·
IF 4.197
Zhiqiang Ye,Quankun Gao,Xin An,Bo Song,Jingli Yuan
A unique ruthenium(II) complex, [Ru(bpy)2(DNS-bpy)](PF6)2 [bpy: 2,2′-bipyridine, DNS-bpy: 4-(2,4-dinitrophenylthio)-2,2′-bipyridine], that can act as a probe for the recognition and luminescence sensing of biothiols has been designed and synthesized. Due to the presence of effective photo-induced electron transfer (PET) from the potent electron donor (Ru-bpy centre) to the strong electron acceptor (2,4-dinitrophenyl moiety), the Ru(II) complex itself is weakly luminescent. Reaction of [Ru(bpy)2(DNS-bpy)](PF6)2 with biothiols leads to the replacement of the 2,4-dinitrophenyl moiety by biothiols, which results in the loss of PET within the complex, to allow recovery of the MLCT-based emission of the Ru(II) complex with an 80-fold increase in luminescence intensity. Taking advantage of the high specificity and sensitivity, and the excellent photophysical properties of Ru(II) complexes, [Ru(bpy)2(DNS-bpy)](PF6)2 was successfully applied to the luminescence imaging of biothiols in living Daphnia magna. The results demonstrated the practical applicability of [Ru(bpy)2(DNS-bpy)](PF6)2 as a luminescent probe for the monitoring of biothiols in living bodies.
研究领域:
分析化学
·
分子生物学
·
化学生物学
·
生物成像
·
无机化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）