CATALYSIS COMMUNICATIONS
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2023
·
IF 3.7
Yanni Guo,Hanqiong Jia,Jiayao Qi,Binbin Fan,Bo Qin,Jinghong Ma,Yanze Du,Ruifeng Li
In the hydrocracking of 9, 10-dihydroanthracene, acid sites and their locations in the Y zeolites play crucial roles. Hydrogen transfer is the dominant reaction for the industrial Y zeolites with undeveloped mesopores whether at low or high temperatures. Those with developed mesopores exhibit enhanced ring-opening and cracking ability due to the improved molecular transport and accessibility of acid sites. Their ring-opening and cracking ability is crucially related to the amount of highly strong Brønsted acid sites in the high-silica Y zeolites. The reaction processes of 9, 10-dihydroanthracene hydrocracking over the industrial Y zeolites with different properties were expounded rationally.
研究领域:
化学工程
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催化科学
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产品关联
DOI
高影响因子
Energies
·
2023
·Vol. 16
·期 8
·3333
·
IF 3.2
Derui Jin,Ji Mi,Yongsheng Guo,Yitong Dai,Wenjun Fang
It was found in our previous work that hyperbranched polyester (HPE) can generate radicals and accelerate the chemical reactions of hydrocarbon fuels used as initiators. In this work, the evaporation and autoignition characteristics of JP-10 droplets with or without HPE were investigated using the high-speed backlight imaging technique in detail. The results indicate that the puffing and micro-explosion phenomena of HPE-blended JP-10 droplets can accelerate fuel evaporation and autoignition. When a 0.1% mass concentration of HPE was used, the droplet lifetime was reduced by 16.5% in evaporation at 850 K and 18.0% in autoignition at 900 K. A mechanism of HPE that promotes puffing and micro-explosions was proposed by analyzing droplet images of combustion and SEM images of combustion residues. Overall, this study provides a method for improving the evaporation and autoignition performance of JP-10.
研究领域:
燃烧学
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化学工程
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航空动力学
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产品关联
DOI
高影响因子
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
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2023
·
IF 6
Wenpeng Hong,Yu Zhang,Jiaxing Song,Haipeng Liu,Ling Zhang,Hang Wang,Yan Zhang,Haifeng Jiang
The extraction of phenolic compounds from biomass is an important way to replace chemical synthesis techniques, and catalytic pyrolysis of biomass is an effective method to obtain phenolic compounds with high selectivity. In this work, cobalt-modified montmorillonite K-10(CMT) catalyst was prepared by using cobalt salt and montmorillonite K-10(MMT), and used to catalyze the pyrolysis of corn stalk(CS) to produce phenol-rich bio-oil. The catalytic pyrolysis characteristics reflected by the liquid and gaseous components were compared using gas chromatography-mass spectrometry(GC-MS) and online mass spectrometry(online MS), and the catalytic pyrolysis behavior of corn stalk was analyzed by using the thermogravimetric analyzer(TGA). The addition of catalyst resulted in the increase of apparent activation energy of pyrolysis process but increased selectivity for phenolic compounds. Compared with the blank sample, the relative content of phenolic compounds in bio-oil increased by 11.99 %, and the selectivity of alkyl-phenols was stronger. In addition, the results also showed that the synthesized catalyst promoted the production of H 2 and CH 4 during the catalytic pyrolysis. The optimum ratio of the prepared catalyst was 6%Co/15%MMT. These works provide an alternative approach to upgrading bio-oil product.
研究领域:
能源与燃料化学
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催化材料科学
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产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2020
·
IF 4.939
Zhang Haocui,Xiao Zhourong,Yang Mei,Tian Yajie,Li Guozhu,Zhang Xiangwen,Liu Guozhu
As the only H 2 resource on aircraft from the steam reforming of the jet fuels on board, catalytic steam reforming of JP-10 (one of Jet fuels) over nickel-based catalyst Ni/SBA-15 were first carried out in a fixed bed tube reactor to produce hydrogen on-site or on board. A series of Ni/SBA-15 catalysts with different Ni content (3, 5, 8 and 10.8 wt%) were prepared by a modified incipient wetness impregnation method with addition of sucrose as ligand. And the effect of operation conditions of temperature (630–700 °C), nickel loading, liquid hour space velocity (LHSV = 5, 10, 15 ml/g cat ·h), steam to carbon molar ratio (S/C = 3, 5) on the catalytic activity and selectivity was investigated. It was found that 8Ni/SBA-15 was the optimal catalyst for steam reforming of JP-10 even with a higher LHSV and fuel gas concentration, and approximately 100% conversion of JP-10 with over 80% selectivity to hydrogen under the recommended experimental conditions of 680 °C, S/C of 5, LHSV of 10 ml/g cat ·h. The catalytic activity of 8Ni/SBA-15 dropped slowly to 84% after 6.5 h in the stability test and the carbon deposited was less with just 6% mass loss from TGA measurement (coke deposition rate 0.01g C /g cat h), which ascribed to possible reasons including confine effect of mesochannel of SBA-15, strengthened structure of mesochannels due to embeded Ni particles, and higher temperature to suppress the main carbon producing reaction.
研究领域:
化学工程
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能源科学
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产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2018
·
IF 5.667
Ming Liu,Jinglan Kan,Yuqing Yao,Yunqian Zhang,Bing Bian,Zhu Tao,Qianjiang Zhu,Xin Xiao
Herein, we report the facile preparation of two solid luminescent materials made from cucurbit[10]uril-based porous supramolecular assemblies , from simple precipitation of cucurbit[10]uril (Q[10]) in HCl solution (A) or HNO3 solution (B). Loading Q[10]-based porous supramolecular assemblies A or B with various fluorophore guests ( FG s), including dyes and fused ring compounds, to yield solid luminescent materials ( FG @ A s and FG @ B s) that exhibited fluorescence enhancement or colour changing fluorescence emission . Moreover, these solid luminescent materials could respond to certain volatile organic compounds, demonstrating promise as solid sensors.
研究领域:
材料科学
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化学
✓ 已验证
DOI
高影响因子
MOLECULES
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2023
·Vol. 28
·期 5
·2272
·
IF 4.6
Zhangxi Gao,Mei Xiang,Mingyang He,Weiyou Zhou,Jiayao Chen,Jiamin Lu,Zeying Wu,Yaqiong Su
Catalytic conversion of CO2with the surplus glycerol (GL) produced from biodiesel manufacturing has attracted much academic and industrial attention, which proves the urgent requirement for developing high-performance catalysts to afford significant environmental benefits. Herein, titanosilicate ETS-10 zeolite-based catalysts with active metal species introduced by impregnation were employed for coupling CO2with GL to efficiently synthesize glycerol carbonate (GC). The catalytic GL conversion at 170 °C miraculously reached 35.0% and a 12.7% yield of GC was obtained on Co/ETS-10 with CH3CN as a dehydrating agent. For comparison, Zn/ETS- Cu/ETS-10, Ni/ETS-10, Zr/ETS-10, Ce/ETS-10, and Fe/ETS-10 were also prepared, which showed inferior coordination between GL conversion and GC selectivity. Comprehensive analysis revealed that the presence of moderate basic sites for CO2adsorption-activation played a crucial role in regulating catalytic activity. Moreover, the appropriate interaction between cobalt species and ETS-10 zeolite was also of great significance for improving the glycerol activation capacity. A plausible mechanism was proposed for the synthesis of GC from GL and CO2in the presence of CH3CN solvent over Co/ETS-10 catalyst. Moreover, the recyclability of Co/ETS-10 was also measured and it proved to be recycled at least eight times with less than 3% decline in GL conversion and GC yield after a simple regeneration process through calcination at 450 °C for 5 h in air.Keywords:CO2;glycerol;glycerol carbonate;ETS-10 zeolite;cobalt-based catalyst
研究领域:
化学工程
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环境科学
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产品关联
DOI
PubMed
高影响因子
DENTAL MATERIALS
·
2017
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IF 4.07
Ying Chen,Zhicen Lu,Mengke Qian,Huaiqin Zhang,Chen Chen,Haifeng Xie,Franklin R. Tay
Objectives To examine whether solvents and changing the molecular structure of 10-Methacryloyloxydecyl dihydrogen phosphate (10-MDP) affect its chemical affinity to Yttria-stabilized tetragonal zirconia polycrystals (Y-TZP). Methods The present work investigated the chemical affinity between Y-TZP and 10-MDP dissolved in different solvents (acetone/ethanol/water or mixture) using X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, and thermodynamic calculations. Shear bond strength (SBS) tests were used to evaluate the influence of different solvents on 10-MDP bonding. In addition, several phosphate ester monomer variants were created by changing the 10-MDP molecular structure. Changes included extending/shortening the spacer chain-length, and installing hydroxyl or carboxyl groups as side chains at different positions along the spacer chain. The thermodynamic parameters of the complexes formed between the 10-MDP variants and tetragonal zirconia were evaluated. Results The acquired data indicated that solvent is necessary for the formation of Zr–O–P bonds between 10-MDP and Y-TZP. Solvents affected the chemical affinity of 10-MDP to Y-TZP; acetone facilitated the best bonding, followed by ethanol. Changing the molecular structure of 10-MDP affected its chemical affinity to Y-TZP. The variants 15-MPDP, 12-MDDP, 6-hydroxyl-10-MDP and 6-carboxy-10-MDP all exhibited higher thermodynamic stability than 10-MDP when coordinated with tetragonal zirconia. In contrast, 2-MEP, 5-MPP, 10-hydroxyl-MDP, 10-carboxy-MDP, 5,6-dihydroxyl-10-MDP and 5,6-dicarboxy-10-MDP exhibited lower thermodynamic stability. Significance 10-MDP coordinates with zirconia through dissociating in solvents. Changing the molecular structure of 10-MDP theoretically affects its chemical affinity to Y-TZP.
研究领域:
牙科学
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材料科学
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化学
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产品关联
DOI
PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2019
·Vol. 43
·期 18
·7028-7034
·
IF 3.069
Weitao Xu,Ming Liu,Mary Clare Escaño,Carl Redshaw,Bing Bian,Ying Fan,Zhu Tao,Xin Xiao
The interaction between cucuribit[10]uril (Q[10]) and a series of 4-pyrrolidinopyridinium salts bearing aliphatic substituents at the pyridinium nitrogen, namely 4-(C4H8N)C5H5NRBr, where R = Et (g1), n-butyl (g2), n-pentyl (g3), n-hexyl (g4), n-octyl (g5), n-dodecyl (g6), has been studied in aqueous solution by 1H NMR spectroscopy, electronic absorption spectroscopy and mass spectrometry. The results revealed that the guests g1–g5 are located completely inside the cavity differing only in the orientation of g1, g4 and g5 which are aligned with the portal, whilst g2 and g3 are perpendicular to it. For g6, the tetrahydropyrrole moiety remains outside of the portal. DFT calculations confirm the stability of the guests in the Q[10] and the possibility of their curved structure inside the Q[10].
研究领域:
化学
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分子生物学
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产品关联
DOI
高影响因子
Journal of Water Process Engineering
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2020
·
IF 3.465
Zhiling Ma,Qunpeng Jia,Yanzhe Shi,Xiaofei Duan,Bing Han
TXP-10 is a commercial member of alkylphenol polyethoxylate surfactant family that is widely adopted as emulsifier, detergent and dispersing agent in agriculture and industry. However, it has adverse effects on environmental and public health due to the risk of eutrophication, oestrogenic activities and anti-precipitation properties. Here, we evaluated critical parameters and addressed the mechanism of aeration-assisted photodegradation of TXP-10 by using TiO 2 particulates as model photocatalysts. It was found that O 2 aeration could significantly enhance photocatalytic degradation efficiencies with a high synergetic index of 3.30 at an optimum rutile composition of 90 wt.%. Trapping experiments and superoxide radical quantification suggest two parallel mechanism pathways (O 2 -sensitive and -insensitive) dependent on phase composition of photocatalyst and irradiation intensity. Furthermore, the anti-precipitation property of TXP-10 solution during photocatalysis was evaluated and correlated to transformation of hydrophobic groups to hydrophilic derivatives. This work would gain important enlightenment into the mechanism of synergistic effect of aeration-assisted photocatalysis and its essential role in the environmental remediation.
研究领域:
环境科学
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化学工程
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产品关联
DOI
高影响因子
BIOCHEMICAL ENGINEERING JOURNAL
·
2021
·
IF 3.978
Shuiquan Chen,Meng Zang,Lin Li,Juntao Chen,Qiyou Liu,Xiwen Feng,Shuo Sun,Chuanwei Zang,Chaocheng Zhao
Biodesulfurization is a promising, environmentally friendly method to desulfurize the organosulfur compounds in crude oils through the highly selective cleavage of carbon-sulfur bonds under mild reaction conditions. In this study, the behavior of a hydrophobic bacterium, Gordonia sp. SC-10, was evaluated in the presence of diesel oils. The biodesulfurization pathways, bacterium hydrophobicity , and cell ultrastructure were investigated, and the capability of strain SC-10 to desulfurize diesel oil was also studied. The results showed that strain SC-10 can desulfurize organosulfur compounds through sulfur-specific desulfurization pathways by producing corresponding hydroxylated products in oil-water polyphasic systems. Mycolic acids consisting of 47 and 58 carbon atoms chains were produced on the cell surface, and inclusion bodies were produced in the cells, both of which may improve the bioavailability of the substrates, thereby enhancing its adaptability to oil-water polyphasic systems. To our knowledge, this is the first report of intracellular inclusion body formation during biodesulfurization. Strain SC-10 also exhibited broad substrate specificity towards organosulfur compounds and effectively desulfurized diesel oils. The sulfur content in real-life diesel oil was reduced from 167.7 mg/L to 19.7 mg/L, with 88.3% of sulfur removed after five days of biodesulfurization. This study showed that Gordonia sp. SC-10 can be effectively used for the biodesulfurization of diesel oils.
研究领域:
微生物学
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环境科学
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产品关联
DOI
高影响因子
FUEL
·
2022
·
IF 8.035
Lei Shi,Ping Xu,Rui Wang,Weixin Tang,Tao Ding,Rongpei Jiang,Changhua Zhang
Ignition delay times of JP-10 in air and the vitiation effect of NO 2 on JP-10 autoignition at high temperatures were investigated behind reflected shock waves. The experiments were carried out at pressures of 2 and 10 atm, temperatures between 900 and 1460 K, fuel lean and stoichiometric conditions with and without 1.0 % NO 2 . The experimental results show that the ignition delay times of JP-10/air decrease with the increase of pressure or the decrease of equivalence ratio. The effect of adding 1.0 % NO 2 is pressure dependence. At 10 atm, the addition of NO 2 promotes the ignition of fuel, which shortens the ignition delay time. At 2 atm, the addition of 1.0 % NO 2 inhibits the ignition of JP-10, which prolongs the ignition delay time. A chemical kinetic mechanism of JP-10/NO 2 consisting of 290 species and 1768 reactions was developed by extending from a C0-C5 alkane and a cyclopentene sub-mechanism. The proposed mechanism has been well validated by ignition delay times, laminar flame speeds and species concentration profiles from literature. To further investigate the autoignition of JP-10 and the vitiation effect of NO 2 , kinetics analyses including reaction pathways and sensitivity coefficients were performed by the developed mechanism. The main consumption pathways of JP-10 in air are H-abstraction reactions from JP-10 by HO 2 radicals. With 1.0 % NO 2 vitiation, the addition of NO 2 has a strong effect on JP-10 consumption via the H-abstraction pathway JP-10 + NO 2 = C 10 H 15 + HONO, which further affects the autoignition of JP-10.
研究领域:
燃烧学
·
化学动力学
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产品关联
DOI
高影响因子
KOREAN JOURNAL OF CHEMICAL ENGINEERING
·
2018
·Vol. 35
·期 8
·1642-1649
·
IF 2.199
Wang Yushun,Du Tao,Fang Xin,Meng Da,Li Gang,Liu Liying
CO 2 capture from humid flue gas is always costly due to the irreplaceable pretreatment of dehydration in current processes, which creates an urgent demand for moisture-insensitive adsorbents with considerable CO 2 uptakes as well as remarkable H 2 O tolerances. In the present work, the microporous titanium silicate molecular sieve ETS-10 was synthesized with coal fly ash as the only silica source. The as-synthesized ETS-10 was characterized by X-ray diffraction, scanning electronic microscopy and infrared spectroscopy to verify its crystal morphology, in which neither impurity nor aggregation was observed. The following CO 2 adsorption experiments on the thermal gravimetric analyzer demonstrated its similar CO 2 adsorption capacity yet dramatical adsorption kinetics among some other microporous materials, e.g., potassium chabazite. These specific properties consequently guaranteed its favorable CO 2 adsorption capacity even at high temperatures (1.35 mmol/g at 393 K) and shortened the breakthrough time of single CO 2 flow to less than 20 s. In CO 2 /H 2 O binary breakthrough experiments, the as-obtained ETS-10 still maintained excellent CO 2 uptake of 0.81 mmol/g at 323 K, regardless of the presence of water vapor, making it a promising substitute for direct CO 2 separation from humid flue gases at practical conditions of post-combustion adsorption.
研究领域:
材料科学
·
环境工程
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）