JOURNAL OF ALLOYS AND COMPOUNDS
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2024
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IF 5.8
Xue Wu,Hui Li,Wenlin Xu,Ge Fei,Minghao Zhou,Xin Zhao
Lignin accounted for the second largest amount in biomass, and was regarded as an important carbon source and important renewable source for value-added chemicals. Herein, a series of lignin-derived carbon-based heterogeneous catalyst was synthesized through a simple hydrothermal method , using Co-MOFs as template. Lignin was introduced as a carbon material into MOF catalysts. Through some characterizations, it has been proven that lignin has been successfully introduced into MOF materials and significantly improved the catalyst performance. Then, lignin-MOF derived catalysts (Co/C-EL-X) were successfully introduced into the catalytic hydrodeoxygenation of lignin-derived phenols . The addition of enzymatic hydrolysis lignin (EL) in catalysts, calcination temperature and some other factors were investigated in detail, considering the catalytic performance during the HDO of vanillin and other typical lignin-derived phenols. Co/C-EL-0.5(500) exhibited the best catalytic performance for the conversion of different kinds of lignin-derived phenols to either 2-methoxy-4-methylphenol (MMP) or cyclohexanol . Under the optimal conditions of 240 °C, 0 MPa N 2 , and 2 h, the conversion rate of vanillin reached 100 %, and the yield of 4-methyl-2-methoxyphenol (MMP) was up to 92 %. Furthermore, vanillin could also be converted into 4-methylcyclohexanol (MCYL) by changing the initial nitrogen pressure. Also, Co/C-EL-0.5 (500) exhibited high activity for the conversion of other lignin-derived phenols into cyclohexanol (COL). This work provided a novel strategy for the catalytic valorization of lignin sources.
研究领域:
化学工程
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可再生资源利用
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DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
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2022
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IF 9.136
Aotian Gu,Peng Wang,Kaiwei Chen,Elvis Djam Miensah,Chunhui Gong,Yan Jiao,Ping Mao,Kai Chen,Jinlong Jiang,Ying Liu,Yi Yang
Based on two topologically distinct MOFs, the core–shell bimetallic MIL-101/ZIF-67 x (M/Z x ) were successfully prepared to activate the self-decomposition of peroxymonosulfate (PMS) for 2-chlorophenol (2-cp) degradation. The M/Z x not only inherited the merits of single-metal MOFs such as high surface area and pore volume, but also exhibited superior catalytic performance. In the M/Z x /PMS system, 90% of the 2-cp (100 mg/L) was removed within 10 min with a reaction rate of 0.241 min −1 . This observation was attributed to the synergistic catalysis of cobalt and iron active sites in M/Z x , which greatly promoted the Co 2+ /Co 3+ redox cycle, thereby enhancing the catalytic performance. Further investigation found that both radical and non-radical pathway jointly promote the degradation of 2-cp, and the singlet oxygen ( 1 O 2 ) mediated non-radical pathway serve a predominant role. Meanwhile, SO 4 ·- and · OH also accelerated this process. The possible degradation pathway was proposed by identifying the intermediates of 2-cp degradation. This work provides some new ideas for the design of multi-metal MOFs for environmental remediation.
研究领域:
环境科学
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材料科学
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DOI
高影响因子
APPLIED CATALYSIS B-ENVIRONMENTAL
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2025
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IF 21.1
Ruting Huang,Peidong Ma,Yeyin Zhang,Kaiming Chen,Liping Wang,Ranran Wang,Xianyang Shi,Ying Yu
The enrichment efficiency during the high-value conversion of carbon dioxide still presents certain limitations in practical applications. Iron-cobalt-based metal-organic framework (MOF) nanoparticles, which exhibit lower toxicity to Microcystis aeruginosa , have been successfully introduced into microalgae solutions to address the issue of low CO 2 concentration in interfacial reactions. When 1,4-naphthalenedicarboxylic acid was employed as an organic ligand under synthesis conditions of 130°C, pH 3.5, and a reaction time of 15 h, the resulting MOF exhibited a CH₄ yield of 92.6 μmol g⁻¹ h⁻¹ in the photocatalytic system at room temperature (25°C). The combination of Microcystis aeruginosa with the optimal Fe-Co-MOFs system achieved a selectivity of up to 96.1 % in converting CO 2 into CH 4 . When Microcystis aeruginosa was cultured in a modified medium with a pH of 6.78 and 5 mg of NDC-T130 at 25°C for 12 h, an OD 600 of 0.192 ± 0.01 was observed. The CH₄ yield from the Microcystis aeruginosa -NDC-T130 co-culture composite system was 1.46 times that of the Fe-Co-MOFs. Density-functional theory calculations indicate that carbon dioxide molecules preferentially adsorb on the crystal surfaces of (CoFe 2 )O 4 (113) and (Co 0.457 Fe 0.543 )(Co 1.543 Fe 0.457 )O 4 (311), with the Co site being more likely to serve as the reactive site for CO 2 photoreduction to CH 4 within the Fe-Co-MOFs. Transcriptome analysis demonstrates that MOFs enhance the dark reactions of microalgae and facilitate further CO 2 fixation for photosynthesis and electron transfer, which are crucial for improving the high-value CO 2 conversion efficiency of this system. This strategy provides both experimental and theoretical support for iron-based MOFs as photocatalytic materials, regardless of CO 2 concentration.
研究领域:
环境科学
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生物技术
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材料科学
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DOI
高影响因子
NEW JOURNAL OF CHEMISTRY
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2023
·Vol. 47
·期 30
·14169-14176
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IF 3.3
Guohua Chen,Liying Wang,Yunfei Liu,Xin Miao,Zhenzhu Cao,Yongfeng Zhang
Cobalt-based metal–organic frameworks (Co-MOFs) supported by pyromellitic acid (PMA) were synthesized using a facile one-pot solvothermal method. Morphologies and sizes were tuned by assembly of Co-MOFs in different solvent ratios. Multilayered derivatives were obtained by calcination of Co-MOFs at 350 °C under argon and used as anode material for lithium-ion batteries (LIBs), showing a high reversible specific capacity (1116.7 mA h g−1 after 100 cycles at a current density of 200 mA g−1). The excellent electrochemical performance may be attributed to the specific structure formed during calcination, that is to say, the inner layer of the material retained the porous MOFs, and a small amount of oxide and carbon layers wrapped around the outer layer of the MOFs.
研究领域:
材料科学
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能源存储
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DOI
高影响因子
INORGANIC CHEMISTRY
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2025
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IF 4.7
Xue Luo,Yingying Xue,Leilei Xu,Linshui Lian,Cai-e Wu,Yan Cui,Weixin Zou,Lin Dong,Fei Gao,Mindong Chen
This study presents a systematic investigation into the catalytic oxidation of toluene using metal–organic framework (MOF)-derived porous metal oxide catalysts obtained through controlled pyrolysis. The MOF-derived catalysts (Mn3O4-BTC, CeO2-BTC, Co3O4-BTC) demonstrated remarkable improvements in catalytic activity and stability compared to their commercial counterparts (Mn3O4-c, CeO2-c, Co3O4-c), achieving 90% toluene conversion (T90) at significantly lower temperatures of 240 °C, 241 °C, and 237 °C, respectively. Besides, a comprehensive suite of characterization techniques was employed to elucidate the structure–activity relationships. Specifically, various traditional and in situ characterization techniques, including X-ray diffraction (XRD), N2 physisorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), H2 programmed reduction (H2-TPR), online-tandem thermogravimetry-mass spectrometry (online-tandem TG-MS), and in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS), were employed to elucidate crystallinity, porosity, morphology analysis, probe surface chemistry, redox properties, real-time tracking of thermal decomposition, and reaction mechanisms during the catalytic oxidation of toluene. It was found that the enhanced catalytic performance could be attributed to the synergistic effects of a high surface area, well-dispersed active sites, and abundant oxygen vacancies. These insights provided fundamental insights into the design and optimization of MOF-derived catalysts for efficient volatile organic compounds (VOCs) abatement in environmental catalysis.
研究领域:
环境催化
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材料科学
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化学工程
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纳米技术
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产品关联
DOI
PubMed
高影响因子
APPLIED ORGANOMETALLIC CHEMISTRY
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2025
·Vol. 39
·期 9
·e70363
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IF 0
Zi-hang Yuan,Si-ya Zheng,Yu-mei Dai,En Tang
The escalating global challenges posed by antibiotic resistance and oxidative stress demand the urgent development of dual-functional materials integrating both antimicrobial and antioxidant capacities to address these intertwined biological threats. This raises a pivotal question: Why not engineer a material capable of simultaneously delivering antioxidant and antibacterial functionalities? To bridge this critical gap, we strategically designed two novel Co and Zn metal–organic frameworks (MOFs) through supramolecular interactions to achieve synergistic antimicrobial–antioxidant performance, rigorously validated via multimodal characterization. Different from traditional antibiotics, these MOFs exert antibacterial effects by controlling the release of metal ions and other mechanisms. Co and Zn-MOFs demonstrated robust antimicrobial efficacy against both Gram-negative and Gram-positive bacteria, coupled with potent antioxidant properties. Zn-MOFs exhibited enhanced antibacterial activity by intensifying membrane disruption via strengthened hydrophobic interactions with bacterial surfaces, whereas Co-MOFs showcased superior antioxidant capacity derived from their redox-active nature. This study unravels the critical mechanistic interplay between metal-bacteria interfacial dynamics and the preservation of cell wall structural integrity. These MOFs redefine multifunctional material paradigms for combating drug-resistant pathogens and oxidative damage, offering transformative potential for biomedical innovations and beyond.
研究领域:
材料科学
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纳米技术
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生物医学工程
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药物化学
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微生物学
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生物化学
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产品关联
DOI
FUEL
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2025
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IF 7.5
Yuanyuan Cui,Gang Fu,Jiaxing Wen,Li Yang,Jiaxu Zhang,Jianmin Sun
The direct synthesis of cyclic carbonates from olefins involves a tandem process of olefin epoxidation and CO 2 cycloaddition, but designing a single catalyst with multiple active sites remains a challenge. In this work, a series of dual ligands quaternized Zr-based MOFs (Zr-Bpydc(Py + Br − )/CoTCPP-x, x = 1–5) were successfully synthesized by co-assembling 2,2′-bipyridine-5,5′-dicarboxylic acid (Bpydc) and cobalt(II) 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin (CoTCPP) with Zr 6 clusters, followed by post-synthetic quaternization to incorporate nucleophilic Br − sites. Among them, Zr-Bpydc(Py + Br − )/CoTCPP-4 exhibited the best catalytic performance under mild reaction conditions (80 °C, 1.0 MPa, 12 h), achieving styrene conversion of 94.2 % and styrene carbonate (SC) selectivity of 66.5 %, significantly outperforming most previously reported heterogeneous catalytic systems under cocatalyst-free conditions. The excellent catalytic activity was attributed to the synergistic effect among redox-active Co 2+ sites, Lewis acidic Zr 4+ and Co 2+ sites, Br − sites, and basic pyridyl sites. Importantly, the catalyst also demonstrated broad substrate applicability and good recyclability, with negligible activity loss over five consecutive cycles. Furthermore, density functional theory (DFT) calculations elucidated the energy profile and reaction pathway of the styrene oxidative carboxylation reaction, revealing the cooperative roles of multiple active sites in both epoxidation and CO 2 cycloaddition reactions. Therefore, this work proposes a strategy based on the synergy of multiple active sites for developing efficient and recyclable heterogeneous MOF catalysts for CO 2 conversion.
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DOI
高影响因子
Sustainable Materials and Technologies
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2025
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IF 9.2
Yingli Yang,Hailiang Zhang,Xiaoxia Jia,Guoli Zhang,Gang Li,Kaiying Wang
Metal-organic frameworks (MOFs) have emerged as promising supercapacitor electrode materials due to their structural tunability and high density of electroactive sites. However, intrinsically low electrical conductivity fundamentally constrains their electrochemical performance. To overcome this limitation, we implement a defect engineering strategy, constructing missing-linker defects and Ni dopants within 2D CoNi-BTC/IPA nanosheets via one-pot solvothermal synthesis. This synergistic strategy simultaneously modulates the electronic structure of MOFs while generating supplementary electroactive sites, thereby enhancing charge transfer kinetics and specific capacity—collectively enabling exceptional electrochemical performance. The optimized architecture achieves a high specific capacity of 1220.4 F g −1 at a current density of 0.5 A g −1 , representing a five-fold improvement compared to Co-BTC (226.9 F g −1 at 0.5 A g −1 ). Even with an increase in current density from 0.5 to 10 A g −1 , it retains an excellent capacity retention rate of 96.8 %. The CoNi-BTC/IPA//AC hybrid supercapacitor device showcases a power density of 687.7 W kg −1 alongside an energy density of 50.4 Wh kg −1 . Furthermore, it maintains 80 % capacity retention after undergoing 8000 cycles of charging and discharging.
研究领域:
材料科学
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电化学
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纳米材料
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能源存储
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功能材料
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产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
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2024
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IF 6.3
Zhuangzhuang Xiong,Wenhui Zhang,Siyuan jin,Ruizhi Wu,Fuqiu Ma,Xingwei Wang,Guixiang Wang
In recent years, metal–organic framework materials (MOFs) have garnered significant attention in the field of metal corrosion protection. In this study, novel Co-MOFs were synthesized using cobalt nitrate as the metal source and 4,4′-bipyridine as the organic ligand. A one-step solvothermal method was employed to synthesize a black MOFs/LDH composite coating, integrating corrosion resistance, friction reduction, and hydrophobicity into a single coating. The successful reaction between metal ions and organic ligands was confirmed through FTIR, FE-SEM, EDX, XRD, and XPS characterization tests. Cross-sectional SEM and EDX analyses demonstrated the successful synthesis of the coating. Electrochemical tests indicated that after 14 days of immersion in 3.5 wt% NaCl, the composite coating exhibited the lowest corrosion current of 2.23 × 10 −9 A∙cm −2 , outperforming the aluminum substrate (5.99 × 10 −6 A∙cm −2 ) and anodized aluminum (7.08 × 10 −7 A∙cm −2 ). Hydrophobicity tests showed that without additional modification with low surface energy substances, the composite coating had a contact angle of 154.7°, demonstrating excellent hydrophobicity. Tribological tests revealed that the composite coating exhibited superior tribological performance, with a friction coefficient of 0.3.
研究领域:
材料科学
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电化学
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表面工程
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DOI
高影响因子
MATERIALS RESEARCH BULLETIN
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2017
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IF 2.446
Jixiang Xu,Jianyang Gao,Yong Liu,Qingyun Li,Lei Wang
A facile method for fabrication of In 2 O 3 /Co 3 O 4 @palygorskite composites from a Co/In-based metal-organic framework (MOF) was reported. First, Co/In-MOFs hybridized with palygorskite (PAL) was prepared via a one-pot solvothermal method. Second, In 2 O 3 /Co 3 O 4 @PAL composites were obtained by pyrolysis of In 2 O 3 /Co 3 O 4 @PAL in air. It was found that the In 2 O 3 /Co 3 O 4 @PAL composite exhibited higher photocatalytic activities than In 2 O 3 /Co 3 O 4 to the degradation of MB and TC under visible-light irradiation. About 99% of MB (within 40 min) and 80% of TC (within 120 min) were degraded using In 2 O 3 /Co 3 O 4 @5.0%PAL as catalyst. It was supposed that the efficient adsorption of MB and TC, and electrostatic interactions between electron–hole and PAL were responsible for such improvement. The photocatalytic degradation mechanisms of MB and TC on the In 2 O 3 /Co 3 O 4 @PAL were investigated. This work shows that hybridization MOFs with PAL could enhance the photocatalytic properties of MOFs-derived metal oxides for water treatment.
研究领域:
环境科学
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材料科学
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产品关联
DOI
高影响因子
JOURNAL OF RARE EARTHS
·
2024
·
IF 5.2
Danfeng Deng,Wenjing Song,Weizuo Li,Qiang Li,Xin Wang
A composite metal-organic frameworks (MOFs) structure, designated as Co-hmta@La-salen, was synthesized through coordination interactions between a one-dimensional lanthanum MOFs (La-salen) with high density of uncoordinated imine (–CH=N–) groups and a cobalt-based MOFs (Co-hmta) structure prepared using hydrogen bonding stacking with hexamethylenetetramine (hmta) as the organic ligand. Subsequently, the Co-hmta@La-salen composite was chosen as a template for the pyrolysis process to synthesize a La(OH) 3 supported metallic Co catalyst incorporating carbon-nitrogen (Co/La(OH) 3 -CN-hmta) catalyst. The catalytic results show that Co/La(OH) 3 -CN-hmta (54% and 46% selectivity for aniline and N-phenylbenzylamine, respectively) displays superior cascade performance compared to classic Co/La(OH) 3 -CN-nit catalyst (69% and 31% selectivity for aniline and N-phenylbenzylamine, respectively). Moreover, the kinetic test results indicate that N-alkylation is the rate-limiting step of the overall cascade reaction. The Co/La(OH) 3 -CN-hmta catalyst can be separated from the reaction system using a magnet, and it also exhibits good cyclic stability. All of these suggest that the “MOFs plus MOFs via coordination” templating method can be employed as an efficient strategy for the preparation of supported catalysts.
研究领域:
化学
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催化材料科学
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DOI
高影响因子
危险品化学品经营许可证（带存储）