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Geoenergy Science and Engineering · 2025 · IF 4.6

Foam stability and acidizing effect evaluation of a foam acid fluid system for low-temperature dolomite geothermal reservoir stimulation

Ou Jiang,Xiuhua Zheng,Pei Wu,Luyao Ma,Xu Liu,Pengfei Jin,Pengxiang Zhang,Yang Yang,Haoyu Yu

Acidizing improves reservoir productivity, and foam acid fluid systems achieve both effective acidizing and reservoir protection compared to conventionally utilized acid fluids. Nevertheless, the current application of foam acid fluids is restricted to oil-gas reservoir stimulation, owing to the differences in development conditions between oil-gas and geothermal reservoirs. The transformative application of foam acid fluids from oil-gas to geothermal reservoirs can address the problems induced by conventional acid fluids in geothermal reservoirs, such as limited effective acidizing distance and difficulties in flowing back residual fluids. Here, a foam acid fluid system with typical foaming agents, including sodium dodecyl sulfate (SDS), cocoamidopropyl betaine (CAPB), dodecyl trimethyl ammonium bromide (DTAB) and decaethylene glycol monododecyl ether (DGME), with various foam stabilizer xanthan (XC) contents (0.3%−1.2%) is proposed. Its feasibility in low-temperature (25°C−90°C) geothermal reservoir stimulation is verified through foam stability and acidizing effects, containing dissolution and corrosion inhibition performances. The results shows that the foam acid fluids with DTAB and DGME at 1.2% XC have a required foam stability. A network micro-structure of foam stabilizers, the stronger intermolecular forces in the foaming system, and the chemical reaction stability of foaming agents, mutually contribute to the foam stability. Compared to non-foam acid fluids, foam acid fluids significantly retards acid-rock reaction, with a more uniform dissolution of the cuttings microscopically. The existence of bromide ion (Br – ) in DTAB enhances the corrosion of N80 steel, which is above an accepted corrosion speed. This study highlights the great application potential of foam acid fluid system in an efficient stimulation of low-temperature dolomite geothermal reservoirs.

研究领域: 地热能 · 石油工程 · 储层改造 · 胶体与界面科学 · 化学工程
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Journal of Materials Chemistry C · 2022 ·Vol. 10 ·期 21 ·8356-8363 · IF 8.067

Bidentate aliphatic quaternary ammonium ligand-stabilized CsPbBr3 perovskite nanocrystals with high PLQY (92.3%) and superior stability

Ye Li,Miaoling Cai,Mengling Shen,Yuting Cai,Rong-Jun Xie

The stability of perovskite nanocrystals (NCs) is greatly limited due to highly dynamic binding of ligands, which hinders their applications in optoelectronic devices. In this paper, a new ligand strategy was employed to prepare CsPbBr3 NCs via a facile room temperature (RT) ligand-assisted reprecipitation (LARP) method, where N1.N2-didodecyl-N1.N1.N2.N2-tetramethylethane-1.2-diaminium bromide (DTDB) as the sole capping ligand and an additional Br resource was used. Compared to other ligands with one coordinating group, this class of bidentate ligand can be tightly anchored to the surface of NCs with double N+ sites. The as-synthesized DTDB-CsPbBr3 NCs exhibited a high photoluminescence quantum yield (PLQY) of 92.3% and also showed a superior colloidal stability even under intense purification for up to ten cycles. Compared to the dodecyltrimethyl ammonium bromide (DTAB) ligand capped-CsPbBr3 NCs, the DTDB-CsPbBr3 NCs display obviously enhanced stability to light, heat and water. X-ray photoelectron spectroscopy (XPS) results revealed that the DTDB-CsPbBr3 NCs have a Br− rich surface, which accounts for the high stability and PLQY. Hence, DTDB is a promising ligand to prepare perovskite NCs with higher optical performance.

研究领域: 材料科学 · 纳米技术 · 光电技术
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