Optical properties of Ce: GdYAG phosphor in glass with high quality LAS glass system and its application in laser illumination
Nowdays, the demand for high-power laser lighting applications is on the rise, however, phosphor in glass (PiG) prepared using conventional glass systems often experience damage under intense laser irradiation. To tackle this issue, we introduce a novel LAS glass system for phosphor encapsulation to create PiG, and by utilizing a spray coating technique, we blend PiG with high thermal conductivity sapphire to obtain phosphor in glass film (PiF), effectively improving laser irradiation resilience and optical characteristics. In this study, a novel LAS glass system (SiO 2 –Li 2 CO 3 –MgO–Al 2 O 3 –CaO–P 2 O 5 –K 2 O–ZrO 2 –Na 2 O) was utilized to encapsulate Ce:GdYAG phosphors to prepare a series of PiG and PiF. The glass system exhibits multi-directional interlocking lithium disilicate crystals, significantly enhancing the glass's strength and fracture toughness. There is no apparent interface reaction between the glass system and the phosphors, indicating effective protection of the phosphor particles. The PiF sample demonstrates a minor decrease of 5.2 % in internal quantum efficiency compared to the original phosphor, while boasting a high thermal conductivity of 7.4 W m −1 K −1 . Notably, the optimized PiF shows remarkable enhancements with a saturation threshold of 4.37 W mm −2 , surpassing PiG (1.668 W mm −2 ), and achieving LF max of 424.41 lm and LE max of 147.16 lm W −1 . It features a high color rendering index (CRI) of 68.7 and low color correlated temperature (CCT) of 3646 K, significantly improving laser irradiation resistance and optical quality, making it a promising warm yellow laser illumination converter for diverse lighting applications.
危险品化学品经营许可证（带存储）