MICROPOROUS AND MESOPOROUS MATERIALS
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2022
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IF 5.876
Zhiqiang Zhou,Yuanping Liao,Huiyan Wu,Qi Xiao,Yi Liu,Liyun Yang
Herein, zeolitic imidazolate framework-8 capped gold nanoclusters (AuNCs@ZIF-8) was fabricated and developed as an “on-off-on” fluorescent nanoprobe for selectively and sensitively detecting KMnO 4 and ascorbic acid (AA). The prepared AuNCs@ZIF-8 initially exhibited strong fluorescence at 595 nm KMnO 4 could quench the fluorescence of AuNCs@ZIF-8, rendering the fluorescence signal of AuNCs@ZIF-8 in the “off” state. The probe allows KMnO 4 to be detected with a 10 nM detection limit and the linear analytical range was 0.05–2 μM. When AA was added into the AuNCs@ZIF-8/KMnO 4 system, the fluorescence of the AuNCs@ZIF-8 recovered due to the redox reaction between KMnO 4 and AA, and the fluorescence signal of the system turned “on”. The detection limit of AA was 37 nM in a good linear concentration range of 0.05–5 μM. Furthermore, this AuNCs@ZIF-8 nanoprobe was successfully used for AA detecting in fresh orange juices with the recoveries ranged from 96.6% to 108.2%, which validates the potential applicability of this strategy.
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高影响因子
Advanced Composites and Hybrid Materials
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2022
·Vol. 5
·期 3
·2378-2386
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IF 11.806
Chen Wenjing,Lin Hong,Wu Yunying,Yang Meng,Zhang Xianjing,Zhu Shihua,He Maoting,Xie Jianxin,Shi Zhengjun
Nitrogen-doped carbon dots (N-CDs) were prepared from A uricularia auricula (L.ex Hook.) Underw via a one-step hydrothermal method. The N-CDs were spherical with an average particle size of 2.85 nm. The optimal excitation and emission wavelengths were 324 nm and 400 nm, respectively. There was considerable overlap between the excitation or emission spectrum of N-CDs and the UV absorption band of MnO 4 − . The inner filter effect (IFE) was formed between N-CDs and MnO 4 − , which led to the fluorescence quenching of N-CDs. The fluorescence quenching intensity of the system showed a good linear relationship with the concentration of MnO 4 − from 0.15 to 9.00 μM, and the limit of detection (LOD) of MnO 4 − was 0.12 μM. The proposed method was then used to measure MnO 4 − in polluted water with recoveries of 99.42 to 101.16%. The synthesized N-CDs offering trace MnO 4 − detection in simulation sample are extremely profound for environmental evaluation. Graphical abstract N-CD fluorescent probes were facile prepared from biomass Auricularia auricula Underw for the sensing of MnO 4 − based on IFE.
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高影响因子
CRYSTENGCOMM
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2020
·Vol. 23
·期 2
·482-491
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IF 3.117
Lin-Hui Wu,Shu-Li Yao,Jing Li,Hui Xu,Teng-Fei Zheng,Sui-Jun Liu,Jing-Lin Chen,He-Rui Wen
A novel luminescent CdII-based metal–organic framework {[Cd(BBIP)(TBIP)]·EtOH}n (1) derived from the multidentate 5-tert-butylisophthalic acid (H2TBIP) and the semi-rigid N-donor 3,5-bis(benzimidazol-1-yl)pyridine (BBIP) has been solvothermally synthesized and structurally characterized by using infrared spectroscopy, thermal analysis, single-crystal X-ray diffraction and powder X-ray diffraction. The adjacent CdII ions are linked by two carboxylate groups of one TBIP2− ligand with chelating mode to form a one-dimensional CdII-TBIP2− chain, which is further connected by the BBIP ligand to obtain a two-dimensional network. Interestingly, the fluorescence experiments indicate that 1 could be considered as a good multi-responsive sensing material for detecting Fe3+, MnO4−, Cr2O72−, salicylaldehyde (SA) and ethylenediamine (EDA) via the turn-off effect, with the detection limits of 0.53, 0.98, 3.6, 0.42 and 5.3 ppm, respectively. The luminescence quenching effect induced by Fe3+ could be mainly ascribed to the competitive absorption mechanism. The electron-transfer transition and competitive absorption mechanism could be used to explain the luminescence quenching of MnO4− and Cr2O72−. The turn-off effect of 1 on SA could be ascribed to the photoinduced electron-transfer and competitive absorption mechanisms. Meanwhile, the possible mechanism of fluorescence quenching caused by EDA could be attributed to the structure collapse. More importantly, 1 could be regenerated and reused after five cycles for Fe3+, MnO4−, Cr2O72− and SA detection. In a nutshell, 1 could be employed as a multi-responsive luminescent sensor used for the highly selective and sensitive detection of metal ions, anions and small organic molecules.
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高影响因子
MICROCHEMICAL JOURNAL
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2022
·
IF 5.304
Panpan Wang,Junxia Wang,Tingting Liu,Zhengpeng Sun,Ming Gao,Kai Huang,Xuedong Wang
As one kind of high nutrition fruits, abandoned loquat causes great waste due to short storage period. For resource utilization, we herein fabricated the loquat fruit-based carbon quantum dots (CQDs) by a facile/green hydrothermal method. The as-fabricated CQDs showed spherical shape with an average size of 4.46 nm, and richness in functional hydroxyl and carboxyl moieties on their surface. Under daylight and UV light, the as-fabricated CQDs displayed light yellow and blue color, respectively, with a fluorescence quantum yield of 10.36%. Upon the addition of MnO 4 − , the fluorescence intensity of loquat-based CQDs was prominently quenched in a concentration-dependent manner, suggesting the feasibility for constructing a sensitive “ON-OFF” nanoprobe. By virtue of changes in UV-Vis absorption, fluorescence lifetime, Stern-Volmer constant and zeta potential, the MnO 4 − -triggered quenching mechanisms were attributable to the joint action of inner filter effect and static quenching. Under optimized conditions, the CQDs supplied wide linear range of 0.2–150 μM, low detection limit of 0.06 μM, and high recovery of 96.0–106.0% for MnO 4 − in environmental waters. Especially, it exhibited the superior selectivity and anti-inference capacity for other commonly existed cations and anions in waters. In contrast to China authentic indirect iodometry method and previously reported approaches, the newly developed “ON-OFF” nanoprobe possesses comparable or even better analytical performance. As far as our information goes, it is the first report on the loquat fruit-based CQDs for successful application in the assay of trace-level MnO 4 − in environmental waters, thereby showing great potential in conventional monitoring.
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高影响因子
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