SYNTHETIC METALS
·
2016
·
IF 2.299
Gang Fu,Li Ma,Mengyu Gan,Xiuling Zhang,Meng Jin,Yao Lei,Peishu Yang,Maofa Yan
This research paper describes a facile strategy to synthesize the novel 3D Spongia-shaped polyaniline/MoS 2 nanospheres composite under the addition of polyvinylpyrrolidone (PVP) (named sPANI/A-MoS 2 ), and this composite displays excellent electrochemical properties as an electrode material for supercapacitors. The structure and morphology of the as-prepared 3D sPANI/A-MoS 2 are characterized by scanning electron microscopy (SEM), Fouriertransform infrared (FT-IR), X-ray diffraction (XRD), X-ray photoelectron spectrum (XPS), Raman spectroscopy measurements and Thermogravimetric Analysis (TGA). Cyclic voltammograms (CV) and galvanostatic charging/discharging (GCD) tests are adopted to evaluate the electrochemical performances of the composite. All the results powerfully demonstrate the successful fabrication of 3D sPANI/A-MoS 2 . The maximum specific capacitance of this composite reaches up to 605 F g −1 at a current density of 1 A g −1 , and the energy density of 53.78 Wh kg −1 is obtained at a power density of 0.4 kW kg −1 . Notably, the capacity retention of the as-fabricated sPANI/A-MoS 2 composite electrode can maintain 88.6% (well above 59.8% for sPANI) after constant charge-discharge 1000 cycles, showing an excellent electrochemical stability.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2021
·Vol. 32
·期 14
·18741-18750
·
IF 2.478
Qin Ruifei,Liu Lina
Multifunctional Fe 3 O 4 /Eu(DBM) 3 phen/PVP ((DBM: dibenzoylmethane, phen: 1,10-phenanthroline, PVP: polyvinyl pyrrolidone) microfibers were constructed by simple electrospinning process. The structure and morphology of the microfibers were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images. The diameters of pure PVP microfibers and the microfibers doped only with Fe 3 O 4 nanoparticles (NPs) were uniformly distributed, with an average diameter of about 360 nm. When 3% Eu(DBM) 3 phen complex and Fe 3 O 4 NPs were both added to the precursor for electrospinning, the microfibers became very inhomogeneous in diameter. The photoluminescent properties of pure Eu(DBM) 3 phen complex and composite microfibers were also studied. The characteristic emission peaks of Eu 3+ appeared in the composite microfibers. The intensities of emission and excitation spectra gradually decrease with adding more Fe 3 O 4 NPs. The unit mass of the pure europium complex in some composite microfibers gave stronger luminescence than the pure europium complex. The fluorescence lifetime of 5 D 0 state in the composite microfibers is longer than that of pure europium complex. Additionally, the magnetic properties of Fe 3 O 4 NPs and the composite microfibers were investigated. The saturation magnetization of the composite microfibers was smaller than that of pure Fe 3 O 4 NPs.
研究领域:
材料科学
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纳米技术
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光学
·
磁学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2018
·Vol. 135
·期 40
·46717
·
IF 1.901
Chang Hu,Zhiping Du,Xiumei Tai,Xiaoying Liu
The interactions between the mixed surfactants sodium dodecyl benzenesulfonate (SDBS) and modified oil ethoxylate (SOE-60) with polyvinylpyrrolidone (PVP) were studied at 25 ± 1 °C using a surface tension meter, Ubbelohde viscometer, and fluorescence spectrophotometer. Interaction mechanisms of SDBS/SOE-60-PVP systems were explained by the “necklace and bead” model. The results showed that the interaction could be divided into three parts by two characteristic concentrations: the critical aggregation concentration (cac) and the polymer saturation point (psp). The interaction mechanisms of SDBS/SOE-60-PVP systems are consistent with the “necklace and bead” model. The binding mixing surfactant micelles, formed by free SDBS and SOE-60 molecules, were bound to PVP chains by hydrophobic and ion–dipole interactions. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135 , 46717.
研究领域:
高分子化学
·
物理化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2020
·Vol. 138
·期 11
·50043
·
IF 2.52
Haitao Meng,Tong Xu,Mingyuan Gao,Jie Bai,Chunping Li
Oil–water separation is an urgent issue due to the frequently occurred oil leakages and increasing discharge of oily wastewater. The pollutional and wastewater can not only damage the environment, but endanger human health. Owing to the small particle size of the oil contamination, it is still a challenge for the separation of oil–water emulsion. In this study, we developed a facile strategy to prepare a hydrophilic polyvinylpyrrolidone/polyacrylonitrile (PVP/PAN) nanofibrous membrane for oil–water mixture and emulsion separation. The lowest water contact angle on the membrane surface can achieve 16.7°, thus the membranes can effectively resist the oil contamination on them. Moreover, the membrane can efficiently separate oil–water mixtures and emulsion by gravity. In addition, it can separate oil–water mixtures in harsh conditions (pH = 1 and 14). Membranes prepared in this work would hold a great potential in the practical use of water treatment and environmental industry.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry C
·
2025
·
IF 5.1
Jingyi Wang,Lishuai Zong,Yuhang Wang,Zichun Ding,Runze Liu,Jinyan Wang,Xigao Jian,Chenghao Wang
With the rapid advancements of communication technology, developing multifunctional thermally conductive materials is crucial to addressing future heat management challenges. In this study, highly thermally conductive PPENK/PVP modified BN (PPENK/MBN) multilayer nanocomposite films inspired by wafer biscuits were constructed through a simple and efficient strategy. Verified by X-ray microscopy (XRM), the designed wafer biscuit-like structure provided abundant internal heat conduction pathways. As a result, the PPENK/MBN nanocomposite films with 39.2 wt% MBN content exhibited in-plane and out-of-plane thermal conductivities of 9.66 W m−1 K−1 and 1.13 W m−1 K−1, respectively, as well as excellent dielectric properties with a dielectric constant of 3.51 and a dielectric loss value as low as 0.010@15 GHz. Furthermore, the composites demonstrated a high thermal decomposition temperature of 511.3 °C. This study lays a foundation for the preparation of high thermal conductivity nanocomposites and provides possible applications in thermal management.
研究领域:
材料科学
·
热管理技术
✓ 已验证
产品关联
DOI
高影响因子
OPTICAL MATERIALS
·
2018
·
IF 2.32
Xiaolin Zhang,Jianguo Tang,Haidong Li,Yao Wang,Xinzhi Wang,Yanxin Wang,Linjun Huang,Laurence A. Belfiore
This work demonstrated red light emitting nano-PVP fibers that incorporated with novel three-layer nanostructure of Ag@SiO 2 @Eu(tta) 3 phen nanoparticles (Ag@SiO 2 @Eu(tta) 3 phen-NPs), and the hybrid nano-PVP fibers were fabricated via a remarkably simple electrostatic spinning method. For Ag@SiO 2 @Eu(tta) 3 phen-NPs, the thickness of SiO 2 is optimized to obtain the maximum luminescent intensity , as results, the optimized thickness of SiO 2 is 20 nm. And the corresponding luminescent intensity (612 nm) of the Ag@SiO 2 @Eu(tta) 3 phen-NPs is enhanced up to 10 times compared with the pure Eu(tta) 3 phen complex, which indicates that with 20 nm SiO 2 thickness, the localized surface plasmon resonance (LSPR) effect of Ag@SiO 2 exhibits highest performance for enhancing luminescence. Moreover, the luminescent PVP fibers emit bright red light under the fluorescence microscope, which definitely confirms that the microenvironment provided by PVP polymer is absolutely suitable for the fluorescent composites.
研究领域:
材料科学
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纳米技术
·
光学
·
聚合物科学
✓ 已验证
产品关联
DOI
高影响因子
ACS Biomaterials Science & Engineering
·
2021
·
IF 4.749
Jiarui Wu,Zhanjie Zhang,Chenxu Qiao,Changfeng Yi,Zushun Xu,Tianyou Chen,Xiaofang Dai
In recent years, the combination treatment of chemotherapy and photothermal therapy (PTT) has emerged as an efficient approach to improve anticancer activity. Here, we combine zeolitic imidazolate framework-67 (ZIF-67) and CuSe to build a multifunctional therapeutic platform (ZIF-67@CuSe@PVP) with an efficient chemo-photothermal therapy for cancer treatment. ZIF-67@CuSe@PVP nanoparticles were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), dynamic light scattering (DLS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV–vis, Fourier transform infrared (FT-IR), and nitrogen adsorption–desorption isotherms. These nanoparticles exhibited excellent pH-responsive doxorubicin hydrochloride (DOX) releases due to the decomposition of ZIF-67 and excellent photothermal conversion efficiency (36%) without apparent deterioration during three cycles. In vivo biodistribution evaluation revealed the passive tumor-targeting ability of ZIF-67@CuSe@PVP@DOX via the enhanced permeability and retention (EPR) effect. Both in vitro and in vivo data demonstrated excellent anticancer efficacy of ZIF-67@CuSe@PVP in tumor-bearing mice. This multifunctional therapeutic platform could have certain clinical application potential.
研究领域:
纳米医学
·
肿瘤学
·
材料科学
✓ 已验证
DOI
PubMed
高影响因子
DRUG DEVELOPMENT AND INDUSTRIAL PHARMACY
·
2025
·
IF 2.2
Wenhui Zhou,Mengmeng Han,Haosen Zhang,Tianwei Zhang,Haiyun Tian,Tingting Yang,Tao Liu
Objective This study investigated the effect of molecular interactions between drug and polymers on preparation of nanoamorphous indomethacin (IND) through milling of solid dispersions (SDs).Significance The polymer selection (molecular interaction) emerged as a critical factor in the dynamic milling process for achieving nanoamorphous drug.Methods Polyvinylpyrrolidone (PVP) and hydroxypropyl methylcellulose (HPMC) were selected as models. Amorphous dispersions were used to prepare nanoamorphous drugs by applying wet milling. Molecular simulations were employed to elucidate the molecular mechanisms of drug–polymer miscibility, interaction energy, and molecular migration.Results Both PVP and HPMC related SDs could be nanosized after milling. The rate of size reduction might be related to the solid state of the dispersions. The combination of amorphous PVP SDs with reduced particle size significantly improved the dissolution rate of IND. However, HPMC-based samples exhibited recrystallization during milling. Molecular simulation indicated that PVP formed strong molecular interaction with the drug to maintain the amorphous form, which contributed to avoid recrystallization induced by the external milling forces. The radial distribution function of hydrated IND/HPMC amorphous cells demonstrated the absence of hydrogen bonding interactions between IND and HPMC.Conclusion PVP contributed to maintain the amorphous state during the milling process, which resulted from the higher molecular binding energy compared to HPMC. Controlled milling of amorphous SD with optimized polymer selection could simultaneously achieve nanoamorphous particle and enhanced dissolution rate.
研究领域:
药剂学
·
材料科学
✓ 已验证
DOI
PubMed
高影响因子
MOLECULES
·
2025
·Vol. 30
·期 5
·1133
·
IF 4.6
Yuansong Zhou,Fengyu Gao,Lei Yi,Junyi Wang,Honghong Yi,Xiaolong Tang
In an O 2 -containing environment, achieving efficient selective catalytic reduction of nitrogen oxides (NOx) by carbon monoxide (CO) using non-noble metal catalysts remains a formidable challenge. To balance the catalytic oxidation of CO and the catalytic reduction of NOx, we need to develop a catalyst with strong reductibility and weak oxidizability for the CO selective catalytic reduction of NOx (CO-SCR) reaction in the presence of O 2 . In this study, we synthesized the CoCeOx-PVP catalyst via a coprecipitation method and employed various characterization techniques, including BET, SEM, XRD, Raman, XPS, H 2 -TPR, and O 2 -TPD. The analysis results indicate that the addition of polyvinylpyrrolidone (PVP) alters the surface structure of the catalyst, increases the particle size, and enhances the concentration of surface oxygen vacancies. These structural effects facilitate electron circulation and accelerate the migration of oxygen species, thereby improving the catalytic reduction performance of the catalyst and increasing the conversion rate of NOx. At 250 °C and with 5 vol% O 2 , the conversion rates of NOx and CO can attain 98% and 96%, respectively, accompanied by a remarkable N 2 selectivity of 99%. Following a sustained reaction period of 6 h, the conversion efficiencies of both NOx and CO remain above 95%. However, during extended testing periods, as the oxygen vacancies are progressively occupied by O 2 , the oxygen vacancies generated through the reduction of NO with CO fall short of sustaining the CO-SCR reaction over the long haul. Subsequently, the oxidation reactions of NO and CO come to dominate, resulting in a decline in the NOx conversion rate. Notably, the CO conversion rate still maintains 100% at this point. Based on the results of in situ diffuse reflectance infrared Fourier transform spectroscopy (in situ DRIFTS) experiments, we proposed a reaction mechanism for the CO-SCR process over the CoCeOx-PVP catalyst under O 2 -containing conditions. This study provides an effective strategy for the application of non-noble metal catalysts in the field of CO-SCR. Although maintaining long-term activity of the catalyst remains a challenge in the presence of O 2 , the catalyst in this study exhibits a slower deactivation rate compared to traditional non-noble metal catalysts.
研究领域:
催化化学
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环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2021
·Vol. 32
·期 15
·20295-20305
·
IF 2.478
Zhao Yaxin,Liu Dan,Yan Zhuqing,Zhang Zhidong,Zheng Yongqiu,Zhang Yanjun,Xue Chenyang
In recent years, the demand for wearable devices has promoted the research of flexible thermoelectric generators. Herein, this work reports a facile method to prepare the flexible Ag 2 Se/polyvinyl pyrrolidone (PVP) composite films. The Ag 2 Se nanorods are synthesized by the template method and then mixed with PVP solution to form the composite film optimized by the content of Ag 2 Se. The maximum power factor of the film is 16.18 µW m −1 K −2 at 320 K, and the thermoelectric generator (TEG) has an output voltage and power of 5.49 mV and 55.57 nW at a temperature difference of 40 K, respectively. Moreover, the Ag 2 Se/PVP film has good flexibility and can withstand multiple bending, the electrical conductivity reaching 89.8% and 76 % at 500 and 1000, respectively. PVP has an excellent protective capabilities effect so that the TE performance can remain stable in 40 days, and then the electrical conductivity only drops to 89 % of the initial value at 50 days. This work provides an effective method for preparing wearable thermoelectric devices, which can be extended to other composite materials.
研究领域:
材料科学
·
能源技术
✓ 已验证
产品关联
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2020
·
IF 3.99
Yicong Xiang,Xiaoqing Peng,Xiangyue Kong,Zhiri Tang,Hong Quan
Nanostructures have been studied and applied in many fields for their outstanding properties. On account of the similar dimensions to the biomolecules, smart designed nanostructures are the rising materials in biotechnology and medical engineering. Our work reported the reduction method to synthesize AuPd@PVP nanoparticles (NPs) in the presence of polyvinyl pyrrolidone (PVP), which act as both surfactant and stabilizing agent. The existence of PVP shell guarantees the good biocompatibility both in vivo and in vitro , and makes it easy to modify on the surface. The combination takes both advantages of Au and Pd. The absorption region is broadened while enhancing the photothermal conversion ability, that makes AuPd@PVP NPs excellent photothermal therapy (PTT) agent under NIR laser irradiation of lower power. Meanwhile, the NPs also contribute to radiotherapy (RT) as the sensitizer. Combination and cooperation of PTT and RT make it more efficient for cancer therapy. Thus, the excellent features of photothermal conversion, radiosensitivity, and biocompatibility, signify the immense potential of AuPd@PVP NPs for application in tumor treatment.
研究领域:
纳米医学
·
生物技术
·
肿瘤学
✓ 已验证
产品关联
DOI
高影响因子
International Journal of Nanomedicine
·
2022
·
IF 7.033
Qingxin Fan,Hao Wu,Qingquan Kong
Background The frequent occurrence of failed back surgery syndrome (FBSS) seriously affects the quality of life of postoperative lumbar patients. Epidural adhesion is the major factor in FBSS.Purpose A safe and effective antiadhesion material is urgently needed.Methods A superhydrophilic PLGA-g-PVP/PC nanofiber membrane (NFm) was prepared by electrospinning. FTIR was performed to identify its successful synthesis. Scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and water contact angle measurement were performed. CCK-8 assays were performed in primary rabbit fibroblasts (PRFs) and RAW264.7 cells to explore the cytotoxicity of PLGA-g-PVP/PC NFm. Calcein-AM/PI staining was used to measure the adhesion status in PRFs. ELISA was performed to measure the concentrations of TNF-α and IL-10 in RAW264.7 cells. In addition, the anti-epidural adhesion efficacy of the PLGA-g-PVP/PC NFm was determined in a rabbit model of lumbar laminectomy.Results The PLGA-g-PVP/PC NFm exhibited ultrastrong hydrophilicity and an appropriate degradation rate. Based on the results of the CCK-8 assays, PLGA-g-PVP/PC NFm had no cytotoxicity to PRFs and RAW264.7 cells. Calcein-AM/PI staining showed that PLGA-g-PVP/PC NFm could inhibit PRF adhesion. ELISAs showed that PLGA-g-PVP/PC NFm could attenuate lipopolysaccharide-induced macrophage activation. In vivo experiments further confirmed the favorable anti-epidural adhesion effect of PLGA-g-PVP/PC NFm and the lack of a strong inflammatory response.Conclusion In this study, PLGA-g-PVP/PC NFm was developed successfully to provide a safe and effective physical barrier for preventing epidural adhesion. PLGA-g-PVP/PC NFm provides a promising strategy for preventing postoperative adhesion and has potential for clinical translation.
研究领域:
生物医学工程
·
材料科学
·
神经外科
✓ 已验证
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）