INORGANIC CHEMISTRY
·
2022
·
IF 5.436
Feng Guo,Duo-Fu Li,Fang Gao,Kai Xu,Jun Zhang,Xiu-Guang Yi,Dong-Ping Li,Yong-Xiu Li
Luminescent lanthanide cages have many potential applications in guest recognition, sensing, magnetic resonance imaging (MRI), and bioimaging. However, these polynuclear lanthanide assemblies’ poor stability, dispersity, and luminescence properties have significantly constrained their practical applications. Furthermore, it is still a huge challenge to simultaneously synthesize and design lanthanide organic polyhedra with high stability and quantum yield. Herein, we demonstrate a simple and robust strategy to improve the rigidity, chemical stability, and luminescence of an Eu(III) tetrahedral cage by introducing the conjugated planar auxiliary phen ligand. The self-assembled tetrahedral cage, (Eu4L4)(phen)4 [L = (4,4′,4″-tris(4,4,4-trifluoro-1,3-dioxobutyl)-triphenylamine), phen = 1,10-phenanthroline], exhibited characteristic luminescence of Eu3+ ions with high quantum yield (41%) and long lifetime (131 μs) in toluene (1.0 × 10–6 M). Moreover, the Eu(III) cage was stable in water and even in an aqueous solution with a pH range of 1–14. 3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay and cellular imaging revealed that the Pluronic F127-coated hybrid material, (Eu4L4)(phen)4@F127, exhibited low cytotoxicity, good biocompatibility, and cellular imaging ability, which may inspire more insights into the development of lanthanide organic polyhedra (LOPs) for potential biomedical applications.
研究领域:
化学
·
生物医学工程
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Frontiers in Chemistry
·
2022
·
IF 5.545
Chen Haiyun,Huang Jie,Zhang Rongjing,Yan Fei
In this study, we demonstrated the highly sensitive detection of alpha-fetoprotein (AFP) by electrochemiluminescence (ECL) and electrochemistry (EC) based on the gated transport of the bifunctional probe (tris(1,10-phenanthroline) ruthenium (II) chloride, Ru (phen)3Cl2) into the nanochannels of vertically ordered mesoporous silica films (VMSFs). Due to the negatively charged surface and ultrasmall pore size, VMSF displays a signal amplification effect on Ru (phen)3Cl2 and is suitable for the construction of sensors with excellent sensitivity. With the linkage of (3-glycidyloxypropyl) trimethoxysilane, the anti-AFP antibody could covalently bind to the external surface of VMSF, generating a highly specific recognized sensing interface toward AFP. When AFP is presented, the formed immunocomplex hinders the diffusion of Ru (phen)3Cl2 to the underlying electrode surface, resulting in a decreased ECL or EC response. The dual-mode detection of AFP is achieved with a relatively low limit of detection (0.56 fg/ml for ECL and 4.5 pg/ml for EC) and a wide linear range (10 fg/ml∼1 μg/ml for ECL and 10 pg/ml∼1 μg/ml for EC). Moreover, owing to the inherent anti-fouling property of VMSF, satisfactory results in the analysis of human serum were obtained, showing the great potential of the designed strategy in clinical diagnosis.
研究领域:
生物医学工程
·
分析化学
·
临床诊断
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2022
·
IF 9.221
Gang-Gang Yang,Xiao-Jun Hu,Wei Liu,Xia Xu
Endoplasmic reticulum (ER) is the origin of lipid droplets (LD). Excessive lipid exposure results in ER stress which associates with many diseases. However, the change of the lipid droplet viscosity under ER stress is still unrevealed. Hence, it is important to develop a viable tool to investigate the lipid droplet viscosity under ER stress. In this study, a novel viscosity-sensitive fluorescent probe Ru(phen-CA) 3 Cl 2 with long-lived phosphorescence, good spectral stability and large stokes shifts was developed. The probe is prominently located at lipid droplet organelles rather than at lysosome and mitochondria, showing highly sensitive to viscosity. The fluorescence intensity is obviously increased with time under the treatment of dexamethasone and rapamycin. In-vitro and in vivo experiments further confirm that this probe can be used for real-time monitoring the changes of lipid droplet viscosity in response to ER stress. This novel probe provides an effective approach to elucidate the viscosity change in lipid droplets under ER stress.
研究领域:
细胞生物学
·
生物物理学
·
药学
✓ 已验证
DOI
高影响因子
OPTICAL MATERIALS
·
2020
·
IF 2.779
Aiqin Zhang,Zhi Wang,Weize Hong,Yining Zhang,Jiandong Guo,Yongchao Wang,Yanqin Miao,Husheng Jia,Hua Wang,Bingshe Xu
A novel bonded phosphor poly(Eu(TTA) 2 (phen)MAA-co-VA) (Eu-PVA, for short) was prepared employing the technology of coordination-polymerization-alcoholysis. The bonded Eu-PVA fluorescent nanofibers were prepared by electrospinning, having the initial decomposition temperature of 290 °C higher 51 °C than that of the doped nanofibers. A relationship is established between the fiber morphology and the fluorescence intensity of the bonded fiber Eu-PVA, predicting fluorescence quenching according to the morphological evolution. Compared with the corresponding fluorescent phosphors, both doped and bonded fluorescent fibers exhibit obvious fluorescence enhancement effects in that nanofibrosis increase the specific surface of the fibers and decrease the diffuse reflection and the light loss owing to the smoother surface of the fibers than that of the phosphors. Furthermore, security paper with both masking and security has been fabricated applying the bonded fluorescent nanofibers into pulp, being extended to the development of banknotes, bills, and securities.
研究领域:
材料科学
·
化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF RARE EARTHS
·
2025
·
IF 7.2
Xianglong Li,Yige Wang,Huanrong Li
High-performance elastomers have attracted considerable scientific attention owing to their ubiquitous applications across industrial sectors and daily life scenarios. Despite their technological prevalence, the development of multifunctional elastomeric systems that simultaneously demonstrate exceptional mechanical robustness, remarkable self-healing capability, and intrinsic photoluminescent characteristics remains a critical challenge in advanced materials engineering. In this work, a photoluminescent self-healing polyurethane elastomer with synergistically enhanced network architecture was fabricated through strategic integration of hydrogen-bonded functional motifs and lanthanide (Ln 3+ ) coordination complexes featuring dynamic metal-ligand coordination bonds. Consequently, the elastomer achieves exceptional mechanical performance, a high strength of 64.04 MPa, an elongation at break of 2159.18% and an ultrahigh toughness of 512.32 MJ/m 3 , which is 3.2 times the toughness of typical spider silk (≈160 MJ/m 3 ), even surpasses the toughest spider silk found to date (≈ 354 MJ/m 3 ). These exceptional mechanical characteristics are principally attributed to the synergistic interplay between rationally architected Eu 3+ -ligand coordination clusters and hierarchically structured hydrogen-bonding domains comprising multifunctional acylsemicarbazide/urethane motifs. The hierarchical hydrogen-bond arrays and Ln 3+ -ligand coordination bonds function as dynamic and firm crosslinks, operating through reversible breakage-reformation cycles to dissipate mechanical energy. This network design simultaneously confers high strength, autonomous self-healing, and recyclability.
✓ 已验证
产品关联
DOI
高影响因子
BIOSENSORS & BIOELECTRONICS
·
2019
·
IF 9.518
Huifang Zhang,Fang Luo,Peilong Wang,Longhua Guo,Bin Qiu,Zhenyu Lin
A simple and sensitive electrochemiluminescence (ECL) aptasensor has been developed for bisphenol A (BPA) detection. The capture DNA (CDNA) was modified on the heated indium-tin-oxide (ITO) working electrode surface firstly and then hybridized with BPA aptamer to form double strand DNA (dsDNA). The presence of target can cause the releasing of aptamer from the electrode surface since the aptamer prefers to switch its configuration to combine with BPA. Subsequently, the free CDNA will induce hybridization chain reaction (HCR) to produce long dsDNA on the electrode surface. Ru(phen) 3 2+ can integrate into the grooves of dsDNA to act as an ECL reagent, thus enhanced ECL signal can be detected. The temperature control during the processes of target recognition and HCR were realized through the heated electrode instead of the bulk solution heating. Furthermore, the performance of the ECL aptasensor can be further enhanced at elevated electrode temperature. Under the optimized conditions, the ECL intensity of the system has a linear relationship with the logarithm of BPA concentration in the range of 2.0 pM-50 nM. The limit of detection (LOD) at 55 °C (electrode surface temperature) was calculated to be 1.5 pM, which was approximately 6.5-fold lower than that at 25 °C. The proposed biosensor has been applied to detect the BPA in drink samples with satisfactory results.
研究领域:
分析化学
·
环境科学
·
生物化学
·
传感器与执行器
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF HAZARDOUS MATERIALS
·
2022
·
IF 14.224
Zhengwen Wei,Xiang-fei Lü,Wei Wang,Giuseppe Mele,Zhen-Yi Jiang
Phenanthrene (PTH) and 9-phenanthrol (9-PTH) exhibited severe health threats and ecological hazards, for this reason, exploring a high-efficient removing strategy for PTH and 9-PTH could be considered of great urgency. Herein the 4,4'-biphenyldicarboxaldehyde m-phenylenediamine Schiff base magnetic polymer (magnetic BIPH-PHEN) was successfully fabricated via Schiff base polycondensation reaction and the subsequently one-pot embedded method. The mutual aromatic nucleus of BIPH-PHEN polymer and PTH/9-PTH could form π–π interaction, thus improving the capture ability, the embedded Fe 3 O 4 nanoparticles provided the possibility for rapid separation. The physical and chemical properties of the magnetic BIPH-PHEN were systematically characterized. The removal rate of magnetic BIPH-PHEN towards PTH and 9-PTH was 85.65 % and 98.52 %, respectively (PTH or 9-PTH: 8 mg/L; Adsorbent: 0.2 g/L). The DFT calculations including energy calculations and electrostatic potential distribution analyzed the different bonding modes and proposed the most possible bonding modes in the adsorbent/adsorbate system. Moreover, the LUMO and HOMO orbits combined with energy gaps analysis proved the existence and specific types of the π–π interaction. The monolayer adsorption occurred on the homogeneous magnetic BIPH-PHEN surface, simultaneously the chemisorption was dominant. This work not only proposed new sights on assembling magnetic Schiff base polymer for removing polycyclic aromatic hydrocarbons, but also provided a deeper understanding of intramolecular interactions.
研究领域:
环境科学
·
材料科学
·
理论化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2018
·Vol. 42
·期 18
·15061-15067
·
IF 3.201
Jing Ma,Bing Yan
We prepared multi-component luminescent hybrid films based on a silicon chip by a covalent functionalization strategy of both metal–organic frameworks (ZIF-90) and lanthanide complexes. Herein the Si chip is firstly covalently modified by aminopropyltriethoxysilane (APTES) via a hydrolysis and condensation reaction, and then ZIF-90 is covalently grafted onto the surface of Si chip through imine condensation with APTES to form the hybrid films (Si-APTES-ZIF-90). Ternary lanthanide complexes with 3-methacryloxypropyltrimethoxysilane (MPTMS) and Phen (1,10-phenanthroline) are introduced to the above film systems through MPTMS as a covalent linker. The final multi-component hybrid films (Phen-Ln-MPTMS-Si-APTES-ZIF-90) display the typical Ln3+ (Ln = Eu, Tb, Sm and Dy) luminescence through the energy transfer from the MPTMS-Si-APTES-ZIF-90 host. Moreover, fine tuning of the luminescence color for these films is discussed by adjusting the excitation wavelength. Phen-Ln-MPTMS-Si-APTES-ZIF-90 (Ln = Eu, Sm, Dy) can exhibit white color emission closely by selective excitation. In addition, the consolidation stability under airflow of the film and the luminescence stability of the film under certain humidity environments are discussed.
研究领域:
材料科学
·
化学
·
光学
✓ 已验证
DOI
高影响因子
INORGANICA CHIMICA ACTA
·
2013
·
IF 1.687
Yan-Jing Gu,Bing Yan
The synthesis of organics 9-hydroxyphenalenone (HPO), 2-methyl-9-hydroxyphenalenone (MHPO), 6-hydroxybenz[de]anthracen-7-one (HBAO), 5-amino-1,10-phenanthroline (phen-NH 2 ) and its functionalized mesoporous MCM-41 by covalent band are reported, as well as those of Europium (III) hybrid mesoporous materials, EuL 3 phen-MCM-41 (L = HPO, MHPO, HBAO). The photoluminescence and microstructural properties are characterized, and the XRD and BET results revealed that all of these hybrid materials have uniformity in the mesostructure. It is worth noting that the excitation spectra of these hybrid materials have a broad absorption, which occupies from UV to visible region (250–475 nm). Upon ligand-mediated excitation with the visible light, the low efficient energy transfer exhibit between the organic ligands and europium(III) ion under visible excitation, but the maximum wavelength (456 nm/457 nm/451 nm) located at blue light region, which is in consistent with the blue LED light, then might be a feasible alternative in producing time-resolved luminescence under LED-excitation.
研究领域:
材料科学
·
化学
·
光电技术
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）