JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
·
2021
·Vol. 329
·期 2
·1011-1017
·
IF 1.371
Ma Yu,Dou Weixin,Yang Weiting,Yang Weikang,Pan Qinhe
Recently, highly porous metal–organic frameworks (MOFs), with excellent porosity and abundant functional groups, have represented a new addition to the area of capturing uranium ion pollutants. To achieve high adsorption capacity and removal efficiency of uranium, it is significant to modify the morphology of MOF-based adsorbents. In this contribution, two hollow structured ZIF-8 adsorbents were used for the adsorptive separation of uranium from aqueous solution. Both of them showed faster adsorption rate and larger adsorption capacity than pristine ZIF-8, providing the prospect of hollow MOF materials to the application of uranium extraction.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF SOLID STATE CHEMISTRY
·
2023
·
IF 3.3
Wei Yang,Yudi Kong,Hong Yin,Mingli Cao
Water pollution caused by severe heavy metal contamination poses a significant threat to freshwater resources and aquatic ecosystems, necessitating effective removal strategies. This study focuses on the synthesis of highly crystalline ZIF-8 particles using an energy-efficient, cost-effective in-situ self-assembly method. The resulting particles exhibit exceptional specific surface area (1663.413 m 2 /g) and particle sizes ranging from approximately 60 to 80 nm. We conducted batch adsorption experiments using Cu(II) and Pb(II) solutions as representative models of water pollution to evaluate ZIF-8's adsorption capacity for these heavy metal ions . Remarkably, ZIF-8 demonstrated a significantly higher maximum adsorption capacity for Cu(II) (378.5 mg/g) compared to Pb(II) (92.74 mg/g) under identical experimental conditions. By employing adsorption kinetics and isotherm models, as well as density functional theory calculations, we elucidated that Cu(II) removal from water by ZIF-8 relies on ion exchange and coordination interactions, whereas Pb(II) elimination primarily occurs through surface adsorption due to ZIF-8's elevated micropore structure and specific surface area. Moreover, we proposed a sustainable solution by solidifying the waste ZIF-8 adsorbent into cement-based materials, offering an innovative and environmentally friendly alternative to landfill disposal. This methodology not only demonstrates noteworthy economic effectiveness but also ensures harm-free treatment and repurposing of waste adsorbents, providing valuable insights into secure and sustainable heavy metal removal strategies.
研究领域:
环境科学
·
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
Energies
·
2023
·Vol. 16
·期 21
·7232
·
IF 3.2
Congxiu Guo,Guilin Li,Yujia Wu,Xuhui Wang,Yu Niu,Jiao Wu
Porous carbon materials derived from ZIF-8 have attracted extensive research attention on account of their large surface area, tunable mesoporosity and abundant nitrogen content. However, directly carbonized ZIF-8 usually suffers from a low electronic conductivity, poor wettability and relatively low mesoporosity, which severely restricts their capacitive performance. Herein, P-doped modified carbon materials derived from ZIF-8 (ZPCs) were synthesized by using nontoxic phytic acid as a phosphorus source, followed by carbonization at high temperature. Benefiting from its relatively high specific surface area of 911.7 m2g−1and higher ratio of mesopores, as well as N, O and P doping, ZPC-1000 delivers the largest specific capacity, up to 219.4 F g−1at 1 A g−1, among the prepared samples and an outstanding cycle span, retaining 100% capacity after 2000 cycles at 5 A g−1. In this work, we highlight the strategy of constructing a synergistic effect between high mesoporosity and heteroatom doping, which can greatly boost the capacitive performance of carbon materials.Keywords:P doping;ZIF-8;porous carbon;capacitive performance
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
ACS Catalysis
·
2024
·
IF 11.3
Decun Luo,Chun-Ran Chang,Zhun Hu
In this study, tetrabutylammonium bromide (TBAB) with a cationic radius of 4.94 Å was encapsulated in ZIF-8 with a pore size of 3.4 Å by a one-step method. The TBAB@ZIF-8 catalyst showed superior catalytic activity on the reaction of CO2 with propylene oxide (PO) than TBAB and the zeolitic imidazolate framework, respectively, showing a synergistic effect. The synergist effect was related with the compensation effect between the adsorption of CO2 and the loop-opening of PO, where ZIF-8 provided the active sites for CO2 adsorption and Br– in TBAB promoted the opening of the loop of PO. The catalytic performance of TBAB@ZIF-8 illustrated a volcano curve with the increase of the TBAB content. The addition of TBAB could have resulted in a positive effect on the loop-opening of PO. However, excessive TBAB hindered mass transfer and reduced the CO2 adsorption of ZIF-8, which was certified by the CO2 adsorption test. Diffuse reflectance infrared Fourier transform spectroscopy results showed that TBAB@ZIF-8 catalysts proceed in a new reaction pathway and that the rate-determining step of the reaction was the opening of the loop of PO. These results provided a guideline for the development of immobilization of homogeneous catalysts for CO2 fixation.
研究领域:
材料科学
·
化学工程
·
环境科学
✓ 已验证
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2022
·
IF 10.383
Qianxi Wang,Yuting Lei,Yunyi Cui,Jingruolan Lin,Wei Huang,Yi He
Thermogravimetric analysis (TGA) is a key material characterization method for studying the thermal stability and thermochemical process. However, the common TGA for bulk samples lacks sufficient spatial information, which blurs the intrinsic thermal decomposition characteristic and limits the understanding of the structure–performance relationship. Here, we report a dark-field microscope (DFM) method for studying thermal desorption process of I2 from I2-loaded zeolitic imidazolate framework-8 (I2@ZIF-8). Because of the high spatial resolution, DFM enables the imaging and tracking of the local mass loss of I2 in single I2@ZIF-8 particles at different reaction temperatures. We obtain from the DFM images the single-particle thermogravimetric and differential thermogravimetric curves to evaluate the inherent thermal stability of single I2@ZIF-8 particles. We also find the heterogeneous thermal decomposition property among different I2@ZIF-8 particles. Furthermore, we demonstrate the capacity of DFM to quantitatively determine thermal kinetics parameters such as the diffusion coefficient and activation energy of I2 in individual and multiple ZIF-8 particles. These useful results are essential for developing high-efficient porous adsorbents for the capture of I2.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2022
·
IF 6.371
Yu Zhu,Qinyun Xv,Dan Wang,Bingxin Sun,Yujia Wang,Zhiguo Han,Yongbo Gou,Jiayu Liu,Bingdong Li
The overuse of norfloxacin (NOR) has attracted wide attention because of the persistence and bio-accumulate in ecosystems and the negative impacts on human health. To solve the environmental issue, BiOI/TiO 2 p-n heterojunctions have been developed and decorated with a porous ZIF-8 to obtain novel hollow BiOI/TiO 2 /ZIF-8 heterojunctions, which were further characterized by XRD, SEM, HRTEM , XPS , BET, UV–vis DRS, photoluminescence , ESR , photocurrent and EIS analyses. The BiOI/TiO 2 /ZIF-8 heterojunctions exhibited evidently improved photocatalytic performance compared with pristine BiOI , TiO 2 and BiOI/TiO 2 composites under visible light irradiation. ZIF-8 plays a key role in both the enhancement of adsorption and the photocatalytic activity in NOR removal. ·O 2 - and ·OH radicals were the two dominating active species in the photocatalytic process according to the trapping experiments. In 2-BTZ system, large specific surface area, highly effective charge carrier migration with inhibiting recombination, more negative CB and positive VB to generate more active ·O 2 - and ·OH species resulted in superior photocatalytic activity. This work provides a new idea to design a kind of photocatalytic heterostructure with more active species for potential application in the field of environmental treatment.
研究领域:
环境科学
·
材料科学
·
光催化技术
✓ 已验证
产品关联
DOI
高影响因子
CHINESE JOURNAL OF POLYMER SCIENCE
·
2019
·Vol. 38
·期 6
·638-643
·
IF 2.804
Yang Xuan-He,Yao Yan-Qing,Huang Mu-Hua,Chai Chun-Peng
A bulk Poly(vinyl alcohol)/ZIF-8 (PVA/ZIF-8) porous composite with aligned porous structure was prepared by ice-templating method. The microstructure of PVA/ZIF-8 porous composites was characterized by scanning electron microscopy (SEM). The results showed that the composites had regular pore structure and ZIF-8 nanoparticles were evenly distributed on the skeleton of PVA. X-ray diffraction (XRD) test results showed that the crystalline structure of ZIF-8 was well preserved in the composites. The specific surface area of the composite was characterized by nitrogen adsorption/desorption test. The specific surface area of the composite was up to 1160 m 2 ·g t1 . PVA/ZIF-8 porous composites could also support a certain weight with almost no volume shrinkage. The carbon dioxide adsorption quantity of the composite was up to 11.3 cm 3 ·g t1 , proving that PVA/ZIF-8 porous composite has a good application prospect in the field of carbon dioxide adsorption.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF SOLID STATE CHEMISTRY
·
2022
·
IF 3.656
Chenyang Qi,Jiang Li,Yayun Shi,Bowen Zhang,Tongdan Chen,Chen Wang,Qihang Liu,Xiaowei Yang
Ion sieving is essential for biological systems and membrane-based applications. At present, metal-organic framework (MOF) membranes are of great interest for use in ion separation, but it remains a great challenge to design high quality MOF membranes with a simple preparation process and desirable ion selectivity. Herein we fabricate a MOF composite membrane , containing highly penetrated ZIF-8 channels. The ZIF-8 channels are the dominant pathways for ion transport and display a good Li + /Mg 2+ sieving performance (Li + /Mg 2+ = 6.1). The simulation reveals that the Li + /Mg 2+ selectivity is associated with the significant disparity of transport energy barrier between them, which is caused by the different extent of ion dehydration in angstrom-scale ZIF-8 channels. This work provides an effective strategy to develop ionic sieving membranes based on penetrating MOF channels for lithium extraction.
研究领域:
材料科学
·
化学工程
·
环境科学
✓ 已验证
DOI
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2025
·
IF 2.5
Zhile Xiong,Yuewen Chen,Weidong Xie,Jiali Huang,Xiaoli Zhang,Xiya Zhang,Hai Liu
The electrocatalytic reduction of CO2 using renewable electricity offers a sustainable approach for the production of valuable chemicals. However, this process is often hindered by low catalytic activity and poor selectivity. In this study, we have developed a novel electrocatalyst that integrates ZIF-8-regulated ZnO interfaces, undercoordinated surface sites, and mesoporous nanostructures. This design enabled the ZnO/ZIF-8 catalyst to achieve excellent CO2 conversion performance, with a CO2 Faraday efficiency of more than 91% over the potential range of -1.0 V to -1.6 V and a high current density compared to reversible hydrogen electrodes. At the optimal potential of -1.4 V, the CO Faraday efficiency reaches 95.57%, accompanied by a current density of -8.16 mA/cm2. The porous nature and superior CO2 adsorption ability of the ZIF-8 shell layer foster an optimal setting for CO2 conversion while enhancing the exposure of active sites. Additionally, the synergistic coupling of ZnO and ZIF-8 interfaces fine-tunes the electronic structure of the active sites, thereby enhancing CO2RR efficiency.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
Catalysts
·
2021
·Vol. 11
·期 8
·934
·
IF 4.146
Yong Cheng,Xiuxiu Wang,Yu Mei,Dan Wang,Changchun Ji
Considering the photocatalytic performance of CDs, ZnO, and the unique porous nanostructure and stability of ZIF-8, we prepared ZnCDs/ZnO@ZIF-8 zeolite composites. The resultant material represented an enhanced ability for the photodegradation of TC compared with that of ZnCDs and ZnO. The photocatalytic degradation efficiency reached over 85%. The catalytic activity of the composites was maintained after four cycles. The experimental result indicated that ⋅O2radical was the active species in the reaction.Keywords:carbon dots;zeolite composites;photocatalytic;tetracycline
研究领域:
材料科学
·
环境科学
·
化学
✓ 已验证
产品关联
DOI
高影响因子
Advanced Materials Interfaces
·
2016
·Vol. 3
·期 24
·1600725
·
IF 3.365
Xiu Dai,Yu Cao,Xiaowei Shi,Xinlong Wang
In this study, the nanoparticles of metal–organic framework ZIF-8 are incorporated into the poly(lactic acid) (PLA) to prepare the nanocomposite electrospun membrane. The diameter and the surface roughness of the fibers can be successfully controlled by increasing the content of ZIF-8 in the membranes. The prepared PLA/ZIF-8 membranes have increased oil wettability and significantly improved mechanical property compared with pure PLA membrane. The tensile strength, stain at break of PLA/ZIF-8 membrane with 0.5 wt% ZIF-8 are increased to 5.02 MPa and 88.81% compared to 2.77 MPa and 57.89% for pure PLA membranes, respectively. The PLA/ZIF-8 membranes are proved to be good candidate for oil/water separation with high efficiency because of the fast oil wetting ability, the roughness of fibers, and the adsorption effect of the porous ZIF-8 nanoparticles.
研究领域:
材料科学
·
环境工程
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2024
·
IF 6.3
Tianyi Zhang,Da Teng,Jiaojiao Zhang,Zihui Meng,Lili Qiu
The unique periodic structure of photonic crystals demonstrates an effective slow photon effect that enhances the interaction between light and matter. This study designed and prepared MOF photonic crystal beads, and significantly improved the photocatalytic efficiency by utilizing the slow light effect. Utilizing microfluidic technology, ZIF-8 was self-assembled to form photonic crystal beads (PCB-Z) to enhance adsorption properties and light absorption. The surface of PCB-Z is modified with CdS to form a heterostructure (PCB-ZC), which widens the absorption spectrum, reduces the carrier recombination rate, and increases the specific surface area, while the photocurrent intensity of PCB-ZC is about 1.8 and 29 times that of CdS and PCB-Z. Under the combined effect of photonic crystal structure, ZIF-8/CdS heterojunction and slow photon effect, the degradation rate of Rhodamine B by PCB-ZC was 15.22 times higher than the disordered ZIF-8 powder, and the photocatalytic performance was significantly improved. The dominant role of holes in Rhodamine B degradation was confirmed by free radical trapping experiments and EPR tests. This research confirms that MOF-based photonic crystals can be assembled into periodic structures to enhance adsorption properties and light absorption, which provides a new paradigm for the development of MOF-based photocatalysts.
研究领域:
材料科学
·
光化学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）