SEPARATION AND PURIFICATION TECHNOLOGY
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2024
·
IF 8.1
Shuang Zheng,Lin Ding,Feilong Hu,Yong Zhang,Zhaofeng Ouyang,Shujuan Yang
In this work, the novel metal organic frameworks/multi-branched nanocellulose (Ni-Zn MOF@Multi CNC) fillers with different three-dimensional nanostructures are fabricated via two in-situ growing strategies, which were blended into Polyether sulfone (PES) matrix to construct composite ultrafiltration (UF) membranes. Furthermore, the effects of two structures of fillers on construction and performance of composite membranes are detailed investigated here. The results confirmed that the obtained PES composite membranes exhibited excellent permeability and selectivity because of the ultra-high hydrophilicity, abundant pores, and more negative charge of Ni-Zn MOF@Multi CNC fillers. Besides, compared with nanosphere structure of Ni-Zn MOF@Multi CNC, the nanoflower filler could provide more pores and cavities to enable higher water permeance, and more active surface charge (more -COO- groups) to increase protein rejection. The Ni-Zn MOF@Multi CNC 0.05 /PES membrane showed an 83 % higher permeance (up to 1151.00 L/m 2 h) and greatly improved BSA rejection (99 %). The Ni-Zn MOF@Multi CNC 0.05 /PES membrane has been successfully applied to different wastewater treatment, and shows expectant ultrafiltration performance.
研究领域:
材料科学
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环境工程
·
生物医学工程
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产品关联
DOI
高影响因子
JOURNAL OF CHROMATOGRAPHY A
·
2018
·
IF 3.716
Ning Zhang,Chuanhui Huang,Ping Tong,Zunmei Feng,Xiaoping Wu,Lan Zhang
Volatile polycyclic aromatic hydrocarbons (PAHs) in water and soil are associated with status in the human body. Development of simple, efficient detection method is challenging due to the coating could be attacked by the abundance of water in the direct-immersion solid-phase microextraction. The stability of coating is essential to the analysis results. In this paper, a stable Ni-Zn MOF/g-C 3 N 4 (MG NFs) nanoflowers with cavity traps structure was firstly reported and acted as solid-phase microextraction (SPME) adsorbent for PAHs. Markedly enhanced moisture and acid stability of the MG NFs was obtained through the doping the hydrophobic graphitic carbon nitride (g-C 3 N 4 ) and metal ions into metal organic frameworks (MOFs). The aperture environment and ambient environment of MG NFs were changed by the doping of the Ni and the g-C 3 N 4, respectively. The moisture and acid stability of MG NFs were prominently increased under the dual protection. Compared to commonly used commercial coatings, the MG NFs own large surface area, unique nanoflowers structure and numerous open metal sites on the nanosheets, which demonstrated significant extraction superiority for PAHs. The MG NFs coated fiber was used for the SPME preconcentration of PAHs and couped with GC–MS for detecting PAHs. It presented low detection limits (0.1–3.0 ng L −1 ), wide linearity (0.3–5000.0 ng L −1 ) and good linearity (the correlation coefficient >0.9951). The inter-day and intra-day relative standard deviation (RSD) (n = 3) for three replicate extractions using one fiber was 3.8%–9.1%, and 3.5%–9.2%, respectively. The fiber-to-fiber reproducibility (n = 3) was 4.2–11.8%. The coupling method was successfully applied in the analysis of real water and soil samples with satisfactory recoveries of 82.9–109.2%, 84.2–106.4%, and the corresponding RSDs were 2.4–11.3%, 3.6–10.8%, respectively. The results indicated the effectiveness of NG NFs coated fiber in further practical application.
研究领域:
环境科学
·
分析化学
✓ 已验证
DOI
高影响因子
PHYSICA E-LOW-DIMENSIONAL SYSTEMS & NANOSTRUCTURES
·
2020
·
IF 3.57
Sittipranee Ploychompoo,Qianwei Liang,Xin Zhou,Chen Wei,Hanjin Luo
Contamination of drinking water with heavy metals, particularly arsenic (As), is a persistent problem with serious public health implications worldwide. In this study, we present a zinc based metal-organic framework (Zn-MOF-74) and polyacrylamide polymer (PAM) coated on reduced graphene oxide (rGO) as an effective adsorbent for the removal of arsenite (As(III)) from water. Zn-MOF-74 nanoparticles were prepared by room-temperature precipitation and these were immobilized on rGO surface grafted PAM by a free-radical polymerization method, (Zn-MOF-74/rGO/PAM nanocomposites). The experimental data correlates well with the pseudo-second-order kinetic model and Langmuir isotherm, and the maximum adsorption capacity ( q max ) was 282.4 mg g −1 at pH 10, 298 K. The removal efficiency was rapid, removing more than 99.8% of As(III) from a 0.2 mg L −1 solution and achieving drinkable levels in 15 min. Thermodynamic data revealed that the process was spontaneous and endothermic. Furthermore, the adsorbent revealed high stability in pH range 4–10 and could be reused at least four times. Adsorption mechanism involved a synergistic combination of chemisorption and physisorption. FTIR and XPS analyzes revealed that the amide group (–NH 2 ) and hydroxyl group (–OH) on Zn-MOF-74/rGO/PAM dominate in their adsorption.
研究领域:
环境科学
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材料科学
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水处理
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纳米技术
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产品关联
DOI
高影响因子
CRYSTENGCOMM
·
2019
·Vol. 21
·期 42
·6414-6422
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IF 3.382
Rui Zhang,Wanqing Song,Mingjing Wang,Huiming Ji
Metal–organic framework (MOF) materials with controlled microstructures have become popular in the last few decades. In this study, Zn-MOF precursors with diverse crystallinity and particle size (20–800 nm) were synthesized using an accelerating or retarding nucleation process by introducing various secondary ligands, which were employed as modulators in the coordination and ligand exchange equilibria according to their different acidity coefficients. Thus, the pore size of MOF-derived ZnO clusters was different, resulting in diverse gas sensing properties. Moreover, large precursor-derived ZnO-(2 and 3) assemblies with the micropore sizes of 1 nm and 0.75 nm showed size-selective sensing and better performance, which exhibited a higher and fast response (4 s) to butanone and n-butanol with the lengths of 0.664 nm and 0.499 nm, respectively, and a low limit of detection (0.1 ppm). This simple method of controlling the nucleation of MOFs and the pore size of ZnO assemblies paved a new way towards the design of the microstructure of MOF-based functional materials.
研究领域:
材料科学
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化学
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产品关联
DOI
高影响因子
MICROCHIMICA ACTA
·
2020
·Vol. 187
·期 9
·1-11
·
IF 6.232
Tang Tingting,Yang Fan,Wang Lina,Zhao Chunxin,Nie Fei,GuopingYang
An ultrasensitive sandwich electrochemiluminescence (ECL) biosensor was designed for determination of concanavalin A (ConA) through the specific carbohydrate-ConA interactions. Three-dimensional porous metal-organic framework (Zn-MOF) was synthesized, which loaded a large amount of luminescent reagents as luminol by encapsulating into its pores to form Zn-MOF@luminol complex. Interestingly, Zn-MOF also acted as the coreactant accelerator in the luminol-H 2 O 2 ECL system. This Zn-MOF@luminol complex was used as the signal probe to achieve a super strong and stable ECL signal. In addition, three-dimensional hierarchical molybdenum disulfide nanoflower and multiwalled carbon nanotubes complex (MoS 2 NF@MWCNTs) with peroxidase-mimicking enzyme property were used as a substrate to modify the glassy carbon electrode to further enhance the ECL signal of luminol by promoting decomposition of H 2 O 2 into reactive oxygen species (ROSs). In addition to the horseradish peroxidase (HRP) catalysis effect on the luminol ECL signal, a triple amplified ConA sandwich ECL sensor with high sensitivity sensor was constructed. The linear range for ConA detection was from 0.5 pg/mL to 100 ng/mL with a detection limit of 0.3 pg/mL ( S / N = 3). The recovery test for ConA in human serum samples was performed with satisfactory results.
Graphical abstract
研究领域:
生物传感器
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分析化学
·
电化学
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产品关联
DOI
PubMed
高影响因子
FOOD CHEMISTRY
·
2024
·
IF 8.5
Biao Jia,Baoshan He,Renli Liu,Jinping Yang,Wenjie Ren,Zhiguang Suo,Yiwei Xu
The conductivity of Zn-MOF-on-Co-MOF synthesized by one-pot method is improved by searching for the optimum carbonization temperature, which overcomes the limitation of traditional MOF. In order to further enhance electron transfer, the mesoporous PtPdCo trimetal was introduced, which provided considerable load capacity for methylene blue (MB) and reverse complementary DNA (sDNA), and also showed excellent catalytic activity for MB. In this study,the conductivity of aptasensor was improved by modifying carbonized MOF as the base material. In the presence of fipronil (FIP), Apt tended to bind to FIP and was separated from the electrode surface, so that the remaining single-stranded complementary DNA (cDNA) were hybridized with signal probe (MB@PtPdCo/sDNA) and amplified the electrochemical signal. By modifying the substrate, competitive amplification strategy and signal probe material to catalyze signal molecules, the sensor performs multiple signal amplification, and the electrical signal is significantly improved. The sensor has a wide detection range 100 pg/mL to 100 μg/mL and a low detection limit of 76 pg/mL.
研究领域:
分析化学
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环境科学
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食品安全检测
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产品关联
DOI
PubMed
高影响因子
ACS Applied Nano Materials
·
2018
·
IF 0
Jiuhai Wang,Yadi Fan,Hang-wei Lee,Changqing Yi,Changming Cheng,Xin Zhao,Mo Yang
Here, a novel colorimetric sensing platform for highly selective detection of Fe3+ in aqueous solutions was developed based on zero-dimensional Zn-MOF-74 [Zn2(DOBDC), DOBDC = 2,5-dihydroxyterephthalic acid] nanodots. The first ultrasmall Zn-MOF-74 nanodots with the average size within 10 nm were successfully synthesized by manipulating the initial conditions with a diluted material system. It was found that the ultrasamll MOF nanodots had a highly selective interaction with Fe3+ and showed a specific blue colorimetric change in aqueous solution. The highly dispersive nature in aqueous solution and high surface-to-volume ratio help MOF-74 nanodots closely interact with the targeted Fe3+ ions with a low limit of detection of 1.04 μM and a fast response within seconds. Finally, we demonstrate that the selective Fe3+ sensing mechanism of Zn-MOF-74 nanodots is due to the selective framework disruption and the formation of Fe-DOBDC salt complex with blue color. It is the first report of nanoscale MOF based colorimetric Fe3+ sensor with low limit of detection (LOD) comparable even to fluorescent MOF based Fe3+ sensors, which could be easily observed by naked-eye without expensive fluorescence apparatuses. The good colorimetric stability in aqueous environment, low limit of detection, rapid response, and nanosize nature enable this MOF nanodot to be a good Fe3+ sensing probe for biological and environmental sensing applications.
研究领域:
材料科学
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分析化学
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环境科学
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产品关联
DOI
MICROCHIMICA ACTA
·
2020
·Vol. 187
·期 8
·1-9
·
IF 6.232
Wei Yu-ping,Zhang Yi-wen,Chen Jing-Shuai,Mao Chang-jie,Jin Bao-Kang
An ultrasensitive electrochemiluminescence biosensor was established based on the Zn-MOF/GO nanocomposite. Ag(I)-embedded DNA complexes were used as a signal amplification reagent. In this work, 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin (TCPP) and Zn 2+ were integrated into a porphyrin paddlewheel framework (Zn-MOF) by a hydrothermal method. The synthesized Zn-MOF material has electrochemiluminescence property, and the luminescence intensity is improved after being composited with graphene oxide (GO). Based on the composite material, we constructed an ultrasensitive ECL biosensor for the p53 antibody detection. The composite material acted as an admirable substrate and then loaded plenty of p53 antigens to recognize the target (p53 antibody) accurately. Because of the bridging effect of streptavidin and biotin-conjugated goat anti-rabbit IgG (bio-ab2), the rich-C DNA with positive correlation with the target was modified on the electrode and then captured the co-reactant accelerator Ag + to amplify the signal. Therefore, the ECL biosensor response increases with increasing p53 antibody concentration. In the range 0.1 fg/mL–0.01 ng/mL, the response signal of the biosensor has a good linear relationship with the p53 antibody concentration. The detection limit is 0.03 fg/mL (S/ N = 3). Impressively, the biosensor not only featured high sensitivity, good stability, and excellent specificity for the detection of p53 antibody, but also provides a new way for early detection of cancer.
Schematic representation of the electrochemiluminescence sensor based on a Zn-MOF/GO nanocomposite, which can be applied to the determination of p53 antibody.
研究领域:
分析化学
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生物化学
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纳米技术
·
癌症研究
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DOI
PubMed
高影响因子
INORGANIC CHEMISTRY
·
2024
·
IF 4.3
Mengyun Lu,Xinwen Jia,Wenjing Zhang,Wuduo Zhao,Ajuan Yu,Gangfeng Ouyang
The enantioselective performance of porous chiral metal–organic frameworks (CMOFs) is closely related to the pore size and uniformity of easily accessible active sites. The chiral recognition efficiency of microporous CMOFs is hindered by the restricted diffusion of the guest. Hierarchical porous chiral CMOFs with multiple pore size regimes ranging from micropores to macropores have emerged as potential candidates in chiral separation applications. 3DOM Zn-MOF-74 crystalline porous material with ordered macro–micropore structure was prepared with a general bottom-up strategy by carrying out the controllable confined growth of Zn-MOF-74 precursor in a removable three-dimensional ordered macroporous (3DOM) polystyrene (PS) template. Then l-tryptophan ( l -Trp) was introduced into MOFs by the strategy of postsynthetic modifications, and finally, a chiral hierarchical porous functional material 3DOM Zn-MOF-74-l-Trp was successfully fabricated. Based on the two luminescent centers from the achiral ligand H4DOBC and chiral ligand l-Trp, the proportional fluorescence sensor 3DOM Zn-MOF-74-l-Trp was hopeful to be applied in the field of enantioselective fluorescence sensing. The enantioselectivity factor values of microporous M-Zn-MOF-74-l-Trp for 1,1′-bi-2-naphthol (Binol) and mandelic acid (MA) were 1.08 and 1.12, respectively. In comparison, the construction of hierarchical porous structure greatly enhanced the chiral recognition performance, which may be due to the improved mass-transfer efficiency of chiral guest molecules and highly swelled accessibility to the chiral recognition sites in this CMOF composite, making the enantioselectivity factor values correspondingly increased to 1.29 and 2.26, respectively.
研究领域:
材料科学
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化学
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产品关联
DOI
PubMed
高影响因子
INORGANIC CHEMISTRY
·
2024
·
IF 4.3
Xue Ye,Chenxi Bai,Peipei Zhang,Fuyuan Han,Junyu Xia,Xinhua Gao,Wenlin Xu,Lisheng Guo,Jie Li
Metallic atoms within metal–organic framework (MOF) materials exhibit a distinctive and adaptable coordination structure. The three-dimensional (3D) pore configuration of MOFs enables the complete exposure of metal active sites, rendering them prevalent in various catalytic reactions. In this study, zinc (Zn) atoms within Zn-based MOF materials, characterized by an abundance of valence electrons, are utilized for the transesterification of dimethyl carbonate (DMC). Additionally, the introduction of zirconium (Zr) effectively addresses the susceptibility of the MOFs’ crystal structure to dissolution in organic solvents. The formulated catalyst, Zn-10%Zr-MOF(300), demonstrates remarkable catalytic performance with 91.5% DMC selectivity, 61.9% propylene carbonate (PC) conversion, and 56.6% DMC yield. Impressively, the catalyst maintains its high performance over five cycles. Results indicate that Zr interacts with Zn, forming new coordination bonds and enhancing the catalyst crystal structure stability. Moreover, electron transfer intensifies the alkalinity of the active Zn atoms, enhancing the overall catalyst performance. This research informs the development of transesterification heterogeneous catalysts and broadens the application scope of MOF catalysts.
研究领域:
材料科学
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催化
·
化学工程
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产品关联
DOI
PubMed
高影响因子
INORGANIC CHEMISTRY
·
2022
·
IF 5.436
Guoxu Qin,Yaqiong Kong,Tianjue Gan,Yonghong Ni
Facile and rapid detection of residual organic pesticides on the fruits and vegetables has recently drawn increased attention in the food safety field. Herein, a surfactant-assisted solvothermal route with subsequent post-modification was designed for the preparation of Eu3+-functionated Zn-BDC ultrathin nanosheets (labeled as Eu3+@Zn-MOF-NS, BDC: 1,4-benzenedicarboxylate) with the thickness of 5 nm. The as-obtained Eu3+@Zn-MOF-NS could be homogeneously dispersed in aqueous systems to form a highly-stable collosol. Under the UV excitation of 325 nm, the as-obtained Eu3+@Zn-MOF-NS displayed red photoluminescence emission of Eu3+ ions, which could be notably quenched by an organochlorine pesticide, 2,6-dichloro-4-nitroaniline (DCNA), without interferences from ions, organic small molecules, and other pesticides. The detection limit and Ksv were 0.17 μM (35 ppb) and 3.2 × 105 M–1 in the water system, respectively. Moreover, the present 2D Eu3+@Zn-MOF sensor was also employed for the detection of DCNA in Chaohu Lake water and tap water and in apple, cabbage, and pakchoi samples with the relative standard deviation (RSD) ranging from 4.74 to 9.77%. Further investigations revealed that the competitive absorption between DCNA and the as-obtained Eu3+@Zn-MOF-NS resulted in the fluorescence quenching of the probe.
研究领域:
食品安全
·
分析化学
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2016
·Vol. 6
·期 51
·45475-45481
·
IF 3.289
Yi Yang,Kang Shen,Jun-zhong Lin,Yong Zhou,Qiao-yun Liu,Cheng Hang,Hani Nasser Abdelhamid,Zhen-qin Zhang,Hong Chen
A novel zinc-based luminescent metal–organic framework (Zn-MOF) has been successfully constructed based on a designed flexible and electron-rich N-involved linker (HL = 4-(bis(4-(pyridin-4-yl)phenyl)amino)benzoic acid). The framework of this Zn-MOF exhibits a 2-fold interpenetrated network which is composed of (3,3)-c sheets. The Zn-MOF has a strong solid state emission at 512 nm. The luminescence signal of the Zn-MOF can be quenched efficiently by trace amounts of electron-deficient nitroaromatics, especially 2,4,6-trinitrophenol (TNP). The quenching constant (Ksv) for TNP is 2.11 × 104 M−1, indicating that this framework can be employed as an excellent chemical sensor for identifying and quantifying TNP. This work highlights a strategy for designing a N-involved π-electron-rich enhanced ligand with nucleophilic properties for MOF-based materials as sensors. It also paves the way toward exploring other more efficient MOF materials as sensors for determining electron-deficient nitroaromatics.
研究领域:
材料科学
·
化学传感
·
分子设计
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）