CRYSTENGCOMM
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2012
·Vol. 15
·期 3
·560-569
·
IF 3.842
Zhifeng Jiang,Jimin Xie,Deli Jiang,Xiaojun Wei,Min Chen
Nickel nanoparticles with different sizes and morphologies were prepared with nickel chloride as the source of nickel and hydrazine hydrate as a reductant. Cetyltrimethyl ammonium bromide (CTAB), polyethylene glycol-10000 (PEG-10000), gelatin and their composites were used as modifiers in this research. The particles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM) and Fourier transform infrared (FTIR). The effect of using single modifiers and their composites was investigated. The results revealed that the kind of modifier used had a significant effect on the morphology and size of the Ni nanostructure. The possible formation mechanism of nickel nanoparticles was also investigated. All of the formed nickel nanoparticles showed excellent catalytic activity in the reduction of p-nitrophenol compared to the commercial RANEY® Ni. The catalytic activity of nickel particles prepared in the presence of composite modifiers was higher than nano nickel catalysts prepared in the presence of single modifiers. The magnetic property, possible catalytic mechanism and the possibility of reusability were also investigated.
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JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
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2014
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IF 3.679
X.-H. Lu,X.-L. Wei,D. Zhou,H.-Z. Jiang,Y.-W. Sun,Q.-H. Xia
A series of the supported nickel catalysts have been synthesized through impregnation, characterized by X-ray diffraction, N 2 sorption measurement, temperature programmed H 2 reduction and X-ray photoelectron spectroscopy. The morphology and particle size of catalysts are imaged by scanning electron microscope. The catalysts have efficiently catalyzed the one-step hydrogenation of 1,5-dinitronaphthalene to 1,5-diaminodecahydronaphthalene. The catalyst 10%Ni/SiO 2 -1a is the most active for the titled hydrogenation with 100 mol% conversion and 95.3% selectivity, applicable for the catalytic one-step hydrogenation of nitro-aromatic compounds. The reducibility of NiO species on different supports has been carefully studied. Some factors such as the type of carriers, the addition of modifiers, the silica source, the Ni loading, the H 2 pressure and the reaction temperature and time play important roles in controlling the hydrogenation. In addition, the negative effect of the water amount has been observed. The recycling tests reveal the recyclability and stability of the supported Ni catalyst.
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CARBON
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2014
·
IF 6.16
Chao Ding,Weili Wei,Hanjun Sun,Jinhua Ding,Jinsong Ren,Xiaogang Qu
A reduced graphene oxide (rGO) supported chiral-modified Ni catalyst was synthesized, characterized and employed for asymmetric hydrogenation. The prepared hybrid catalyst could produce each enantiomer with d - or l -tartaric acid as chiral modifier and exhibited a high TOF (20160 h −1 ) and enantioselectivity (enantiomeric excess, 98.5%) for asymmetric hydrogenation of methyl acetoacetate. The high catalytic activity and enantioselectivity were mainly attributed to the unique properties of the support rGO, as it had a large specific surface area to sustain and stabilize Ni particles and its high charge carrier mobility could enable the readily transfer of electrons in the reaction process. Besides, the catalyst could also gain an enhanced reactant sorption with the support of rGO, thus achieved a greatly catalysis enhancement. The ferromagnetism of Ni made the catalyst easier for separation and reuse. The catalytic and recycling performance of the prepared chiral Ni catalyst demonstrated that rGO was indeed a promising support to improve activity, enantioselectivity and durability of catalysts, and the prepared catalysts were promising reusable heterogeneous catalysts for asymmetric hydrogenation.
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ENERGY & FUELS
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2015
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IF 2.79
Yetao Jiang,Zheng Li,Xing Tang,Yong Sun,Xianhai Zeng,Shijie Liu,Lu Lin
In the present study, cellulolytic enzyme lignin, which was isolated from enzymatic hydrolysis residues of bamboo, could be efficiently depolymerized into oily products with a yield of over 60 wt % using a range of acidic zeolites and/or Raney Ni catalysts. The degraded products are mainly composed of phenolic monomers, which can be used as versatile chemicals or the precursor for biofuel production. The yields of monophenols were 12.9 wt % and no more than 5.0 wt % when catalyzed by Raney Ni or acidic zeolites, respectively. However, a yield of monophenols as high as 21.0–27.9% was obtained using a Raney Ni combination with acidic zeolite catalysts. Matrix-assisted laser desorption ionization time-of-flight mass spectrometry analysis revealed that the depolymerization level of the oily fraction catalyzed by a combination of catalysts was more complete in comparison to those catalyzed by an independent catalyst. The results indicated that the catalytic activity of a fully heterogeneous catalyst combination for the depolymerization of cellulolytic enzyme lignin was proven to be superior to that of either component alone.
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VACUUM
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2015
·
IF 1.858
Zhaobing Cai,Guo Jin,Xiufang Cui,Yang Li,Yang Fan,Jiahui Song
In this work, a NiCrCoTiV HEA was fabricated by vacuum hot-pressing sintering after planetary ball milling. The microstructure and phase composition were studied by experiment and thermodynamic simulation. The results show that some discrepancies are found between the calculated and experimental results, and the main difference is the existence of TiO phase. Experimental results indicate that, the alloy consists of a BCC phase, an FCC phase, an eta (η) phase, a TiO phase and Ni 2 V 3 intermetallic compounds , and BCC phase is enriched with Cr and V elements, FCC phase is enriched with Co, Ti and Ni and heavily depleted by V and Cr, and eta phase is enriched with Ni, Ti, and Co elements. The thermodynamic simulation results suggest that the solidification simulation predicts the composition of BCC phase, FCC phase and eta (η) phase very well, but can't predict the presence of Ni 2 V 3 intermetallic compounds. Without regard to the composition of each phase, the results of the simulated equilibrium phase diagram seem to be much closer to the experimental results.
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2015
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IF 3.313
Lei Wang,Pengjin Ye,Fang Yuan,Shuzhen Li,Zixin Ye
In this work, we report a novel means, named liquid phase in-situ hydrodeoxygenation of bio-derived phenol to cyclohexene and cyclohexane over Raney Ni and Nafion/SiO 2 . In this method, producing hydrogen , hydrogenation and dehydration are merged and coupled owing to the close reaction conditions. The overall specific reaction pathway was studied and influences of Nafion loading, temperature, H 2 O/MeOH ratio and the quantity of catalysts on the reaction were also researched. In terms of 3 g phenol, the suitable operating conditions are drawn as follows: the Nafion loading 13 wt%, the reaction temperature 200 °C, H 2 O/MeOH ratio 20 mL:15 mL, Raney Ni 1 g, Nafion/SiO 2 0.3 g. The conversion rate of phenol and the total yield of cyclohexene and cyclohexane can reach respectively 100% and 87%. The whole reaction system is performed in the liquid phase using in situ hydrogen produced from methanol aqueous-phase reforming, not requiring an external source of hydrogen. The operating conditions are gentle, and the cost is considerably reduced.
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SURFACE & COATINGS TECHNOLOGY
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2015
·
IF 1.998
Xiaogang Guo,Xueming Li,Hongru Li,Daixiong Zhang,Chuan Lai,Wulin Li
In this study, the nano-Al/Ni energetic composite coatings (ANECCs) have been successfully fabricated by the electrophoretic deposition (EPD) method at the room temperature and normal pressure. Isopropyl alcohol is demonstrated to act as the suitable dispersion agent for the EPD. The SEM and EDS results show that the obtained ANECCs are relatively smooth and evenly distributed. Both the phase constitution and exothermic behavior of the ANECCs are characterized by X-ray diffraction (XRD) and differential scanning calorimetry (DSC) analysis at the same while. In addition, the kinetics of the nanoparticles during the EPD process are investigated in detail. The exothermic performance of products studies show that the ANECCs prepared by EPD exhibit the great combustion performance and thermodynamic properties. Furthermore, the combustion processes of samples are recorded and analyzed by the high-speed photography. This work demonstrates that EPD method is a facile and effective approach in the preparation of Al/Ni energetic coatings with the widespread application.
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ACS Applied Materials & Interfaces
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2016
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IF 7.145
Hai-Bo Zhao,Zhi-Bing Fu,Hong-Bing Chen,Ming-Long Zhong,Chao-Yang Wang
Electromagnetic microwave absorption materials have attracted a great deal of attention. Foams for the low density and tunable porosity are considered as ideal microwave absorbents, while with the requirement of improving their inherent electromagnetic properties. In this manuscript, an innovative, easy, and green method was presented to synthesize an electromagnetic functionalized Ni/carbon foam, in which the formation of Ni nanoparticles and carbon occurred simultaneously from an affordable alginate/Ni2+ foam precursor. The resultant Ni/carbon foam had a low density (0.1 g/cm–3) and high Ni nanoparticles loading (42 wt %). These Ni nanoparticles with a diameter of about 50–100 nm were highly crystallized and evenly embedded in porous graphite carbon without aggregation. Also, the resultant foam had a high surface area (451 m2 g–1) and porosity and showed a moderate conductivity (6 S/m) and significant magnetism. Due to these special characteristics, the Ni/carbon foam exhibited greatly enhanced microwave absorption ability. Only with 10 wt % of functional fillers being used in the test template, the Ni/carbon foam based composite could reach an effective absorption bandwidth (below −10 dB) of 4.5 GHz and the minimum reflection value of −45 dB at 13.3 GHz with a thickness of 2 mm, while the traditional carbon foam and nano-Ni powder both showed very weak microwave absorption (the minimum reflection value < –10 dB). This foam was demonstrated to be a lightweight, high performance, and low filler loading microwave absorbing material. Furthermore, the detailed absorption mechanism of the foam was investigated. The result showed that the derived strong dielectric loss, including conductivity loss, interface polarization loss, weak magnetic loss, and naoporosity, contributes a great electromagnetic absorption.
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PubMed
高影响因子
Journal of Energy Chemistry
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2017
·
IF 2.594
Xiaoyu Wang,Wei Chen,Zheng Li,Xianhai Zeng,Xing Tang,Yong Sun,Tingzhou Lei,Lu Lin
In this study we report a new reaction pathway in which the hydroxyl and the aldehyde groups of 5-hydroxymethyl furfural were aminated respectively. Hydroxyl group was aminated via Ritter reaction followed by direct reductive amination of aldehyde group. For the Ritter reaction of 5-hydroxymethyl furfural, mixture of trifluoromethane sulfonic acid and phosphoric anhydride showed good performance and the intermediate N -acyl-5-aminomethyl furfural with the highest yield of 89.1 wt% was obtained. Optimization of direct reductive amination of 2,5-bis(aminomethyl) furan was conducted and a yield of 45.7 wt% was achieved. This study presents a simple way for preparing bis(amino)furans from renewable biomass based 5-hydroxymethyl furfural, which enriches the biorefinery concept from biomass.
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SURFACE & COATINGS TECHNOLOGY
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2017
·
IF 2.589
Lianbo Wang,Ming Chen,Huabing Liu,Chuanhai Jiang,Vincent Ji,Florent Moreira
In present work, the ternary Ni-Ti-CeO 2 composite coatings were electrodeposited on Al matrix composite (CNT/7075) in traditional Watts' solution containing various concentrations of CeO 2 nanoparticles and constant concentration of Ti microparticles . The effects of CeO 2 nanoparticles on microstructure and corrosion resistance of the obtained composite coatings were comprehensively investigated. The incorporation of moderate CeO 2 nanoparticles (less than 10 g L − 1 in Watts' solution) gave rise to grain refinement, random-orientation growth of nickel deposit and smooth surface of the composite coating. Corrosion tests of the Ni-Ti-CeO 2 composite coatings in 3.5 wt% sodium chloride (NaCl) at 25 °C illustrated the optimised microstructure favoured the enhancement of corrosion resistance. Further analyses of the corrosion behavior demonstrated that the embedded CeO 2 nanoparticles facilitated the formation of a compact passive film on the surface of the composite coatings during corrosion and promoted the formation of TiO 2 on the surface of Ti microparticles. The formation of TiO 2 not only protected the Ti metal particles but also helped to improve the corrosion resistance of the composite coatings, because the TiO 2 coated Ti microparticles decreased the attack probability of nickel deposits by corrosive medium. Typically, the Ni-Ti-CeO 2 composite coating electrodeposited in Watts' solution containing 10 g L − 1 CeO 2 nanoparticles possessed the best corrosion resistance and excessive CeO 2 nanoparticles deteriorated the corrosion resistance.
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Theranostics
·
2017
·
IF 8.766
Xiaoyu Wang,Wen Cao,Li Qin,Tingsheng Lin,Wei Chen,Shichao Lin,Jia Yao,Xiaozhi Zhao,Min Zhou,Cheng Hang,Hui Wei
Catalytic nanomaterials with intrinsic enzyme-like activities, called nanozymes, have recently attracted significant research interest due to their unique advantages relative to natural enzymes and conventional artificial enzymes. Among the nanozymes developed, particular interests have been devoted to nanozymes with peroxidase mimicking activities because of their promising applications in biosensing, bioimaging, biomedicine, etc. Till now, lots of functional nanomaterials have been used to mimic peroxidase. However, few studies have focused on the Ni-based nanomaterials for peroxidase mimics. In this work, we obtained the porous LaNiO 3 nanocubes with high peroxidase-like activity by inducing its 3+ oxidation state in LaNiO 3 perovskite and optimizing the morphology of LaNiO 3 perovskite. The peroxidase mimicking activity of the porous LaNiO 3 nanocubes with Ni 3+ was about 58~fold and 22~fold higher than that of NiO with Ni 2+ and Ni nanoparticles with Ni 0 . More, the porous LaNiO 3 nanocubes exhibited about 2-fold higher activity when compared with LaNiO 3 nanoparticles. Based on the superior peroxidase-like activity of porous LaNiO 3 nanocubes, facile colorimetric assays for H 2 O 2 , glucose, and sarcosine detection were developed. Our present work not only demonstrates a useful strategy for modulating nanozymes' activities but also provides promising bioassays for clinical diagnostics.
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PubMed
高影响因子
RSC Advances
·
2016
·Vol. 6
·期 19
·15354-15361
·
IF 3.289
Xinhuan Lu,Yang chen,Zhenshuang Zhao,Hao Deng,Dan Zhou,Changcheng Wei,Renfeng Nie,Qinghua Xia
The carbon supported 10% Ni catalysts doped with 3‰ Rh have been prepared by an impregnation method. These catalysts have been used to catalyze the one-step hydrogenation of nitrobenzene to cyclohexylamine. The results show that the 3‰ Rh–10% Ni/CSC (biocarbon) catalyst exhibits an excellent performance to achieve 100 mol% conversion of nitrobenzene and 91.6% selectivity of cyclohexylamine under reaction conditions of 3.5 MPa and 140 °C. The recycling tests reveal recyclable stability of 3‰ Rh–10% Ni/CSC. This catalyst is active for the hydrogenation of a series of electron-deficient nitrobenzenes. Some factors such as the type of carriers, the content of Ni and Rh, the type of metals and additives play important roles in controlling the selective hydrogenation.
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