JOURNAL OF RARE EARTHS
·
2023
·
IF 4.9
Baochen Wang,Shifeng Sun,Zeqi Li,Zongwang Li,Weiwei Lin,Chao Zeng,Yan-gai Liu,Ruiyu Mi
Rare earth co-doped phosphor for fluorescence intensity ratio (FIR) thermometer has gained increasing attention in recent years. Herein, the novel Tb 3+ and Eu 3+ co-doped K 3 SrBi(P 2 O 7 ) 2 (KSBP) phosphate phosphors were reported. The crystal structure of the title phosphor was determined using Rietveld refinement and proved to have a three-dimensional structure. The time-resolved spectroscopy reveals that there is almost no energy transfer between Tb 3+ and Eu 3+ . More importantly, Tb 3+ and Eu 3+ emissions show different thermal quenching behaviors, which claims the potential of this material for application in optical thermometer. The FIR of the typical KSBP:0.02Tb3+,0.04Eu3+ sample demonstrates a polynomial relationship as a function of temperature and the absolute and relative sensitivity are 0.025 K –1 and 0.59%/K, respectively. In general, our study reports a novel and potential KSBP:Tb 3+ ,Eu 3+ phosphate phosphor that is promising for use in high-sensitive FIR thermometers.
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高影响因子
NEW JOURNAL OF CHEMISTRY
·
2022
·Vol. 46
·期 40
·19153-19160
·
IF 3.925
Zhenyu Lu,Gongke Li,Yufei Hu
A Tb3+ functionalized triazine-porous organic framework (Tb3+/TAPOF) was prepared by introducing Tb3+ into a triazine-porous organic framework through a coordination bond. Combining the advantages of both Tb3+ and TAPOF, Tb3+/TAPOF showed good thermal stability, a high specific surface area, and excellent fluorescence performance. As the concentration of ciprofloxacin became higher, the intensity of the peak at 544 nm increased, while that of the peak at 440 nm did not change. Thus, a ratiometric fluorescent sensor based on Tb3+/TAPOF for selective ciprofloxacin determination was constructed, and the mechanism of ciprofloxacin determination was studied using the UV-vis and phosphorescence spectra and fluorescence lifetime. A good linear relationship, under the optimized conditions, was obtained between the I544/I440 value and the ciprofloxacin concentration in the range of 0.06 μmol L−1 to 5.0 μmol L−1, and the limit of detection (LOD, S/N = 3) was 19 nmol L−1. Moreover, the ratiometric fluorescent sensor based on Tb3+/TAPOF was applied to the determination of ciprofloxacin in aquatic products with recoveries in the range of 96.1–108.6%. These results obtained by the ratiometric fluorescence method and the high-performance liquid chromatography (HPLC) method are consistent for determination of aquatic products, which further proves that this method based on Tb3+/TAPOF is accurate. Generally, these results demonstrate that the Tb3+/TAPOF based ratiometric fluorescent sensor has an extensive application prospect in ciprofloxacin determination in the aquatic product industry.
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JOURNAL OF RARE EARTHS
·
2022
·
IF 4.632
Yaling Zhang,Lingcong Fan,Xuefeng Wang,Jiansheng Xie,Ying Shi
Rare earth doped 12CaO·7Al 2 O 3 (C12A7) glass-ceramics are one of attractive photonic materials due to their high transparency, high luminescent efficiency and eco-friendly nature. A series of C12A7 glasses with different Tb 3+ doping concentrations was prepared by aerodynamic levitation method. The C12A7:Tb glass-ceramics were obtained via in-situ growth from the glasses with the identical chemical composition at 800 °C. The microstructure observation demonstrates that the elemental distributions of Ca and Al are homogeneous in the glass-ceramics and the grain size of C12A7 is 4–70 nm. The in-line transmittance of glass-ceramics reaches as high as 82% at 1500 nm. The emission spectra of the C12A7:Tb glass-ceramics present characteristic Tb 3+ emission peaks at 486 nm ( 5 D 4 → 7 F 6 ), 541 nm ( 5 D 4 → 7 F 5 ), 585 nm ( 5 D 4 → 7 F 4 ) and 621 nm ( 5 D 4 → 7 F 3 ). The photoluminescence lifetime of C12A7:0.3%Tb glass-ceramic is 1.9 ms. Compared with the emission intensity of the glasses, that of the glass-ceramics increases due to the reducing in concentration of oxygen vacancy associated with network forming (NWF) cations. The highly transparent C12A7:Tb glass-ceramics may be a promising candidate for green light source in solid state lighting.
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Journal of Materials Chemistry B
·
2022
·Vol. 10
·期 34
·6443-6452
·
IF 7.571
Dan Xiu,Sibo Zhao,Zhenhua Li,Yanan Xu,Yao Wang,Zhijun Zhu,Min Zhang,Christopher D. Snow,Laurence A. Belfiore,Jianguo Tang
In this work, a designed porous DNA crystal with high intrinsic biocompatibility was used as the scaffold material to load fluorescent guest molecules to detect anti-cancer drugs. It is shown here that the synthesized crystals have the characteristics consistent with the designed large solvent channels, and can therefore accommodate guest molecules such as fluorescent proteins that cannot be accommodated by less porous crystals. Eu(TTA)3phen and Tb(acac)3phen lanthanide complexes were individually noncovalently loaded into the porous crystals, resulting in hybrid luminescent DNA crystals. Emodin, an anti-cancer, anti-tumor, anti-inflammatory drug, was found to quench lanthanide complexes in solution or in crystals. Notably, emodin is the active ingredient of Lianhua Qingwen Capsule, an anti-COVID-19 drug candidate. Therefore, the porous DNA crystals reported here have potential applications as a biocompatible and theranostic delivery biomaterial for functional macromolecules.
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高影响因子
Optical Materials Express
·
2021
·Vol. 11
·期 9
·2828-2838
·
IF 3.442
Taisen Li,Jin Liu,Xinzhi Wang,Abdur Raheem Aleem,Yao Wang,Matt J. Kipper,Laurence A. Belfiore,Jianguo Tang
Multimodal nanoprobes are of great significance in clinical diagnosis, because they integrate the advantages of multiple imaging methods. The combination of multiple imaging modes provides more comprehensive and complex information than single-mode imaging, which can greatly improve clinical diagnoses. In this paper, Gd3+ and Tb3+ co-induced polyelectrolyte nanoaggregates (GTIPAs) are introduced as a novel dual-mode imaging probe. Containing gadolinium and terbium, GTIPAs are regular spherical nanoparticles, whose diameters are about 150 nm. As a fluorescent nanomaterial, GTIPAs have strong and stable luminescence intensity. At the same time, as an MRI contrast agent, GTIPAs exhibit a good contrast effect and a high longitudinal relaxation rate. In addition, the polyelectrolytes reduce the cytotoxicity of the complexes, confering excellent biocompatibility and water solubility. Therefore, GTIPAs are non-toxic luminescence/magnetic resonance dual-mode imaging probes.
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DALTON TRANSACTIONS
·
2020
·Vol. 49
·期 43
·15433-15442
·
IF 4.174
Yini Mao,Zhiyi Wang,Rui Ye,Li Jiang,Shanshan Hu,Jun Yang
Octahedral [CaY]F2 crystals with an average particle size of 1 μm were synthesized via a mild one-step hydrothermal route without employing any surfactants. Various morphologies, including cubes, truncated cubes, truncated octahedrons, and spheres, were achieved via manipulating the amount of EDTA used, and a possible growth mechanism was proposed based on the surface energies of different crystal planes and the influence of the surfactant. XRD, SEM, EDS, TEM, HRTEM, and PL analysis were used to characterize the products. The effects of the morphologies and Li+ doping concentrations on the luminescence intensities of the [CaY]F2:Ce3+/Tb3+ phosphors were explored, and the strongest luminescence intensity is obtained when the sample is cubic with (100) crystal faces and the doping concentration of Li+ is 0.25 mol%. Additionally, multicolor emission (blue → aquamarine blue → green) was obtained from [CaY]F2:Ce3+/Tb3+ phosphors via adjusting the doping concentration of Tb3+, which resulted from the Ce3+ → Tb3+ energy transfer behavior; the energy transfer here happened through a dipole–dipole mechanism. This work may result in the as-synthesized phosphors having great application potential in many optoelectronic device fields, such as in displays and multicolor lighting.
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CRYSTAL RESEARCH AND TECHNOLOGY
·
2020
·Vol. 55
·期 8
·2000001
·
IF 1.169
Tingting Chen,Ke Li,Huibing Mao,Ye Chen,Jiqing Wang
The YVO 4 nanomaterials doped with the Yb 3+ /Tb 3+ /Eu 3+ ions and their mixture with the Au nanoparticles are synthetized with a classical sol-gel method. With the excitation of a 975 nm laser, both the doped YVO 4 sample and the corresponding mixture sample have a series of upconversion emission peaks of Eu 3+ and Tb 3+ , which includes the 5 D 0 → 7 F j transitions of the Eu 3+ ions and the 5 D 4 → 7 F j transitions of the Tb 3+ ions. The slope values of the log-log plots of laser power dependence for the upconversion emission intensities range from 1 to 2, which confirms that the upconversion process is a two-photon process. With the plasmon coupling, the slope value for the power dependence of the magnetic dipole transition 5 D 0 → 7 F 1 of the Eu 3+ ions decreases from 1.4 to 1.1, while it increases for other electric dipole transitions. Because of the plasmon coupling, the emission peak of the Eu 3+ at about 2.095 eV decreases significantly and almost cannot be observed. Meanwhile, the emission peak of the Tb 3+ at about 2.113 eV increases significantly and becomes the main emission peak in the yellow band. This phenomenon confirms that there is different mechanism for the magnetic and electric dipole emission with the plasmon coupling.
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ANALYST
·
2010
·Vol. 135
·期 8
·2139-2143
·
IF 3.272
Lun Wang,Cai-Ling Zhou,Hong-Qi Chen,Jing-Guo Chen,Jie Fu,Bo Ling
An efficient fluorescence energy transfer (FET) system between CePO4:Tb3+ nanocrystals as donor and 6-mercapto-5-triazole[4,3-b]-S-tetrazine as acceptor was built. CePO4:Tb3+ nanocrystals were synthesized in aqueous solutions, and characterized by transmission electron microscopy, electron diffraction pattern spectroscopy and spectrofluorometry. Under alkaline conditions, 6-mercapto-5-triazole[4,3-b]-S-tetrazine was generated by redox reaction of formaldehyde (HCHO) with 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole (AHMT) at room temperature. The degree of the overlap was effective for FET between the emission spectrum of CePO4:Tb3+ and the absorption spectrum of 6-mercapto-5-triazole[4,3-b]-S-tetrazine. Based on this system, a simple and sensitive fluorescence method for the selective determination of formaldehyde in aqueous solutions was developed. Under optimal conditions, the quenched fluorescence intensity increased linearly with the concentration of HCHO ranging from 1.03 × 10−9 to 1.03 × 10−5 mg mL−1 with a correlation coefficient of 0.9976. The limit of detection was 1.65 × 10−10 mg mL−1. Compared with several methods, the proposed method had a wider linear range, higher selectivity and sensitivity. Moreover, analytical application of the method was demonstrated by water samples.
研究领域:
分析化学
·
环境监测
·
纳米材料
·
生物传感
·
分子探针
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ADVANCED MATERIALS
·
2024
·
IF 27.4
Hang Yang,Yi Wei,Haonan Ju,Xinru Huang,Jun Li,Wei Wang,Dengfeng Peng,Dong Tu,Guogang Li
Elastico-mechanoluminescence technology has shown significant application prospects in stress sensing, artificial skin, remote interaction, and other research areas. Its progress mainly lies in realizing stress visualization and 2D or even 3D stress-sensing effects using a passive sensing mode. However, the widespread promotion of mechanoluminescence (ML) technology is hindered by issues such as high stress or strain thresholds and a single sensing mode based on luminous intensity. In this study, a highly efficient green-emitting ML with dual-mode stress-sensing characteristics driven by microscale strain is developed using LiTaO 3 :Tb 3+ . In addition to single-mode sensing based on the luminous intensity, the self-defined parameter ( Q ) is also introduced as a dual-mode factor for sensing the stress velocity. Impressively, the fabricated LiTaO 3 :Tb 3+ film is capable of generating discernible ML signals even when supplied with strains as low as 500 µst. This is the current minimum strain value that can drive green-emitting ML. This study offers an ideal photonic platform for exploring the potential applications of rare-earth-doped elastico-ML materials in remote interaction devices, high-precision stress sensors, and single-molecule biological imaging.
研究领域:
材料科学
·
光电子学
·
传感器
·
生物医学工程
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CHEMPHYSCHEM
·
2019
·Vol. 20
·期 6
·861-867
·
IF 3.077
Xiaojiao Kang,Wei Lü,Hongcheng Wang,Dongxiong Ling
A series of Ca 9 Ga(PO 4 ) 7 :Ce 3+ /Tb 3+ /Dy 3+ /Mn 2+ phosphors with tunable color, in which Ce 3+ acts as the sensitizer, was synthesized. Energy transfer (ET) from Ce 3+ to Tb 3+ /Dy 3+ /Mn 2+ was investigated in detail. Tb 3+ /Dy 3+ /Mn 2+ single-doped Ca 9 Ga(PO 4 ) 7 can exhibit green, yellow, and red emission, respectively. Incorporating Ce 3+ into a Tb 3+ /Dy 3+ /Mn 2+ single-doped Ca 9 Ga(PO 4 ) 7 phosphor can remarkably promote the luminous efficiency of the Tb 3+ /Dy 3+ /Mn 2+ ions. This enhancement originates from an efficient ET from Ce 3+ to Tb 3+ /Dy 3+ /Mn 2+ . The ET was validated by luminescence spectra, decay dynamics, and schematic energy levels. Moreover, the intensity ratio of red emission of Mn 2+ to violet emission of Ce 3+ was analyzed based on energy-transfer and lifetime measurements. In Ce 3+ -Tb 3+ , Ce 3+ -Dy 3+ , and Ce 3+ -Mn 2+ doped Ca 9 Ga(PO 4 ) 7 , the emitting color changed from violet to green, yellow, and red, respectively, which indicates the potential use of this new tunable phosphor in UV light-emitting diodes. Graphical Energy transfer from Ce 3+ to Tb 3+ /Dy 3+ /Mn 2+ in Ca 9 Ga(PO 4 ) 7 is investigated as a function of the Ce 3+ /Tb 3+ /Dy 3+ /Mn 2+ concentration and based on the photoluminescence emission/excitation spectra and decay curves. Through dual energy transfer, the emitting colors can change to green, yellow, and red from the initial blue color. The results suggest that the material is suitable for UV-white LEDs.
研究领域:
材料科学
·
发光材料
·
光学性质
·
固态化学
·
光子学
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SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2024
·
IF 4.3
Yuwei Guan,Yanhong Lu,Yun Wei
Cytochrome c (Cyt- c ) was commonly an intrinsic biomarker for a variety of cellular characteristics, such as respiration, energy levels, and apoptosis. Herein, a simple fluorescence sensor was constructed for the detection of Cyt- c in buffer and real serum samples. The carbon dots doped with Tb 3+ on the premise of 1-(2-pyridylazo)-2-naphthol (PAN) were fabricated and used as a dual-emission ratiometric fluorescent probe for detecting Cyt- c based on the internal filtering effect (IFE). As a fluorescent probe for ultra-sensitive detection, Cyt- c was quantitatively detected at different concentrations from 1 to 1000 nM. The fluorescent detection method for Cyt- c showed a good linear relationship from 1 to 50 nM, and the limit of detection (LOD) was 0.35 nM. In the recovery range of 101.27–103.39 % in human serum samples, the relative standard deviation (RSD) was less than 3.27 % (n = 3). In the end, the possible structures of CDs were predicted by DFT theoretical simulation calculations. All the results proved the ability of carbon dots as fluorescent probes to detect biomarkers and the application prospects in bioanalysis.
研究领域:
生物化学
·
分析化学
·
医学检测
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DALTON TRANSACTIONS
·
2023
·Vol. 52
·期 37
·13304-13315
·
IF 4
Yuhong Zhang,Bo Sun,Jian Liu,Ziyi Zhang,Hang Liu
A series of Tb3+/Mn4+ co-doped double-perovskite oxides Sr2LuTaO6 (SLT) phosphors are synthesized by a solid-state method. The results of structural characterization prove that the Tb3+ and Mn4+ ions are successfully doped into the SLT host. The photoluminescence excitation (PLE) and photoluminescence (PL) spectra of Sr2LuTaO6:Tb3+, Sr2LuTaO6:Mn4+ and Sr2LuTaO6:Tb3+/Mn4+ are illustrated in detail. Under ultraviolet (UV) excitation, bright green and red lights are obtained from the Sr2LuTaO6:Tb3+/Mn4+ phosphor. In particular, the emission intensity of Tb3+ ions in Sr2LuTaO6:Tb3+/Mn4+ is enhanced by the energy transfer (ET) process from Mn4+ to Tb3+. The thermal enhancement of Tb3+ ion radiation in Sr2LuTaO6:Tb3+/Mn4+ also proves the ET process (Mn4+ → Tb3+). In addition, the thermal enhancement of Tb3+ ion radiation and the thermal quenching of Mn4+ ion radiation in the Sr2LuTaO6:Tb3+/Mn4+ system can be applied to develop optical thermometry based on luminescence intensity ratio (LIR) technology. Therefore, the LIRs of Mn4+ (2Eg → 4A2g) and Tb3+ (5D4 → 7F5,4) are investigated in the temperature range from 313 to 573 K. The absolute sensitivity (Sa) and relative sensitivity (Sr) of the Sr2LuTaO6:Tb3+/Mn4+ phosphor are calculated. The maximum values of Sa and Sr are obtained from the LIR of Tb3+: 5D4 → 7F4 (570–599 nm) and Mn4+: 2Eg → 4A2g (625–705 nm). The maximum Sa is 10.18% K−1 at 543 K, and the maximum value of Sr reaches 1.98% K−1 at 543 K. These results confirm that the ET process from Mn4+ to Tb3+ contributes to increasing the temperature measuring sensitivity of the Sr2LuTaO6:Tb3+/Mn4+ phosphor. Therefore, the Sr2LuTaO6:Mn4+/Tb3+ phosphor has prospective potential in optical thermometry and provides advantageous guidance for designing high-sensitivity optical thermometers.
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