Analytical Methods
·
2014
·Vol. 7
·期 4
·1463-1470
·
IF 1.938
Yaoyao Jia,Qing Jin,Yan Li,Yuxiu Sun,Jianzhong Huo,Xiaojun Zhao
Metal–organic framework MIL-100(Fe) has high surface area, mesoporous cages, metal active sites and excellent water stability. These fascinating properties endow MIL-100(Fe) with the potential to extract organic dyes from environmental water samples. In the present work, MIL-100(Fe) is synthesized and applied as an adsorbent to remove three different types of dyes from aqueous solution in view of assessing the adsorption isotherms, kinetics and thermodynamics, desorption, and adsorbent regeneration. The adsorption for methylene blue and methyl blue follows a pseudo-second-order kinetics and fits the Freundlich model. The adsorption is a spontaneous process, but is controlled by different thermodynamic parameter changes. Moreover, MIL-100(Fe) could hardly adsorb isatin. Variables influencing the adsorption efficiency, such as adsorption time, temperature, solution pH, adsorbent dosage and salt concentration, are investigated. No remarkable effects of pH and ionic strength are observed for the adsorption of methylene blue and methyl blue on MIL-100(Fe). The used MIL-100(Fe) could be regenerated effectively and recycled without a significant loss of adsorption ability. The adsorption efficiency is about 100% for methylene blue and 52.1% for methyl blue, and the developed method is applied to remove two types of dyes in local water samples.
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APPLIED SURFACE SCIENCE
·
2025
·
IF 6.9
Xin Liang,Laishi Li,Yusheng Wu,Feng Liu,Yuzheng Wang
The efficiency of Fenton-like catalysts was critically affected by the rapid transfer of Fe 2+ /Fe 3+ , a process that was essential for the formation of active free radicals by H 2 O 2 . Herein, we synthesized CuS/Fe 3 O 4 @MIL-100(Fe) (CFM) ternary composites using hydrothermal and in-situ growth methods to enhance the degradation of oxytetracycline hydrochloride (OTC-HCl) in a Fenton-like photocatalytic system. The incorporation of CuS as a co-catalyst into the double iron-based system significantly enhanced photocatalytic activity, achieving a 95.31 % degradation efficiency for OTC-HCl within 50 min under optimized conditions. The catalyst had good reusability, has 86.64 % degradation efficiency after five magnetic recovery cycles, and still showed good catalytic performance in the presence of five different concentrations of common anions. Further analysis using active species quenching and electron paramagnetic resonance (EPR) experiments revealed the role of oxygen-containing radicals in the process. Liquid chromatography-mass spectrometry (LC-MS) and density functional theory (DFT) calculations provided OTC-HCl degradation pathways and intermediates. X-ray Photoelectron Spectroscopy (XPS) analysis indicated that CuS enhanced the performance of the bis-iron-based materials by improving the transfer efficiency of Fe 2+ /Fe 3+ and Cu + /Cu 2+ ions, which in turn accelerated the generation of reactive radicals from H 2 O 2 .
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Journal of Materials Chemistry A
·
2024
·Vol. 12
·期 21
·12712-12720
·
IF 10.7
Tianhao Yu,Peng Gao,Hong Du,Ling Dong
Metal–organic frameworks (MOFs) have recently been reported as promising catalysts for the oxygen evolution reaction (OER). Hence, we chose hydroxyl-rich 2,5-dihydroxyterephthalic acid as the ligand to prepare a novel MIL-100 and wrapped it on the NiCo-ZIF-67 surface to obtain an amorphous hollow material (NiCo-ZIF-67@Fe-MIL-100, denoted as NiCo-ZIF@MIL). The composite material presents a low overpotential (η ≈ 139 mV @ 10 mA cm−2), a small Tafel slope (119 mV dec−1) and great stability for the OER in 1 M KOH solution. Density Functional Theory (DFT) calculations show that the hydroxyl-rich structure, which accelerates OH− transfer and promotes the formation of the Co–O–Fe bridge, effectively reduces the reaction energy barrier (from 2.67 eV for NiCo-ZIF-67 to 2.08 eV for NiCo-ZIF@MIL). This work provides an important reference for the development of double-MOF materials.
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LANGMUIR
·
2024
·
IF 3.7
Liyun Zhang,Xin Wen,Qingxia Ming,Xue luo,Tianfeng He,Tian Chen,Minghang Jiang,Mengjun Wang,Lan Ma
With environmental pollution becoming more serious, developing efficient treatment technologies for all kinds of organic wastewater has become the focus of current research. In this work, the coaxial electrospinning technology was used to one-step fabricate a porous and underwater superoleophobic polyacrylonitrile nanofibrous membrane with an Fe-based metal–organic framework (MIL-100(Fe)). Benefiting from the synergistic effect of two jets, the nanofibers are smaller and denser, which prompt the exposure of more nanomaterial additives (MIL-100(Fe)). The BET surface area increased to 202.888 m2/g, and the membranes demonstrated outstanding underwater superoleophobicity. Moreover, compared with traditional blended matrix membranes by the single-axis method, separation of the modifier and membrane matrix material by coaxial methods also maintained excellent mechanical properties, which enhanced Young’s modulus 3.4 times (∼1.34 MPa). As a result, facing soluble dyes, the porous C-PAN/MIL-100(Fe) membrane can demonstrate outstanding and fast adsorptive property (the Qm of MB and CR reached 44.71 and 88.74 mg g–1, respectively). For oily emulsion, the hydrophilic and oleophobic nanofibrous reticular surface provided excellent separation performance (flux: 1124.0–1549.3 L m–2 h–1, R > 98%). Moreover, the porous and underwater superoleophobic C-PAN/MIL-100(Fe)-0.5 membrane can synchronously purify the dye/oil mixture emulsions by one-step filtration. Based on the above performance, we believe that the modified nanofibrous membrane prepared by one-step coaxial electrospinning technology can promote more studies of the development of membrane preparation technology in the field of oily wastewater treatment.
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2025
·
IF 9
Yan Zhu,Jun Zhang,Shikui Jia,Lei Wu,Shihao Wang,Wenwen Wang,Yaoyao Zhang,Feng Xu,Wei Liu
Solar interface evaporator has been played an increasingly important role for sewage treatment and desalination, etc. due to its processability, comprehensive application. However, for instance, energy collection rate and utilization efficiency for solar interface evaporation has still an urgent need for improvement. Hence, a series of MXene/ reduced carboxylated carbon nanotubes (RCNT)/ Polyvinyl alcohol (PVA) (MCP) solution were directional frozen and then dried by low-temperature vacuum method to successfully prepare a bionic lotus-like multi-layer PVA-based aerogel. Particularly, when the component ratio of the MXene: RCNT: PVA was 6: 24: 70, the water and brine evaporation rate of M 6 /C 24 /P 70 composite aerogel reached respectively 3.35 kg·m −2 ·h −1 and 2.51 kg·m −2 ·h −1 , while for the PVA aerogel were just 0.63 kg·m −2 ·h −1 and 0.37 kg·m −2 ·h −1 . Importantly, the evaporation efficiency for the M 6 /C 24 /P 70 can achieve 132.7 %, which exceeds that of most of evaporators in the published reports and the phenomenon was defined firstly self-accelerating evaporation. This work not only explores the preparation strategy for the distinguished biomimetic solar-derived evaporator, but also broadens the functional application scope of PVA-based aerogels.
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DALTON TRANSACTIONS
·
2025
·
IF 3.3
Yanjia Zhou,Xiao-Dong Tang,Jingjing Li,Da-Yong Qing,Hong Wang
MIL-101(Cr) and MIL-100(Fe) are both representative MIL-type Metal-Organic-Frameworks (MOFs) materials, renowned for their large specific surface areas and size-tunable characteristics, making them suitable candidates for Li+ extraction from lithium-containing solvent. By introducing -NH2 functional groups and using LiNO3 as both a template and mineralizer, the functionalized MOF materials Li/NH2/MIL-101(Cr) and Li/NH2/MIL-100(Fe) were synthesized. Following modification, their Li+ adsorption capacities were increased, reaching 43.58 and 38.22 mg/g, respectively. The dosage of mineralizer, initial Li+ concentration, adsorbent dosage, solution pH value, and temperature all have an impact on the adsorption capacity of adsorbents. In addition, through the establishment of the pseudo-first-order kinetic model, pseudo-second-order kinetic model, as well as Langmuir and Freundlich thermodynamic models, it can be known that the adsorption of the materials belonged to monolayer chemisorption, and the adsorption process was exothermic. Furthermore, both adsorbents showed good reusability, retaining over 85% of their initial adsorption capacity after four adsorption-desorption cycles, highlighting their practical applicability in lithium recovery processes. In Mg-Li mixed solution systems, both materials exhibited exceptional Li+ selectivity. At a low Mg2+/Li+ ratio of 3, the separation factor (α) exceeded 80; even at a high Mg2+/Li+ ratio of 10, α remained near 50. Additionally, in systems with coexistence of multiple interfering ions, the distribution coefficient (Kd) followed the order: Li+ ≫ Mg2+ > Ca2+ > Na+ > K+. In the mixed systems, Li/NH2/MIL-101(Cr) and Li/NH2/MIL-100(Fe) exhibited certain separation effect for Li+ against competing cations.
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ENERGY
·
2025
·
IF 9.4
Delin Lyu,Xuanjie Cui,Yuanqing Qu,Zhengyang Liu,Xiangning Liu,Zhen Huang,Dong Han
Increasing the compression ratio in spark-ignition (SI) engines improves thermal efficiency but raises knock risk. Knock resistance is measured by Research Octane Number (RON) in Cooperative Fuel Research (CFR) engines under standard conditions, which differ from modern SI engines. The CFR engine's knock sensor, fitted with a low-pass filter, fails to accurately detect high-frequency knock oscillations, making conventional RON inadequate for assessing knock resistance in modern engines. To address this, the CFR engine was modified by replacing the knock sensor with a cylinder pressure sensor for direct combustion pressure measurement and upgrading the carburetor to electronic fuel injection. Under stoichiometric conditions, the Maximum Amplitude of Pressure Oscillation (MAPO) and Integral of Modulus of the Pressure Oscillation (IMPO) methods were applied to evaluate PRF blends with RONs of 88–100. Strong correlations were observed between the fuels RON and both IMPO and MAPO measurements, with coefficients of determination of 0.98 and 0.99, respectively. This study also analyzed error sources and quantified measurement inaccuracies in both methods, with IMPO showing lower absolute error of RON and variability. To verify the reliability of the IMPO and MAPO methods in evaluating high-octane fuels, particularly those with RON >100, these methods were applied to test TRFs and oxygenated fuel blends with RONs of 94–108. Results showed deviations from conventional measurements; however, for fuels with RON >100, both methods effectively distinguished fuel knock resistance capacity. Additionally, IMPO and MAPO captured the knock resistance improvements for the addition of ethanol and 2-MF in gasoline blends.
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JOURNAL OF HAZARDOUS MATERIALS
·
2024
·
IF 12.2
Chunhui Zhang,Yue Gao,Cuiping Wang,Hongwen Sun
Here, we present a first investigation of the inhibition mechanism of surfactant Triton X-100 (TX-100) on the oxidation degradation of polycyclic aromatic hydrocarbons (PAHs) in site soil aggregates using sodium citrate assisted Fe 2+ -activated persulfate (SC/Fe 2+ /PS). First, TX-100 was not only competed the adsorption sites of soil aggregates with PS, but also consumed PS, which inhibit the PAHs remediation rate in the TX-100 elution followed by the SC/Fe 2+ /PS oxidation system from 55.6% in the oxidation system to 50.3%. Furthermore, in the oxidation followed by elution system, PAHs was adsorbed on the iron minerals produced during the oxidation, which would be form a bound PAHs that was difficult to react with PS, and then re-eluted to the soil by the TX-100. Additionally, it was found that the oxidative and the elution efficiency of PAHs exhibited negative correlations with aggregate particle sizes. Finally, soil microorganism communities were more strongly changed by SC/Fe 2+ /PS oxidation and PAHs concentration than that of TX-100 elution, with obvious alterations bacteria than fungi, the effects of SC/Fe 2+ /PS and PAHs concentration on microorganism communities were opposite. This study provided a proof of regulating mechanisms for the site soil remediation using surfactants combined with the iron-PS system. Environmental Implications Surfactants may have inhibitory effects in advanced oxidative systems on the removal of PAHs and may alter soil microorganism diversity. It is necessary to comprehensively analyze the intrinsic regulatory mechanisms, and the correlation between the remediation process and soil microbial community structure of surfactants affecting the remediation efficiency of PAHs in site soil aggregates. This work comprehensively discussed the controlling mechanisms of surfactants affect the oxidation remediation of PAHs in the site soil and providing new insights for the design of the remediation technologies for the soil polluted with PAHs in the future.
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ADVANCED FUNCTIONAL MATERIALS
·
2025
·
IF 19
Yan Zhang,Xiaowei Chen,Wei Li,Baoyi Wang,Qian Zhang,Zhuo Zhao,Yafei Wang,Ying Guan,Yongjun Zhang
The freezing of the dispersion medium causes a huge deterioration in mechanical performance, conductivity, and optical properties of gel materials, limiting their functionality in low-temperature environments such as outer space, deep sea, and polar areas. Here, a deep eutectic solvent is developed using 2-methyl-1,3-propanediol as a hydrogen bond donor and choline chloride as a hydrogen bond acceptor, achieving remarkably low freezing temperature of −107.7 °C, while also exhibiting transparency, stability, and ionic conductive capabilities across a broad temperature range. Utilizing this solvent as a dispersion medium, microphase-separated eutectogels are prepared via the copolymerization of acrylamide and acrylic acid. Retaining its stretchability, high toughness, and energy dissipation capability at −100 °C, the gel thereby serves as an exceptional materials for impact resistance, vibration damping, and temperature sensing. Finally, the development of 2-methyl-1,3-propanediol based solvent and gel materials is expected to offer a new solution for cryo-science and antifreeze applications.
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MATERIALS & DESIGN
·
2022
·
IF 9.417
Zhiming Hu,Caina Xu,Yonghao Liang,Taiyuan Liu,Huayu Tian,Yingchao Zhang
Compared with visceral cancers, breast cancer is epidermal and can be efficiently eliminated by photoacoustic imaging (PAI)-guided cancer therapy. In this study, we developed multifunctional nanoparticles (DMTH NPs) by loading doxorubicin (DOX) into MIL-100, which were modified with tannic acid (TA) and hyaluronic acid (HA) using a simple and convenient method. MIL-100 (Fe) in DMTH NPs allowed for chemodynamic therapy by converting endogenous hydrogen peroxide (H 2 O 2 ) into •OH through a Fenton-like reaction to assist DOX in killing cancer cells. DMTH NPs had high DOX loading efficiency for chemotherapeutic function and had the ability for photoacoustic imaging (PAI) and photothermal therapy (PTT) after being modified by TA. Specifically, DMTH NPs targeted tumors and had low toxicity in vivo . Ultimately, the released DOX and •OH cooperated in killing MCF-7 cells effectively in vitro . The enhanced and precise breast cancer treatment was achieved using a PAI-guided chemodynamic/chemo/photothermal synergistic therapy under laser irradiation in vivo . Overall, this work presented an innovative strategy for designing multifunctional nanoparticles for effective imaging-guided combination therapies to combat breast cancer.
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JOURNAL OF HAZARDOUS MATERIALS
·
2017
·
IF 6.065
Shuzhi Liu,Min Yang,Yijiang Liu,Hongbiao Chen,Huaming Li
A new colorimetric fluorescent probe (MCy) for CN − is designed and synthesized based on triphenylimidazole-hemicyanine dyad. The probe shows high selectivity towards CN − in 100% aqueous solution even in the presence of other competitive anions such as F − , Cl − , AcO − , NO 2 − , H 2 PO 4 − , I − , SCN − , SO 4 2− , NO 3 − , HCO 3 − , Br − and S 2− . Upon nucleophilic addition of CN − to the indolium group, the probe displays large blue-shift in UV–vis spectrum and remarkable “turn-on” fluorescence owing to the disruption of intramolecular charge transfer. Meanwhile, the probe also undergoes a naked-eye discernible color change from orange to light pink in the sunlight as well as an obvious fluorescence color change from non-emissive to bright blue under a UV lamp. The detection limit of CN − in aqueous solution can be as low as 20.6 nM, which is much lower than the permissible level of CN − in drinking water according to the WHO. In addition, the probe has been successfully used to determine CN − in real water samples as well as to fabricate test paper kit for CN − detection.
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Chemical Engineering Journal Advances
·
2023
·
IF 0
Mengsi Cheng,Ying Fang,Zhaoguang Yang,Xinghao Liu,Bo Qiu,Tong Zhang,Haipu Li,Wenbo Zhao
MIL-100(Fe) was modified by amino groups (MIL - 100(Fe) - NH 2 ) to enhance the removal of antimonate (Sb(V)) with low concentration (50−200 μg/L) from natural water through batch adsorption experiments. With the initial Sb(V) concentration up to 200 μg/L, the residual Sb(V) concentration after treated by MIL - 100(Fe) - NH 2 was only 3.52 ± 0.131 μg/L, lower than the drinking water standards (5 μg/L) in China, while that was much higher (94.2 ± 3.52 μg/L) after pristine MIL-100(Fe) treatment. Based on results of XPS analysis, and adsorption kinetics and isotherms, we concluded that Sb(V) substituted the terminal −OH groups of MIL-100(Fe) to form inner-sphere complexes by coordination reactions with Fe nodes and be adsorbed by hydrogen bonding as well. The grafted amino groups (−NH 2 ) adsorbed Sb(V) by hydrogen bonding and facilitated the coordination reactions between Sb(V) and Fe nodes. The higher K L value (0.0116 ± 0.00,118 L/μg) obtained by fitting with the Langmuir isotherm model, while that of unmodified MIL-100(Fe) was 4.74 × 10 −4 ± 5.85 × 10 −5 L/μg, also confirmed that the −NH 2 groups greatly enhanced the affinity between MIL-100(Fe) and Sb(V). Furthermore, MIL - 100(Fe) - NH 2 still worked nicely in a wide pH range (2 − 12), with varied ionic strength (0.05 µmol/ L −1.5 mol/L), coexisting ions (CO 3 2− , NO 3 − , SO 4 2− , Cl − , H 2 PO 4 − ), and even in the real water bodies. Additionally, MIL - 100(Fe) - NH 2 exhibited good reusability and low Fe leaching (99.92 μg/L). We hope MIL - 100(Fe) - NH 2 become a candidate for effective removal of Sb(V), even other heavy metals from natural waterbodies.
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