JOURNAL OF CHEMICAL AND ENGINEERING DATA
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2023
·
IF 2.6
Jie Yang,Huan Zhou,Jie Li,Cunbing Xu,Yifan Li,Sifan Wang,Jiangbo Chen
The solid–liquid phase equilibria of the Ba2+//Cl–, S2–, and OH––H2O quaternary system and its three subternary systems at 298.15 K are studied via the isothermal solubility phase equilibrium method. The solubility data, liquid properties of density and pH, and phase diagrams of the ternary and quaternary systems are obtained. Solid species of Ba(OH)2·8H2O, BaCl2·2H2O, Ba(OH)Cl·2H2O, and BaS exist in the quaternary system and corresponding ternary systems at 298.15 K. The four solid species build up two invariant points, one disproportionate and one proportionate, and four phase regions. The largest phase area is covered by Ba(OH)·8H2O, and the lowest water point is the proportionate invariant point saturated by BaCl2·2H2O, Ba(OH)Cl·2H2O, and BaS.
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高影响因子
JOURNAL OF CHEMICAL AND ENGINEERING DATA
·
2023
·
IF 2.6
Xudong Yu,Xia Feng,Shan Feng,Yun Peng,Ying Zeng
The solid–liquid equilibria of the quinary system Li+, K+, Mg2+//Cl–, B4O72––H2O at 323.2 K were investigated by the isothermal dissolution method. The solubility, refractive index, and density of the system were determined, and the corresponding space phase diagram, planar projection diagram, water content diagram, and density/refractive index vs composition diagrams saturated with MgB4O7 are constructed based on the experimental data. The result shows that there are double salts of lithium carnallite (LiCl·MgCl2·7H2O) and carnallite (KCl·MgCl2·6H2O) formed in the system. The space phase diagram consists of five invariant points, 16 isothermal solution curves, and eight crystalline regions (Li2B4O7·3H2O, K2B4O7·4H2O, KCl, MgB4O7·9H2O, KCl·MgCl2·6H2O, MgCl2·6H2O, LiCl·MgCl2·7H2O, LiCl·H2O). Under the saturation of salt MgB4O7, the crystalline region of Li2B4O7·3H2O is the largest in the planar projection diagram of this system, and the solubility of LiCl is the largest. A comparison of planar projection diagrams (under the saturation of salt MgB4O7) of the system at 273.2 and 323.2 K shows that the crystallization regions of Li2B4O7·3H2O, KCl·MgCl2·6H2O, LiCl·MgCl2·7H2O, and LiCl·H2O increase along with the temperature, while those of K2B4O7·4H2O and KCl decrease. The results show that low temperature is conducive to the extraction of potassium in the form of K2B4O7·4H2O and KCl and has less entrainment loss; high temperature is beneficial to the precipitation of Li2B4O7·3H2O.
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Crystals
·
2023
·Vol. 13
·期 6
·983
·
IF 2.7
Hao Zhao,Zishuai Jiang,Chengyu Wang,Yudong Li
The research on rapid and efficient detection of microplastics in water is still in its early stages. Fluorescence feature recognition represents an important and innovative approach to microplastic detection. While carbon quantum dots have been widely used in various environmental detection methods, their use for detecting microplastics in water environments has been rarely reported. In this study, N and Cl co-doped carbon quantum dots were synthesized via a hydrothermal method. The heteroatom doping process endowed them with blue luminescence properties, and their adsorption for microplastics was improved through the introduction of positive and negative charges and intermolecular forces. By utilizing a combined mechanism of fluorescence and Rayleigh scattering, the detection of polystyrene microplastics with three different particle sizes was achieved. In the detection process, it exhibits excellent light stability. Notably, the nano-polystyrene exhibited a good nonlinear relationship within the range of 0.01 g/L to 0.001 g/L, with R2values of 0.923 and 0.980 and a detection limit of 0.4 mg/L. These findings provide a novel approach for the detection of nano microplastics.Keywords:lignin;carbon quantum dots;co-doping;microplastic detection
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ACS Applied Nano Materials
·
2023
·
IF 5.9
Yanchao Yu,Yuan Gao,Wenjuan Wang,Hanyang Chen,Yuzhe Yun,Seeram Ramakrishna,Jun Zhang,Yun-Ze Long
Traditional detection methods usually use a spectrometer, which requires a professional tester to operate and is not convenient to carry around. Herein, we designed a 5G smartphone-based portable test sensor that uses a CsPbBr3 composite fibrous membrane prepared by a one-step in situ growth method as the test paper, and the test is realized by taking pictures with the smartphone. This portable detection method requires only one drop of liquid to be detected (<25 μL), which is superior to many detection systems that require a large amount of liquid to be detected (>1 mL). Moreover, the detection sensitivity can reach 0.1 ppm, which is more sensitive than the CsPbBr3 composite fiber membrane prepared by the conventional encapsulated method. In addition, this CsPbBr3 composite fiber membrane is reusable and can still achieve highly sensitive detection with a single drop after 100 uses. This smartphone-based portable test sensor is small in size and easy to use and can be used at home or outdoors anytime and anywhere.
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INORGANIC CHEMISTRY
·
2023
·
IF 4.6
Mei Hu,Nuerbiye Tuerhong,Zhaohui Chen,Qun Jing,Ming-Hsien Lee
Enthusiasm for the exploration of nonlinear alkali metal borates remains high. Focusing on the Li–B–O–X (X = Cl and Br) system, two examples of noncentrosymmetric borates, Li3B8O13Cl and Li3B8O13Br, were obtained using a high-temperature solution method under vacuum conditions. Structurally, the Li3B8O13X crystals exhibit two independent alternately arranged three-dimensional B–O network structures formed by the basic building block unit B8O16. The performance measurements demonstrate their short ultraviolet cutoff edges. The theoretical calculation indicates that the BO3 units dominate the contribution to their large optical anisotropy with the birefringence, 0.094 and 0.088@1064 nm for Li3B8O13Cl and Li3B8O13Br, respectively.
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PubMed
高影响因子
POLYMER
·
2022
·
IF 4.432
Ling-jie Zhang,Jian Liu,Long-bo Luo,Xiang-yang Liu,Xu Wang
The combination of high breakdown strength and low dielectric loss has always been a challenge for the preparation of high energy storage density dielectric films . In this work, in order to optimize their dielectric performances, we develop a series of all-organic PI composite films by introducing perchlorinated hexa-peri-hexabenzocoronene (Cl-HBC) molecules with a concentration (0.01–0.1mol%) into PI film. Even at an ultra-low concentration, the Cl-HBC molecule with a quasi-two-dimensional structure would successfully induce the in-plane orientation of PI macromolecular chains and reduce their orientation confusion and molecular cavity. Thus, the existence of Cl-HBC obviously limits the chain mobility of PI in PI-Cl-HBC film under the electric field, which is supposed to reduce the dielectric loss of resulted films. Moreover, Cl-HBC molecules are equipped with a low Lowest Unoccupied Molecular Orbital (LUMO) of about −3.52eV and could work as an electron trap and block the conduction of electrons in the PI composite film. Here, the breakdown strength of the composite film was improved from 442 kV/mm (pure PI) to 539 kV/mm and the dielectric loss was reduced to 0.002. To our best knowledge, it is the first time to significantly enhance the dielectric strength and largely reduce its dielectric loss simultaneously by preparing PI composite film. Meanwhile, compared with pure PI, the energy storage density of composite film increases by 43% and 96% at room temperature and 150 °C, respectively.
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Journal of Materials Chemistry C
·
2022
·Vol. 10
·期 22
·8815-8823
·
IF 8.067
Runda Guo,Weizhuo Zhang,Xin Li,Linyuan Lian,Hongting Chen,Chencheng Peng,Liang Sun,Shiyuan Liu,Jianbing Zhang,Lei Wang
Blue emitting CsPb(Br–Cl)3 perovskite nanoparticles (NPs) play an important role in optoelectronic applications. However, the synthesis of stable blue perovskite NPs with excellent photoluminescence quantum yield (PLQY) is still challenging. Here, a new strategy of conveniently using strontium halides and amine halides for simultaneous doping and surface passivation of CsPb(Br–Cl)3 perovskite NPs is proposed. Through experimental studies and calculations, it is found that divalent Sr2+ cations can partly replace the B-site Pb2+ ions in the lattice structure of perovskite NPs and cause a slight lattice contraction, not only passivating the defects but also providing chances for bluer NPs. As a result, the deep-blue CsPb(Br–Cl)3 perovskite NPs with PL emission centered at 455 nm and a high PLQY of 96% were obtained. In addition, a white light-emitting device (WLED) with the NPs as an emissive layer exhibited a maximum power efficiency of 76 lm W−1 with Commission International de L’Eclairage (CIE) coordinates of (0.33, 0.34). These findings provide fundamental insights into the excited state dynamics of colloidal cesium lead halide (CsPbX3) perovskite NPs that can be used as components of LEDs for practical applications.
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MATERIALS RESEARCH BULLETIN
·
2022
·
IF 5.6
Yi Wang,Shaoqi Zhang,Yuxiang Yan,Hengdong Ren,Jian Chen,Lizhe Liu,Xinglong Wu
A series of flower-like BiOCl x Br 1-x (x = 0∼1) with different Cl − doping contents were prepared via a simple co-precipitation method. Experimental results show that BiOCl 0.2 Br 0.8 (20 mg) can decompose tetracycline hydrochloride (20 mg/L) of ∼100% within 30 min, which is far higher than those of the previously reported BiOCl and BiOBr. Microstructural and spectroscopic characterization demonstrates that Cl − doping can effectively change the growth orientation of the layered BiOCl x Br 1-x nanosheets to expose more (102) active surfaces. Density of states calculations and radical trapping experiments reveal that strong coupling between the electronic states of multi-anions adjusts the band structure, which improves light absorption and generation of main active species ⋅O 2 − . Meanwhile, strong polarization caused by anionic doping also promotes separation and migration of the photogenerated carriers to different positions of the active surface. As a result, the photocatalytic activities are improved largely and optimal in BiOCl 0.2 Br 0.8 .
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Nanomaterials
·
2021
·Vol. 11
·期 12
·3242
·
IF 5.076
Yu Sun,Jin Chen,Fengchao Wang,Yi Yin,Yan Jin,Jun Wang,Xiaogai Peng,Ruiyi Han,Canyun Zhang,Jinfang Kong,Jing Yang
Nowadays, Mn-doping is considered as a promising dissolution for the heavy usage of toxic lead in CsPbX3perovskite material. Interestingly, Mn-doping also introduces an additional photoluminescence band, which is favorable to enrich the emission gamut of this cesium lead halide. Here, a solution spraying strategy was employed for the direct preparation of CsPbxMn1−x(Br,Cl)3film through MnCl2doping in host CsPbBr3material. The possible fabrication mechanism of the provided approach and the dependences of material properties on Mn-doping were investigated in detail. As the results shown, Pb was partially substituted by Mn as expected. With the ratio of PbBr2:MnCl2increasing from 3:0 to 1:1, the obtained film separately featured green, cyan, orange-red and pink-red emission, which was caused by the energy transferring process. Moreover, the combining energy of Cs, Pb, and Mn gradually red-shifted resulted from the formation of Cs-Cl, Pb-Cl and Mn-Br coordination bonding as MnCl2doping increased. In addition, the weight of short decay lifetime of prepared samples increased with the doping rising, which indicated a better exciton emission and less defect-related transition. The aiming of current work is to provide a new possibility for the facile preparation of Mn-doping CsPbX3film material.Keywords:MnCl2doping;CsPbxMn1−x(Br,Cl)3;thin films;solution spraying
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CHEMICAL PHYSICS LETTERS
·
2021
·
IF 2.328
Xi Wang,Jiali Yan,Hao Wang,Daoli Yang,Jinli Zhai,Xiaoya Gao,Chao Gong,Wenjie Zhu,Yongming Luo
To use solar energy effectively, BiOX (Cl, Br, I) nanosheets with reasonable band gap structure were prepared by ultrasonic assisted hydrothermal method. The prepared BiOX (Cl, Br, I) nanosheets removed 90% of CBZ within 5 min, showing rapid degradation kinetic of 0.3858 min −1 . The improved photocatalytic activities can be due to the reduced recombination of photoinduced electron-hole pairs, strong visible-light absorption ability, large surface area and pore. Radicals experiments indicated that the BiOX (Cl, Br, I) generated main holes ( h + ) and minor electrons ( e − ) to degrade CBZ. These results demonstrated the good feasibility of BiOX (Cl, Br, I) nanosheets in the degradation of CBZ under simulated solar light irradiation.
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ACS Omega
·
2020
·
IF 2.87
Hao Xu,Lijie Huang,Mingzi Xu,Minghui Qi,Tan Yi,Qi Mo,Hanyu Zhao,Chongxing Huang,Shuangfei Wang,Yang Liu
1-Ally-3-methylimidazolium chloride ([Amim]Cl), dimethyl sulfoxide (DMSO), and CaCl2 were selected to construct dissolution systems to produce value-added products from pretreatment of waste corrugated cardboards (P-WCCs). The dissolution behaviors of P-WCCs before and after ball milling were studied in different dissolution systems. The regenerated cellulose films were quickly and efficiently prepared via dissolving, regenerating, and pressurized drying. When 4 wt % waste corrugated cardboard was dissolved in [Amim]Cl for 4 h at 90 °C, the regenerated cellulose films featured tensile strengths as high as 59.00 MPa. Adding 40% DMSO and 2 wt % CaCl2 increased the tensile strength of the film to a maximum value of 85.86 MPa. This demonstrates that DMSO improves the ability of WCC to dissolve in ionic liquids; Ca2+ improves the tensile strength and thermal stability of the regenerated cellulose film but reduces its transparency. This work provides a new, simple, and highly efficient way to use WCCs for packaging and wrapping.
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JOURNAL OF NANOPARTICLE RESEARCH
·
2020
·Vol. 22
·期 6
·1-11
·
IF 2.132
Zhao Yubin,Xie Cong,Song Yuxiang,Yang Ping
The photoluminescence (PL) of doped ions is depended strongly on the position of the ion in the substrate. Ion doping endows semiconductor nanocrystals with novel properties. In this paper, Mn:CsPb(Cl/Br) 3 nanocrystals (NCs) with different halogen ratios were obtained by one-pot hot injection synthesis and halogen ion exchange. The emission of Mn 2+ from 4 T 1g - 6 A 1g d-d transition was observed in the case of changing the molar ratio of Cl/Br for Mn:CsPb(Cl/Br) 3 NCs. In the case of a Cl/Br ratio of 4/1, the PL peak of perovskite became weak and Mn 2+ emission was enhanced. After I − ion exchange, the emission of Mn 2+ was observed in Mn:CsPb(Cl/Br) 3 with Cl/Br ratio of 1/4, in which the PL efficiency of the nanocrystals reached 55.74%. Thus, Cl − ions increase the band gap and effectively promote the emission of Mn 2+ . At the same time, the morphology of the samples after ion exchange always remains cube. The lifetimes of the nanocrystals were short aged with increasing Cl − ions and prolonged with increasing I − ions. Because these Mn:CsPbX 3 (x = Cl, Br, I) NCs with different halogen ratios revealed highly stabile blue to red emission, the nanocrystals would be utilizable for further applications.
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危险品化学品经营许可证（带存储）