APPLIED CATALYSIS B-ENVIRONMENTAL
·
2019
·
IF 14.229
Dandan Zhu,Qixing Zhou
In this study, a series of NCN/BiWO (NCN = N-doped graphitic carbon nitride , BiWO = Bi 2 WO 6 ) were fabricated successfully, which were characterized by XRD, TEM, FTIR, BET, UV–vis spectrometry, XPS and PL. Under visible light irradiation, the optimum mass ratio of 60 % NCN/BiWO could reach 93.1 % removal efficiency of phenol within 5 h, which was about 6.9 times as that pure Bi 2 WO 6 . And the degradation rate constant of 60 % NCN/BiWO (2.6726 min -1 ) was about 18.5 times as that of pure Bi 2 WO 6 (0.1442 min -1 ). According to the result of UV–vis absorption spectra, VB-XPS spectra and photoelectrochemistry performance, the photocatalytic mechanism of 60 % NCN/BiWO was revealed, indicating that the narrow band gap of 60 % NCN/BiWO is the main factor on the high photocatalytic activity . The stable and recyclable properties also were done, showing highly suitable for practical application.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2020
·
IF 7.489
Jingwei Huang,Tingting Liu,Rongfang Wang,Mingyi Zhang,Lei Wang,Houde She,Qizhao Wang
Cobalt oxide is an excellent water oxidation cocatalyst used in photoelectrochemical (PEC) water splitting field. Finding a facial way to load cobalt oxide on a semiconductor anode is important to effectively realize PEC water splitting on a large scale. In this work, a simple impregnation and calcination method is developed to fabricate CoO x /BiVO 4 anode. The constructed CoO x /BiVO 4 anode provides a photocurrent of 3.1 mA cm −2 at 1.23 V vs. RHE, about 2.8 times that of BiVO 4 anode (1.1 mA cm −2 ). Furthermore, both the charge separation and injection efficiency are improved by loading CoO x nanoparticles onto the BiVO 4 layer. Importantly, input voltage–output current characteristic curves are used for the first time to prove the formation of p-n junction between CoO x and BiVO 4 , which benefits to the separation of photogenerated holes and electrons. All results indicate that the impregnation and calcination method is efficacious for facile fabrication of CoO x /BiVO 4 photoanode with high performance.
研究领域:
材料科学
·
能源科学
✓ 已验证
DOI
高影响因子
ACS Sustainable Chemistry & Engineering
·
2022
·
IF 9.224
Tao Ding,Yishuang Wu,Xun Zhu,Guiying Lin,Xun Hu,Hongqi Sun,Yong Huang,Shu Zhang,Hong Zhang
Co-doping of heteroatoms into the support of metal-supported catalysts is a prevalent method to improve the catalytic performance by adjusting metal–support interactions. This paper investigated the catalytic performances of Ru supported on biomass-derived char (Ru@Char), N-doped char (Ru@N-Char), and N,P-co-doped char (Ru@NP-Char) in the emerging lignin-first depolymerization for both poplar (hardwood) and pine (softwood) samples, with an emphasis on the production of phenolic monomers. Various characterizations of the prepared catalysts showed that the codoping of N,P not only facilitated the formation of micropores in the char but also introduced weak and moderate acid sites. Furthermore, the sizes of Ru nanoparticles on the codoped char became smaller, and the proportion of metallic Ru species was increased, resulting from electron transfer from Ru to the codoped char. The yields of the phenolic monomers from poplar and pine over Ru@NP-Char were as high as 57.98 and 17.53 wt % Klason lignin, respectively, which were improved by factors of 1.4–2.5 in comparison to Ru@Char and Ru@N-Char. Full delignification during the depolymerization of both poplar and pine was also achieved over Ru@NP-Char.
研究领域:
催化化学
·
生物质能
·
材料科学
✓ 已验证
DOI
高影响因子
ACS Applied Nano Materials
·
2023
·
IF 5.9
Zhan Cheng,Hongmin Zhu,Hanyang Ji,Zhenyu Yuan,Fanli Meng
N-butanol, a standard volatile organic compound (VOC) gas with toxicity and flammability, seriously endangers human life and health. It is imperative to achieve rapid and trace detection of n-butanol. Oxygen vacancies have been proven to be an essential factor for VOC gas adsorption at the surface of metal oxide semiconductor (MOS) gas sensors. In view of the above, BiFeO3 (BFO) nanoparticles with abundant oxygen vacancies were prepared via simple sol–gel and annealing. Crystal structure, morphology, and compositions were systematically analyzed by a series of characterizations (XRD, SEM, HRTEM, EPR, and XPS). The response of the synthesized BFO-2 sensor reached 19.37 to 100 ppm n-butanol with a detection limit of 0.28 ppm at an optimal operating temperature of 280 °C. In addition, BFO-2 also has a fast response time, good stability and repeatability, and favorable selectivity to n-butanol. It is crucial to systematically explore the excellent selectivity of BFO sensors due to their abundant oxygen vacancies and large intrinsic crystal defects. Herein, adjusting the calcination temperature is one constructive strategy to tune the oxygen vacancy, which would prompt the gas sensing performance of BFO sensors to n-butanol.
研究领域:
材料科学
·
传感器技术
·
环境监测
✓ 已验证
DOI
高影响因子
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2022
·Vol. 169
·期 5
·053505
·
IF 4.386
Yanfang Song,Jinxiong Wu,Jiliang Zheng,Yiwei Sun,Andrei Ivanets,Guangming Du,Xintai Su
The doping of multiple heteroatoms can improve the electrochemical properties of carbon substrates. However, in existing studies, carbon, iron and nitrogen sources are generally mixed directly and then pyrolyzed for secondary activation. This tends to form aggregates of metal particles or metal oxides and requires the consumption of large amounts of alkali and energy. Therefore, there is an urgent need to develop an environmentally friendly technology capable of uniformly doping iron and nitrogen into carbon materials. In this work, porous Fe–N–C composites were prepared at 600 °C using potassium humate (HA-K) obtained from cotton straw by low-temperature pyrolysis as the carbon source, and urea-iron complexes formed by the pre-coordination of urea and Fe as the iron and nitrogen sources. In the absence of secondary activation, the best sample Fe-NHPC-2 had a good mesoporous structure with high specific surface area (889. 01 m2 g−1). It had a high specific capacitance of 256.8 F g−1 at a current density of 0.5 A g−1. The capacitance retention was 92.6% after 10,000 cycles at a current density of 10 A g−1. In the symmetric supercapacitor application, the energy density reached 33.16 Wh kg−1 when the power density was 600.2 W kg−1.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
·
2020
·
IF 3.807
Chenyang Shi,Bo Hong,Xueya Zhang,Qian Xiang,Zhian Zhang,Kai Zhang,Jing Fang,Yanqing Lai
Lithium-sulfur batteries are considered to be the most promising high-energy-density storage system, yet the dissolution of polysulfides during the charging process limits the utilization, and cycle stability of active materials, which affects the practical application of lithium-sulfur batteries. Herein, a poly( N -methylaniline) (PMAn) coating film is formed in situ on the cathode surface by electrochemically polymerizing the monomer of N -methylaniline(MAn) contained in the electrolyte during film formation process. The PMAn coating film on the surface of the cathode can prevent the dissolution of polysulfide, then reduce the loss of active material, and slow the oxidation of polysulfide by lithium nitrate , resulting in improved cycle stability. As a result, the lithium-sulfur battery with 0.5 wt% MAn render an initial discharge specific capacity of 1224 mAh/g and a capacity retention of 63.79% for 200 cycles, which is better than the performance of the battery without MAn.
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
·
2025
·Vol. 61
·期 5
·872-880
·
IF 0.9
Tong Mengnan
A versatile, convenient, mild, and efficient method for the synthesis of N-benzoyloxyamines containing alkenone or allyl ester groups, starting from hydroxylamine derivatives, is developed and successfully extended to a broader range of tertiary amine analogs.
研究领域:
有机化学
·
药物化学
·
合成化学
·
生物医学化学
·
分子设计
✓ 已验证
DOI
高影响因子
JOURNAL OF POLYMER RESEARCH
·
2019
·Vol. 26
·期 4
·1-11
·
IF 1.53
Yang Zhouxiaoshuang,Wang Feng,Liu Hui
With the spiropyran-containing compound as the initiator, dual responsive spiropyran-ended poly(N-vinyl caprolactam) (SP-PNVCL) was synthesized by atom transfer radical polymerization. The structure of the resulting polymer was characterized by 1 H NMR and gel permeation chromatography, and the polymer had both reversible light-responsive and thermo-sensitive behaviors. Metal ions could be bound between merocyanine formed by photoisomerization of spiropyran and the amino group of N-vinyl caprolactam unit through synergetic coordination. The complexation of SP-PNVCL with several metal ions was investigated by UV-Vis absorption spectroscopy, and it was found that SP-PNVCL might be used as a potential recognition probe for Fe 2+ , accompanied by obvious color change from colorless to brown by naked eye. The detection limit and photo-reversible recyclable behaviors of SP-PNVCL for Fe 2+ were also investigated in details. The kind of spiropyran-ended poly(N-vinyl caprolactam) had great application potential in environment protection and biological area.
研究领域:
高分子化学
·
环境科学
·
生物医学工程
·
分析化学
·
材料科学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2014
·Vol. 5
·期 9
·6666-6674
·
IF 3.708
Linlin Duan,Wei Huang,Yatao Zhang
N-Halamine grafted halloysite nanotubes (N-halamine@HNTs) were used as an antibacterial agents to fabricate polyethersulfone (PES) ultrafiltration (UF) hybrid membranes. N-Halamine@HNTs were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectra (XPS). The chemical compositions, storage modulus, tan δ, morphology and performance of the membranes were characterized by attenuated total reflection-Fourier transform infrared spectra (ATR-FTIR), dynamic mechanical analysis (DMA), water contact angle, scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), overall porosity and pore size measurements. The results showed that the hydrophilicity of the membranes was improved greatly after adding N-halamine@HNTs. Water flux of the hybrid membrane could reach as high as 248.3 L m−2 h−1 when the content of N-halamine@HNTs was 1.0 wt%. In addition, the antibacterial test indicated that the hybrid membranes showed good antibacterial activity against E. coli.
研究领域:
材料科学
·
环境工程
·
生物医学工程
✓ 已验证
DOI
高影响因子
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
·
2015
·Vol. 30
·期 5
·1098-1102
·
IF 0.399
Zhou Yong,Liu Fude,Wu Haiyan,Duan Lijie,Qu Boyang
One conjugated polymer consisting of carbazole and 3-hexylthiophene moiety, poly (N-Hexyl-2,7-di(2-(4-hexylthiophene)carbazole) (PNDC), has been synthesized by ferric chloride oxidative polymerization. The monomer N-Hexyl-2,7-di(2-(4-hexylthiophene)carbazole was synthesized and characterized by IR, 1 H-NMR, 13 C-NMR and MS. UV-vis absorption spectrum, fluorescence spectrum, photoluminescence spectrum and electrochemical properties of the polymer were investigated. Polymer PNDC shows maximum peak appearing at 394 nm in UV-vis absorption spectrum, strongest fluorescence-emission at 482 nm in fluorescence spectrum and maximum emission peak at 492 nm in photoluminescence spectrum. The band-gap ( E
g ), HOMO energy ( E
HOMO ), and LUMO energy ( E
LUMO ) of the polymer were obtained as 2.58, -5.32, and -2.74 eV, respectively.
研究领域:
材料科学
·
有机化学
✓ 已验证
DOI
高影响因子
ACS Applied Nano Materials
·
2022
·
IF 6.14
Xiaoxiang Wu,Yali Liu,Mengge Li,Wenxuan Guo,Tianjian Ou,Cong Xiao,Jiadong Yao,Ying Yu,Yuan Zheng,Yewu Wang
Photodetectors based on two-dimensional materials and their van der Waals (vdW) heterojunctions usually have excellent optoelectronic performance and great potential applications. Herein, gallium (Aladdin, particles, 99.999% trace metal basis), selenium (Aladdin, powder, 99.999% trace metal basis), and iodine (Alfa Aesar, 99.999% trace metal basis) are the raw materials for the growth of gallium selenide (GaSe) single crystals by the chemical vapor transport method, in which iodine is the transport agent. Subsequently, GaSe nanoflakes are exfoliated from the grown bulk GaSe crystals by mechanical exfoliation. The n-Si/p-GaSe van der Waals vertical heterojunctions have been designed and fabricated for photodetection, which show good characteristics including a high responsivity of 1.74 A/W and a fast response/recovery time of 48 μs/88 μs under zero bias owing to their type-II band structure and built-in electric field. The results indicate that n-Si/p-GaSe vdW vertical heterojunctions are promising candidates in future ultrafast optoelectronic devices.
研究领域:
光电子学
·
材料科学
·
纳米技术
·
半导体器件
✓ 已验证
DOI
高影响因子
JOURNAL OF MOLECULAR STRUCTURE
·
2024
·
IF 4
Zahid Nawaz,Nevin Gürbüz,Muhammad Naveed Zafar,Muhammad Nawaz Tahir,İsmail Özdemir,Ryan J. Trovitch
A mild catalytic protocol for aldehyde, amine, and alkyne coupling (A 3 -coupling) allows for the selective synthesis of propargyl amines using 5,6-dimethylbenzimidazole-derived N-heterocyclic carbene (BNHC) silver(I) catalysts. A series of BNHC Ag(Ⅰ) halide complexes were synthesized and their structures have been elucidated through the use of multinuclear NMR and FT-IR spectroscopy. Furthermore, the pseudo-linear geometry of two different compounds was substantiated by single-crystal X-ray diffraction. Silver-based A 3 -coupling was achieved for both acyclic and cyclic secondary amines using a diverse set of alkynes to afford propargyl amines with yields of up to 95 %. The present approach is environmentally benign and water is generated as the sole byproduct.
研究领域:
有机化学
·
催化化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）