查找使用阿拉丁产品的科研文献

In2O3 and Au nanoparticles co-modified WS2 microsheets for enhanced NO2 gas sensing at room-temperature

Cuixian Luo,Yimeng Dong,Yongjiao Sun,Yurong Huang,Lingrong Xue,Lifang Ren,Daming Wang,Minzhe Qin,Xinke Li

Tungsten disulfide (WS2) is emerging with dazzling visibility as a “layered material beyond graphene and molybdenum disulfide” due to its exquisite tunable electronic, surface structure, high carrier mobility, and physicochemical stability. In this article, In2O3 and Au nanoparticles (NPs) co-modified WS2 microsheets were prepared for detecting NO2 at room temperature (RT). The In2O3 and Au NPs were anchored on the surface of WS2 microsheets, which could be observed by the characterization. The NO2 sensing performance at RT was optimized by adjusting the contents of In2O3 and Au NPs. The proposed gas sensor based on Au1WIn6 (WS2 microsheets co-modified with 6 wt% In2O3 and 1 wt% Au NPs) showed the highest response (46.91 to 50 ppm NO2), limit of detection (LOD; 18.9 ppb), excellent linearity within the test range, and good stability under various relative humidity (RH), bending degrees, and bending times. The excellent result is attributed to the formation of a heterojunction, which increases the number of ionized oxygen adsorption sites and facilitates the reaction between NO2 gas and Au1WIn6. Therefore, it is believed that decorating WS2 microsheets with metal oxide and noble metal NPs is a promising strategy to improve the NO2 sensing property at RT.

Pt-In2O3 mesoporous nanofibers with enhanced gas sensing performance towards ppb-level NO2 at room temperature

Yunshi Liu,Xing Gao,Feng Li,Geyu Lu,Tong Zhang,Nicolae Barsan

Pt-loaded In 2 O 3 mesoporous nanofibers (NFs) have been prepared by electrospinning, followed by a facile reduction method. The sample obtained by adding tea saponin into the spinning solution, sample In-TS, displays a more than 4 times higher specific surface area, value of 86.9 m 2  g −1 , than that of conventionally prepared samples. The loading with small-sized Pt nanoparticles (NPs) determines excellent gas sensing performance towards NO 2 down to ppb level (R g /R a  = 2.8 to 10 ppb and 23.9–1 ppm) at room temperature (RT), by that significantly lowering the power consumption. The reason is that the open pores and channels on the mesoporous NFs generated by the foaming agent not only promote the adsorption and desorption of NO 2 molecules on the sensing layers, but also improves the transduction function of the sensors by ensuring that there are no parts of the fiber that are not accessible to the gases. The introduction of Pt to the mesoporous NFs could accelerate the dissociation of absorbed oxygen and the active surface reactions in NO 2 owing to the catalytic property and chemical sensitization of well-dispersed Pt NPs. Due to the unique gas sensing performance, sample In-TS-Pt has a prospect for applications in low-concentration NO 2 detection at RT.

A CH3NH3PbI3 film for a room-temperature NO2 gas sensor with quick response and high selectivity

Xianwei Fu,Shilong Jiao,Ning Dong,Gang Lian,Tianyu Zhao,Song Lv,Qilong Wang,Deliang Cui

A room-temperature NO2 gas sensor with excellent performances is fabricated using an MAPbI3 (MA = CH3NH3+) thin film. It presents a high response even under extremely low NO2 concentrations. Its average response and recovery times are only ∼5 s and ∼25 s at room temperature, respectively, exhibiting its quick-responsive character. In addition, the MAPbI3-based NO2 sensor exhibits good selectivity. Interestingly, the sensitivity of the MAPbI3-based NO2 sensor is strikingly improved under high-pressure gas conditions. This phenomenon can be used for the online monitoring of chemical reaction processes and in situ detection of trace-level gas impurities under high-pressure conditions. Furthermore, based on theoretical calculations, a simple model is proposed to illustrate the corresponding gas-sensing mechanism.

Construction of highly efficient In2O3/SnO2 sensor for real-time NO2 monitoring at near room temperature

Ji Li,Ming Yang,Jiangbin Guo,Xianfa Zhang,Yingming Xu,Xiaoli Cheng,Lihua Huo

NO 2 is a dangerous gaseous pollutant, which is also a precursor to the formation of photochemical smog and ozone. It has negative impacts on the environment and human beings at local, regional and even the whole global scale. In this context, it is imperative to develop the efficient sensing materials for detecting NO 2 gas. In this study, a near room temperature NO 2 sensing material (In 2 O 3 /SnO 2 heterostructure) with “4S” index (selectivity, sensitivity, speed, stability) was constructed, it overcomes the drawbacks of traditional detection techniques and solves the unavoidable problems of metal oxide semiconductors in the sensing process (high temperature, cross response, weak response at low concentration, etc.). Meanwhile, the synergy between the surface structure and heterostructure interface of In 2 O 3 /SnO 2 has been thoroughly analyzed. More importantly, this study also sampled and monitored ambient air samples from different geographical locations and different time points in cities, which provides strong support for promoting the application of MOS sensors in real environment.

Wearable Inorganic Oxide Chemiresistor Based on Flexible Al2O3-Stabilized ZrO2 Ceramic Sponge Substrate for NO2 Sensing

Xiaowei Li,Mengjie Guan,Yu Liu,Haipeng Dong,Xinghua Li,Changlu Shao,Dongxiao Lu,Yichun Liu

Wearable gas sensors, possessing the advantages of high sensitivity, excellent flexibility, high permeability, low weight, and workability at ambient conditions, hold great promise for real-time health monitoring and early warnings of poisonous gases. However, obtaining high-performance wearable gas sensors utilizing the current well-developed inorganic semiconductor oxide sensing materials is still very limited due to their fragile and rigid nature. Herein, a newly designed wearable gas sensor based on an all-inorganic ASZ (Al2O3-stabilized ZrO2)/ZnO/SnO2 nanofibers is introduced for the first time. The flexible ASZ ceramic sponge substrate (with a Young’s modulus of 4.15 MPa) and ultrathin ZnO/SnO2 sensing layer endow the wearable gas sensor with promising properties such as super flexibility (with a bending radius of 5 mm), high gas permeability, and low weight. Furthermore, driven by UV light irradiation, this all-inorganic wearable sensor also demonstrates a stable NO2 sensing response under different bending states at room temperature, which enables the gas sensor to be more compatible with wearable sensing applications. This work offers a general method to achieve a high-performance wearable gas sensor based on inorganic materials and provides new insights into their potential in wearable gas-sensing applications.

A room-temperature nitrite-based hybrid bimetal molecular ferroelectric material: [(R)-3-quinuclidinol]2[LiCo(NO2)6]

Zhi-Yuan Yue,Rong-Meng Liao,Wang Luo,Na Wang,Le-Ping Miao,Heng-Yun Ye,Chao Shi

Organic–inorganic hybrid molecular ferroelectrics have attracted broad attention in the field of research of ferroelectric materials. Following the surge of stable candidates, hybrid bimetal molecular-based materials have been recently explored to achieve excellent ferroelectricity. However, rare hybrid bimetal molecular ferroelectrics were reported. Inspired by “ferroelectrochemistry”, a chiral nitrite-based hybrid bimetal molecular ferroelectric material, [(R)-3-quinuclidinol]2[LiCo(NO2)6] (1), was reported. The ferroelectric-paraelectric phase transition (C2 ↔ P321) behaviour of 1; was found at 343 K (Curie temperature, Tc) with a spontaneous electronic polarization (Ps) of 0.52 μC cm−2 and a coercive field (Ec) of 48 kV cm−1 at 298 K. Various-temperature single crystal structural analysis and dielectric constant measurements reveal that the rapid rotation of the organic cation and slight order–disorder transition of the NO2− anion are the origin of the ferroelectricity. To our knowledge, 1 is the first example of a nitrite-based hybrid bimetal molecular ferroelectric material that is triggered by an external electric field. This finding establishes a clear stimulus–structure–response relationship in advanced hybrid ferroelectric materials.

The High Sensitivity NO2 Surface Acoustic Wave Sensor with New Sensing Film Made by a Novel Method

Youwang Hu,Chengzhi Xu,Ji'an Duan,Jiwen Xiang,Shu Wang,Xiaoyan Sun

Surface Acoustic Wave (SAW) sensors have received great attention because of their compact design and excellent sensing performance, including high sensitivity, low detection limits. However, SAW sensors generally suffer from low quality of the solid thin films which has a significant effect to the detection performance of the sensors. To solve this problem, three different methods (spin coating, drop coating and spray coating) for fabricating thin films have been investigated for gaseous nitrogen dioxide (NO2) SAW sensors in this work. Spray coating method showed its advantages in improving the solid film quality of the sensing layer and the performance of the sensors. SEM characterization shows that the spray coating films are more uniform and poly-porous. Sensors with spray coating film can detect NO2 range from sub ppm to hundreds ppm with high sensibility and stability. Its sensitivity is 42.31 Hz/ppm and its sensing limit is down to 57.2 ppb.

High-Throughput Experimental Technology: Rapid Identification of the Precious Metal Modified In2O3 for NO2 Low-Temperature Sensing

Deqi Zhang,Qian Du,Li Yang,Jiyun Gao,Jianhong Yi,Ming Hou,Shenghui Guo,Hongbo Zeng

[EMIm]NO2-Modified PVDF–HFP Ionic Gel Electrolyte Membranes for Improved Lithium-Ion Transport and Interfacial Stability

Ruifeng Wang,Huangxin Cheng,Jiangnan Li,Gengzhe Shen,Yu Li,Jingmei Lyu,Zhengjian Chen

Gel polymer electrolytes typically suffer from low ionic conductivity, limited oxidative stability, and thermal runaway. Nitrate additives can be beneficial, but they are limited by poor solubility. Herein, sandwich-structured ionic liquid gel electrolyte membranes were fabricated by incorporating a polyethylene (PE) interlayer between two poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF–HFP) layers loaded with LiTFSI and 1-ethyl-3-methylimidazolium nitrate ([EMIm]NO2). The PFENE3 membrane prepared with 22.9 wt % [EMIm]NO2 shows optimal overall performance. Specifically, the PE scaffold provides robust mechanical strength (36.7 MPa). The incorporation of [EMIm]NO2 induces multiple synergistic effects: (i) increasing ionic conductivity to 5.03 × 10–4 S cm–1 at 25 °C by suppressing PVDF–HFP crystallinity; (ii) achieving a high Li+ ion transference number (0.449) by confining other charge carriers within the TFSI-[EMIm]+-NO2 hydrogen-bonding network; and (iii) the sacrificial decomposition of NO2 to form robust protective interphases on both the anode and cathode. Consequently, Li/PFENE3/Li symmetric cells demonstrated stable cycling for over 600 h at 0.3 mA cm–2. Furthermore, the Li/PFENE3/NCM622 full cell delivered an initial capacity of 170.9 mAh g–1 at 0.1 C and 159.3 mAh g–1 at 0.5 C, with 78% retention after 100 cycles, significantly outperforming [EMIm]NO2-free systems. These findings provide a viable strategy for developing high-performance and safe Li-metal batteries.

On-chip surface-enhanced Raman scattering arrays for selective sensing of NO2 exhaust emissions from construction machinery

Yaping Tian,Ran Xu,Luqing Chen,Yuanyuan Liu,Xinming Nie,Xinyu Liu,Shoufeng Tang,Lulu Qu

Nitrogen oxides from construction machinery exhaust pose a significant threat to the environment and human health. Therefore, effective capture and highly selective detection of NO 2 is of utmost importance. Surface-enhanced Raman scattering (SERS) is a spectroscopic technique that provides molecular fingerprint information and enables qualitative and quantitative analysis of molecules at extremely low concentrations. However, the application of SERS for gas molecules with small scattering cross sections, such as NO 2 , is still in its infancy. Based on this, a sensing device for capturing and selectively detecting NO 2 from construction machinery exhaust was developed. The device consists of a gas collection module and a Raman signal amplification module containing a 4, 4’-diaminodiphenyl disulfide (APDS) probe-modified flexible Au@PDMS chip. The Au@PDMS chip amplifies the Raman signals of molecules, while the APDS selectively and rapidly captures NO 2 . The proximal electron-rich nitrogen atom and the ortho-electron-poor aromatic hydrogen atom of the APDS probe form a stable six-membered ring complex with the N atom of NO 2 , and hydrogen bonding interactions occur between the H atom in APDS and the O atom in NO 2 . This ring complexation allows the Au@PDMS chip to capture NO 2 quickly and effectively, resulting in changes in SERS signals and facilitating quantitative analysis of NO 2 . Combined with the gas detection device, the chip can identify NO 2 within 5 min with a detection limit of 3.5 ppm. This sensor device has high selectivity for NO 2 detection in real exhaust gases and has great potential for practical detection of construction machinery exhaust gases.

Synergistically enhanced room-temperature NO2 gas sensing via Au-decorated hierarchical SnO2 nanosheets under blue light excitation

Yihui Wang,Ting Yu,Huijun Yin,Shangyi Shen,Zhenqi Yang,Bohui Wang,Xingjie Wu,Honglong Chang,Haitao Zhao

Nitrogen dioxide (NO 2 ), a significant atmospheric pollutant primarily emitted from combustion processes, poses substantial environmental and health risks, underscoring the critical need for accurate detection methods. Conventional SnO 2 -based sensors are typically constrained by high operating temperatures and limited sensitivity. This study overcomes these limitations by introducing a novel approach that combines noble metal modification with bandgap-matched light excitation, enabling high-performance NO 2 detection at room temperature. Au/SnO 2 composites with hierarchical nanosheet architectures were synthesized via hydrothermal and impregnation methods, as confirmed by SEM. Their sensing properties were systematically investigated under blue light excitation. Among the samples tested, the 2.5 wt% Au/SnO 2 sensor demonstrated superior performance, exhibiting a remarkable response (149.25 @ 5 ppm), a low detection limit (150 ppb), and excellent selectivity, long-term stability, and humidity tolerance at room temperature. First-principles calculations reveal that the enhanced sensor performance originates from a synergistic effect between Au nanoparticle decoration, which enhances NO 2 adsorption and charge transfer, and the additional photogenerated carriers induced by blue light excitation. This study provides novel material design insights for developing high efficiency room temperature NO 2 sensors.

Low detection limit and high sensitivity NO2 gas sensor based on PdO/NiMoO4/NiO ternary composite materials

Zhang Saisai,Liu Shijie,Xing Mingli,Zhang Bo,Zhang Bowen,Wang Na Luo Yan

Developing nitrogen dioxide (NO 2 ) gas sensors that simultaneously deliver high sensitivity, selectivity, and long‑term stability remains a considerable challenge for practical applications. In this work, nanoflower‑like PdO/NiMoO 4 /NiO composites with tunable PdO loadings were fabricated via a hydrothermal method combined with in‑situ impregnation and annealing. The constituent nanosheets measure approximately 200 nm in length and 20 nm in thickness. The optimized sensor with 0.5 wt% PdO loading achieves a response of 59.94 toward 1 ppm NO 2 at 160 °C, representing a 3.7‑fold enhancement over the unmodified NiMoO 4 /NiO sensor, along with good selectivity and long‑term stability. This performance improvement is attributed to the synergistic effects of heterojunction formation and PdO catalytic activation, which facilitate charge transfer and surface reaction kinetics. These results demonstrate the potential of the ternary composite for practical NO 2 detection. Graphical The alternative text for this image may have been generated using AI.