TRIBOLOGY INTERNATIONAL
·
2024
·
IF 6.1
Zeyang Wu,Jie Fei,Chang Li,Jifeng Yan,Xinyu Ke,Lehua Qi
As a nanoscale carbon material, carbon spheres (CS) are expected to achieve ideal lubrication performance by reducing direct contact between friction pairs and bearing loads. In this work, 2D Cu-MOFs surface modified (CS@Cu(BDC)) CS was added to the base oil, which exhibited a remarkable reduction in friction coefficient and wear rate (62.2%, 33.9%), the width of the friction pair wear marks was decreased by 30.8% relative to the base oil. The improvement in performance can be attributed to the polishing, repairing, filling and tribo-film forming effects of CS@Cu(BDC). This work provided an effective strategy for diversifying the surface structure of CS and opened new avenues for the development of a new generation of green and efficient lubricant additives .
✓ 已验证
产品关联
DOI
高影响因子
ANALYTICA CHIMICA ACTA
·
2024
·
IF 5.7
Kexi Sun,Chao Liu,Yi Cao,Jianxia Zhu,Jialin Li,Qing Huang
Background Rapid and accurate detection of glutathione content in human blood plays an important role in real-time tracking of related diseases. Currently, surface-enhanced Raman scattering/spectroscopy (SERS) combined with nanozyme material has been proven to have excellent properties in the detection applications compared to many other methods because of it combines the advantages of trace detection capability of SERS and efficient catalytic activity of nanozymes. However, there are still existing problems in real sample detection, and to achieve quantitative detection is still challenging. Results In this study, gold nanoparticles (AuNPs) were synthesized in situ on the surface of two-dimensional Cu-porphyrin metal-organic framework (MOF) nanosheets to produce the AuNPs@Cu-porphyrin MOF nanozyme, which exhibited both oxidase-like activity and SERS detection ability. On one hand, the intrinsic oxidase-like activity of the nanozyme could be inhibited due to the chelation of glutathione (GSH) and Cu, which thus led to the visual color change of the solution. On the other hand, the abundant Raman “hot spots” at the nanogap generated by Au NPs and the internal standard (IS) signal provided by Cu- meso -tetra (4-carboxyphenyl) porphine (Cu-TCPP) MOF improved the sensitivity and quantitative accuracy of detection. Significance and novelty A dual-mode signal output sensor based on the nanozyme was thus established, which could be used in the trace detection of GSH. Such a dual-mode sensor possesses excellent detection performance, with the advantage of both wide detection range from 1 to 300 μM in the colorimetric detection mode and high sensitivity with LOD of 5 nM in the SERS detection mode, and can be applied to GSH detection in actual serum samples with reliable results.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
LANGMUIR
·
2024
·
IF 3.7
Yuyun Wang,Guoliang Zhang,Duo Yang,Yang Li,Wei Yin,Jingshui Xu
At present, Ni-based coatings are rarely used in the field of voltage control friction because of their poor antifriction, wear resistance, and conductive properties. Therefore, in this paper, Cu-BTC@Ag nanocrystals were used to enhance the nickel coatings, and the effect of voltage on their tribological properties was also investigated. It was found that the grains of coating were refined via the addition of Cu-BTC@Ag nanocrystals, leading to an improvement in the hardness and corrosion resistance of this composite coating. The tribological performance of nickel composite coating could be controlled under different electrical fields. With the comparison of the pure Ni-based coating, the average friction coefficient and wear volume of its composite coating with 5 wt % Cu-BTC@Ag were reduced by 7.0 and 91.8%, respectively, which showed excellent wear resistance without an applied voltage. Under the condition of 20 V, the 5 wt % Cu-BTC@Ag/Ni-based composite coating owned outstanding antifriction performance. Therefore, Cu-BTC@Ag played an intelligent role in regulating the friction of Ni-based coatings under an external voltage. It is due to the accumulation of Cu-BTC@Ag nanocrystals on the surface of the coating under the action of voltage, which played the role of supporting load and effectively reducing wear.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CATALYSIS TODAY
·
2017
·
IF 4.636
Xinli Tong,Linhao Yu,Xuan Luo,Xuli Zhuang,Shengyun Liao,Song Xue
The efficient transformation of furfural (FUR) with aliphatic alcohols to achieve the carbon-chain growth has been developed using a binary Cu-Ce oxide as the catalyst. In the presence of molecular oxygen, the tandem oxidative condensation of FUR with n -propanol is successfully performed, in which an 85.4% conversion of FUR in 95.3% selectivity of 3-(furan-2-yl-)-2-methylacryaldehyde was obtained. The effects of different Cu/Ce ratios and base additives were investigated in detail. As a result, it is found that the CuO-CeO 2 (1: 9) catalyst is optimal and potassium carbonate is a suitable additive. Next, the recycling of CuO-CeO 2 catalyst was tested and there is no obvious activity loss after being reused five times. Moreover, the oxidative condensation of FUR with various aliphatic alcohols including ethanol, isopropanol, n -butanol and n -hexanol was studied where the long chain alcoholic molecule hinders the proceeding of reaction. Finally, based on the experimental results and reaction phenomena, a possible mechanism for the oxidative condensation of FUR with n -propanol-O 2 is proposed.
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2024
·
IF 6.3
Jiaqiang Wen,Yue Gong,Ting Tan,Tao He
CO 2 reduction is a potential way to kill two birds with one stone by converting greenhouse gas into fuels through clean energy. Cu-based catalysts, with a wide range of products, often have limited selectivity and low activity for specific products. In this study, Cu 2 O was used as the oxide-derived copper (OD-Cu) substrate, which was loaded with CuPd nanoparticles by using pulsed potential and galvanic replacement. Theoretical calculations revealed that the strong H-affinity Pd sites can reduce the selectivity of formate by stabilizing *COOH and simultaneously lowering the d -band center of neighboring Cu. Additionally, the asymmetric C–C coupling of *CHO+*CO, distributed between Cu and Pd sites, can lower the free energy change of rate-determining step to promote production of the C 2+ products. Faradaic efficiency (FE) of the C 2+ products over Cu 2 O-CuPd 0.5μM was more than three times higher than that over untreated Cu 2 O NW, rising from 16.50 % to 54.47 % under −1 V ( vs RHE) bias. Moreover, the FE for formate and CO decreased respectively from 28.57 % and 19.30 % to 3.69 % and 11.82 %, accompanied by a simultaneous increase in current density by 71.49 %.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2024
·
IF 9.4
Dehe Fan,Shiji Zhang,Yumeng Li,Hua Bin,Ruopeng Li,Yaqiang Li,Maozhong An,Peixia Yang,Jinqiu Zhang
Copper-based tandem catalysts are effective candidates for yielding multi-carbon (C2+) products in electrochemical reduction of carbon dioxide (CO 2 RR). However, these catalysts still face a significant challenge regarding in the low selectivity for the production of a specific product. In this study, we report a high selectivity of 77.8 %±2 % at −1.0 V (vs RHE) for the production of C 2 H 4 by using a Cu 88 Ag 12 NW catalyst which is primarily prepared through a combined Cu-Ag co-deposition and wet chemical method, employing an attractive strategy focused on regulating the microenvironment over Cu-Ag nanowires. The experimental and computational studies show that the higher *CO coverage and lower intermediate adsorption energy are important reasons for achieving the high C 2 H 4 selectivity of Cu 88 Ag 12 NW catalyst. Comsol simulation results indicate that dense nanowires exhibit a nano-limiting effect on OH − ions, thereby leading to an increase in local pH and promoting coupling reactions. The catalyst demonstrates no noticeable decrease in current density or selectivity even after 12 h of continuous operation. The Cu-Ag nanowire composite exhibits remarkable catalytic activity, superior faradaic efficiency, excellent stability, and easy synthesis, which highlights its significant potential for electro-reducing carbon dioxide into valuable products.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
·
2024
·Vol. 48
·期 26
·11776-11782
·
IF 2.7
Yuwei Yan,Hongyan Li,Songnan Li,Jiawei Zhang,Jingxiang Zhao,Qinghai Cai
Copper, iron–chloride ionic liquids (ILs) were immobilized on SBA-15 via N-methylimidazole grafting with C–Cl in chloropropylsilane pre-anchored on SBA-15, followed by FeCl3 and CuCl2 coordination to imidazolium chloride to generate a double metal IL-supported mesoporous composite (SIL-CuFe). The prepared composite exhibited an effective catalytic performance for the solvent-free oxidation of styrene to benzaldehdye (BzH) with H2O2 oxidant, offering 51% conversion, a turnover number (TON) of 330.5 mol molFe+Cu−1, and a selectivity of 71% at a reaction temperature of 70 °C. The composite catalyst can be easily recovered and effectively reused without a significant loss in activity and selectivity. The quenching experiments by adding tert-butanol (TBA), 1,4-benzoquinone (p-BQ) and L-histidine (L-HIS) in the reaction system were conducted to identify the type of reactive O species, specifically ˙OH, ˙O2−, and 1O2, produced by catalyst activation with H2O2 and played a main role in the oxidation. The reaction mechanism of the oxidation process is also proposed.
✓ 已验证
产品关联
DOI
高影响因子
LUMINESCENCE
·
2024
·Vol. 39
·期 8
·e4871
·
IF 3.2
Yaru Wang,Chaohai Pang,Xionghui Ma,Mingyue Wang,Xiaopeng Wu,Sixin Liu,Shuhuai Li
Graphene oxide (GO) and copper nanoparticles (Cu NPs) were incorporated to modulate and enhance the fluorescence properties of pegylated graphite phase carbon nitride (g-C 3 N 4 -PEG). Combined with the specific recognition capability of a molecular imprinted polymer (MIP), a highly sensitive and selective fluorescent molecular imprinted probe for dopamine detection was developed. The fluorescent g-C 3 N 4 -PEG was synthesized from melamine and modified with GO and Cu NPs to obtain GO/g-C 3 N 4 -PEG@Cu NPs. Subsequently, MIP was prepared on the surface of GO/g-C 3 N 4 -PEG@Cu NPs using dopamine as the template molecule. Upon elution of the template molecule, a dopamine-specific GO/g-C 3 N 4 -PEG@Cu NPs/MIP fluorescence probe was obtained. The fluorescence intensity of the probe was quenched through the adsorption of different concentrations of dopamine by the MIP, thus establishing a novel method for the detection of dopamine. The linear range of dopamine detection was from 5 × 10 −11 to 6 × 10 −8 mol L −1 , with a detection limit of 2.32 × 10 −11 mol L −1 . The sensor was utilised for the detection of dopamine in bananas, achieving a spiked recovery rate between 90.3% and 101.3%. These results demonstrate that the fluorescence molecular imprinted sensor developed in this study offers a highly sensitive approach for dopamine detection in bananas.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
FATIGUE & FRACTURE OF ENGINEERING MATERIALS & STRUCTURES
·
2024
·Vol. 47
·期 8
·2905-2921
·
IF 3.1
Siran Wang,Zhangcheng Yin,Xudong Rong,Haipeng Song,Xudong Yang,Naiqin Zhao
The unsatisfactory fatigue performance of Al foams significantly limits their engineering applications. Meanwhile, the unique pore structure of metal foams makes it still challenging to assess its fatigue. Herein, we report an innovative strategy for preparing carbon nanotubes reinforced Al-Cu-Mg (CNTs/Al-Cu-Mg) composite foams, which exhibit superior compressive strength (16.17 MPa) and fatigue strength (11.17 MPa). Statistics analysis confirms that the fatigue life ( N f ) follows Weibull distribution, and P-S-N curves were obtained to calculate the theoretical stress level required to achieve the expected N f . Moreover, computer vision is utilized to monitor the fatigue deformation process and effectively detect fatigue crack initiation sites. Notably, the accuracy of predicted N f obtained by this method is exceptionally high (98.32%). This work provides a theoretical and practical basis for designing metal foams with superior fatigue properties and offers a promising bottom-up tactic for predicting the N f of metal foams to prevent fatigue failure. Highlights The CNTs/Al-Cu-Mg composite foams possess the superior fatigue strength of 11.17 MPa. The application of computer vision enables the accurate monitoring of FCIS. A novel exploration into the fatigue assessment of metal foams is developed.
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2025
·
IF 7.7
Qiang Chen,Yi Cai,Tianyu Jiang,Qing Chen,Jianhua Wang,Yong Zhao
Double-hole optical fiber (DHF) exhibits considerable potential for sensing applications due to its distinctive structural characteristics. In this study, a Sagnac interference (SI) optical fiber sensor based on a corroded DHF shows high refractive index (RI) sensitivity, allowing for the detection of copper ions, Cu(II), at very low concentrations. The dependence of DHF corrosion on the birefringence and RI sensitivity are investigated by the optical simulation. Experimental results illustrate that the RI sensitivity reaches 3267 nm/RIU within the range of 1.3333–1.3743, exhibiting good linearity. A chitosan derivative (CSD) with ion-imprinted (IIM) treatment is coated on the surface of the corroded DHF for Cu(II) detection. It is demonstrated that within the concentration range of Cu(II) from 10 −15 to 10 −6 M, both the maximum and average sensitivities can reach 12.08 × 10 9 and 129.96 nm/μM, respectively, without interference from other metal ions or temperature (25.3–44.0 ℃). The proposed corroded DHF sensor is a good candidate for RI and Cu(II) concentration detection due to its simple structure, high sensitivity, and selectivity.
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Nano Materials
·
2024
·
IF 5.3
Changyu Pu,Xin Wang,Enchan Wang,Yuyang Wu,Xinru Zhang,Jiahao Liu,Yanqiang Di,Zeyi Jiang,Lin Qiu,Ting Gao,Aihui Chou,Xinxin Zhang
Developing polymer-based composites using high-performance heterostructure fillers is of significant importance for the thermal management of electronic devices. Herein, hydrophilic copper-graphene (Cu-GNP) heterostructure fillers modified with amino functional groups via polydopamine surface modification and calcination reduction were prepared. Subsequently, Cu-GNP/poly(vinyl alcohol) (PVA) thermal conductive composites were fabricated using a solution blending method, where hydrogen bonds were formed between the fillers and the PVA matrix. For composites containing 20 wt % Cu-GNP fillers, their in-plane thermal conductivity reaches 18.49 W·m–1·K–1 and the tensile strength is 25.97 MPa, representing increases of 20.61% and 24.25%, respectively, compared to GNP/PVA composites with equivalent filler contents. This improvement is attributed to the enhanced interaction between Cu-GNP and the PVA matrix due to the formation of hydrogen bonds. Additionally, these composites also exhibit a certain level of electrical insulation properties, making them promising candidates for heat dissipation applications in electronic devices.
✓ 已验证
产品关联
DOI
高影响因子
INORGANIC CHEMISTRY
·
2024
·
IF 4.3
Jiahui Zhao,Yixuan Zhao,Xuefeng Shao,Ying Sun,Huang Wen,Jian Liu
Developing a synthesis-free, multifunctional, and effective colorimetric assay system based on 3,3′,5,5′-tetramethylbenzidine (TMB) oxidation is attractive yet challenging. Herein, we established a synergetic Cu2+/Cr6+-promoting strategy for TMB-based colorimetric detection of Cr6+. By introducing Cu2+, critical TMB·+···Cu(I/II)···TMB charge transfer complex (TMC) intermediates were in situ formed to reduce the activation energy of TMB oxidation, thereby accelerating Cr6+-mediated TMB oxidation. TMC intermediates also played a pivotal role in H2O2-participated TMB oxidation, clarifying the secondary responsibility of reactive oxygen species frequently caused by Fenton-like reactions. Leveraging the synergetic capacity between Cu2+ and Cr6+ for TMB oxidation, we demonstrated sensitive and specific colorimetric detections for Cr6+ with a limit of detection of 0.006 μM. With its convenient operation and rapid responsiveness, this strategy successfully enabled the practical detection of Cr6+ in real water samples. This work not only enhances the understanding of the internal acceleration mechanism in colorimetric sensing but also provides valuable opportunities to advance synthesis-free detection platforms.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）