JOURNAL OF ALLOYS AND COMPOUNDS
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2023
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IF 6.2
Aiting Chen,Yanping Wei,Du Tuo,Chuanqin Zhou,Shuting Shi,Nana Tang,Quanguo He,Jun Liu
A facile and novel electrochemical determination of Fluoxetine (FLX) at submicromolar concentration Niobium carbide (Nb 2 CT x ) and Nitrogen-doped Reduced Graphene Oxide (NRGO) hybridized electrodes as sensing platform is demonstrated. Herein, Niobium carbide (Nb 2 CT x ) was successfully prepared by etching Nb 2 AlC and then ultrasonically compounded with Nitrogen-doped Reduced Graphene Oxide (NRGO), to form a well-dispersed Nb 2 CT x /NRGO composite, which was modified onto a glassy carbon electrode (GCE). The morphology, structure and electrochemical property of the Nb 2 CT x /NRGO/GCE was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV). The electrocatalytic activity of the Nb 2 CT x /NRGO/GCE for FLX oxidation was studied in detail. The peak currents showed two good linear relationships (R 2 = 0.9962 and 0.9949) with FLX concentrations (1.0–10 µM and 10–100 µM) and a detection limit of 0.34 µM (S/N = 3). The sensor has good selectivity, repeatability, reproducibility and stability, and is capable of sensitively determining FLX in human serum and urine samples of clinical biological fluids. This work is believed to be of great significance and of broad interest for research on innovative MXene materials development and biomedical sensing applications.
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CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Qinghong Ji,Xinxin Sheng,Xiaolong Li,Shuang Liu,Qiufei Chen,Pengzong Guo,Yabi Yang,Youyou Huang,Guoliang Zhang,Xiang Lu,Jinping Qu
Infrared stealth materials are in increasing demand with the development of infrared detection technology. However, most reported materials focus solely on emissivity control or temperature control, resulting in brief and less ideal infrared stealth effect. Herein, a double layer MXene@polyvinyl alcohol (PVA)/phase change capsules (PCC) aerogel composite inspired by the skin-fat structure of camel for infrared camouflage was successfully fabricated via a facile freeze-drying followed by spraying method. The PVA/PCC aerogel composite with high latent heat (155.2 J/g) and strong mechanical properties (772.6 kPa), obtained by an in-situ one-step method, is adopted as a temperature control layer, benefiting from the prominent thermal insulation of porous structure and effective heat absorption of PCC. The low emissivity (0.249) of the MXene layer on the surface of aerogel composite makes its radiation temperature recognized by the thermal imager much lower than its actual temperature. By integrating thermal insulation, heat absorption and emissivity reduction strategies, MXene@PVA/PCC aerogel shows no difference with the background in the infrared thermal imager (radiation temperature difference less than 10 °C), achieving superior infrared stealth for medium and low temperature scenarios, and provides novel ideas for developing more high-performance infrared stealth materials.
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COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING
·
2023
·
IF 8.7
Xiao-Ai Ye,Si-Ying Zhang,Da-Qiang Zhao,Ling Ding,Kan Fang,Xu Zhou,Gui-Gen Wang
2D MXene are showing great prospects for EMI shielding by virtue of abundant surface functional groups and outstanding metallic electrical conductivity . However, it remains a great challenge to simultaneously achieve flexible, lightweight and high stability in MXene shielding materials due to inferior mechanical strength and poor oxidation stability. Gelation paves up an effective and facile strategy to develop highly stable and conductive 3D porous Ti 3 C 2 T x architectures. Herein, super-flexible and highly conductive H-Ti 3 C 2 T x MXene composite films with 3D macro-assemblies for EMI shielding were fabricated through a gelation-densification process initiated by hydrochloric acids, and two-step vacuum-assisted filtration followed by freeze-casting approach. The obtained nanocomposite films manifest satisfactory mechanical properties with a tensile strength of 116.51 MPa, excellent EMI SE of 55.14 dB, superior SSE/t and high EMI SE retention after 5000 cycles of bending deformation. In addition, the as-prepared nanocomposite papers demonstrate outstanding thermal management performances such as rapid response time, high Joule heating temperature (118 °C) at low applied voltage (2.5 V) and eminent working stability (4000 s).
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WATER RESEARCH
·
2023
·
IF 12.8
Yi-Lin Liu,Chao Zhang,Lulin Guo,Qingming Zeng,Rongzhong Wang,Haodong Chen,Qingyan Zhang,Qingyi Zeng
Proper disposal of uranium-containing waste is of utmost importance for safeguarding the environment and human health. In this study, we proposed a novel zero-dimensional (0D)/two-dimensional (2D) nanocomposite material, nZVC/Ti 3 C 2 , composed of nano zero-valent copper (nZVC) nanoparticles loaded onto Ti 3 C 2 MXene nanoflakes, which was prepared using a simple in situ chemical reduction method. The uniform dispersion of 0D nZVC nanoparticles, with a size of approximately 5 nm, onto the 2D ultrathin Ti 3 C 2 MXene effectively prevented agglomeration and corrosion of nZVC. This unique configuration provided numerous adsorption sites for UO 2 2+ and facilitated a fascinating charge channel for reducing adsorbed UO 2 2+ into low-mobilized UO 2 by nZVC. Under the synergistic effect of Ti 3 C 2 MXene and nZVC, remarkable efficiency and selectivity of nZVC/Ti 3 C 2 for U (VI) removal were demonstrated, which exhibited an exceptional adsorption capacity of up to 360 mg/g, coupled with a high removal efficiency of 97.5 % and rapid kinetics. Importantly, the presence of humic acid did not significantly affect the U (VI) removal efficiency of the composite because of the reduction effect of nZVC. The underlying mechanism of U (VI) removal was elucidated, revealing the involvement of reductive immobilization in the form of UO 2 (as high as 73.6 %), inner-sphere surface complexation, and hydrolytic precipitation. This mechanism was dependent on the availability of active nZVC and the solution's pH. These findings highlight the potential of nZVC/Ti 3 C 2 composites as efficient decontaminants for radioactive wastewater , thus contributing to advancements in environmental remediation endeavors.
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CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Hengrui Wang,Kexin Chen,Yongqian Shi,Yanjun Zhu,Songqiong Jiang,Yan Liu,Shijie Wu,Chenxin Nie,Libi Fu,Yuezhan Feng,Pingan Song
The demand for high-strength, flexible, and multifunctional electromagnetic interference (EMI) shielding materials has significantly increased in many fields. Herein, inspired by reinforced concrete pouring in construction, we propose a “consolidating” method to successfully fabricate flame-retardant thermoplastic polyurethane (TPU) reinforced bacterial cellulose (BC)/MXene/modified silicon carbide nanowires (MSiCnw) aerogel composites. The obtained aerogel composites have a disordered pore structure, in which BC/MXene/MSiCnw is used as the internal skeleton, and the tightly attached flame retardant TPU sheet is used as the protective layer. The as-synthesized aerogel composites possess excellent mechanical properties, withstanding repeated compression and exhibiting a compressive strength of 8.86 kPa which is 735.8% higher than that of BC aerogel. At a low MXene content (6.17 wt%), the aerogel composite exhibits an EMI utilization efficiency of 1209.08 dB/g g −1 and an average EMI shielding effectiveness of up to 81.6 dB (K-band). Furthermore, the aerogel composites show excellent flame retardant property (69.8% reduction in peak of heat release rate). More interestingly, the aerogel composite displays satisfactory thermal insulation performances and reaches a low thermal conductivity of 34.4 mW/m K −1 . Overall, the as-prepared highly fire safe BC/MXene/MSiCnw/FRTPU aerogel composites show multifunctional properties, making them suitable for applications in electromagnetic shielding and thermal insulation.
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JOURNAL OF MATERIALS SCIENCE
·
2023
·Vol. 58
·期 34
·13875-13887
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IF 4.5
Cheng Hengyi,Zuo Tongcheng,Chen Yixiang,Yu Dan,Wang Wei
With the advent of an ageing society, wearable strain sensors have great prospects for applications in artificial intelligence, motion detection and healthcare, and have attracted much attention from researchers. But the challenges of poor wear comfort, low sensitivity and clumsy appearance still greatly limited their practical applications. To address these problems, a facile strategy for the fabrication of fibrous strain sensors by wet spinning is proposed. Polyvinyl alcohol/waterborne polyurethane/MXene (PVA/WPU/MXene) is the main component to construct the conductive part of the fiber-based materials and aqueous calcium chloride solution is used as a coagulation bath in the spinning process. The relevant physicochemical properties of the resulting conductive fibers were characterized and tested. Though the facile wet-spinning process, an effective conductive network was achieved in the prepared stretchable sensor with excellent mechanical properties and chemical stability and can be woven into various fabric forms according to practical demanding. It was demonstrated that a sensitivity of 5.61 could be obtained with an elongation at break of over 358%. In addition, the sensing and weaving properties of the composite fibers were characterized, and application performance was measured by placing them on the elbow, wrist, and knee. As a result, the PVA/WPU/MXene composite fiber strain sensor displays a linear response, good sensitivity and cyclic stability and has great potential for wearable strain sensors and flexible strain sensors in complex environments
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
·
2023
·
IF 10.9
Wen Xiao,Huan Yu,Chenghao Xu,Zhongyi Pu,Xiangyu Cheng,Fang Yu,Chao Liu,Qinfang Zhang,Zhigang Zou
Developing high-efficiency photocatalysts for tetracycline hydrochloride (TCH) degradation is of great significance to ecosystems and human beings. In this work, a two-step process of exfoliation and re-stacking was performed to prepare re-stacked HTiNbO 5 nanosheets (R-HTNS) and then coupled with Ti 3 C 2 MXene to construct Ti 3 C 2 MXene/R-HTNS (MX/RTS) with a 2D/2D Schottky heterojunction. These 2D/2D heterostructures between Ti 3 C 2 MXene and R-HTNS can produce an internal electric field and provide maximum interface area for efficient charge transfer across the intimate interface. The photocatalytic performance of samples was evaluated by TCH degradation under simulated sunlight. The MX/RTS composites, with an optimal sample of 3-MX/RTS, show enhanced photocatalytic activity for TCH degradation compared with R-HTNS. The characterization results reveal that the introduction of Ti 3 C 2 MXene can significantly increase specific surface area for providing more reactive sites and broaden the light absorption region. Besides, the incident light energy is absorbed by the Ti 3 C 2 MXene component in MX/RTS composites to generate photothermal energy (heat), which facilitates the charge carrier separation and surface reaction kinetics. Thus, the enhanced TCH photodegradation activity for MX/RTS composites is due to the introduction of Ti 3 C 2 MXene, which possesses the synergistic effect of the increased specific surface area, improved light-harvesting capacity, 2D/2D Schottky heterojunction, and photothermal energy effect. Additionally, the TCH photodegradation behavior is deliberated with a detailed discussion on various coexisting ions. During TCH photodegradation, the active radical species are determined for 3-MX/RTS. According to the characterization results, the possible TCH photodegradation pathway and mechanism over 3-MX/RTS are explored. This work may offer a novel insight for constructing MXene-based heterostructured photocatalysts with high efficiency.
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Nano Energy
·
2021
·
IF 17.881
Pengfei Yan,Liang Ji,Xiaopeng Liu,Qinghua Guan,Junling Guo,Yonglong Shen,Haijun Zhang,Weifeng Wei,Xinwei Cui,Qun Xu
2D heterostructures offer a great opportunity in seeking high-performing energy storage materials ; however, performance ceiling exists, limited by their van-der-Waals (vdW) interactions. Here, we explore a novel 2D, amorphous MoO 3−x (aMoO 3−x ) on Ti 3 C 2 -MXene, non-vdW heterostructure via a facile synthesis route. Density functional theory computations suggest that the non-vdW heterostructure can strongly stabilize aMoO 3−x while maintaining electrical conductivity at a high level. Facile 2D Li-ion diffusion can then be achieved in the restacked 2D non-vdW heterostructures due to the weakened interactions between two defective MoO 3−x layers, leading to a capacitor-like interlayer diffusion reaching a large capacity of 426 C g −1 on the surface of the amorphous layer and a diffusion-controlled intralayer diffusion of 546 C g −1 within the amorphous layer. These characteristics optimize Li-ion storage kinetics while achieving full capacities of amorphous materials with high stability. This work might offer a feasible platform of 2D non-vdW heterostructures for boosting and understanding Li-ion storage performance.
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ACS Nano
·
2021
·
IF 15.881
Junming Cao,Ziqi Sun,Junzhi Li,Yukun Zhu,Zeyu Yuan,Yuming Zhang,Dongdong Li,Lili Wang,Wei Han
As a typical family of two-dimensional (2D) materials, MXenes present physiochemical properties and potential for use in energy storage applications. However, MXenes suffer some of the inherent disadvantages of 2D materials, such as severe restacking during processing and service and low capacity of energy storage. Herein, a MXene@N-doped carbonaceous nanofiber structure is designed as the anode for high-performance sodium- and potassium-ion batteries through an in situ bioadsorption strategy; that is, Ti3C2Tx nanosheets are assembled onto Aspergillus niger biofungal nanoribbons and converted into a 2D/1D heterostructure. This microorganism-derived 2D MXene-1D N-doped carbonaceous nanofiber structure with fully opened pores and transport channels delivers high reversible capacity and long-term stability to store both Na+ (349.2 mAh g–1 at 0.1A g–1 for 1000 cycles) and K+ (201.5 mAh g–1 at 1.0 A g–1 for 1000 cycles). Ion-diffusion kinetics analysis and density functional theory calculations reveal that this porous hybrid structure promotes the conduction and transport of Na and K ions and fully utilizes the inherent advantages of the 2D material. Therefore, this work expands the potential of MXene materials and provides a good strategy to address the challenges of 2D energy storage materials.
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ACS Nano
·
2021
·
IF 15.881
Xiaodong Zhu,Ziyi Cao,Wenjie Wang,Haijing Li,Juncai Dong,Shangpeng Gao,Dongxiao Xu,Lei Li,Jianfeng Shen,Mingxin Ye
Mn-based aqueous zinc-ion batteries (ZIBs) are promising candidate for large-scale rechargeable energy storage because of easy fabrication, low cost, and high safety. Nevertheless, the commercial application of Mn-based cathode is hindered by the challenging issues of low rate capability and poor cyclability. Herein, a manganese–vanadium hybrid, K–V2C@MnO2 cathode, featured with MnO2 nanosheets uniformly formed on a V2CTX MXene surface, is elaborately designed and synthesized by metal–cation intercalation and following in situ growth strategy. Benefiting from the hybrid structure with high conductivity, abundant active sites, and the synergistic reaction of Mn2+ electrodeposition and inhibited structural damage of MnO2, K–V2C@MnO2 shows excellent electrochemical performance for aqueous ZIBs. Specifically, it presents the high specific capacity of 408.1 mAh g–1 at 0.3 A g–1 and maintains the specific capacity of 119.2 mAh g–1 at a high current density of 10 A g–1 in a long-term cycle of up to 10000 cycles. It is superior to almost all reported Mn-based cathodes for ZIBs in the aqueous electrolyte. The superior electrochemical performance suggests that the Mn-based cathode materials designed in this work can be a rational approach to be applied for high-performance ZIBs cathodes.
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Journal of Energy Chemistry
·
2021
·
IF 9.676
Zehui Fan,Chen Zhang,Wuxing Hua,Huan Li,Yan Jiao,Jingyi Xia,Chuan-Nan Geng,Rongwei Meng,Yingxin Liu,Quanjun Tang,Ziyang Lu,Tongxin Shang,Guowei Ling,Quan-Hong Yang
Lithium-Sulfur (Li-S) batteries with high theoretical energy density are promising energy storage systems in the next decades, while the lithium polysulfides (LiPSs) shuttling caused by the sluggish sulfur redox reaction severely lowers the practical performance. The use of interlayer between the cathode and separator has been widely investigated to physically or chemically block the LiPSs, while the introduction of catalytic materials is a more effective strategy to accelerate the conversion of LiPSs. MXene with rich surface chemistry has shown its potential for facilitating the catalytic conversion, however, the aggregation of MXene sheets usually leads to the loss of the catalytic active sites. Herein, we report a diatomite/MXene (DE/MX) hybrid material as the bifunctional interlayer for improving the adsorption/conversion of LiPSs in Li-S batteries. The diatomite with porous structure and rich silica-hydroxyl functional groups could trap LiPSs effectively, while prevent the aggregation of MXene. The DE/MX based interlayer showed bifunctions of enhancing the chemical adsorption and promoting the conversion of LiPSs. The Li-S batteries with the DE/MX interlayer delivered an improved cycling stability with a low capacity decay of 0.059% per cycle over 1000 cycles at 1.0 C. Moreover, stable 200 cycles can be realized with a high sulfur loading electrode up to 6.0 mg cm −2 . This work provides an effective strategy to construct bifunctional interlayers for hindering the shuttling of LiPSs and boosting the practical application of Li-S batteries.
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JOURNAL OF POWER SOURCES
·
2021
·
IF 9.127
Zheng Bo,Kexin Yi,Huachao Yang,Xinzheng Guo,Zhesong Huang,Zhouwei Zheng,Jianhua Yan,Kefa Cen,Kostya (Ken) Ostrikov
Ever-increasing mass loading of transition metal oxides (TMOs) yields high pseudocapacitance in laboratory electrochemical capacitors . However, their performance based on whole electrode mass is still far from industry standards. Highly-promising solution based on loading TMOs into 3D porous electrodes causes a yet unresolved challenge to find ways to achieve ultimate energy storage by atomically precisely loading less active material. Inspired by single-atom catalysis, we propose a new “ more from less but precise ” concept of homogeneously dispersing a common MnO 2 TMO via atomic sites to maximize atom redox reaction efficiency for industry-relevant pseudocapacitance. The concept is materialized by multifunctional MXene aerogel with super-hydrophilicity and surface functional groups, which provides 3D atomic nucleation sites to homogeneously load in-situ -formed, covalently-bonded MnO 2 nanosheets . The gravimetric capacitance of MnO 2 is largely enhanced, yielding superior pseudocapacitance of >400 F/g at > 5 mg/cm 2 that is typically achieved at 10 times lower loadings. Outstanding electrode areal capacitance is achieved using 2–3 times less MnO 2 mass, demonstrating industry-relevant pseudocapacitance almost twice higher than in state-of-the-art devices. MnO 2 /MXene//MXene asymmetric supercapacitor shows practically-high energy (~50.1 Wh/kg) and power (~10.0 kW/kg) densities, among the best MnO 2 pseudocapacitors . Capacitive-mechanism-controlled redox reactions, rarely achievable in diffusion-controlled porous pseudocapacitive electrodes, are revealed.
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