Journal of the Iranian Chemical Society
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2021
·Vol. 19
·期 4
·1489-1497
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IF 2.019
Chen Mei-Ling,Qiu Yun,Xu Ling,Tan Juan
This paper reports two new Cd(II)-based coordination polymers which are formulated as {[(CH 3 ) 2 NH 2 ][Cd(btc)]} n ·n(DMF) ( 1 ) as well as [Cd 3 (btc) 2 (2-bpmh)(H 2 O) 6 ]} n ·3n(H 2 O) ( 2 ) (H 3 btc = 1,3,5-benzenetricarboxylic acid, 2-bpmh = N , N -bis-pyridin-2-ylmethylene-hydrazine) under the solvothermal reaction conditions, compounds 1 – 2 exhibit intense luminescence emission and excellent photocatalytic property for MB decomposition under the light irradiation of UV. For the children lobar pneumonia treatment, we use ELISA detection kits to determine the TNF-α and IL-1β levels released by the lung epithelial cells. In addition to this, we can also determine the NF-κB’s activation levels by real-time RT-PCR.
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INDUSTRIAL CROPS AND PRODUCTS
·
2021
·
IF 5.645
Guangyu Wu,Qi Liu,Jingyi Wang,Siye Xia,Hualong Wu,Jiaxiang Zong,Jiangang Han,Weinan Xing
Wastewater containing pharmaceuticals can be bioaccumulated, posing a potential risk to drinking water, human health, and ecosystems. In order to make the adsorption process more suitable for actual application, rape straw biomass fiber (treated by an acidified sodium chlorite solution, 5%) and Fe 3 O 4 embedded β-CD to prepare a novel adsorbent (RSBCDF), which was used for the removal of ibuprofen (IBP) from aqueous solution. The RSBCDF was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET) measurements, scanning electron microscopy (SEM), and zeta potential measurements. The synthesized adsorbent was studied with regard to IBP removal percent under different adsorption conditions such as varying initial pH levels (4–10), initial ibuprofen concentrations (20−160 mg/L), contact time (5−150 min), and the dosage of adsorbent (10−100 mg) via batch adsorption experiments. The adsorption kinetics, thermodynamics, and isotherms were also investigated. The IBP adsorption behaviour followed a pseudo-second-order kinetic model and the Freundlich isotherm model. The maximum adsorption capacity obtained for ibuprofen was 48.29 mg/g. The values of Gibbs free energy change were negative (-2.58∼-3.56KJ/mol), suggesting that the process of ibuprofen adsorption onto adsorbent was spontaneous. The positive value of standard enthalpy change (12.09 kJ/mol) indicated that the adsorption process was endothermic. The obtained results prove that RSBCDF is a proficient and economically suitable material for removing IBP from water environments.
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CHEMICAL ENGINEERING JOURNAL
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2019
·
IF 8.355
Bao-Lin Zhang,Wei Qiu,Pan-Pan Wang,Yu-Lei Liu,Jing Zou,Lu Wang,Jun Ma
This study examined the effects of two kinds of iron-trimesic metal-organic frameworks (MOFs) [MIL-100(Fe) and Fe-BTC] on adsorption of Pb(II) and Cd(II). For both materials, adsorption of Pb and Cd nearly approached equilibriums in the initial 2 min with high pseudo-second-order kinetics rate constants (0.895 g·mg −1 ·min −1 for Pb and 1.416 g·mg −1 ·min −1 for Cd). Both materials showed better adsorption performance with the increase of solution pH (from 2 to 7). Adsorption processes were endothermic, entropy-increased and spontaneous. The higher enthalpy change ( Δ H 0 ) and entropy change ( Δ S 0 ) values for Cd adsorption reflected the more difficult adsorption of Cd compared with Pb, which is related with more negative hydration enthalpy ( Δ H hyd Θ ) and larger ionic radius of Cd. Multilayer adsorption phenomena appeared with no maximum adsorptive capacity observed. Both Langmuir-Freundlich and Freundlich-BET models could well describe isotherms. Multilayer adsorption may be attributed to the formation of inner-sphere complexation and outer-sphere complexation. Bockris-Devanathan-Muller (BDM) electrical double layer theory was used for illustrating adsorption mechanism. The fixed-bed adsorption experiments with Fe-BTC showed outstanding elimination performance in initial operating period (>99.8% for Pb and >99.6% for Cd), with effective filtration volume of 980 mL for Pb and 300 mL for Cd. Recyclability test showed that Fe-BTC could be well regenerated by ethylenediamine tetraacetic acid disodium salt (EDTA-2Na). This study showed that MIL-100(Fe) and Fe-BTC are potential for practical heavy metal removal applications.
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ANALYTICA CHIMICA ACTA
·
2019
·
IF 5.256
Liubing Kong,Ying Gan,Tao Liang,Longjie Zhong,Yuxiang Pan,Dmitry Kirsanov,Andrey Legin,Hao Wan,Ping Wang
As a powerful tool for medical diagnosis and bioanalysis , conventional optical spectrometers are generally expensive, bulky and always require an accompanying data processing device. In this work, we developed a novel smartphone-based CD-spectrometer (SCDS) for high sensitive and ultra-portable colorimetric analysis , with the advantage of cost-effective and simplicity. The distance between the light source and slit, the structure of SCDS and the parameters of camera in the smartphone were all optimized to ensure the best analytical performance. Besides, the SCDS employed HSV color model and utilized the overall intensity calculated by summing V-value of adjacent position for the absorbance measurement. In this way the errors caused by the low resolution of CD-grating can effectively be eliminated to promote the sensitivity of the SCDS. The performance of the SCDS was first validated for colorimetric detection of BSA with a detection limit of 0.0073 mg/mL, which is superior compared to that of the microtiter plate reader (MTPR). Moreover, by combining with 3,3′,5,5′-tetramethylbenzidine-manganese dioxide (TMB-MnO 2 ) nanosheets reaction, a high sensitive and specific system for ascorbic acid detection was established. The SCDS gives a detection range from 0.6250 μM to 40 μM with a detection limit of 0.4946 μM for AA detection. Compared to other studies, the SCDS features wide detection range and very low detection limit with low cost instrument. Therefore, the SCDS will be an ideal and promising colorimetric system for point-of-care (POC) application in food security, disease diagnosis and environmental monitoring.
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PubMed
高影响因子
Journal of Cleaner Production
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2018
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IF 5.651
Peng Liu,Yining Gao,Fazhou Wang,Lu Yang
Heavy metal contamination is an important environmental issue . Heavy metal removal by cementitious materials would be an efficient method because of their large-scale exposure to rainwater and groundwater. In this study, 3-thiocyanatopropyltriethoxysilane (TCPS)-modified Fly ash (T-FA) beads were prepared and incorporated into pervious concrete . The functionalized pervious concrete was used to sequester Cd (II) from solution, utilizing the chelating property of the thiocyanate on TCPS. TCPS molecules were chemically bonded onto FA beads after alkali activation , which was confirmed by IR spectroscopy. IR shows the vibration of Si OH and the asymmetric vibrations of CH 2 and CN on TCPS. In addition, 29 Si NMR spectroscopy identifies a new peak at −47.22 ppm assigned to T 2 [RSi(OSi) 2 OH]. T-FA beads can efficiently remove Cd (II) when immersed and stirred in a CdCl 2 solution. An equally significant sequestration capacity was demonstrated when T-FA beads were incorporated in pervious concrete. Cd (II) concentrations were reduced from 300 to 15.86 ppm when a 100 × 100 × 100 mm 3 T-FA-loaded concrete specimen was exposed to a 5 L CdCl 2 solution.
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BIOMATERIALS
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2013
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IF 7.604
Ke Ding,Lihong Jing,Chunyan Liu,Yi Hou,Mingyuan Gao
Magnetically engineered Cd-free CuInS 2 @ZnS:Mn quantum dots (QDs) were designed, synthesized, and evaluated as potential dual-modality probes for fluorescence and magnetic resonance imaging (MRI) of tumors in vivo . The synthesis of Mn-doped core–shell structured CuInS 2 @ZnS mainly comprised three steps, i.e., the preparation of fluorescent CuInS 2 seeds, the particle surface coating of ZnS, and the Mn-doping of the ZnS shells. Systematic spectroscopy studies were carried out to illustrate the impacts of ZnS coating and the following Mn-doping on the optical properties of the QDs. In combination with conventional fluorescence, fluorescence excitation, and time-resolved fluorescence measurements, the structure of CuInS 2 @ZnS:Mn QDs prepared under optimized conditions presented a Zn gradient CuInS 2 core and a ZnS outer shell, while Mn ions were mainly located in the ZnS shell, which well balanced the optical and magnetic properties of the resultant QDs. For the following in vivo imaging experiments, the hydrophobic CuInS 2 @ZnS:Mn QDs were transferred into water upon ligand exchange reactions by replacing the 1-dodecanethiol ligand with dihydrolipoic acid-poly(ethylene glycol) (DHLA-PEG) ligand. The MTT assays based on HeLa cells were carried out to evaluate the cytotoxicity of the current Cd-free CuInS 2 @ZnS:Mn QDs for comparing with that of water soluble CdTe QDs. Further in vivo fluorescence and MR imaging experiments suggested that the PEGylated CuInS 2 @ZnS:Mn QDs could well target both subcutaneous and intraperitoneal tumors in vivo .
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
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2017
·Vol. 24
·期 29
·23144-23152
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IF 2.741
Wang Li,Lu Yixin,Yang Chen,Chen Chengyu,Huang Weilin,Dang Zhi
The stability of nanoparticles (NPs) in aquatic environments is important to evaluate their adverse effects on aquatic ecosystems and human health. Nanoparticle stability is known to be influenced by coexisting ions and dissolved organic matter. This study was designed to investigate the effects of coexisting low-level Cd(II) on the stability of humic acid-coated nano-TiO 2 (HA-TiO 2 ) particles in aquatic environments by measuring their aggregation kinetics through time-resolved dynamic light scattering (DLS) and monitoring suspended HA-TiO 2 concentrations via optical absorbance changes over time. The particles exhibited aggregation behavior consistent with the classic Derjaguin–Landau–Verwey–Overbeek (DLVO) theory. The results showed that Cd(II) concentration, pH, and ionic strength had various effects on the aggregation kinetics of the HA-TiO 2 NPs. The HA-TiO 2 particles aggregated faster as the Cd(II) concentration increased whereas the stability of the nanoparticles increased as the solution pH increased or ionic strength decreased regardless of the Cd(II) concentration. At the fixed pH and ionic strength conditions, the addition of Cd(II) promoted aggregation of nanoparticles, leading to higher attachment efficiencies. The enhanced aggregation of the HA-TiO 2 NPs in the presence of coexisting cadmium ions in aqueous solutions indicated that the fate and transport of nanoparticles could be greatly affected by heavy metals in aquatic environments.
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RSC Advances
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2017
·Vol. 7
·期 59
·36929-36934
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IF 3.108
Danfeng Qin,Ruiyu Xu,Hangjia Shen,Xamxikamar Mamat,Le Wang,Shanshuang Gao,Ying Wang,Nuerbiya Yalikun,Thomas Wagberg,Shiguo Zhang,Qunhui yuan,Yongtao Li,Guangzhi Hu
Nitrogen-doped mesoporous carbon (NMC) derived from a single small-molecule protic salt (p-phenylenediamine bisulfate) is used for sensing toxic heavy metal ions. Using Nafion, bismuth and NMC to anchor the glassy carbon electrode surface, the fabricate electrode shows high sensitivity for detecting Cd(II) and Pb(II). The limits of detection (S/N = 3) are estimated to be 0.3 μg L−1 for Cd(II) and 0.4 μg L−1 for Pb(II), respectively, which are 10 and 25 times lower than the maximum acceptable content for drinking water recommended by the WHO. Furthermore, the sensor is successfully used to analyze Cd(II) and Pb(II) in tap-water with high anti-interference capability and good recovery.
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Journal of Materials Chemistry A
·
2017
·Vol. 5
·期 30
·15797-15807
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IF 8.867
Dan Zhao,Xiao-Hui Liu,Yue Zhao,Peng Wang,Yi Liu,Mohammad Azam,Saud I. Al-Resayes,Yi Lu,Wei-Yin Sun
Excess and deficiency of iron(III) and antibiotics from normal permissible limits will induce serious disorders, so their detection is important but challenging. In this work, by introducing a new amino triazole ligand N1-(4-(1H-1,2,4-triazole-1-yl)benzyl)-N1-(2-aminoethyl)ethane-1,2-diamine (L), a series of Cd(II)-based metal–organic frameworks (MOFs) [Cd3(BDC)3(DMF)2] (1), [Cd(L)(BDC)]2·2DMF·H2O (2), [NaCd2(L)(BDC)2.5]·9H2O (3), [Cd2(L)(2,6-NDC)2]·DMF·5H2O (4) and [Cd2(L)(BPDC)2]·DMF·9H2O (5) were synthesized. MOFs 1, 2 and 3 obtained under the same conditions with the same auxiliary ligand (H2BDC) but different amounts of alkali (NaOH) show distinct 3D, 1D and 3D framework structures, respectively, in which L and BDC2− exhibit varied coordination modes. 4 and 5 with 3D structures were isolated by using longer auxiliary ligands of 2,6-H2NDC and H2BPDC. The porosity and excellent fluorescence performance of 3, 4 and 5 make them potential luminescent sensors for Fe(III) and antibiotics. The results show that 3, 4 and 5 represent high sensitivity for the detection of Fe(III) ions with detection limits of 155 ppb for 3, 209 ppb for 4 and 297 ppb for 5 due to the existence of open channels and chelating NH2 sites. In addition, the strong emissions of 3, 4 and 5 can be quenched efficiently by trace amounts of NFs (nitrofurazone, NZF; nitrofurantoin, NFT; furazolidone, FZD) antibiotics even in the presence of other competing antibiotics such as β-lactams (penicillin, PCL). They are responsive to NZF with detection limits of 162 ppb for 3, 75 ppb for 4 and 60 ppb for 5.
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CERAMICS INTERNATIONAL
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2024
·
IF 5.1
Wenwu Zhao,Jinqiang Liu,Haijing Zhou,Jianyuan Yu,Bin Hao,Jian Liu
The efficient photogenerated carriers separation is the key factor in enhancing the activity of photocatalysts to solve environmental pollution problems. The internal polarized electric fields in polar materials most likely provide a more direct and stronger driving force for photogenerated carriers separation. Here, we investigate polar ε -Cd(IO 3 ) 2 (CIO) with two different morphologies as an efficient photocatalyst for the photodegradation of antibiotics and dyes. According to the theoretical calculation of the ratios of m h */ m e * along three different crystal axis directions, the photogenerated carrier separation efficiency along the c -axis direction is the largest, which matches the direction of the polarized electric field in the crystal. The internal polarized electric field promotes the separation of photogenerated carriers, leading to a high transfer efficiency of the catalyst. Moreover, photodegradation experiments demonstrate that the photocatalytic activity of CIO-1 is approximately 3 times that of TiO 2 P25. This study provides some insights that might aid the development of polar photocatalysts with superior performance.
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JOURNAL OF DISPERSION SCIENCE AND TECHNOLOGY
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2024
·
IF 1.9
Chunlai Wu,Yalei Miao,Juan Li,Jiaxiang Cao
Ionic liquids have been considered as green solvent for metal ion extraction. However, the high cost, low efficiency and hard phase separation limit their application. In this work, nano SiO2 supported ionic liquid (SiO2@NH-IL) prepared via simple homogeneous sol-gel method was used for adsorptive removal of Cd(II) from water sample. The material was characterized by XRD, TEM and FT-IR and zeta potential analysis. The adsorption kinetics, adsorption isotherm and reusability as well as the adsorption mechanism were investigated. The effects of solution pH and temperature were also studied. It was found that this nano-adsorbent could be used to remove trace level of Cd(II) efficiently due to the strong coordination of Cd(II) with the ionic liquid. Thermodynamic and kinetic studies showed that the adsorption rate increased with the increase of temperature, the maximum adsorption capacity was 112.13 mg g−1 at higher temperature (i.e. 80 °C), and the adsorption equilibrium could achieve in 30 min. The nano-adsorbent could be easily regenerated by 0.5 mol L−1 of HCl and reused as least ten adsorption/desorption cycles. The as-prepared nano-adsorbent are potential candidate for adsorptive removal of Cd(II) in polluted wastewater, especially with higher temperature.
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CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Zhenlei Wang,Tingting Zhang,Yunliang Zhao,Yanhui Miao,Lingjie Zhang,Damiano Sarocchi,Shaoxian Song,Qiwu Zhang
Large scale of Cd-contaminated soil has become a serious threat to environmental safety and human health, whereas field applicability of existing remediation technologies has encountered numerous obstacles, such as poor stability, secondary pollution, long operation time, and high chemical cost. Herein, a novel activated calcite with significantly enhanced immobilization stability of Cd in soil has been synthesized based on mechanochemical technology. Our results demonstrate that the passivation rate of bioavailable Cd in Cd-contaminated soil (initial concentration 3 mg/kg) could be maintained at 65 % after 50 days of passivation cultured with activated calcite. Mechanistic studies have revealed that the outstanding performance is attributed to the enhancement of the CO 3 2– and Ca 2+ release properties of calcite through mechanical activation, leading to a 550 % increase in Ca 2+ release. The CO 3 2– fraction binds in situ to the free Cd in the soil, forming a stable carbonate-bound state. Simultaneously, the OH – released from the continuous hydrolysis of CO 3 2– effectively regulates and stabilizes the soil pH within the neutral range. Further, SEM-EDS and sequential extraction procedures (SEP) analyses implied that the specific adsorption of Cd by in-situ formed iron oxides in soil was visibly related to the release of OH – from activated calcite and immobilized the free state Cd in the more stable iron oxide-bound state. The current work shows the high sustainability and stability of Cd-contaminated soil immobilization by activated calcite materials.
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