ACS Nano
·
2015
·
IF 12.881
Feng Zhang,Haizheng Zhong,Cheng Chen,Xian-gang Wu,Xiangmin Hu,Hailong Huang,Junbo Han,Bingsuo Zou,Yuping Dong
Organometal halide perovskites are inexpensive materials with desirable characteristics of color-tunable and narrow-band emissions for lighting and display technology, but they suffer from low photoluminescence quantum yields at low excitation fluencies. Here we developed a ligand-assisted reprecipitation strategy to fabricate brightly luminescent and color-tunable colloidal CH3NH3PbX3 (X = Br, I, Cl) quantum dots with absolute quantum yield up to 70% at room temperature and low excitation fluencies. To illustrate the photoluminescence enhancements in these quantum dots, we conducted comprehensive composition and surface characterizations and determined the time- and temperature-dependent photoluminescence spectra. Comparisons between small-sized CH3NH3PbBr3 quantum dots (average diameter 3.3 nm) and corresponding micrometer-sized bulk particles (2–8 μm) suggest that the intense increased photoluminescence quantum yield originates from the increase of exciton binding energy due to size reduction as well as proper chemical passivations of the Br-rich surface. We further demonstrated wide-color gamut white-light-emitting diodes using green emissive CH3NH3PbBr3 quantum dots and red emissive K2SiF6:Mn4+ as color converters, providing enhanced color quality for display technology. Moreover, colloidal CH3NH3PbX3 quantum dots are expected to exhibit interesting nanoscale excitonic properties and also have other potential applications in lasers, electroluminescence devices, and optical sensors.
研究领域:
材料科学
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纳米技术
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光电子学
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显示技术
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光子学
✓ 已验证
DOI
高影响因子
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
·
2023
·Vol. 39
·期 4
·654-659
·
IF 3.1
Zhu Xia,An Jiakun,Chen Gaoyu,Xing Chenyu,Bao Jianchun,Xu Xiangxing
Perovskite single crystals are prominent semiconductor materials due to their high carrier mobility, long carrier diffusion length, and large absorption coefficient. They can be used as optoelectronic functional materials for narrowband or broadband photodetectors. In this report, the photodetection band tunability was achieved by doping MAPbX 3 (MA=methylammonium, X=Cl/Br/I) perovskite single crystals with sub-nano carbon dots (MAPbX 3 -C). The sub-nano size and good dispersibility of the carbon dots ensured controllable doping. The absorption of the sub-nano carbon dots and trap states in the MAPbX 3 -C single crystals resulted in the special responsivity spectrum features.
研究领域:
材料科学
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光电子学
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半导体物理
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纳米技术
·
光子学
✓ 已验证
DOI
高影响因子
FirePhysChem
·
2026
·
IF 3.6
Handong Shi,Shijiao Li,Chuanhao Xu,Kai Han,Fan Liao,Yanpeng Lv,Guoqiang He,Wenxuan Liang,Chongwei An
This work presents a molecular-to-structural strategy for fabricating high-performance CL-20-based composite energetic materials using direct ink writing (DIW). A poly(vinyl alcohol)/poly(acrylic acid)/modified potassium titanate whisker (PVA/PAA/ M-PTW) interpenetrating polymer network (IPN) was designed to simultaneously enhance mechanical strength and reduce mechanical sensitivity. The hydrogen bonding–covalent crosslinking–filler reinforcement mechanism ensured uniform dispersion of CL-20 crystals and strong interfacial adhesion within the polymer matrix. Surface modification of PTW with 5 wt% KH-550 improved compatibility with the IPN, yielding printed structures with excellent form accuracy and adhesion to aluminum substrates (0.961 MPa). The optimized composite exhibited high compressive strength (16.77 MPa) and reduced impact and friction sensitivities compared with ε-CL-20 and submicron CL-20 samples. It achieved stable detonation wave transmission within a 90°-160° corner range in a 1.2 × 1.2mm charge slot, with the critical detonation size reaching 0.3m × 0.3mm. The measured detonation velocity of 7267.9m/s (83.2% of theoretical). These results demonstrate that the DIW-based PVA/PAA/M-PTW system enables the precise construction of high-strength, low-sensitivity energetic composites with reliable detonation performance, providing a promising pathway for advanced micro-scale energetic devices.
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产品关联
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2026
·
IF 9.1
Kaijie Pei,Hang Lyu,Ai-Bo Jia,Rong Zhong,Chuping Chang,Xiaosi Su
Ammonium in groundwater hampers sustainable water use, calling for efficient, stable in-situ remediation technologies. In this study, we design a novel coated sustained-release candle (CSRC) that contains peroxymonosulfate (PMS) and chloride ions (Cl − ). The aim is to construct an in situ long-acting SO 4 • − –Cl − oxidation system for groundwater ammonium removal. The outer coating effectively addressed the issue of “burst release” of paraffin-based sustained-release materials during the initial release stage. It also prolonged the effective release period and guaranteed the synchronous PMS and Cl − release. Systematic static release experiments revealed the critical roles of the CSRC diameter and reagent-to-paraffin mass ratio in regulating the release profiles. Column experiments demonstrated that CSRC deployment within an injection well significantly enhanced the reagent release compared to direct embedding. In addition, the groundwater flow rate exerted no influence on the CSRC release. The long-term operation confirmed the sustained generation of Cl•/ClO• and effective ammonium removal along the flow path. Moreover, three-dimensional tank experiments under varying hydraulic gradients and screen lengths showed that increases in the hydrodynamic conditions and well-screen length markedly improved the radial penetration and vertical dispersion of reagents in the aquifer and enabled the effective ammonium removal for up to 56 days. Collectively, this work presents a feasible and engineered strategy by adjusting the reagents ratio, diameter, and CSRC length that achieves the stable, long-term in-situ chemical oxidation of ammonium in groundwater. This work offers theoretical insights and practical guidance for applying sustained-release material-based remediation systems in the field.
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DOI
高影响因子
INORGANIC CHEMISTRY COMMUNICATIONS
·
2025
·
IF 5.4
Jianwei Dao,Liang Yang,Zhihao Jiang,Zihao Han,Tiqin Wei
Narrow-band red inorganic phosphors excited by near-ultraviolet (n-UV) light have significant application potential in the manufacture of white light-emitting diodes (LEDs) with high R9 index. Novel near-UV-excitable Eu 3+ doped K 3 Ca 2 (SO 4 ) 3 × (X = F, Cl, Br) halosulphate phosphors were synthesized via high-temperature solid-state reaction method. By modifying the non-activating ions in the host matrix, the luminescence properties of Eu 3+ were effectively enhanced across various matrices, thereby optimizing the performance of this series of phosphors. As-prepared phosphors can be activated under 397 nm excitation and emit red light at 619 nm, corresponding to 5 D 0 → 7 F 2 transitions of Eu 3+ . Optimization of the doping concentration revealed that the optimal Eu 3+ concentration for different host matrices is 0.13. Notably, the K 3 Ca 2 (SO 4 ) 3 F host matrix doped with Eu 3+ exhibits stronger emission intensity and better performance. The K 3 Ca 2 (SO 4 ) 3 F:0.13Eu 3+ phosphor exhibited long fluorescence lifetime of 0.42 ms and high color purity of 92.25 %. The emission intensity of K 3 Ca 2 (SO 4 ) 3 F:0.13Eu 3+ at 423 K can retain 89.5 % of its value at room temperature. A white LEDs device was fabricated by mixing and encapsulating K 3 Ca 2 (SO 4 ) 3 F:0.13Eu 3+ phosphor with commercial BaMgAl 10 O 17 :Eu 2+ blue and (Ba, Sr) 2 SiO 4 :Eu 2+ green phosphors onto 397 nm n-UV InGaN chip. The device emits bright white light and exhibits high color rendering index (Ra = 79.9, R9 = 86.5) and a suitable correlated color temperature (CCT = 5915 K) at 50 mA drive current. The results suggest that this work provides new assistance in achieving high color rendering white LEDs excited by n-UV light.
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高影响因子
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS
·
2025
·
IF 6.2
Chenhao Li,Yi Niu,Linlin Yi,Yaoqiang Li,Jia Fu,Fang Tang,Kaiyuan Li,Yanyan Zou
This paper explores the application of zeolitic imidazolate framework-8 (ZIF-8) in pyrolytic disposal of poly(vinyl chloride) (PVC), with the goal of assessing the in situ catalytic removal and capture effect of ZIF-8 on Cl, elucidating the migration pattern of Cl, revealing the mechanism of in situ Cl capture by ZIF-8. The results demonstrate that excellent catalytic and Cl trapping properties are exhibited by ZIF-8, and an additional 311.1 mg/g of organic Cl from PVC is facilitated to be removed at 250 ºC. The catalytic effect enhances Cl trapping at low temperatures. The solid-solid reaction between PVC and ZIF-8 during in situ pyrolysis significantly improves Cl capture compared to ex situ pyrolysis. During in situ pyrolysis, ZIF-8 shows excellent Cl capture between 250 and 350 ºC, where Cl is primarily captured in the solid phase as inorganic Cl. ZIF-8 achieves optimal Cl capture at 300 ºC, reaching a peak HCl removal rate of 89.5 %. At this temperature, the content of solid-phase inorganic Cl reaches a maximum of 442.0 mg/g, accounting for 78.7 wt% of the total Cl content. The key to Cl capture lies in the chemical adsorption sites of Zn²⁺ and organic ligands in the ZIF-8 structure, which can react with Cl in both solid-solid and gas-solid reactions. Additionally, crystals formed during pyrolysis create an adsorption barrier, ultimately enabling efficient Cl capture.
研究领域:
环境科学
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材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
CORROSION SCIENCE
·
2025
·
IF 8.5
Shiyao Du,Dongfang Jia,Xin Guo,Jinke Wang,Zhibin Chen,Lingwei Ma,Dawei Zhang
The coupling effect of adipic acid and Cl - on the corrosion of SAC305 solder alloy is systematically investigated. Electrochemical measurements prove that Cl - could completely destroy the protectiveness of adipic acid and accelerate metal corrosion. Morphology characterizations and XPS analyses verify that the amount of adsorbed adipic acid on the metal surface is largely reduced due to competitive adsorption of Cl - . TEM and Mott-Schottky tests further reveal that the defect density of the oxide film developed in Cl - environment is three times higher than that in adipic acid, which is responsible for the faster anodic dissolution.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED CATALYSIS B-ENVIRONMENTAL
·
2022
·
IF 24.319
Xiao Yu,Mengyi Shi,Yixuan Fan,Lixia Yang,Jie Zhang,Wei Liu,Weili Dai,Shuqu Zhang,Lei Zhou,Xubiao Luo,Shenglian Luo
Mn 2 O 3 is an exceptional earth-abundant mineral that has been extensively applied in catalytic oxidation because of the strong redox couples like Mn 3+ /Mn 2+ and Mn 4+ /Mn 3+ exposed on Mn 2 O 3 surface. Herein, the catalytic activity of Mn 2 O 3 in photothermal degradation of toluene was regulated by halogens including F - , Cl -, and Br - . As the electronegativity ordered in F (3.98) > O (3.44) > Cl (3.16) > Br (2.96), F - doped Mn 2 O 3 overperforms Cl - doped and Br - doped Mn 2 O 3 in decomposing toluene. DFT theoretical calculation illustrates that F - attracts the shared electrons from Mn to itself, the deviated charge center stretches the adjacent Mn-O bonds and boosts the generation of abundant oxygen vacancies, helping to strengthen the catalytic activity of Mn 2 O 3 . Conversely, Mn-O bonds are shortened by Cl - and Br - that have lower electronegativity than O. The multiple electrons circling Cl - and Br - push Mn towards O and squeeze Mn-O bonds, resulting in the formation of passivated Mn 2 O 3 . In conjunction with Mn redox couples and oxygen vacancies, 99% of 400 ppm toluene can be eliminated by F - doped Mn 2 O 3 , corresponding mineralization rate is high up to 95.8%.
研究领域:
催化
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环境科学
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材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2025
·
IF 8.2
Kun Lang,Yuanyingxue Gao,Xudong Xiao,Qi Li,Mingyang Liu,Jianan Liu,Huiquan Gu,Wei Wu,Huiyuan Meng,Baojiang Jiang
Seawater electrolysis offers a sustainable pathway for green hydrogen production, but chloride-induced side reactions, particularly chlorine evolution (ClER), limit the stability and efficiency of catalysts. Based on an interface-engineering strategy, a bifunctional CoP–MXene electrocatalyst was designed and fabricated, in which electrons are transferred from the Ti sites of the MXene support to the adjacent Co active centers of CoP. This directional electron donation modulates the Co electronic structure, generating electron-rich Co sites that effectively suppress Cl– adsorption via electronic repulsion while preserving the OH– reaction pathways through favorable proton–electron coupling. X-ray absorption fine structure (XAFS) spectroscopy, in situ Raman spectroscopy, and density functional theory (DFT) calculations further validate this electron modulation mechanism. In 1 M KOH electrolyte, CoP–MXene achieves a hydrogen evolution reaction (HER) overpotential of only 93 mV at 10 mA cm–2 and an oxygen evolution reaction (OER) current density of 50 mA cm–2 at 346 mV. In alkaline seawater, CoP–MXene exhibits exceptional HER performance (10 mA cm–2 @ 101 mV). Moreover, in an anion exchange membrane (AEM) electrolyzer (at 2 A cm–2 current density), the catalyst maintains over 500 h of stability in seawater with only 8.5% current decay, significantly outperforming the control samples. This study provides a new design strategy for the development of chloride-resistant electrocatalysts, advancing the application of seawater electrolysis technologies.
研究领域:
电化学
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催化
·
能量转换
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材料科学
·
可再生能源
·
表面科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Materials Science and Engineering B-Advanced Functional Solid-State Materials
·
2021
·
IF 4.051
Zhihao Chen,Haiyang He,Zhuoqi Wen,Zhongjie Cui,Shiliang Mei,Dan Yang,Xian Wei,Wanlu Zhang,Fengxian Xie,Bobo Yang,Ruiqian Guo
Broadband emission Mn 2+ doped lead halide perovskites are deemed as promising phosphor materials for solid state white light-emitting-diodes (WLEDs). Herein, we report a facile gram-scale synthesis of Mn-doped CsPb(Br/Cl) 3 phosphors by doping MnCl 2 into CsPbBr 3 perovskite nanocrystals at room temperature. The obtained phosphors present dual-color emission with blue emission at 463 nm and red emission at 602 nm. Increasing MnCl 2 doping amount can enhance the red emission while more 3-Aminopropyltrimethoxysilane (APTMS) ligands can repress Mn related impurity and provide high stability. Further, two kinds of WLEDs (monocomponnet and two-component) are demonstrated. The monocomponent WLED exhibits warm white light under various driving currents (30 mA–150 mA), and the two-component WLED shows good chromatic performance close to ideal white light (0.33, 0.33), demonstrating their potential applications in WLED devices.
研究领域:
材料科学
·
光学工程
✓ 已验证
DOI
高影响因子
Materials Today Chemistry
·
2022
·
IF 7.613
J. Ding,X. Cui,Q. Ren,Y. Mao,J. Zhang,G. Zhou,X.-M. Zhang
Organic-inorganic metal halides have garnered extensive attention due to their versatile structures as well as fascinating optical properties , among which especially antimony halides are the focus of recent research. Herein, we design a series of novel zero-dimensional (0D) antimony halides of (C 13 H 14 N 3 ) 3 SbCl 6– x Br x ( x = 0, 3, 6) with bright and tunable broadband emissions from yellow (576 nm) to orange (600 nm), which are attributed to the triplet self-trapped excitons (STEs) of the six-coordinated [SbX 6 ] 3– (X = Cl − or Br − ) units. The role of halogens on their specific 3 P 1 → 1 S 0 transition is determined, wherein Cl/Br transmutation reveals a common law modulating photoluminescence behaviors. Furthermore, a new two-step compound technology is innovatively developed for performance optimization, enabling by incorporating the pristine antimony halides into polymethyl methacrylate (PMMA) with high transparency and strong moisture resistance . The composites (C 13 H 14 N 3 ) 3 SbCl 6– x Br x /PMMA ( x = 0, 3, 6) were fabricated through a demanding technology that significantly improve the processability and water stability of antimony halides while maintaining high photoluminescence quantum yields . This work not only proposes a method for halogen substitutions to tune emission, but also opens up a feasible research avenue for performance optimization in the multifunctional luminescence materials.
研究领域:
材料科学
·
光学
·
化学工程
✓ 已验证
DOI
高影响因子
LANGMUIR
·
2023
·
IF 3.9
Fang Chen,Li Yin,Teng He,Tao Chen,Hangbo Yue,Chufen Yang
To enhance the stability of the polymeric micelles and optimize their drug-controlled release ability, three disulfide-linked polyethylene glycol methyl ether methacrylate–disulfide–poly(ε-caprolactone-co-γ-amine−ε-caprolactone) (PPEGMA-SS-P(CL-co-ACL)) polymers were synthesized and characterized by 1H NMR, GPC, and FT-IR successfully, and their dual pH/reduction-responsive cross-linked polymeric micelles were prepared for paclitaxel (PTX) delivery by using 2,3-dimethylmaleic anhydride (DMMA) as the cross-linking agent. The PTX loading capacity (LC) and encapsulation efficiency (EE) values of the cross-linked micelles formed by PPEGMA8-SS-P(CL47-co-ACL15) achieved were 23.96% and 71.58%, slightly higher than those of un-cross-linked micelles. Both particle sizes of blank micelles and in vitro drug release of PTX-loaded micelles confirmed that compared with those un-cross-linked micelles, the cross-linked micelles were more stable at pH 7.4 + 0 mM DTT, with a PTX cumulative release of 13% at 120 h, while the PTX cumulative release of the cross-linked micelles at pH 5.0 + 10 mM DTT were close to that of un-cross-linked micelles after 60 h, indicating the successful reversible cross-linking and smooth drug release of the cross-linked micelles. The cytotoxicity assay showed that PPEGMA8-SS-P(CL47-co-ACL15) and its cross-linked micelles had low cell cytotoxicity, and both PTX-loaded micelles revealed a certain inhibitory effect on HepG2 cells. These results revealed that the dual pH/reduction-responsive cross-linked polymeric micelles prepared from PPEGMA8-SS-P(CL47-co-DCL15) were a promising candidate for PTX delivery.
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产品关联
DOI
PubMed
高影响因子
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