JOURNAL OF ALLOYS AND COMPOUNDS
·
2020
·
IF 4.65
A.Y. Chen,H.H. Liu,P. Qi,X.F. Xie,M.T. Wang,X.Y. Wang
3D flower-like MoS 2 /NiCo(OH) 2 CO 3 (MoS 2 /NiCoHC) composites are synthesized by a hydrothermal method using MoS 2 nanospheres as precursors. The microstructure of the composite is characterized by X-ray diffraction, Raman spectroscopy , scanning electron microscopy, transmission electron microscopy and X-ray photoelectron spectroscopy. The MoS 2 nanospheres are served as nucleating agent to trigger the formation of NiCoHC nanosheets , which self-assemble into 3D flower-like MoS 2 /NiCoHC particles. The MoS 2 /NiCoHC composites exhibit a high supercapacitive performance with a specific capacity of 583 C g −1 (1296 F g −1 ) at 1 A g −1 and a long-term cycling stability by retaining 94.3% after 2000 cycles in 2 M KOH. Moreover, the asymmetric supercapacitor of MoS 2 /NiCoHC as the positive electrode and commercial active carbon as the negative electrode achieves a high power density of 375 W kg −1 at 16.4 Wh kg −1 . The enhanced performance of the MoS 2 /NiCoHC composite can be attributed to the larger surface area provided by 3D flower-like structure and the synergy of the two hybrids.
✓ 已验证
产品关联
DOI
高影响因子
CHEMISTRY OF MATERIALS
·
2020
·
IF 9.567
Yangfan Lin,Jingwei Jiang,Yaguang Zhang,Xueqin He,Jianguo Ren,Peng He,Chunlei Pang,Chengmao Xiao,Deren Yang,Ning Du
The promoting effect of hydroxyls on a silicon surface on the decomposition of an electrolyte is studied by comparing the performance of silicon–hydroxyl (Si–OH) and silicon–alkyl (Si–C3H7) electrodes. X-ray photoelectron spectroscopy (XPS) characterization of solid electrolyte interphase (SEI) layers on both electrodes demonstrates the influencing mechanism that hydroxyls can react with LiPF6 to form POF3, which further induces the decomposition of the electrolyte solution. This study provides a new consideration that limiting the amount of hydroxyls on the silicon surface in an appropriate range is significant to the electrochemical performance of silicon-based anode materials.
✓ 已验证
产品关联
DOI
高影响因子
Natural Product Communications
·
2020
·
IF 0.468
Qiushan Zhang,Jin Shao,Tong Zhao,Lei He,Huiping Ma,Linlin Jing
In the present study, the antioxidant property of 4 flavones (moslosooflavone, wogonin, isowogonin, and norwogonin) was evaluated using 6 different assays: 1,1-diphenyl-2-picrylhydrazyl (DPPH·), superoxide (O2 •−), and nitric oxide (NO) radical scavenging assays, ferrous iron chelation, reducing power, and total antioxidant capacity. The 4 flavones exhibited antioxidant activities with decreasing order as norwogonin > isowogonin >> wogonin> moslosooflavone. The present results demonstrated that norwogonin and isowogonin exhibited excellent antioxidant activity, which was mainly based on the presence of C-8 hydroxyl group.
✓ 已验证
产品关联
DOI
高影响因子
ATMOSPHERIC ENVIRONMENT
·
2020
·
IF 4.039
Fenghua Li,Shanshan Tang,Narcisse T. Tsona,Lin Du
Kinetics and mechanism of α-terpineol oxidation by OH radicals were studied in the aqueous phase under acidic condition, and the optical properties of the reaction products were examined. Using the relative rate method, the rate constant of α-terpineol reaction with OH radicals was determined to be (1.3 ± 0.3) × 10 10 M −1 s −1 . The reaction products were analyzed by gas chromatography-mass spectrometry (GC-MS) and the reaction mechanism was proposed. The absorbance changes of the products were monitored by a UV–vis spectrophotometer, and α,β-unsaturated ketone compounds were observed. A certain distribution of α-terpineol in the aqueous phase has the potential to be conducive to the formation of aqueous secondary organic aerosols. At the same time, in order to investigate the persistence of α-terpineol in the atmosphere, its lifetime towards reaction with OH in atmospheric water was determined to be 6.2 h and 1.0 h in urban and remote area, respectively.
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2020
·
IF 6.182
Ni Han,Qixiang Xu,Gashaw Beyene,Qinfang Zhang
Photocatalytic degradation has been regarded as a promising method for environmental remediation. In this work, layered g-C 3 N 4 /(BiO) 2 (OH) x Cl 2− x (NBHC) heterojunction composites were synthesized by a hydrothermal method. The two-dimensional (2D)/2D porous layered Z-scheme heterojunction leaded to the suppressed recombination and the efficient separation of photogenerated electron-hole pairs. Meanwhile, NBHC composites exhibited a high specific surface area and rich mesopores for more reactive active sites. Thus, NBHC had an excellent photocatalytic degradation performance of pollutant trypan blue (TB). Furthermore, we found that the active species of superoxide radical ( O 2 − ) played a more important role, while hydroxyl radical ( OH) contributed to a lesser extent in photocatalytic degradation of TB based on the active species capture experiment and electron spin resonance (ESR) spectra. A Z-scheme photocatalytic mechanism was proposed to understand the photodegradation of TB. This study may provide a new horizon for constructing novel Z-scheme heterostructure photocatalysts with an excellent performance.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2021
·
IF 5.316
Songmei Li,Yimin Yu,Xiaoyan Sun,Xifeng Ding,Huafang Yang,Shibing Pan,Lixi Wang,Qitu Zhang
Ni(OH) 2 has been acknowledged as a promising oxygen evolution reaction (OER) electrocatalyst owing to its good electrochemical activity and low cost. However, application of the pristine Ni(OH) 2 is limited by the poor conductivity and low exposure of the active sites. Herein, a [email protected] (OH) 2 composite is prepared through a hydrothermal reaction. Heat treatment temperature proves to have a great influence on the electrocatalytic activity. In 0.1 M KOH electrolyte, the composite treated at 175 °C shows an overpotential of only 287 mV to reach the current density of 10 mA·cm −2 . Besides, the low Tafel slope (42 mV·dec −1 ) and superior stability (15 h at 10 mA·cm −2 ) also confirm the composite as an excellent OER electrocatalyst. The brilliant activity and stability toward OER can be attributed to the promoted coupling between Ni and Fe centers and the improved conductivity due to the 2D 18 p-electrons ring conjugate structure of hemin. Besides, effective hydrogen bonds between Ni(OH) 2 and hemin hinder the aggregation of Ni(OH) 2 , which ensures the catalyst enormous accessible active sites. This work offers a new method for the modification of Ni(OH) 2 as OER electrocatalysts. And the application of hemin also serves as a successful case for the use of biomass materials in OER electrocatalysis .
✓ 已验证
产品关联
DOI
高影响因子
Nanoscale
·
2019
·Vol. 11
·期 19
·9444-9456
·
IF 6.97
Xinyi Lian,Zhou Chen,Xiang Yu,Tingting Fan,Yunyun Dong,Hesheng Zhai,Weiping Fang,Xiaodong Yi
To solve the intrinsic deficiency inherited from the large band gap of ZnSn(OH)6 (ZSH), a gradual sulfur doping strategy is first proposed here to expand the optical absorption range, improve the separation efficiency of photogenerated electron–hole pairs, and thus enhance the photocatalytic activity. It is demonstrated that the distribution of sulfur in the flower-like ZSH (the sulfur doped sample is denoted as S-ZSH) tends to be largest on the outer most surface and becomes smaller towards the interior. The S-ZSH therefore has a gradual bandgap structure that is beneficial for transferring photogenerated charge carriers from the interior to the surface, which will greatly enhance the utilization of photoelectrons. As a result, the visible light photocurrent density of S-ZSH and the photocatalytic degradation rate of rhodamine (RhB) are about 5 and 10 times higher than with pristine ZSH, respectively.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CARBOHYDRATE POLYMERS
·
2019
·
IF 6.044
Pengfei Zou,Wen-Hui Lee,Zhiqin Gao,Di Qin,Yuxia Wang,Jiao Liu,Tongyi Sun,Yuanyuan Gao
Novel nanomaterials have been developed for antimicrobial and wound healing applications. Here, we report the preparation of a polyvinyl alcohol/chitosan (PVA/CS) nanofiber with carboxymethyl chitosan nanoparticles (CMCS-OH30 NPs) encapsulating the antibacterial peptide OH-CATH30 (OH-30). The PVA/CS nanofibers containing OH-30 NPs (NP-30-NFs) obtained via electrospinning could achieve a secondary embedded OH-30. The effect of NP-30-NFs on the release of OH-30 was investigated through high-performance liquid chromatography. The antibacterial activities of NP-30-NFs against Escherichia coli and Staphylococcus aureus were studied by bacterial plate counting. NP-30-NFs containing different concentrations of NPs were applied to mouse skin wounds to determine their effectiveness in promoting wound healing. Results showed that NP-30-NFs exhibited antibacterial properties and promoted skin wound healing.
✓ 已验证
DOI
PubMed
高影响因子
BIORESOURCE TECHNOLOGY
·
2018
·
IF 5.807
Taiwan Liao,Ting Li,Xiangde Su,Xiang Yu,Huiyu Song,Yi Zhu,Yuanming Zhang
A series of La(OH) 3 -modified magnetic pineapple biochar (La x -MC) with different contents of La(OH) 3 were prepared and used as phosphate adsorbents for the first time. With the increase of La(OH) 3 content, the adsorption capacity for phosphate increased while the magnetic property decreased. La10-MC exhibited excellent magnetic property for easy recovery and high adsorption capacity up to 101.16 mg P/g, which was 27 times that of pineapple biochar and much higher than most phosphate adsorbents. Adsorption isotherm and adsorption kinetics were better fitted by Langmuir model and pseudo second-order model, respectively. The removal efficiency >96.04% in coexisting ions indicated its high selectivity to phosphate. Little decrease in removal efficiency after three adsorption-desorption cycles suggested its excellent stability and cyclic utilization. Leaching study demonstrated the negligible risk of La 3+ and Fe 3+ leakage during adsorption process. Mechanism study revealed that the adsorption mechanism involved precipitation, electrostatic interaction, ligand exchange and inner-sphere complexation.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Energy Technology
·
2018
·Vol. 7
·期 3
·1800476
·
IF 3.175
Zimin Jiang,Tingting Xu,Shuge Dai,Congcong Yan,Caiyun Ma,Xinchang Wang,Junmin Xu,Sen Zhang,Ye Wang
3D Ni(OH) 2 /tungsten disulfide (WS 2 ) nanofibers composed of ultrathin nanoflakes are synthesized by electrospinning followed by a hydrothermal process, which have a large specific surface of 64.56 m 2 g −1 . When tested in a three-electrode configuration, the WS 2 /Ni(OH) 2 nanofiber-based electrode exhibits a high specific capacity of 354 C g −1 at a current density of 1 A g −1 . The hybrid storage device, in which WS 2 /Ni(OH) 2 nanofibers and graphene are used as the positive and negative electrodes, respectively, exhibits a high energy density of 34 Wh kg −1 at a power density of 940 W kg −1 and a high capacity retention of 83% after 4000 cycles at 4 A g −1 . The as-synthesized 3D Ni(OH) 2 /WS 2 nanofibers provide a way for the WS 2 nanostructure to optimize its viability and potential in constructing a high-performance energy storage device.
✓ 已验证
产品关联
DOI
高影响因子
Marine Drugs
·
2017
·Vol. 15
·期 9
·284
·
IF 3.503
Wenbo Dong,Weiping Li,Yu Chen,Yanchun Ye,Shaohua Jin
In the present work, a fluorescent H2O2biosensor was constructed by encapsulating fluorescent probe Rhodamine B (RhmB) in the hydrophobic cavity of the cyclodextrin (β-CD) and immobilizing catalase (CAT) on the 2-NH2of chitosan (CTS) in a chitosan 6-OH immobilized β-cyclodextrin derivative (CTS-6-CD). The inclusion complex of CTS-6-CD to RhmB (CTS-6-CD-RhmB) was prepared by a solution method. Its structure and inclusion efficiency were determined by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and fluorescence spectroscopy (FL). CAT was immobilized on CTS-6-CD-RhmB to eventually form the functional membrane, CTS-6-CD-RhmB-CAT, via glutaraldehyde crosslinking, which was further characterized by FTIR and FL, and used as a H2O2biosensor. The functional membrane was used to simultaneously oxidize and detect H2O2. The detection condition was optimized as pH 8, a reaction temperature of 25 °C, and an immobilized enzyme concentration of 2 × 10−4mol/L. The fluorescence response of the biosensor exhibited a good linear relationship with the concentration of H2O2in the range of 20 mΜ–300 μM and the detection limit of 10−8mol/L.Keywords:chitosan;catalase;β-cyclodextrin;Rhodamine B;fluorescent biosensor
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RARE METALS
·
2016
·Vol. 41
·期 12
·4273-4278
·
IF 0.957
Huang Shuang,Xu Hua-Lan,Wang Lei,Zhong Sheng-Liang
Rice-like Gd(OH) 3 nanorods were successfully prepared through a facile and rapid microwave-hydrothermal synthesis method without using any surfactants or templates. X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), selected area electron diffraction (SAED) and energy-dispersive spectroscopy (EDS) were used to characterize the samples. Results show that the nanorods have an average length of 400 nm and an average diameter of 50 nm. The effects of reaction parameters such as reaction temperature and time on the preparation were briefly investigated. It is found that the crucial factor for the formation of rice-like Gd(OH) 3 nanorods is reaction time. When the rice-like Gd(OH) 3 nanorods was codoped with Yb 3+ and Er 3+ , strong upconversion emissions could be observed under the excitation of 980-nm-laser, and the calculated CIE color coordinates falls within the yellow region, which may be potential candidate for optical materials.
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）