PROGRESS IN ORGANIC COATINGS
·
2024
·
IF 6.5
Chao-Chen Cai,Juan Qin,Qing-Kai Zhu,Ting-Ting Li,Ching-Wen Lou,Jia-Horng Lin,Hai-Tao Ren
Superhydrophobic materials are currently undergoing rapid development in various industries, with increasing attention being paid to their service life. Herein, we report an all-weather self-healing superhydrophobic cotton fabric based on photothermal and Joule-heating effects, which can be used for efficient oil-water separation. With the assistance of Safranine T, unique cauliflower-like polypyrrole (PPy) was prepared. Subsequently, titanium nitride (TiN) was loaded to enhance the photothermal performance of the fabric, and polydimethylsiloxane (PDMS) was grafted onto surface to improve the water repellency of PPy@TiN/PDMS fabric. The fabric not only has strong light absorption in visible-near infrared region, but also has good Joule-heating effect, up to 116.3 °C (light intensity of 5 sun) and 128.5 °C (voltage of 8 V). Due to unique all-weather heating performance, the migration of low surface energy PDMS chains is accelerated, so that the PPy@TiN/PDMS fabric after air plasma etching and oxydation can quickly heal its water contact angle (WCA) to 156° under light or low voltage conditions. Additionally, the fabric demonstrates an outstanding performance for the separation of various oil-water mixtures and in multiple cycle separation experiments. This study presents a novel approach for extending the longevity of superhydrophobicity and addressing the issue of waste oil treatment.
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高影响因子
CARBON
·
2023
·
IF 10.9
Qingfu Ban,Luwei Li,Huimin Liu,Dong Zhou,Yaochen Zheng,Yusheng Qin,Ruizhe Xing,Jie Kong
Hollow engineering is an effective approach to optimize impedance matching and modify magnetic-dielectric synergy for enhanced wave absorption capability, but the composition and microstructure manipulation of metal-organic frameworks (MOFs)-derived absorbers remains a challenge. Herein, a novel and facile polymerization-induced assembly-etching strategy is proposed for the manufacture of wrinkled zeolitic imidazolate framework-67@polypyrrole (ZIF-67@PPy) microcages using ammonium persulfate catalyzed pyrrole polymerization and concomitant acid etching. Then, hollow cobalt@N-doped carbon microcages (Co@NCMs) with distorted carbon shells, rich core-shell heterojunctions , highly dispersive Co nanoparticles , and abundant heterogeneous interfaces are produced via high-temperature pyrolysis process , which eliminates the need for additional templates and etching agents. Moreover, the hollow microcage structure with interior cavities and mesopores provides superior impedance matching and lightweight characteristics to the absorbers. Therefore, the hollow absorbers demonstrate a minimum reflection loss of −50.4 dB and an effective absorption bandwidth (EAB) of 3.85 GHz at 2.7 mm with a 10 wt% filler loading. In general, the polymerization-indued assembly-etching strategy inspires the hollow engineering of MOF derivatives, and facilitates the development of superior electromagnetic wave absorption (EMA) materials.
研究领域:
材料科学
·
电磁材料
·
纳米技术
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MICROCHIMICA ACTA
·
2026
·Vol. 193
·期 2
·81
·
IF 5.3
Zhang Haili,Peng Man,Lu Anjiang,Peng Xishun,Wang Cunwei,Zu Caizhen,Bai Zhongchen
A surface-enhanced Raman scattering (SERS) sensor of Au/Ag nanoparticles (NPs) grown on ZnO/polypyrrole@Poly(3,4-ethylene dioxythiophene)-poly(styrene sulfonate) (PPy@PEDOT:PSS) film for detecting norfloxacin (NFX) residues in milk is presented. The ZnO/PPy@PEDOT:PSS film was prepared by the electrochemical deposition method. Subsequently, Ag NPs and Au NPs were deposited on the surface of ZnO/PPy@PEDOT:PSS film to form a Au/Ag/ZnO/PPy@PEDOT:PSS film by an electrochemical deposition process and the magnetron sputtering process, respectively. Owing to the charge transfer between the SERS substrate and the NFX molecules, this SERS sensor could effectively identify low-concentration NFX molecules with a limit of detection (LOD) of 0.84 nM. Moreover, it could also recognize NFX residues in milk with recoveries of 91.2% to 108.4%. The SERS sensor of Au/Ag/ZnO/PPy@PEDOT:PSS film had a high sensitivity, excellent long-term stability, and significant potential in food safety monitoring applications. Graphical abstract
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高影响因子
PROGRESS IN ORGANIC COATINGS
·
2022
·
IF 6.206
Xiutian Guo,Jiale Yao,Fengxian Ji,Rui Wang,Longyun Hao
In this study, a stable silver@polypyrrole (Ag@PPy) composite was prepared with the help of sodium dodecyl sulfate (SDS) and polymerizable surfactant ammonium allyloxynonylphenol ethoxylate (DNS-86). It was then combined with polyurethane acrylate (PUA) to prepare a conductive ink and applied on the surface of cotton fabric. By an energy-saving and sustainable UV curing method, the ink was effectively fixed to fabricate flexible and durable textile. The effects of DNS-86 on the properties of Ag@PPy composite were investigated and the results showed that DNS-86 could reduce its size, make its distribution more uniform and improve its stability. Then, the effects of DNS-86 on the performance of conductive coating on fabric were analyzed by measuring the resistance and water contact angle, revealing that DNS-86 could participate in the UV film-forming reaction of PUA molecules, so as to optimize the film structure for higher conductivity. Finally, the effect of DNS-86 on the flexibility and durability of conductive coating were evaluated. The results indicated that DNS-86 could improve the structural integrity and toughness of PUA film, enhance the adhesion between conductive coating and cotton surface, and make it more resistant to various environmental erosions.
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高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2019
·
IF 6.393
Yuling Chen,Wei Huang,Kuijun Chen,Ting Zhang,Yang Wang,Jianmin Wang
Herein, a novel core-shell structure composite with traditional conducting polymer, polypyrrole (PPy) as its core and zeolitic imidazolate framework-8 (ZIF-8) shell structure was successfully prepared. Thanks to the advantages over electrocatalytic surface provided by ZIF-8 shell and a charge collector given by PPy, the obtained core/shell-structured PPy@ZIF-8 composite displayed an excellent electrocatalytic performance towards quercetin (QR) determination. Under the optimized experimental condition, the differential pulse voltammetry (DPV) peak current signals depend linearly on QR concentration in the range of 0.01–7.0 μmol ⋅ L −1 and 7.0–150 μmol ⋅ L −1 with a low detection limit of 7 nmol ⋅ L −1 . Furthermore, the proposed electrochemical sensor also exhibited good sensitivity, excellent selectivity with reasonable reproducibility and stability during the detection of quantitative QR. A satisfactory performance was observed when this novel sensor was applied to detect QR in human plasma samples with recoveries of 99.1–102.6% and R.S.D. (n = 3) < 3.2%. Thus, the current study provides a new and efficient electrocatalyst for designing QR electrochemical sensor based on conductive conjugated polymer/MOFs heterostructure.
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高影响因子
ACS Applied Materials & Interfaces
·
2016
·
IF 7.145
Yu-Da Zhu,Su-Ping Chen,Huan Zhao,You Yang,Xiao-Qin Chen,Jing Sun,Hong-Song Fan,Xing-Dong Zhang
A medical nanoplatform with small size, low cost, biocompatibility, good biodegradability, and, in particular, multifunctionality has attracted much attention in the exploration of novel therapeutic methodologies. As an emerging material of self-assembled porous structure, metal–organic frameworks (MOFs) have high expectations because of their special properties compared to traditional porous materials. Therefore, integration of MOFs and functional materials is leading to the creation of new multifunctional composites/hybrids. Photothermal therapy (PTT), using near-IR (NIR) laser-absorbing nanomaterials as PTT agents, has shown encouraging therapeutic effects to photothermally ablate tumors. However, the most of widely used PTT agents are inorganic materials and nonbiodegradable. Herein, uniform polypyrrole (PPy) nanoparticles (NPs) with good biodegradability were synthesized by a microemulsion method. The PPy NPs were further coated with the mesoporous iron-based MOF structure MIL-100 by interaction between PPy NPs and MIL-100 precursors at room temperature. As a multifunctional nanoplatform, an anticancer drug could easily be loaded into the mesopores of the MIL-100 shell. The PPy core, as an organic photothermal agent, is able to photothermally ablate cancer cells and improve the efficacy of chemotherapy under NIR irradiation. The composites showed an outstanding in vivo synergistic anticancer capacity. Our work could encourage further study in the construction of a synergetic system using MOFs and organic PTT agents.
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CHEMICAL ENGINEERING JOURNAL
·
2025
·
IF 13.2
Tiantian Li,Zhining Huang,Mengfan Hu,Yuen Hu,Ke Quan,Man Zhou,Yao chen,Shaoju Fu
Heavy metal wastewater pollution has been a globally important and serious issue for the industrial manufacturing center. Herein, we developed a novel CAP@Ui0-66-NH 2 @PPy nanocomposite fibrous membrane, by combining the in-situ growth and oxidative polymerization technical routes, which possessed a high specific surface area and abundant amino-active sites to remove Cr (Ⅵ). Systematic characterization showed that the porous structure and in situ growth of MOF provided sites for polymerization of charged polypyrrole (PPy), resulting in the large specific surface area (78.837 m 2 /g) of CAP2@Ui0-66-NH 2 @10 %PPy. The maximum adsorption capacity was as high as 312.70 mg/g at 298 K, which was significantly better than that of CAP (CA and PVP electrostatic spinning and then washing off the PVP) nanomembranes. The adsorption process was consistent with the proposed secondary kinetic and Langmuir model, and the high adsorption capacity was maintained after five rounds of cyclic adsorptions. Through XPS analysis, the abundant amino groups on the surface of the adsorbent material were protonated, caused the electrostatic attraction and ion-exchange interaction with the anion Cr(Ⅵ). These protonated amino groups were able to reduce the toxic Cr (Ⅵ) to non-toxic Cr (Ⅲ), which was immobilized on the surface of the material through chelation. The MOF lattice achieved in-situ growth on porous CA nanofibrous membranes, which significantly enhances the mass-transfer dynamics and the membrane cycling stability, the amine-based functionalization of the UI0-66-NH 2 improved the coordination activity and increased the adsorption efficiency, and polypyrrole (PPy) conductive layer promoted the directional migration of Cr (VI) and effectively suppressed the interference of competing ions. In sum, the prepared CAP@Ui0-66-NH 2 @PPy hybrid fibrous membranes showing great potentially applicable for heavy-metal wastewater treatment.
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TALANTA
·
2024
·
IF 5.6
Xishun Peng,Qixin chen,Xinghua Li,Li Yang,Yiheng Yuan,Cheng Zuo,Zhangyu Zhou,Zhongchen Bai
Crystal violet (CV) residues in Marine food have produced a severe health threat in human life. In this study, we proposed a semiconductor surface-enhanced Raman scattering (SERS) sensor of corrosion-resistant Polyaniline/Graphene oxide (PPy/GO) film by electrochemical growth method to detect CV residues in fresh fish tissue. A PPy/GO dispersion solution was one-step deposited on a stainless steel sheet surface by electrochemical polymerization process to form a PPy/GO composite film acting as a semiconductor SERS substrate. Since the substrate of PPy/GO film was mainly composed of GO sheet without other metals, it had a good corrosion resistance. The SERS enhancement factor and charge transfer intensity P CT of PPy/Go SERS substrate for CV molecules were up to 1.18 × 10 6 and 0.903, respectively. Furthermore, the limit of detection ( LOD ) of PPy/GO SERS substrate could reach 1.58 nM. In addition, SERS sensor of PPy/GO film could identify CV residues in fresh fish tissues, and its recovery rate was 91.8 %–107 %. This preparing method and detecting method we proposed PPy/GO SERS substrate provide a new pathway for detecting CV residues in Marine food.
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Zheng Li,Xin Song,Wenke Li,Xiaolong Ding,Lianjie Li,Meijun Liu,Lanhe Zhang,Chuntao Zhu,Zicheng Chen
A novel lithium (Li) ion-imprinted composite membrane (IIP@PPy/rGO@PVDF) was developed for the selective recovery of Li + through an external-voltage-driven process. This membrane was synthesized by integrating ion-imprinting technology with electrochemically switched ion exchange technology, presenting a highly promising technique for the efficient extraction of Li from brine. The IIP@PPy/rGO@PVDF membrane consisted of polypyrrole (PPy), reduced graphene oxide (rGO), 12-crown 4-ether (12C4), and ethylene dimethacrylate (EDGMA). Furthermore, leveraging the electric field and specific recognition of 12C4 toward Li + , the membrane exhibited excellent ionic adsorption performance, including a high adsorption capacity of 214 mg.g −1 , a superior retention ratio (Maintaining the initial value even after 10 cycles of electrochemical adsorption–desorption), a short equilibration time of <25 min, and an adsorption capacity of 98 mg.g −1 at pH = 1. Subsequently, variations in the average heat of adsorption indicated that the electric field enhanced the adsorption performance. These performances were attributable to the synergistic effects of rGO with PPy. Therefore, IIP@PPy/rGO@PVDF serves as an outstanding candidate for Li extraction in environments with high applied voltages and strong acidity.
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RSC Advances
·
2017
·Vol. 7
·期 84
·53104-53110
·
IF 3.108
Jian Liu,Zhongzhu Wang,Sajid ur Rehman,Hong Bi
Highly uniform core–shell polypyrrole@carbon microspheres (PPy@CM) have been successfully constructed by oxidation polymerization of pyrrole as the shell on the core of carbon microspheres. The thickness of the PPy shell can be easily controlled by modulating the weight ratio of pyrrole monomer and carbon microspheres. Hydrophilic carbon microspheres with abundant hydroxyl groups have a very strong affinity to the conjugated chains of PPy, which is responsible for the spontaneous formation of the uniform core–shell structure. Coating the PPy shell on the carbon core could increase the complex permittivity and dielectric loss due to an additional interfacial polarization. With a proper thickness of the PPy shells, the improved dielectric loss would be induced. The microwave absorbing properties of the PPy@CM powders were investigated by dispersing them in paraffin wax with 40 wt% powders in the frequency range of 2–18 GHz. The PPy@CM-0.6 (0.6 g CM) sample exhibits the maximum reflection loss of −38.1 dB at 11.6 GHz and a bandwidth of less than −10 dB covering 11.17 to 12.26 GHz with the thickness of 3 mm. In addition, the absorption peak sites and bandwidth of the PPy@CM composites can be easily modulated not only by the thickness of the absorbers but also of the PPy shell of the PPy@CM composite. Thus, the PPy@CM composites can be considered as a new type of promising lightweight microwave absorbers to satisfy the applications of microwave absorption in the 8–18 GHz range.
研究领域:
材料科学
·
电磁学
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高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2021
·
IF 7.46
Wei Yang,Chenyuan Weng,Xiaoyun Li,Hongliang He,Jianwen Fei,Wei Xu,Xiaoqiang Yan,Wanying Zhu,Hongsong Zhang,Xuemin Zhou
At present, artificial mimic enzyme has become a powerful substitute for natural enzyme. In particular, the biosensors based on nano-enzymes have been the focus of current research. Herein, a novel magnetic ternary nanocomposite hemin-Fe 3 O 4 @polypyrrole (h-Fe 3 O 4 @ppy) was synthesized by chemical oxidation polymerization. The results showed that the h-Fe 3 O 4 @ppy had stronger peroxidase activity than Fe 3 O 4 nanoparticles (Fe 3 O 4 NPs) and h-ppy NPs, and was indicated by Michaelis-Menten constant (K m ) and maximum initial velocity (V max ). Therefore, we used h-Fe 3 O 4 @ppy catalyzing H 2 O 2 to oxidize the chromogenic substrate TMB, and built Hydrogen peroxide (H 2 O 2 ) and Glutathione (GSH) colorimetric biosensors with the help of signal intrinsic exponential amplification and easy operation. The controllable catalysis was realized by h-Fe 3 O 4 @ppy which was prone to separation. The method of removing h-Fe 3 O 4 @ppy by magnetic separation effectively eliminated the effect of residual catalysis when terminating the reaction. The sensor was then applied to the determination of GSH in biological samples from acute coronary syndrome patients. The linear ranges of H 2 O 2 and GSH were 0.2–100 μM and 0.5–80 μM, respectively. The detection limits of H 2 O 2 and GSH are 0.18 μM and 0.15 μM, respectively. This research not only proposes a new type of nanoenzyme, but also shows the multiple advantages of magnetic nano-enzymes for the construction of biosensors.
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高影响因子
CERAMICS INTERNATIONAL
·
2023
·
IF 5.2
Kai Sun,Xuechun Yang,Yuan Yuan,Jinjiu Qi,Boyang Liu,Andrey Karlovich Sarychev,Runhua Fan
Microwave absorbers have been developed to counter electromagnetic pollution, and enhancing their performance remains an ongoing concern. In this paper, carbon-coated Fe 3 O 4 and polypyrrole (PPy) were combined to construct composites with a core-double-shell structure, and the influences of multiple synergistic effects from ternary components, carbon defects, and microstructure on the electromagnetic properties of Fe 3 O 4 @C@PPy composites were investigated. The Fe 3 O 4 @C@PPy composites were successfully prepared by the low-temperature self-propagation method and in-situ oxidation polymerization process, achieving a −53.67 dB reflection loss at 12.24 GHz when the sample thickness was 2.13 mm, and the effective absorbing (RL < 10 dB) band covered 4.16 GHz (13.84–18 GHz) with a corresponding thickness of only 1.63 mm. The core-double-shell structure perfectly integrated various advantages of each component as well as provided multiple reflections and scatterings. Meanwhile, the polarization loss was notably enhanced by heterogeneous interfaces, and the dielectric-magnetic loss mechanism cooperatively accelerated the dissipation of electromagnetic wave energy.
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危险品化学品经营许可证（带存储）