RSC Advances
·
2023
·Vol. 13
·期 50
·35078-35087
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IF 3.9
Yi Liu,Zhipeng Yuan,Yanrong Chen
Excessive accumulation of bilirubin in patients with hyperbilirubinemia can lead to tissue and organ damage and neurological diseases, and is even life-threatening in severe cases. Hemoperfusion is an effective method for removing bilirubin, but clinically used hemoperfusion adsorbents have unsatisfactory adsorption capacity and kinetics. In order to obtain a safe and efficient bilirubin adsorbent, Zr-based Metal–Organic Framework (MOF) material UiO-66 with high specific surface area and aqueous medium stability was prepared and modified with varying degrees of amination to improve its adsorption capacity. According to adsorption experiments in aqueous solution and simulated plasma, it was confirmed that the unsaturated coordinated zirconium in UiO-66 can effectively induce the aggregation and precipitation of free bilirubin unbound to albumin and the amino group on UiO-66-NH2 has a strong affinity for albumin bound bilirubin. The adsorption effect of UiO-66-NH2 with a high degree of amino modification is significantly stronger than that of UiO-66-NH2 with a low degree of modification. In simulated plasma with a bilirubin concentration of 40 mg dL−1, the adsorption capacities of UiO-66 and UiO-66-NH2-1.9 can reach 69.08 mg g−1 and 81.13 mg g−1. The adsorption isotherm fitting and adsorption kinetics fitting results also show that UiO-66 and UiO-66-NH2 are good adsorbents for bilirubin. In dynamic adsorption, the adsorbents also showed good performance and did not affect the protein in the plasma. The hemolysis test, coagulation time test, and cytotoxicity test confirmed that the bilirubin adsorbents based on UiO-66 and UiO-66-NH2 have good blood compatibility and biocompatibility. This study provides new ideas for the development of a novel bilirubin adsorbent and a theoretical basis for the study of bilirubin adsorption mechanisms.
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International Journal of Low-Carbon Technologies
·
2023
·
IF 2.3
Wang Tingting,Yue Xiaoju,Han Lin,Wang Jinnong,Zhang Yuzhen,Tang Xiaofeng,Wang Shifeng
We reported anchoring mesoporous silica onto the microporous metal–organic frameworks (MOF) (UiO-66-NH2) to obtain a hierarchical porous framework (UiO-66-NH2@SiO2). This strategy maintains the high specific surface area (SA) of the MOF and addresses the mass transfer issue frequently encountered in microporous materials, providing more possibilities for subsequent modified structural frameworks. The structural characteristics of UiO-66-NH2@SiO2 were evaluated by Fourier transform infrared spectroscopy, X-ray diffraction, thermogravimetric analysis, scanning electron microscopy, surface analysis and X-ray photoelectron spectroscopy. In this work, the specific SA of the composite material was 196.667 m2/g, which decreased due to the occupation of some pores by anchored silica. Adsorption experiments showed that the composite material had a better adsorption effect (Congo red, 393.83 mg/g; bromophenol blue, 446.46 mg/g) than UiO-66-NH2, with electrostatic interaction and hydrogen bonding being the main driving forces. Therefore, this is a material that has a positive impact on dye adsorption. The strategy proposed in this work has potential applications not only in the construction of new materials but also in the exploration of dye adsorbents.
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NEW JOURNAL OF CHEMISTRY
·
2023
·Vol. 47
·期 46
·21505-21512
·
IF 3.3
Yuhao Lu,Tao Wang,Chengshun Tang,Qijian Niu,Tianyan You
Oxytetracycline (OTC) residues in the environment seriously endanger ecosystems and human health. Hence, it is critical to develop a selective and sensitive sensor for trace OTC detection. In this work, a facile and highly selective colorimetric aptasensor was constructed for OTC detection by the surface electrostatic assembly between aptamers and Fe-MOFs. Due to the steric effects and the decrease in the electron transfer rate, the peroxidase-like activity of NH2-MIL-88B was significantly inhibited after the adsorption of aptamers. Furthermore, the selective binding between aptamers and OTC triggered the release of aptamers from the surface of NH2-MIL-88B, which led to the reactivation of peroxidase-like activity. The colorimetric aptasensor exhibited a satisfactory detection range (1.0 × 10−10 M to 3.0 × 10−7 M) and the limit of detection (LOD) was as low as 1.9 × 10−11 M. Additionally, the colorimetric aptasensor was successfully used to detect OTC in real samples. The developed colorimetric aptasensor provided an important reference value for the sensitive detection of other antibiotics in the environment.
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Journal of Physical Chemistry C
·
2023
·
IF 3.7
Huan-Yu Chen,Xing-Biao Liu,Qi-Xin Guan,Can-Jun Zou,Ping-Ping Fang
The detection of antibiotics has attracted great attention among scientists and health researchers in the past decades. However, it is still difficult to realize the sensitive and selective detection of antibiotics with similar structures. Herein, the antibiotic molecules of oxytetracycline (OTC) can be sensitively and selectively detected by surface-enhanced Raman spectroscopy (SERS) on NH2–UiO-66(Zr)@Au nanoparticles (NPs). The SERS substrate of NH2–UiO-66(Zr)@Au NPs realizes a detection sensitivity of 1 × 10–12 g·L–1 for 4-mercaptobenzoic acid, indicating its high SERS activity. A high detection sensitivity of 10–11 g·L–1 is obtained for OTC on such a SERS substrate. Besides the high sensitivity, NH2–UiO-66(Zr)@Au NPs can also selectively detect OTC from streptomycin sulfate, salicylic acid, and ofloxacin by SERS on NH2–UiO-66(Zr)@Au NPs, with a selective detection limit of 10–10 g·L–1. Furthermore, OTC can be selectively detected in a real sample of river water with a detection limit of 1.0 × 10–10 g·L–1. Therefore, this study provides an effective way to enrich and detect antibiotics in real samples in the environment.
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NEW JOURNAL OF CHEMISTRY
·
2023
·Vol. 47
·期 40
·18865-18871
·
IF 3.3
Chao Liu,Gang-Gang Chang,Ting-Ting Luo,Yi-Tian Wang,Shi-Tian Xiao,Yao Yao,Hong-Jian Xu,Ge Tian,Christoph Janiak,Hai-Hu Yu,Xiao-Yu Yang
Metal–organic frameworks (MOFs) have great potential for producing photoelectrocatalyzed hydrogen and degrading pollutants, owing to several factors such as high porosity and tunable semiconductor-like properties. Wide band gaps, which restrict their use to only UV light induced reactions, and low efficiencies for the separation of photogenerated charge carriers (electrons and holes) pose significant challenges to the widespread applications of MOFs. In this study, a hierarchical hollow Pt@H-UiO-66-NH2/CdS ternary catalyst was designed and synthesized. The immobilized CdS nanoparticles (NPs) in this catalyst endow the MOF H-UiO-66-NH2 with high visible light absorption ability and the Pt NPs serve as electron sinks to improve charge carrier separation. Furthermore, the hierarchical hollow structure of H-UiO-66-NH2 in the composite contributes to boosting light absorption and shortening the distance for charge transfer. As a proof of principle, Pt@H-UiO-66-NH2/CdS catalyzes methylene blue (MB) degradation with a high rate constant of 1.025 × 10−2 and hydrogen production with a rate of 12 810 μmol g−1 h−1, the latter of which is about 2.3, 11.7 and 173 times higher than those of Pt@UiO-66-NH2/CdS, H-UiO-66-NH2/CdS and Pt@H-UiO-66-NH2, respectively.
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OPTICAL MATERIALS
·
2023
·
IF 3.9
Siyue Wang,Xiaoman Teng,Chao Liu,Hanfei Zhu,Hongbu Cheng,Jing Yan,Li Wang,Zhenyan Liang,Jun Ouyang
Due to a synergistic effect of piezo-catalysis and photocatalysis , piezo-photocatalysis is gaining popularity as an effective approach to remove organic pollutants. In this work, single-component piezo-photocatalytic nanoparticles of UiO-66-NH 2 (Hf) metal-organic frameworks were prepared by a hydrothermal process with an average diameter of ∼52.6 nm. An ultrafast piezo-photocatalysis degradation of RhB solution was achieved by using the UiO-66-NH 2 (Hf) nanoparticles . Under UV light and ultrasound irradiation, the percentage of dye degradation for an initial RhB concentration of 5 mg/L reached 91 % in 60 s. The removal mechanism of RhB was investigated via capture experiments of active species, which revealed that the hydroxyl radicals and hole play a key role in the degradation of RhB. This work provides a reference for the piezo-photocatalytic capability and the underlying mechanism of single-component metal-organic framework based nanomaterials , promoting their further development in technological applications involving highly efficient catalysts.
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2023
·Vol. 30
·期 41
·93877-93891
·
IF 5.8
Zhang Xiaoting,Han Xiaoyu,Liu Yang,Han Runping,Wang Rong,Qu Lingbo
One green adsorbent, UiO-66-NH 2 modified peanut shell (c-PS-MOF), was prepared in a green synthetic route for improving the capture level of aspirin (ASP) and fluoride ion (F – ). The adsorption properties of c-PS-MOF were evaluated by batch experiments and its physicochemical properties were explored by various characterization methods. The results showed that c-PS-MOF exhibited a wide range of pH applications (ASP: 2–10; F – : 3–12) and high salt resistance in the capturing processes of ASP and F – . The unit adsorption capacity of c-PS-MOF was as high as 84.7 mg·g –1 for ASP as pH = 3 and 11.2 mg·g –1 for F – under pH = 6 at 303 K from Langmuir model, respectively. When the solid–liquid ratio was 2 g·L –1 , the content of ASP ( C 0 = 100 mg·L –1 ) and F – ( C 0 = 20 mg·L –1 ) in solution can be reduced to 0.48 mg·L –1 and 1.05 mg·L –1 separately. The recycling of c-PS-MOF can be realized with 5 mmol·L –1 NaOH as eluent. Analysis of simulated water samples showed that c-PS-MOF could be used to remove ASP and F – from actual water. The c-PS-MOF is promising to bind ASP and F – from rivers, lakes, etc. Graphical Abstract
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2023
·
IF 8.6
Yuting Qian,Wenrou Tian,Jun Han,Najun Li,Dongyun Chen,Qingfeng Xu,Hua Li,Jianmei Lu
Catalytic oxidation of HCHO is often limited by the serious recombination of carriers in photocatalysts and the high cost of thermal catalysts based on precious metals. Herein, Bi 4 Ti 3 O 12 nanosheets enriched with bismuth vacancies were synthesized and decorated by UiO-66-NH 2 to obtain VBiTO@NU-66 for efficient removal of HCHO via piezocatalytic oxidation. The Bismuth vacancies in VBiTO enhanced the asymmetry of the crystal structure and introduced the atomic-level channels for energy and electron transfer. After loading UiO-66-NH 2 , the adsorption ability was substantially improved by the formation of Schiff-base covalent bonds between HCHO and –NH 2 . Under the joint action of adsorption and piezocatalysis, piezocatalytic oxidation rate of 300 mg/m 3 HCHO by VBiTO@NU-66 was as high as 95.1% within 3 h, which was 6 times of that of pure BiTO nanosheets. This work offers a novel tactics for the efficient purification of gaseous environmental pollutants.
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JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
·
2023
·
IF 6.1
Fangqing Li,Lin Chen,Yufei Wei,Zhiwei Yin,Keying Que
Membrane distillation (MD) is considered an emerging desalination technology. However, the presence of surfactants allows liquid to penetrate the membrane, resulting in membrane wetting, which hinders the commercialization of MD. In this study, we use very few modified materials to prepare novel Janus thin membranes that immobilize modified materials (graphene oxide (GO) and UiO-66-NH 2 ) on polytetrafluoroethylene (PTFE) hydrophobic base membranes via crosslinkers. The composite thin membrane properties with eight different ratios and contents of GO and UiO-66-NH 2 were fabricated and tested by a feed solution of sodium chloride containing a high concentration of sodium dodecyl sulfate. An optimal ratio of Janus membrane with high flux without affecting the effluent water quality was obtained. The Janus membrane exhibited excellent anti-wetting properties compared to the original PTFE membrane. A desalination rate of up to 99.9% was still available even under 48 h of long-term operating conditions by maintaining a flux of approximately 21.2 L/(m 2 ·h). The anti-wetting mechanism of this membrane was further confirmed by the modified XDLVO model. It suggested that the novel Janus membrane could be a highly promising substitute to the MD process for the resource-based treatment of surfactant-containing wastewater, which played an important role in promoting its application.
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2023
·
IF 8.6
Guoxiang Yang,Longyang Wang,Chencheng Zhang,Ping Li,Hao Du,Yanjie Mao,Mengyi Qiu,Qiang Li,Derek Hao,Qi Wang
Bacterial infection threatens human health, so the design of efficient and stable photocatalytic antibacterial materials has attracted widespread attention. In this regard, a novel photocatalyst GQDs/NH 2 -MIL-125 (GQDs: graphene quantum dots) was prepared by the solvothermal method for photocatalytic disinfection. Since the addition of GQDs enhanced the absorption of visible light and also accelerated the transfer of photogenerated electrons, the photocatalytic performance of GQDs/NH 2 -MIL-125 was significantly improved. 5 wt% GQDs loading sample (2-GQDs/NH 2 -MIL-125) exhibited the best antibacterial properties. The killing efficiency by 2-GQDs/NH 2 -MIL-125 against E. coli and S. aureus (10 7 CFU·mL −1 ) increased from 40 % and 75 % by NH 2 -MIL-125 to 92 % and 93 % within 60 min, respectively. Moreover, through the single-wavelength antibacterial experiments, it was found that the introduction of GQDs led to a wide-range-responsive antibacterial effect. Through photocatalytic trapping experiments and ESR analysis, the dominant roles of superoxide radicals (•O 2 – ) were confirmed in the antibacterial process. Finally, by studying the state of bacteria via TEM, confocal fluorescent images, and gel electrophoresis, it was found that the active substances not only destroyed the cell membranes but also further destroyed DNA to achieve the purpose of completely killing bacteria. This work provides a new method for the rapid disinfection of pathogenic microorganisms using GQDs-related photocatalysts.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2022
·
IF 9.965
Jiajia Wang,Lizhi Wang,Du Zhang,You Wang,Jiawei Li,Fa Zhou,Jianhan Huang,You-Nian Liu
Herein, the covalently connected core–shell metal–organic frameworks (MOFs)@covalent-organic frameworks (COFs) hybrid materials were successfully constructed by coating the stable COF-OH shell on the NH 2 -MIL-125 core. The introduction of the NH 2 -MIL-125 core endowed the hybrid materials with high Brunauer–Emmett–Teller (BET) surface area ( S BET ) and abundant unsaturated metal sites. And the coating of COF-OH shell endowed the hybrid materials outstanding physicochemical stability and visible-light response, and suitable band gaps. Moreover, the thickness of the COF-OH shell was carefully adjusted according to the feeding amount of NH 2 -MIL-125. Impressively, the electron transfer pathway in the formed heterostructure was clarified and it was proven that a type-II heterojunction was generated between the MOFs and the COFs. The formed stable C N covalent bonds in the interfacial layer was beneficial to the photogenerated electron transfer and the electron-hole pairs separation, which greatly enhanced the CO 2 photocatalytic reduction. The product NH 2 -MIL-125@COF-3 exhibited the highest CO yield of 22.93 μmol·g −1 ·h −1 , about 2 times higher than NH 2 -MIL-125 (11.82 μmol·g −1 ·h −1 ) and 3 times greater than COF-OH (7.26 μmol·g −1 ·h −1 ). This work can provide helpful ideas for the careful design of the novel MOFs@COFs hybrid materials as well as useful exploration for the CO 2 photocatalytic reduction.
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TALANTA
·
2019
·
IF 4.916
Ya-Juan Yang,Ying Zhou,Yang Xing,Guo-Mei Zhang,Yan Zhang,Cai-Hong Zhang,Peng Lei,Chuan Dong,Xu Deng,Yujian He,Shao-min Shuang
In this study, a novel aptasensor based on Aptamer/NH 2 Janus particles is developed for the detection of Ochratoxin A(OTA). By coating gold on the hemispherical surface of the aminated polystyrene particles, Ochratoxin A aptamer is immobilized on the surface of the gold layer for selective identification and the other hemispherical able to bind to Glassy carbon electrode via peptide bond. Under optimum conditions, the sensor exhibited a wide dynamic range of OTA concentration from 1 × 10 −5 nM to 10 nM, and the detection limit is 3.3 × 10 −3 pM on condition of acceptable stability and reproducibility. The sensors were showed excellent performance in the detection of OTA in red wine sample with recoveries between 95.7% and 100.18%, which studied by the standard addition spiking technique. This work provides a new idea and method for preparing immune electrochemical sensors and is expected to be used for the OTA detection in red wine sample analysis.
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