INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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2023
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IF 8.2
Ling Sun,Chenghao Yang,Huixin Wang,Xin Jin,Xu Li,Xiangji Liu,Ping Zhu,Chaohong Dong
Imparting flame retardancy to polyester fabrics is still a pressing issue for the textile industry. To this end, a composite coating was developed by phosphite, pentamethyldisiloxane, urea and sodium alginate , and then applied together with calcium chloride to prepare flame-retardant polyester fabrics. The optimized polyester fabrics named PF-HUSC exhibited a rough surface with P, Si, N and Ca element distributions, as observed by scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDX). Flame retardancy evaluations showed that the damaged length of PF-HUSC with a limiting oxygen index (LOI) value of 35.3 ± 0.3 % was reduced from the contrastive 17.6 ± 0.4 cm to 4.6 ± 0.2 cm after vertical burning test. Thermogravimetric (TG) test confirmed that PF-HUSC retained a char residue as high as 35.1 % at 700 °C. Cone calorimetry test displayed that the total heat release (THR) and total smoke production (TSP) values of PF-HUSC were reduced to 3.1 MJ/m 2 and 1.1 m 2 , respectively, as compared to those of pure polyester fabrics. More importantly, PF-HUSC still exhibited higher LOI value than that of pure polyester fabrics after 25 washing cycles. Hence, the coating scheme is considered as a new method to expand the preparation of flame-retardant polyester fabrics.
研究领域:
材料科学
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纺织工程
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化学工程
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DOI
PubMed
高影响因子
FOOD RESEARCH INTERNATIONAL
·
2024
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IF 7
Chengpeng Cheng,Xinru Xie,Shaobo Li,Pengyu Chen,Caiyan Huang,Xiaochun Zheng,Li Chen,Dequan Zhang
The aim of this study was to systematically analyze the differences in bioactive compounds in Ningxia Tan, Oula, and Bahan crossbred mutton, and to examine their effects on minced mutton quality. Initially, characteristic bioactive compounds in mutton were analyzed using principal component analysis. Further investigation assessed the effects of varying concentrations of glycyrrhizin flavonoids (0, 0.04, 0.08, 0.16, 0.32 mg/100 g) and calcium chloride (0, 60, 120 mg/100 g) on mutton quality using an in vitro minced meat system. Results indicated that flavonoids (0.38) and calcium (−0.37) had the highest loadings on the first principal component. The water retention, hardness, and chewiness of the minced mutton gel exhibited a significant increase with the addition of licorice flavonoids and calcium chloride (P < 0.05). The elasticity of the minced mutton gel system was also significantly enhanced. The best water retention was observed with the addition of 0.32 mg/100 g of licorice flavonoids and 120 mg/100 g of calcium chloride, and the gel microstructure was densest under these conditions. These findings suggest that flavonoids and calcium are differential bioactive substances in three breeds of mutton that can improve the physicochemical properties of gelatinous minced mutton products. This study establishes a theoretical foundation for selecting raw materials in meat processing and improving the quality of gelatinized mutton products.
研究领域:
食品科学
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动物营养学
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DOI
PubMed
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2019
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IF 5.107
Hui Dang,Na Li,Zhidong Chang,Benfeng Wang,Yifei Zhan,Xue Wu,Wenbo Liu,Shujaat Ali,Hongda Li,Jiahui Guo,Wenjun Li,Hualei Zhou,Changyan Sun
In the present case, insoluble lithium in the simulated slag which is obtained by pyrometallurgical processing of spent lithium ion batteries (LiBs) is leached aqueously through transformation of insoluble lithium into soluble lithium via roasting with calcium chloride (CaCl 2 ). The change of both Gibbs free energy and the logarithm of the equilibrium constant, which are taken as functions of temperature for the chlorination reaction of simulated slag with CaCl 2 , are predicted through the simulation with an enthalpy, entropy and heat capacity (HSC) programme. The simulation indicates that CaCl 2 is a favourable and effective chlorine donor in this chlorination reaction to yield lithium chloride (LiCl) when the temperature is not less than 500 °C. These predicted results are tested and confirmed experimentally. A maximum of 90.58% lithium recovery can be yielded with the optimal roasting conditions of a temperature of 800 °C for 60 min and a molar ratio of Cl/Li of 1.8:1, along with subsequent leaching conditions of 60 °C for 30 min with a water/calcines mass ratio of 30:1. X-ray diffraction (XRD) results suggest that most of LiAl(SiO 3 ) 2 in the slag disappears under the best reaction conditions and is transformed into LiCl.
研究领域:
材料科学
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环境工程
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DOI
高影响因子
FOOD CHEMISTRY
·
2022
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IF 9.231
Yanni Wu,Shudong He,Tiange Pan,Xinya Miao,Jie Xiang,Yongkang Ye,Xiaodong Cao,Hanju Sun
In order to fortify γ-aminobutyric acid (GABA) of brown glutinous rice (BGR), pre-germination strategy was employed, and effects of low-frequency (28 kHz) ultrasound treatment combined with CaCl 2 stress on the sprout length, germination rate, morphology, color, water, total polyphenol content (TPC), starch, protein, GABA contents and relevant metabolites were investigated. The germination rate would be inhibited under CaCl 2 concentration ≥ 2.0 % during 24 h soaking without ultrasound treatment, and no significant difference was also observed combined with 9 h ultrasound treatment. Ultrasound treatment was beneficial to water absorption, TPC enrichment, energy metabolism, lipid metabolism and protein hydrolysis. Higher contents of GABA (3.29 folds), pyruvic acid (7.63 folds), glycerol (4.88 folds), glutamate (2.02 folds) and glucose (1.32 folds) were obtained due to the antagonistic effect between the 30 w ultrasound treatment and 2.0 % CaCl 2 stress at the 9 h pre-germination, and energy, lipid and protein metabolomic pathways were all involved in the GABA accumulation.
研究领域:
食品科学
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植物生理学
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产品关联
DOI
PubMed
高影响因子
Nano Energy
·
2023
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IF 17.6
Shuai Zhang,Shuo Meng,Ke Zhang,Zhuang Wang,Xiaoyun Xu,Chuanwei Zhi,Shuo Shi,Jinlian Hu
Triboelectric nanogenerator (TENG) is one of the key research directions for future human-computer interaction (HCI), biomedicine, and environmental protection. Bio-based materials are an essential branch of many degradable materials. Keratin has attracted much attention due to its advantages of easy access, biodegradability, and good biocompatibility . A highly sensitive single-electrode TENG (S-TENG) based on CaCl 2 /PVA/keratin and Ecoflex with micro-domes is designed. The excellent stability (18,000 cycles) and stretchability (200%) of the sensor are confirmed by research. Moreover, the presence of CaCl 2 and keratin can significantly increase the S-TENG's output voltage, and the reason is also explored by the density functional theory (DFT) method. Through simulation, it is found that the decrease of the HOMO (highest occupied molecular orbital)-LUMO (lowest unoccupied molecular orbital) gap and the increase of the electrostatic potential are the root causes of the voltage increase. Relying on the excellent characteristics of the S-TENG, finger curvatures, gestures, and object shapes are recognized. Among them, the accuracy of object shape recognition by machine learning algorithm reached 98.1%. This study provides a new method for improving the output efficiency and prolonging the service life of S-TENG and confirms the feasibility of the electron cloud trap model to explain biomass triboelectric materials by keratin and CaCl 2 .
研究领域:
生物材料学
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纳米发电机研究
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环境科学
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产品关联
DOI
高影响因子
ANALYTICAL CHEMISTRY
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2025
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IF 6.7
Chenlu Lin,Xiao Yang
Molten CaCl2 is a viable solvent and electrolyte for extracting target elements from their oxides through electrolysis. However, the accumulation of O2– during electrolysis presents a significant challenge for the commercial application of CaCl2-based technologies. Understanding the behavior of O2– in the melt is crucial for optimizing the process. To address this, we developed an electromotive force (EMF) measuring system to monitor O2– behavior during the Si electrodeposition in molten CaCl2. We explored the thermodynamic properties of O2– in molten CaCl2–CaO (XO2– < 0.03) at 1123 K. The relationship between activity and molar fraction of O2– was established as aO2– = XO2–2.2, indicating strong interactions between O2– and other ions in the melt. EMF measurements confirmed the accumulation of O2– during the electrolysis in molten CaCl2–CaO–SiO2, as evidenced by the significant increase in aO2–. Notably, this accumulation becomes more pronounced with larger cathode areas, which leads to greater carbon contamination. Further investigation revealed that solid SiO2 effectively reduces aO2– in molten CaCl2–CaO to lower levels. By immersing solid SiO2 in melt during electrolysis, the accumulation rate of O2– is slowed, thereby inhibiting carbon contamination and improving current efficiency. These findings provide valuable insights into the use of the EMF measuring system as an effective tool for revealing O2– behavior and optimizing electrolysis processes in molten CaCl2.
研究领域:
材料科学
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电化学
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产品关联
DOI
PubMed
高影响因子
ChemistrySelect
·
2025
·Vol. 10
·期 9
·e202405355
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IF 2
Shaogang Zhang,Xiaolong Ma,Xin Min,Xiaoguang Zhang,Jinhong Li
Graphical A series of EV-CaCl2·6H2O composite PCMs were prepared. SrCl2·6H2O and copper nanoparticles affect the supercooling and thermal conductivity of EV-CaCl2·6H2O composite PCMs, respectively. The non-isothermal melt crystallization process and crystallization activation energy were studied. Solid-liquid phase change materials (PCMs) made from calcium chloride hexahydrate (CaCl 2 ·6H 2 O) offer benefits such as significant latent heat during phase change, high heat storage efficiency, low preparation costs, a nearly constant temperature exothermic process, and environmentally friendly attributes. However, they also face challenges like poor thermal conductivity, susceptibility to leakage, supercooling, and phase separation. The melt impregnation method prepared shape-stable composite PCMs using expanded vermiculite (EV) and CaCl 2 ·6H 2 O as raw materials. The layered pore structure of EV can be used as an encapsulation matrix to prevent the leakage of the CaCl 2 ·6H 2 O liquid phase. Adding 1 wt% strontium chloride hexahydrate (SrCl 2 ·6H 2 O) nucleating agent and 3 wt% copper nanoparticle thermal conductivity enhancer can reduce the supercooling by 8 °C and increase the thermal conductivity by 0.2092 W/(m·K). The kinetic equation effectively describes the non-isothermal melt crystallization process. An increase in the cooling rate creates a thermal hysteresis effect on melt crystallization; the faster the cooling rate, the lower the temperature at which crystallization begins and the shorter the duration required for crystallization to complete. Both SrCl 2 ·6H 2 O and copper nanoparticles can reduce the crystallization activation energy, which is the essential reason for lowering the supercooling of CaCl 2 ·6H 2 O.
研究领域:
材料科学
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化学工程
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产品关联
DOI
高影响因子
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE
·
2021
·Vol. 102
·期 1
·425-433
·
IF 3.639
Yingying Han,Jinhua Du,Yan Wang
BACKGROUND Apple wine is a popular alcoholic beverage for its nutrition and fresh taste. However, the methanol existing in apple wine restricts its quality. Unfortunately, there are no methods to reduce the methanol content in fruit wine. To this end, bentonite (B), calcium chloride (CC) and their combination (B&CC) were added into apple juice in this study. The treated juice (0) and supernatant obtained by standing the juice at 25 °C for 24 h were fermented at 25 °C and 10 °C, respectively. RESULTS Bentonite was an excellent methanol interrupter, a pectin retainer and a wine quality defender both at 25 and 10 °C. The lowest methanol content of 1.41 mg L −1 and higher pectin content of 84.74 mg L −1 were reached in the finished wine by B0 at 10 °C. Calcium chloride decreased pectin content, elevated methanol content and changed the profile of individual organic acids. In fact, the wine by B&CC0 at 25 °C showed dramatic changes in individual organic acids. The content of l -malic acid and succinic acid was only 2.22% and 6.29% of the control, respectively, while the lactic acid content was 17.72 times that of the control. CONCLUSIONS It is suggested that B0 and fermented at 10 °C was the most effective way to decrease methanol content, retain pectin content and defend wine quality. © 2021 Society of Chemical Industry.
研究领域:
食品科学
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化学
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饮料技术
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产品关联
DOI
PubMed
高影响因子
CELLULOSE
·
2025
·
IF 4.8
Zhao Feiyang,Liu Huijuan,Jin Yilin,Ru Hongfu,Wang Longfei,Xiang Shuangfei,Li Hao,Zhao Shujun,Fu Feiya,Camilleri Ing. Duncan,Liu Xiangdong
The application range of rice straw (RS) is limited by its poor flame and water resistance. It’s still a great challenge to endow RS fibers with excellent flame and water resistance properties without compromising the intrinsic mechanical properties. Here, a simple surface treatment strategy of RS fibers via co-treatment with phytic acid (PA) and calcium chloride (CaCl 2 ) was developed. First, PA was grafted onto RS fibers by esterification reaction. Then RS fibers were ionically crosslinked by CaCl 2 treatment. Modified RS fibers (PCRS) were then mixed with unsaturated polyester resin (UPR) to produce PCRS/UPR composites (PCRU). Benefiting from Ca 2+ complexes via the ionic crosslinking between Ca 2+ and –P (=O)–OH of the PA, –OH of the RS fibers, PCRU demonstrates enhanced tensile strength (12.04 MPa), good waterproofing capability, and flame-retardant performance. PCRU exhibites low water absorption rate (5.90%) and dimensional stability (thickness deformation less than 1.76%) after 168 h of water immersion. In addition, the limiting oxygen index and the total heat release of the prepared PCRU composites are 29.7 and 11.3 kJ/g, which reach the standard for flame retardant materials. Therefore, this study provides a simple and green pretreatment strategy of rice straw fiber for the applications in flame retardant, low water absorption, and dimensionally stable composites. Graphical
研究领域:
材料科学
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聚合物复合材料
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表面处理
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阻燃性能
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防水性能
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产品关联
DOI
高影响因子
Tissue Engineering Part C-Methods
·
2020
·Vol. 26
·期 7
·352-363
·
IF 2.608
Xiaolian Niu,Liqin Zhao,Meng Yin,Di Huang,Nana Wang,Yan Wei,Yinchun Hu,Xiaojie Lian,Weiyi Chen
This study aimed at designing a novel electrospun scaffolding material that structurally and chemically resembles native extracellular matrix for bone tissue engineering. Calcium chloride-complexed polyamide66 (PA66/CaCl2) and pure PA66 electrospun nanofibers were fabricated by the electrospinning method. Scanning electron microscopy, X-ray diffraction, and Fourier transform infrared (FTIR) spectroscopy were used to investigate the effect of the presence of ionized salt in the polymer solution on the mechanical properties and other properties of the electrospun scaffolds. The results show that addition of CaCl2 to PA66 solution can achieve an internal modification and improve the tensile strength and modulus of the polymeric electrospun nanofiber. Ca2+ uploaded through electrospun fibers could provide nucleation sites for the formation of hydroxylapatite (HA) coating. After mineralization, the tensile strength and modulus of HA/PA66/CaCl2 scaffolds reach up to 41.33 ± 16.17 MPa and 168.59 ± 42.20 MPa, respectively. LIVE/DEAD assay shows that compared with pure PA66 scaffolds, a greater density of viable MC3T3-E1 cells were seen on the HA/PA66/CaCl2 scaffolds. Cell Counting Kit-8 results indicate that HA/PA66/CaCl2 scaffolds displays a more favorable ability to promote MC3T3-E1 cell proliferation and growth than that of the other groups with the prolongation of culture time. These results demonstrate that HA/PA66/CaCl2 scaffolds that structurally and chemically resemble native bone have a good cytocompatibility, and might be a potential candidate for bone tissue engineering.Color images are available online.Impact statementIn this work, the calcium chloride-complexed polyamide66 (PA66/CaCl2) hybrid nanofibers were prepared by adding CaCl2 to the PA66 formic acid solution before electrospinning, and then mineralized by saturated calcium phosphate solution. The findings of this study show that the addition of CaCl2 could achieve an internal modification, improve the tensile strength and modulus of the polymeric electrospun nanofiber, and provide nucleation sites for biomimetic mineralization. This research provides insight and foundation of application of mineralized PA66/CaCl2 electrospun scaffolding material that structurally and chemically resembles native extracellular matrix for bone tissue engineering.
研究领域:
生物材料学
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组织工程学
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DOI
PubMed
高影响因子
MATERIALS SCIENCE FORUM
·
2021
·
IF 0
Sha Chen,Jing Hua Gong,Jing Hong Ma
Helix is a sophisticated structure in nature and has many unique functions which makes it possible to store more information and energy, even receive more sensitive signals. Besides, as an effective method for preparing hydrogel fibers, microfluidic spinning has achieved unprecedented development in the past decade. However, hydrogel fiber with helical structure has began to be studied only in recent years. In this paper, the helical hydrogel fibers were prepared by the microfluidic spinning method. The microfluidic chip was assembled by PDMS connector, collection tube, inner and outer channels. Sodium alginate (SA) and calcium chloride were used as the core fluid and sheath fluid, respectively. By designing and adjusting the length of the chip, changing the concentration of SA and the ratio of two flow rates (inner flow rate/outer flow rate), a continuous and uniform helical hydrogel fiber was prepared. The relationships between the diameter of the fiber, the pitch of the helix and the concentration of SA, the ratio of two flow rates were discussed. The results showed that the diameter of the fiber was mainly affected by the core fluid. Within a certain range, as the concentration of SA increased, the diameter of the fiber increased. Besides, the pitch of the helix was greatly affected by the flow rate of sheath fluid. As the velocity of the sheath fluid increased, the pitch of the fiber increased. Such helical fiber could be used in micro sensors when added some conductive materials or crosslinked with some temperature responsive polymers such as N-isopropylacrylamide.
研究领域:
材料科学
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生物医学工程
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DOI
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
·
2018
·Vol. 165
·期 11
·E616
·
IF 3.662
Junfeng Li,Mingyong Wang,Jiguo Tu,Shuqiang Jiao
The direct preparation of metallic Sm or alloys from raw oxide Sm2O3 is an attracting but challenging process. The stable electrochemical behavior and low solubility of Sm2O3 limit the extraction of Sm element in molten salts. Here, it is found that metallic Sm is hardly obtained by electro-deoxidation and aluminothermic reduction of solid Sm2O3 pellet according to experiment and calculation. Through the novel electrochemical reduction of solid Sm2O3-Al pellet, Al3Sm alloy with ∼0.4 Sm/Al molar ratio is successfully prepared in calcium chloride melt at 1173 K. The reduction potential of Sm2O3-Al pellet to Al-Sm alloy is more positive than that of calcium. Al plays an indispensable role in the reduction of Sm2O3. The preparation process of alloy can be well identified as two steps: Sm(III) → Sm(II) and Sm(II) → Sm(0). Sm2O3 is firstly converted to Sm(II) based on the combination of electrochemical and aluminothermic reduction. Then, Al3Sm is formed by electrochemical reduction and alloying with Al.
研究领域:
材料科学
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电化学
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冶金学
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产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）