CERAMICS INTERNATIONAL
·
2022
·
IF 5.532
Ziwei Yue,Xiaoliang Ji,Wei Zhou,Zhihao Ji,Fu Guo
Due to a lower intrinsic thermal conductivity , Cu 2 S-based thermoelectric materials are attracting extensive attention. However, they still confront the problem of higher electrical resistivity, which distinctly restricts their thermoelectric application. Herein, we synthesized Ag-incorporated Cu 2-x S micro/nano composites using a hydrothermal method . It was found that the doping of Ag nanoparticles could effectively enhance the electrical transport, while the generated nanopores , caused by the sintering of Ag nanoparticles during the SPS process, reduced the thermal conductivity. As a result, a maximum ZT value of ∼1.5 was obtained at 773 K in the Cu 2-x Ag δ S (δ = 0.5%) micro/nano composites, much higher than that of the pristine Cu 2-x S micro/nano composites. This work provides a new pathway to boosting thermoelectric performance through microstructural engineering.
研究领域:
材料科学
·
能源科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF BIOMATERIALS SCIENCE-POLYMER EDITION
·
2023
·
IF 3.6
Jie Yang,Xiao-Jie Wang,Si-Mei Li,Dong-Xue Jiang,Yu-Xin Liu,Yan Huang,Di-Di Dong,Wei Hu,Bo Liu
Nowadays, chemotherapy is a common clinical treatment for cancer, but it still faces many limitations and challenges. Therefore, the combination of chemotherapy and other treatments often enhances the effectiveness of treatments. Herein, an injectable hydrogel of PC10ARGD/Cu2+/DOX based on Cu2+, hydrophilic doxorubicin (DOX), and genetically engineered polypeptide PC10ARGD was prepared. First, Cu2+ was attached to the histidines in the PC10ARGD polypeptide by the coordination reaction to form PC10ARGD/Cu2+ hydrogel, then the PC10ARGD/Cu2+/DOX hydrogel was prepared by encapsulating the DOX into the PC10ARGD/Cu2+ hydrogel. The results of scanning electron microscopy showed that the PC10ARGD/Cu2+/DOX hydrogel displayed loose porous morphology. In vitro, reactive oxygen species production results showed that the PC10ARGD/Cu2+/DOX hydrogel could continuously produce ·OH in the presence of H2O2. In vitro MTT results showed that the PC10ARGD/Cu2+/DOX hydrogel had a good inhibitory effect on cell activity. Flow cytometry further confirmed the antitumor effect of the PC10ARGD/Cu2+/DOX hydrogel. In vivo experiment results showed that the tumor volume of mice treated with the PC10ARGD/Cu2+/DOX hydrogel was significantly inhibited compared with control groups, which was due to the combination of chemodynamic and chemotherapy. The results of body weight and blood analysis of mice showed that the PC10ARGD/Cu2+/DOX hydrogel possessed good biocompatibility.
研究领域:
生物材料
·
肿瘤学
·
药剂学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CRYSTENGCOMM
·
2023
·Vol. 25
·期 8
·1232-1239
·
IF 3.1
Gui-Mei Huang,Shuang Li,Meng-Xia Ma,Shi-Ming Li,Wen-Qiang Li,Qing-Ling Ni,Liu-Cheng Gui,Xiu-Jian Wang
Four MOFs with mixed ligands, [Zn3(3-BABA)2(bpa)2(H2O)2]n (1), [Cd3(3-BABA)2(bpa)2]n (2), [Cd3(3-BABA)2(bpe)2]n (3), and {[Cd3(3-BABA)2(bib)(DMA)2]·H2O}n (4) (where 3-H3BABA = 4′,4′′′-(((2-carboxyphenyl)azanediyl)bis(methylene))bis(([1,1′-biphenyl]-2-carboxylic acid)), bpa = 4,4′-azopyridine, bpe = 1,2-bis(pyridin-4-yl)ethane, and bib = 1,4-bis(imidazole)butane), have been synthesized. They are characterized by single crystal X-ray diffraction, X-ray powder diffraction (XRPD), thermogravimetric analysis (TGA) and Fourier transform infrared (FT-IR) spectroscopy. In 1, two 3-BABA and two bpa bridge three Zn2+ ions to form a bicyclic [Zn3(3-BABA)2(bpa)2] unit which is further bridged by carboxylate groups with its adjacent units, resulting in a one-dimensional chain. In 2, 3 and 4, the [Cd3(CO2)6] units are bridged by six 3-BABA ligands into a three-dimensional structure. However, the adjacent [Cd3(CO2)6] units in 2 and 3 are doubly-bridged simultaneously by corresponding pyridyl ligands, while the adjacent [Cd3(CO2)6] units in 4 are singly-bridged simultaneously by corresponding pyridyl ligands. The luminescence sensing investigation indicates that compound 1 exhibits extremely sensitive and selective detection of Cu2+ with a detection limit of 0.363 μM, and compounds 2–4 show extremely sensitive and selective detection of Fe3+ with detection limits of 0.539 μM, 0.265 μM, and 0.748 μM, respectively. Competitive experiments in the presence of interfering cations with 1–4 revealed no major change in the quenching efficiency.
研究领域:
化学
·
材料科学
✓ 已验证
DOI
高影响因子
Desalination and Water Treatment
·
2014
·
IF 0.987
Qian Liu,Bingchao Yang,Lujie Zhang,Ruihua Huang
A multifunction adsorbent, activated carbon (AC)/chitosan composite, was synthesized by incorporating AC into chitosan based on the ratio of AC to chitosan being 1/1. The simultaneous adsorption of aniline and Cu2+ from aqueous solution onto AC/chitosan composite was investigated by a batch procedure. These results showed that an adsorbent dosage of 0.3 g was appropriate, and a contact time of 210 min was convenient for reaching adsorption equilibriums for aniline and Cu2+. The simultaneous adsorption of aniline and Cu2+ was realized in a wide pH range. The adsorption process obeyed the pseudo-second-order kinetic model. The adsorption behaviors of aniline and Cu2+ followed Freundlich and Langmuir, respectively. No obvious competitive adsorption existed between Cu2+ and aniline.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
·
2021
·Vol. 413
·期 15
·3945-3953
·
IF 4.157
Yang Jin,Chen Weixing,Chen Xinyu,Zhang Xi,Zhou Hongwei,Du Haotian,Wang Mingcheng,Ma Yiting,Jin Xilang
Novel spherical polymer nanoparticles were synthesized by hyperbranched polyethylenimine (hPEI) and 6-hydroxy-2-naphthaldehyde (HNA) via Schiff base reaction (one-pot reaction), which had great advantages in water solubility and green synthesis. Meanwhile, probe PEI-HNA could quickly detect Cu 2+ in the range of 0–60 μM in 30 s with the detection limit of 243 nM. The fluorescence of PEI-HNA-Cu 2+ could be recovered by the addition of S 2− in 50 s with the detection limit of 227 nM. Based on the excellent optical properties, PEI-HNA has been used in the bioimaging of living cells with excellent cell penetrability and low toxicity. More importantly, PEI-HNA has been doped into filter paper, hydrogel, and nanofibrous film to prepare solid-phase sensors, displaying rapid response and excellent sensitivity. Moreover, the low-cost and simple preparation of these sensors offers great potential and possibilities for industrialization, which could help accelerate the development of sensors in environmental and biological fields.
研究领域:
分析化学
·
生物医学工程
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
KOREAN JOURNAL OF CHEMICAL ENGINEERING
·
2014
·Vol. 31
·期 9
·1608-1615
·
IF 1.241
Liu Qian,Yang Bingchao,Zhang Lujie,Huang Ruihua
A multifunction adsorbent was synthesized by incorporating AC into CTS, and the ratio of AC to CTS was 1/1. The resultant was called activated carbon (AC)/chitosan (CTS) composite. The simultaneous adsorption of phenol and Cu 2+ from aqueous solution onto AC/CTS composite was investigated by a batch procedure. The adsorption processes for both Cu 2+ and phenol obeyed the pseudo second-order kinetic model. Phenol was prone to be adsorbed more quickly as compared with Cu 2+ when they coexisted in solution. The adsorption behavior of both phenol and Cu 2+ followed the Langmuir isotherm. The maximum adsorption capacities of phenol and Cu 2+ were 34.19 mg/g and 74.35 mg/g at 293 K, respectively. No obvious competitive adsorption existed between phenol and Cu 2+ .
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
CHEMISTRY OF MATERIALS
·
2019
·
IF 10.159
Beibei Shan,Yawen Zhao,Yiwen Li,Haitao Wang,Rui Chen,Ming Li
Dual-plasmonic Au–Cu2–xE (x > 0, E = S, Se, Te) hybrids present multifunctionalities for broad applications in photovoltaics, photocatalysis, and biomedicine. However, despite the increasing interest in these dual-plasmonic Au–Cu2–xE hybrids, precise control over the morphology and size of their substituents is crucial but greatly challenging. Herein, a selenium-mediated two-step synthetic approach is developed to prepare the Au@Cu2–xSe nanocrescents with precise control over their size and tunable plasmonic properties through varying the concentration of the SeO2 precursor. The complete encapsulation of the Au domain within the Cu2–xSe layer in the nanocrescent in an asymmetric manner enables the strong coupling between their substituents, significantly enhancing their optical properties supported by both experimental results and theoretical modeling. The increasing Cu2–xSe domain size enables the tuning of carrier densities and thereby molar extinction coefficients corresponding to the respective visible and near-infrared (NIR) plasmon bands of the Au@Cu2–xSe nanocrescents. Electron transfer from the Au to Cu2–xSe domains is unambiguously determined in the Au@Cu2–xSe nanocrescents by transient absorption (TA) and extinction spectral measurements. The Cu2–xSe-dependent bleaching amplitude and carrier dynamics of both visible and NIR plasmon TA signals are observed, along with variations of the carrier–phonon and phonon–phonon relaxation processes. This work not only presents a facile synthetic approach of high-quality dual-plasmonic Au@Cu2–xSe nanocrescents and a fundamental understanding of the coupling mechanism in the Au–Cu2–xSe hybrid system, but also provides a paradigm for the study on the interplay in a dual-plasmonic metal–semiconductor system.
研究领域:
纳米材料科学
·
生物医学工程
·
光子学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
·
2021
·Vol. 35
·期 6
·1021-1030
·
IF 0.957
Wei Junchong,Long Xuejun,Wang Jia,Tang Zheng,Wang Tingting,Kang Hanyu,Liang Shuang
Artificial zeolite was modified by nano-Fe 3 O 4 for development of functional adsorbents. Subsequently, adsorbents such as calcium cross-linked nano-Fe 3 O 4 microspheres (Ca-MS), calcium cross-linked nano-Fe 3 O 4 modified zeolite microspheres (Ca-MZS) and iron cross-linked nano-Fe 3 O 4 modified zeolite microspheres (Fe-MZS) were prepared and compared for their adsorption performance. The effects of adsorbent dosage, solution pH, initial concentration and ion content on the removal of Cu 2+ from wastewater are investigated, and the adsorption kinetics and isotherms for the adsorbent materials were analyzed. The experimental results indicate that for the initial concentration of Cu 2+ of 30 mg/L, the adsorption is noted to be most stable. The optimal initial pH for adsorbing Cu 2+ is observed to be 5.5. At an optimal dosage of Ca-MZS of 900 mg/L, the adsorption capacity is measured to be 28.25 mg/g, along with the removal rate of 72.49%. The addition of Na + and K + affects the adsorption of Cu 2+ . For the Na + and K + concentration of 0.2 mmol/L, the Cu 2+ removal rate by Ca-MZS drops to 11.94% and 22.12%, respectively. As compared with the adsorbents such as Natural Zeolite (NZ), Ca-MS and Fe-MZS, Ca-MZS demonstrates the best removal effect in solution, where the removal rate reaches 84.27%, with the maximum adsorption capacity of 28.09 mg/g. The Cu 2+ adsorption kinetics of Ca-MZS is observed to follow the Elovich kinetic model, with the adsorption isotherm data fitting the Freundlich isotherm model by using the non-linear method.
研究领域:
环境科学
·
材料科学
✓ 已验证
DOI
高影响因子
Materials
·
2025
·Vol. 18
·期 7
·1443
·
IF 3.2
Yanshuang Chen,Yilin Chen,Hanqi Xu,Wenqi Zhao,Guodong Feng,Chunhui Xiao
The accumulation of coal gangue (CG), a byproduct of coal mining, poses severe environmental challenges. This study presents a green strategy to convert CG into high-value NaX zeolite via an alkali fusion–hydrothermal method. Through orthogonal experiments, the optimal synthesis conditions (solid–liquid ratio 1:8, crystallization temperature 110 °C, time 12 h) were identified, yielding NaX zeolite with exceptional crystallinity (98%), specific surface area (703.5 m2/g), and pore volume (0.28 cm3/g). Comprehensive characterization (XRD, SEM-EDS, BET, etc.) confirmed its structural integrity and thermal stability. The synthesized zeolite exhibited remarkable adsorption capacities for Cu2+(185.35 mg/g) and CO2(5.51 mmol/g), following the Langmuir isotherm model. This work not only addresses gangue disposal challenges but also demonstrates a cost-effective route for producing high-performance adsorbents, aligning with circular economy and carbon neutrality goals.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF FLUORESCENCE
·
2022
·Vol. 33
·期 1
·327-337
·
IF 2.525
Ren Yangyang,Han Shuhua
Seminaphthorhodafluor (SNARF) Schiff base (SNARF-SB) bridged periodic mesoporous organosilicas (SSPMOs) with “turn-on” fluorescence enhancement for sensing Cu 2+ were synthesized via a template-directed co-condensation method. Small-angle x-ray scattering (SAXS) patterns, high resolution transmission electron microscope (HRTEM) images, and N 2 adsorption–desorption isotherms indicated the presence of mesoporous structure in the SSPMOs. FT-IR spectra and 29 Si MAS NMR data confirmed the successful incorporation of bridged organic groups in the framework of SSPMOs. The luminous properties that SSPMOs had a selective response to Cu 2+ were investigated by UV–Vis absorption spectroscopy and fluorescence spectroscopy. The limit of detection (LOD) was 5.1 × 10 –7 M and binding stoichiometry was determined 1:1 between SNARF-SB and Cu 2+ . The fluorescence enhancement of SSPMOs towards Cu 2+ was induced by ring-opening of the spirolactam in SNARF-SB in framework of SSPMOs, which was confirmed by FT-IR spectra of SNARF-SB with Cu 2+ . Moreover, SSPMOs have improved fluorescence lifetimes compared with that of SNARF-SB. Therefore, SSPMOs can be a progressive chemical sensor for Cu 2+ due to its high selectivity, recyclability, and stability.
研究领域:
材料化学
·
分析化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF MOLECULAR STRUCTURE
·
2025
·
IF 4.7
Luyue Wang,Yuzhu Chen,Zhengyang Xing,Jie Ma
Real-time monitoring of metal ion species and concentrations in water is a highly active research field. In the paper, a novel fluorescent molecule, (E)-N'-((5-(9-phenyl-9H-carbazol-3-yl) thiophen-2-yl) methylene) terephthalohydrazide (PCTMT), is synthesized via Suzuki reaction and Schiff-base reaction in turn. In the DMF-H 2 O (70 % v/v) solvent system, the PCTMT presents a good aggregation-induced enhancement (AIE) fluorescent effect and good selectivity and anti-interference for monitoring Co 2+ and Cu 2+ in water with a wide pH range. The probe's detection limit (LOD) reached 28.2 nM and 38.7 nM for Co 2+ and Cu 2+ , respectively. The binding constants between PCTMT and Co 2+ and Cu 2+ are calculated as 1.8 ×10 17 M -2 and 2.3 ×10 16 M -2 , at a 2:1 mol ratio. In the probe system, Co 2+ and Cu 2+ can be distinguished by oxalate titration. The detection mechanism is discussed through testing analyses with the theoretical simulation calculation via the density functional theory (DFT) and time-dependent density functional theory (TD-DFT). The probe also indicates good detection capacities in real water samples. This study may promote the development of coordinated-type ion probes and innovation in water quality detection technology.
研究领域:
分析化学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
MICROCHIMICA ACTA
·
2024
·Vol. 191
·期 9
·1-15
·
IF 5.3
Guo Jieli,Li Jin,Xing Xiujing,Xiong Wei,Li Hao
As an ideal transition metal oxide, Co 3 O 4 is a P-type semiconductor with excellent electrical conductivity, non-toxicity and low cost. This work reports the successful construction of Co 3 O 4 materials derived from metal-organic frameworks (MOFs) using a surfactant micelle template-solvothermal method. The modified electrodes are investigated for their ability to electrochemically detect Pb 2+ and Cu 2+ in aqueous environments. By adjusting the mass ratios of alkaline modifiers, the morphological microstructures of Co 3 O 4 -X exhibit a transition from distinctive microspheres composed of fiber stacks to rods. The results indicate that Co 3 O 4 -1(NH 4 F/CO(NH 2 ) 2 = 1:0) has a distinctive microsphere structure composed of stacked fibers, unlike the other two materials. Co 3 O 4 -1/GCE is used as the active material of the modified electrode, it shows the largest peak response currents to Pb 2+ and Cu 2+ , and efficiently detects Pb 2+ and Cu 2+ in the aqueous environment individually and simultaneously. The linear response range of Co 3 O 4 -1/GCE for the simultaneous detection of Pb 2+ and Cu 2+ is 0.5–1.5 μM, with the limits of detection (LOD, S/N = 3) are 9.77 nM and 14.97 nM, respectively. The material exhibits a favorable electrochemical response, via a distinctive Co 3 O 4 -1 microsphere structure composed of stacked fibers. This structure enhances the number of active adsorption sites on the material, thereby facilitating the adsorption of heavy metal ions (HMIs). The presence of oxygen vacancies (O V ) can also facilitate the adsorption of ions. The Co 3 O 4 -1/GCE electrode also exhibits excellent anti-interference ability, stability, and repeatability. This is of great practical significance for detecting Pb 2+ and Cu 2+ in real water samples and provides a new approach for developing high-performance metal oxide electrochemical sensors derived from MOFs. Graphical abstract
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）