Inorganic Chemistry Frontiers
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2020
·Vol. 8
·期 1
·164-172
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IF 5.958
Peng-Fei Li,Chun-Li Hu,Fang Kong,Shao-Ming Ying,Jiang-Gao Mao
Two new yttrium sulfate tellurites, namely, Y3(TeO3)2(SO4)2(OH)(H2O) and Y2(Te4O10)(SO4), were achieved in our exploration of new sulfate tellurites, with a large birefringence in the Y3+–Te4+–SO42− system. The two compounds exhibit two new three dimensional (3D) frameworks composed of different yttrium tellurite layers bridged by sulfate tetrahedra. The tellurite groups in Y2(Te4O10)(SO4) polymerized together into a unique (Te4O10)4− 1D double-strand with an eight-member polyhedral ring tunnel along the a-axis. Optical diffuse reflectance spectra showed that the two compounds present a wide energy band gap with Eg values of 4.4 and 4.1 eV respectively. The birefringence values of Y3(TeO3)2(SO4)2(OH)(H2O) and Y2(Te4O10)(SO4) were calculated to be 0.092 and 0.149 at 532 nm respectively. Furthermore, the anhydrous Y2(Te4O10)(SO4) features a large birefringence, wide energy band gap and high thermal stability. In addition, the IR spectrum, TG-DSC curve and theoretical calculations of the title compound were recorded in this paper.
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MATERIALS CHEMISTRY AND PHYSICS
·
2016
·
IF 2.101
Xiaoniu Yu,Chunxiang Qian
Nano-sized CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 with hexagonal phase have been prepared by simply varying the reactant P/Ce molar ratio in bacterial liquid. The phase composition of two samples was checked via Fourier transform infrared spectroscopy (FTIR), energy dispersive analysis of X-rays (EDS) and X-ray diffraction (XRD) analyses, displaying the presence of CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 with average crystallite size are 32.34 and 15.61 nm, respectively. The scanning electron microscopy (SEM) images show that nano-clusters and sphere-like in shape with a narrow diameter distribution were observed in two samples. The transmission electron microscopy (TEM) photographs further indicate obtained CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 nanoparticles correspond to nanosheets and nanorods , respectively. The emission spectra of CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 display a broad band of 300–380 nm range with the strongest emission at 342 nm in the violet region.
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Journal of Energy Chemistry
·
2016
·
IF 2.322
Ran An,Guizhuan Xu,Chun Chang,Jing Bai,Shuqi Fang
Butyl levulinate (BL) is a promising new candidate as diesel fuel and fuel additive. In this study, an efficient process for a one-pot synthesis of BL from biomass-derived carbohydrates in butanol medium with the catalysis of metal sulfates was developed. The catalytic activity of a series of metal sulfates for the synthesis of BL from fructose was investigated. Among various metal sulfates, ferric sulfate Fe 2 (SO 4 ) 3 was found to be the most efficient catalyst, which gave a remarkably high BL yield of 62.8 mol% under the conditions of 463 K, 3 h, a catalyst dosage of 5.0 g/L, and fructose concentration of 25 g/L. Different carbohydrates including glucose, cellulose , inulin and sucrose were also used for one-pot synthesis of BL with the catalysis of Fe 2 (SO 4 ) 3 , showing the yields of 39.6, 30.5, 56.6 and 50.1 mol%, respectively. In addition, the recycling and reuse of Fe 2 (SO 4 ) 3 was studied by characterizing them using powder X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS). A plausible reaction pathway for the one-pot synthesis of BL from fructose was proposed. This study provides a facile and feasible way for the synthesis of BL from biomass.
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INORGANIC CHEMISTRY
·
2022
·
IF 5.436
Yaoguo Shen,Longjie Huang,Zhifeng Wang,Yingwu Zhou,XiaoLing Xue,Hong Lin,Renwen Yan,Sangen Zhao,Junhua Luo
SO4 tetrahedral groups have weak polarization anisotropy, which thus results in the small birefringence of sulfates. Here, we report new sulfate CsY(SO4)2·4H2O with unprecedented birefringence among deep-ultraviolet (deep-UV) sulfates. Its single crystal (10 mm × 3.5 mm × 1.5 mm) was simply grown by an aqueous solution evaporation technique, and it features a rare layered structure composed of YO9 polyhedra, SO4 tetrahedra, and H2O molecules. Interestingly, each SO4 group donates two oxygen atoms to edge-share with one adjacent YO9 polyhedron and thus causes severe distortion of these groups. The characteristic edge-sharing mode gives CsY(SO4)2·4H2O a large birefringence of ∼0.045@546 nm, which is the maximum among deep-UV sulfates and phosphates with similar non-π-conjugated anionic groups. The ultraviolet–visible-near-infrared diffuse reflection and transmission spectra, infrared spectrum, thermal stability, and theoretical calculations are also presented. The fascinating results will improve our understanding of sulfates and may provide useful insights into the exploration of deep-UV sulfates with large birefringence.
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MOLECULES
·
2026
·Vol. 31
·期 11
·1908
·
IF 5.1
Wei Cao,Lifang Chen,Tingting Wang,Ke Wang,Zhen Song,Zhiwen Qi
In order to address corrosion and pollution problems of liquid acids and limitations of traditional solid acids, sulfated MOF-808-SO4catalysts were developed by creating unsaturated sites in MOF-808 for sulfate grafting with ligand defect engineering. Characterization verified framework integrity, successful sulfate coordination, and maintenance of high surface areas and tunable porosity. Temperature-programmed desorption of ammonia (NH3-TPD) establishes a clear consistent trend between defect density and the concentration as well as the strength of acid sites, indicating that a higher degree of ligand deficiency promotes the formation of more abundant and stronger acid centers. For esterification of acetic acid with n-butanol, the catalyst prepared by replacing 40 mol% of BTC with BDC achieved ≥99% conversion of acetic acid under mild conditions of 2.0 wt% catalyst loading and 1:2 alcohol/acid molar ratio at 120 °C for 6 h, outperforming conventional solid acids. This performance stems from high-density strong Brønsted acid sites strongly coordinated at defects and an open pore structure facilitating diffusion. The catalyst was easily recovered by ethanol washing and maintained stable activity over five cycles without loss of catalytic capability. This work suggests defect engineering as an effective strategy for tuning acidity and catalytic performance in MOF-based solid acids for green esterification.
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PubMed
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Materials Chemistry Frontiers
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2022
·Vol. 6
·期 23
·3567-3576
·
IF 8.683
Peng-Fei Li,Chun-Li Hu,Fang Kong,Jiang-Gao Mao
The exploration of new birefringent materials in the d10 transition metal sulfate selenite system resulted in three new compounds, namely, Hg2(SeO3)(SO4), La2Hg3(SeO3)4(SO4)2(H2O)2 and Ag2Cd(Se2O5)(Se0.3S0.7O4), using mild hydrothermal methods. Hg2(SeO3)(SO4) shows a 3D structure composed of 2D mercury selenite layers connected by 1D mercury sulfate chains; La2Hg3(SeO3)4(SO4)2(H2O)2 features a novel 3D network composed of 1D lanthanum sulfate chains and 2D mercury oxide layers, which are connected by a SeO3 triangular pyramid bridge; Ag2Cd(Se2O5)(Se0.3S0.7O4) exhibits a novel 3D framework that consists of selenate silver layers bridged by SO4 tetrahedra and CdO6 octahedra. These compounds can remain stable above 250 °C and their optical band gap values are larger than 3.5 eV. The birefringence (Δn) of Hg2(SeO3)(SO4) was calculated to be 0.133 at 532 nm and 0.126 at 1064 nm. Hg2(SeO3)(SO4) was proved as the first reported metal selenite sulfate exhibiting a large birefringence. In addition, the IR spectra, TG-DSC curves and theoretical calculations of the three compounds were studied.
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ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
·
2016
·Vol. 642
·期 4
·343-349
·
IF 1.261
Xiao Zhao,Dajiang Mei,Jingli Xu,Yuandong Wu
Three compounds A Sb 2 (SO 4 ) 2 (PO 4 ) ( A = H 3 O + , K, Rb) were obtained from the reactions of Sb 2 O 3 , A 2 CO 3 ( A = Li, Rb) or K 2 SO 4 and NH 4 H 2 PO 4 in H 2 SO 4 (98 %) at 220–250 °C. Their structures were determined by single-crystal X-ray diffraction. All compounds crystallize in the triclinic space group P (no.2) and are isostructural. The crystal structures consist of two-dimensional 2 ∞ [Sb 2 (SO 4 ) 2 (PO 4 )] – anionic layers and alkali cations, which are located between anionic layers. The anionic layers are composed of [SbO 4 ] ψ-trigonal bipyramids, [SbO 5 ] ψ octahedra, [SO 4 ] tetrahedra, and [PO 4 ] tetrahedra. All compounds are characterized by solid state UV/Vis/NIR diffuse reflectance spectra, FT-IR spectroscopy, and Raman spectroscopy.
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ACS Applied Materials & Interfaces
·
2024
·
IF 8.3
Wei Wei,Tao Ye,Zunqiu Xiao,Kejia Xiang,Huaying Wang,Zhongtai Zhang,Shitong Wang,Zilong Tang
The development of cathode materials has always been one of the most crucial areas of research in the field of sodium-ion batteries. Sulfate-based polyanionic materials, known for their high working voltage characteristics, have received widespread attention. In this work, a fluoro-sulfate sodium-ion battery cathode material, Na3Fe2(SO4)3F modified with carbon nanotubes, was developed using a low-temperature solid-state annealing method. This Na3Fe2(SO4)3F cathode exhibits an exceptionally high voltage of 3.77 V, excellent discharge capacity (102 mAh/g at 0.1C), and good rate capability. This material broadens the research directions for cathode materials and holds promise as a foundation for the further development of high-performance sodium-ion batteries.
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INORGANIC CHEMISTRY
·
2020
·
IF 4.825
Xuehua Dong,Ying Long,Xiaoyu Zhao,Ling Huang,Hongmei Zeng,Zhien Lin,Xin Wang,Guohong Zou
Two new antimony fluoride sulfates named A6Sb4F12(SO4)3 (A = Rb, Cs) with unique crown-like clusters have been successfully synthesized by introducing Sb3+ with a stereochemically active lone pair in the sulfate system through a facile hydrothermal method. The structure regulation induced by the cation sizes results in the symmetry difference in these two title compounds, i.e., Rb6Sb4F12(SO4)3 crystallizing in the polar noncentrosymmetric (NCS) space group of P3 and Cs6Sb4F12(SO4)3 in the centrosymmetric (CS) space group of P1̅. Detailed characterizations, including XRD, thermal behaviors, optical properties, and the theoretical calculations, for these two compounds have been performed. The discovery of the unique crown-like clusters observed in A6Sb4F12(SO4)3 (A = Rb, Cs) enriches the diversity of structures for antimony sulfates systems. Simultaneously, a summary and comparison for all reported antimony halide sulfates has been made to illustrate the synergistic effect of the stoichiometric ratio and cation sizes on the macroscopic centricity and the framework structure, which will guide the systematical discovery of antimony(III)-based functional materials in future.
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JOURNAL OF SOLID STATE CHEMISTRY
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2022
·
IF 3.656
Hui Yang,Ziyu Wang,Cuixia Xu,Yuan Lin,Guoliang Liu
The first example of lanthanide borate-sulfate compound, namely, La 2 B 3 O 4 (OH) 3 (SO 4 ) 2 has been obtained through hydrothermal synthesis , which belongs to polar space group Pna 2(1) (No. 33). Its structure possesses double lanthanum sulfate layers in the ab plane in which the lanthanide ions are bridged by SO 4 tetrahedra. These layers are further cross-linked by borate chains into the final 3D framework. It is noteworthy that this compound is the first lanthanide borate-sulfate which crystalizes in polar space group and it displays second-harmonic generation (SHG) signal of about 0.1 times that of KH 2 PO 4 . The SHG coefficient of the compound is ascribed to the synergistic effect of SO 4 units and borate units. Meanwhile, distorted LaO x polyhedra also play an important role in the contribution to SHG response.
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Nano Energy
·
2022
·
IF 19.069
Chaohui Tian,Chenhui Bai,Tao Wang,Zhifeng Yan,Zhiyi Zhang,Kai Zhuo,Hulin Zhang
Thermoelectric hydrogels can be used as energy conversion devices to convert low-grade heat into practical electricity for sustainable energy supply. However, current redox couple-based thermogalvanic gel electrolytes contain toxic metal elements, limiting their non-toxic and environmentally sustainable development. Here, a stretchable, flexible gel thermoelectric device is created by introducing a novel non-toxic redox couple of SO 4 2- /SO 3 2- for the first time, which exhibits a high Seebeck coefficient ( S e ) of 1.63 mV K −1 at the optimal redox couple concentration of 0.1 M. The tensile/compressive stress and deformation at break of the hydrogel electrolyte achieves a superior index due to the hybrid structure formed between PEDOT: PSS and SO 4 2- /SO 3 2- ion-promoted crosslinking PVA network. By subtly doping additional electrolyte ions , the gel affords a favorable ionic conductivity and thermoelectric performance. Furthermore, this PVA-SO 4/3 2- hydrogel shows the capacity of harvesting biothermal energy for operating small electronics at body temperature. This work breaks with conventional redox couples and represents a step towards green sustainable self-powered wearables using a new redox couple with a favorable thermoelectric performance.
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2022
·
IF 5.518
Yan Yi,Xiangyu Wang,Yaxian Zhang,Jun Ma,Ping Ning
The aquatic plant Egeria najas based biochar was innovatively constructed by modifying it with Fe 2 (SO 4 ) 3 (Fe 2 (SO 4 ) 3 @EN-BC) for Cr(VI) removal. The characterizations of Fe 2 (SO 4 ) 3 @EN-BC confirmed that Fe 2 (SO 4 ) 3 was attached to biochar in form of Fe 2 O 3 after hydrolysis and calcination under high temperature. The results showed that Fe 2 (SO 4 ) 3 @EN-BC had a high removal efficiency of Cr(VI) with approaching 99.88%, which was about 7 times higher compared to unmodified biochar (EN-BC). Batch experiments of Cr(VI) removal included initial concentration, reaction temperature, solution pH and kinetics were conducted. The adsorption kinetics could be more accurately explained using pseudo-second order kinetics model , indicating the chemical adsorption controlled the reaction process. According to the Langmuir model, the maximum adsorption capacities for Cr(VI) were 138.79, 159.36 and 190.91 mg/g at 298, 313 and 333 K, respectively. Moreover, based on FTIR and XPS results, the Fe 2 (SO 4 ) 3 @EN-BC surface was loaded with many functional groups conducive to Cr(VI) adsorption. The main removal mechanisms of Cr(VI) by Fe 2 (SO 4 ) 3 @EN-BC included adsorption and reduction, and the percentage of Cr(VI) removed by adsorption and reduction were 19.1% and 80.9%, respectively.
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