IRANIAN POLYMER JOURNAL
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2024
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IF 2.4
Shi Liang,Shen Xue,Qi Hongyun,Zhang Xiaomei,Shu Ruiwen
A novel lignin-based magnetic composite was synthesized using a facile method, with epichlorohydrin (ECH) serving as a cross-linker to bond amino-functionalized magnetic nanoparticles (AMNP), polyethyleneimine (PEI), and sodium lignosulfonate (LS). The synthesized composite (AMNP/LS-PEI) was subjected to characterization through multiple analytical techniques, namely FTIR, XRD, BET, TG, VSM, XPS, FE-SEM, EDS, HRTEM, and TEM. Following the synthesis, a thorough investigation was conducted into the composite’s adsorption capabilities for methylene blue (MB) and methyl orange (MO) dyes through batch adsorption, taking into account pivotal factors, including pH, contact time, solution concentration, and temperature. The experimental data suggested that the adsorption of MO and MB onto AMNP/LS-PEI was in good accordance with the Langmuir isotherm model. The AMNP/LS-PEI demonstrated maximum adsorption capacities ( Q max ) of 482.7 mg g −1 for MO and 375.6 mg g −1 for MB, respectively. The MB and MO-adsorption kinetics onto AMNP/LS-PEI closely fit the pseudo-second-order model. Furthermore, the thermodynamic analysis revealed that the adsorption process of dyes onto AMNP/LS-PEI was an endothermic one. Upon six adsorption–desorption cycles, AMNP/LS-PEI demonstrated sustained adsorption capacity, achieving removal rates of 81.3% for MB and 77.1% for MO, respectively. The potential advantage for practical applications lied in its highly selective adsorption capability for mixed solutions of MB and MO. Specifically, at a pH of 4, MO was preferentially adsorbed, whereas at a pH of 8, MB was favored for adsorption. In addition, the adsorption mechanism of AMNP/LS-PEI toward dyes was explored using FTIR and XPS, and was found to be mainly ascribed to the electrostatic interaction, hydrogen bonding interaction, and cation exchange. Graphical abstract
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SCIENCE OF THE TOTAL ENVIRONMENT
·
2018
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IF 4.61
Shanshan Liu,Heyi Ge,Cuicui Wang,Yu Zou,Jingyu Liu
The objective of this study was to synthesize a novel, efficient and economical bio-adsorbent with three dimensions (3D) structure using a direct assembly method for removal of methylene blue (MB) from aqueous solution. The raw materials were corn straw core (CSC) and graphene oxide (GO). The variables that affected adsorption capacity were tested. GO loading could facilitate the removal rate. When 5 wt% GO was added (CSC-5GO), the removal rate was increased by 21.62% compared to pure CSC (64.58%). Furthermore, the adsorption by CSC-5GO fitted pseudo-second-order kinetic model (R 2 > 0.998) and Temkin model (R 2 > 0.955). The maximum adsorption capacity was 414.03 mg g −1 for MB at pH = 12, 298 K and MB concentration of 1000 mg L −1 . The adsorption thermodynamic test results suggested that the adsorption was a spontaneous, exothermic and randomness decrease process. Furthermore, after five cycles of adsorption-desorption test, the adsorbent removal rate was >90%, which implied that CSC-5GO had an excellent reproducibility.
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CRYSTENGCOMM
·
2024
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IF 2.6
Yang Zhou,Dan Wang,Qiuxiang Feng,Qi Wu,Feng Cao,Li Jiang,Qianli Zhang,Jie Liu
Synthesizing stable MOF materials with good adsorption capability in a relatively green way is well worth investigating. In this work, a stable Ce-UiO-66-NH2 MOF was constructed from Ce(IV) salts and a bifunctional ligand, 2-amino terephthalic acid, in a mixture of water and ethanol at room temperature. The MOF solid was fully characterized and its adsorption properties for methylene blue were investigated in detail. Ce-UiO-66-NH2 showed excellent removal ability of MB over a wide pH range, the adsorption process followed a pseudo-second-order kinetic model, and the isothermal adsorption data fit well with a Langmuir model with a maximum capacity of 427 mg g−1. Moreover, a spontaneous heat adsorption process was concluded from thermodynamic study, and this MOF sorbent can be reused for several cycles with its structural stability maintained. A possible mechanism for MB adsorption was also proposed.
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Nanoscale Research Letters
·
2011
·Vol. 6
·期 1
·1-15
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IF 2.56
Wu Wei,Xiao Xiangheng,Zhang Shaofeng,Ren Feng,Jiang Changzhong
Many methods have been reported to improving the photocatalytic efficiency of organic pollutant and their reliable applications. In this work, we propose a facile pathway to prepare three different types of magnetic iron oxides/TiO 2 hybrid nanoparticles (NPs) by seed-mediated method. The hybrid NPs are composed of spindle, hollow, and ultrafine iron oxide NPs as seeds and 3-aminopropyltriethyloxysilane as linker between the magnetic cores and TiO 2 layers, respectively. The composite structure and the presence of the iron oxide and titania phase have been confirmed by transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectra. The hybrid NPs show good magnetic response, which can get together under an external applied magnetic field and hence they should become promising magnetic recovery catalysts (MRCs). Photocatalytic ability examination of the magnetic hybrid NPs was carried out in methylene blue (MB) solutions illuminated under Hg light in a photochemical reactor. About 50% to 60% of MB was decomposed in 90 min in the presence of magnetic hybrid NPs. The synthesized magnetic hybrid NPs display high photocatalytic efficiency and will find recoverable potential applications in cleaning polluted water with the help of magnetic separation.
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CHEMICAL ENGINEERING JOURNAL
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2017
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IF 6.216
Xinyi Wan,Yingqing Zhan,Zhihang Long,Guangyong Zeng,Yi He
Design and fabrication of structurally optimized absorbents are important for wastewater treatment such as dyes and heavy metals removal. Herein, we reported the core@double-shell structured magnetic halloysite nanotube nano-hybrid absorbent with target micro-structure and high efficiency removal capacity of dyestuffs. Our core@double-shell structured absorbent consisted of a halloysite nanotube as skeleton, an intermediate magnetic nanoparticles coating with more specific surface area and magnetic separation property, and poly(DA + KH550) derivate layer outside provided active adsorption sites. This well-defined core@double-shell configuration was quite distinct from conventional core-shell or hybrid structures. The integrated advantages of HNTs skeleton, Fe 3 O 4 nanoparticles inner shell and poly(DA + KH550) outside shell contributed to the high adsorption capacity of methylene blue (up to 714.29 mg g −1 ) and excellent cycling stability. Furthermore, the novel core@double-shell structured absorbent exhibited better removal efficiency for methylene blue in solution with high pH, and the adsorption process can be described by using the pseudo-second-order model. More importantly, the recycling process of adsorbents was more energetically and economically sustainable by using a permanent magnet. The characteristic high removal capacity, cycling stability and easy separation made core@double-shell structured absorbent promising for the efficient removal of dyestuffs from the wastewater.
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KEY ENGINEERING MATERIALS
·
2017
·
IF 0
Meng Xia Qian,Jian Li Ma,Min Hong Xu
A novel supported catalyst is prepared through immobilization of water soluble phthalocyanine, which is synthesized by modifying tetraminophthalocyanine with cyanuric chloride, onto the supporting material Mg-Al hydrotalcite via co-precipitation method. The structure of the catalyst is characterized by infrared spectroscopy instrument (FT-IR) and X-ray diffractometer. Catalytic activity is examined through comparative experiments. The results show that it exhibits high catalytic activity for degradation of methylene blue (MB) in the presence of H2O2, the remaining rate of MB is 12.02% after 6 h. The reaction process conforms to the equation of pseudo-first-order kinetics, and the correlation coefficient R2> 0.99. The recycling tests for five times are also carried out and prove its reusability in catalytic application.
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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2025
·
IF 8.5
Wenliang Lei,Juan Liu,Wenyong Zhang,Jing Xu,Tao Bo,Zhiwen Wang,Wei Wang
H 2 S is a crucial endogenous gaseous signaling molecule involved in various metabolic pathways and is associated with the biological response to heavy metal stress. The biomineralization of CdS serves as a critical mechanism for responding to cadmium stress and removing Cd 2+ in different organisms. CdS is also a widely utilized semiconductor material for the photocatalytic degradation of dyes. In this study, we found that cysteine synthetase 1 (TtCsa1) is involved in CdS formation under cadmium stress in Tetrahymena thermophila . TtCsa1 also catalyzed CdS formation in vitro, and the synthesized CdS material exhibited controllable particle size and photoluminescence. Concurrently, cysteine and glutathione functioned as capping agents to regulate CdS particle size. The biosynthetically produced CdS degraded 90 % of methylene blue under UV light. Furthermore, CdS-ZnS nanocomposites were synthesized by adding Zn 2+ into the CdS biosynthetic system, which decreased the size of CdS particles and increased the degradation rate of methylene blue. The results indicate that the CdS biosynthesized by TtCsa1 from Tetrahymena thermophila is effective in the photocatalytic degradation of organic dyes.
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MICROCHIMICA ACTA
·
2025
·Vol. 192
·期 3
·1-9
·
IF 5.3
Guo Dongying,Yang Hailiang,Zhang Longyue,Dai Ruoyu,Huang Yuankui,Hu Yaoping
Specific assay for methylene blue (MB) in aquaculture is critically required to assess the safety of ecosystems and aquatic products. In this work, a facile method is demonstrated for ratiometric fluorescence determination of MB based on blue/red dual emissive carbon dots (b/r-CDs). b/r-CDs, derived from the leaves of Impatiens balsamina, show weak and strong emission peaks at 432 and 672 nm, respectively, and possess a high photoluminescence quantum yield of 35.7%. The red fluorescence of b/r-CDs at 672 nm, serving as the response signal, can be significantly quenched by MB due to the mechanism of inner filter effect, while the blue fluorescence at 432 nm is insensitive to MB, thus acting as the background reference. With addition of an increased amount of MB, the fluorescence color of b/r-CDs gradually changes from red to blue, which realizes the visual detection. The linear range and limit of detection are measured to be 0.05–10 μM and 15 nM, respectively. Notably, a portable smartphone sensing platform is built for quantitative detection of MB by analyzing the RGB values. Moreover, the practical applications of b/r-CDs for monitoring MB in real water and aquatic products using both fluorescence spectrophotometer and smartphone achieve satisfactory results. Graphical
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JOURNAL OF MEDICINAL CHEMISTRY
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2025
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IF 6.8
Tianyu Zhu,Jipeng Ding,Fan Zheng,Yanpeng Fang,Wenzhi Huang,Ying Yin,Wenbin Zeng
Nitrogen mustard, a widely used chemotherapeutic agent for more than 70 years, exhibits significant efficacy. However, its clinical applications are severely limited by poor tumor selectivity and severe side effects on normal tissues. To address these limitations, we developed a near-infrared (NIR)-activatable nitrogen mustard prodrug, MBNM. Upon NIR irradiation, the controlled cleavage of the urea bond within MBNM facilitates the simultaneous release of nitrogen mustard and methylene blue (MB), enabling a synergistic approach combining chemotherapy and photodynamic therapy (PDT) for effective tumor suppression. Moreover, the release of MB upon activation enables real-time monitoring of prodrug activation. Notably, MBNM demonstrated significantly improved biosafety compared to free nitrogen mustard. These findings suggest that the photocleavable prodrug MBNM offers a promising strategy for safe and effective combination cancer therapy.
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PHYSICAL CHEMISTRY CHEMICAL PHYSICS
·
2025
·
IF 2.9
Jiaqi Li,Yidan Zhang,Pingyu Luo,Chun Li,Fanming Zeng,Tiantian Sun,Hanhui Lei,Xiaoteng Liu,Chunbo Liu
Persulphate-based advanced oxidation technology efficiently and cost-effectively removes organic dyes from water but designing stable photocatalytic systems and understanding their reaction mechanisms remain key challenges. Metal–organic frameworks (MOFs) have attracted considerable research attention for degrading organic pollutants owing to their high porosity, tunable structure, and ease of modification. In this study, a series of M-MOF-74 (M = Co, Fe, Ni) photocatalysts are synthesized by a hydrothermal method for methylene blue (MB) degradation. Among them, the Co-MOF-74 photocatalytic synergetic peroxymonosulfate system exhibits high catalytic activity after 30 min of visible light irradiation. MB degradation efficiency reaches 94.8%, and the reaction rate constant is 0.210 min−1, which is approximately 19.44 times higher than the reaction rate constant of the original Co-MOF-74. Compared with Fe-MOF-74 and Ni-MOF-74, Co-MOF-74 exhibits better photocatalytic performance due to the dynamic changes in the valence state of cobalt, which more effectively facilitate the activation of PMS. In addition, this study analyses the possible degradation pathways of MB in water and toxicological evaluations of intermediate products, providing new insights for the effective removal of dyes in water.
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Materials Science and Engineering B-Advanced Functional Solid-State Materials
·
2025
·
IF 4.6
Wenjuan Zhang,Qiaohong Zhang,Xiangyue Yang,Mengyu Ran,Yezhi Ding,Peiqing La
Conventional homogeneous catalysts for photo-Fenton reactions suffer from inherent drawbacks, including difficult recovery, poor stability, and rate-limiting steps, which significantly restrict their practical application. To overcome these challenges, a novel photo-Fenton catalytic support, MXene–porous polydopamine (MPP), was fabricated via an interfacial co-assembly strategy. Subsequently, nano zero-valent iron (Fe) was anchored onto the MPP framework to construct a magnetic MXene–porous polydopamine (Fe/MPP) catalyst. The unique multi-interfacial porous structure of Fe/MPP facilitates efficient mass and electron transport, while the synergistic effects of Fe redox cycling and phenol–quinone conversion under light irradiation enhance the Fe 3+ /Fe 2+ regeneration process. As a result, Fe/MPP achieved outstanding photo-Fenton degradation performance, removing 99.89 % of methylene blue (MB, 4 g/L) within 30 min, surpassing most previously reported homogeneous catalysts. Moreover, Fe/MPP exhibits excellent reusability, maintaining over 53 % degradation efficiency after ten consecutive cycles. These results demonstrate that Fe/MPP exhibits high photo-Fenton activity and cycling stability, showing promising potential for practical wastewater treatment applications.
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MOLECULES
·
2025
·Vol. 30
·期 24
·
IF 4.6
Yanfeng Zhang,Yong Huang,Han Leng,Xuwei Chen
The photo-Fenton process is an advanced oxidation method widely employed in environmental remediation. Herein, we developed a novel metal–organic framework@hydrogen-bonded organic framework (MOF/HOF) composite with excellent photo-Fenton-like activity for the efficient degradation of organic dye methylene blue (MB). Cu-based MOF (CuBTC) was firstly prepared via the solvothermal method, then melamine (MA) and trimesic acid (TMA)-based HOF (MA-TMA) was grown in situ on CuBTC with hydrogen bonding interactions to produce the MOF/HOF composite CuBTC-MA. The CuBTC-MA composite could catalyze H2O2to produce active substances for efficient MB degradation. The degradation rate constant of the CuBTC-MA composite was 4.4 times and 16.7 times higher than that of CuBTC and MA-TMA. The remarkably enhanced performance was attributed to the synergistic effect between the efficient separation of electron–holes supported by the type-II heterojunction structure of the CuBTC-MA composite and the Cu(I)/Cu(II) inter-conversion. The CuBTC-MA composite demonstrated exceptional repeatability and maintained a stable performance across a broad pH range. This study provided a novel paradigm for engineering heterogeneous MOF/HOF heterostructures, demonstrating significant potential in advancing photo-Fenton-like catalytic systems for the efficient environmental remediation of organic pollutants through synergistic charge separation and radical generation mechanisms.
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