ChemElectroChem
·
2022
·Vol. 9
·期 7
·e202101574
·
IF 4.782
Jia-Lin Du,Xu Bao,Wei-Bin Zhang,Lun Zhang,Yao-Wen Guo,Xia Zhou,Xian-Li Zhang,Shan-Shan Chai,Shao-Bo Guo,Xiong-Wei Han,Jianping Long
Graphical Layer by layer : The electrochemical kinetics of layered manganese phosphate are improved via interfacial polypyrrole chemical binding for electrochemical supercapacitor application. The major limitation of low-cost and high-safety aqueous manganese-based materials for electrochemical energy storage is largely hampered by their poor cyclic stability, usually caused by the manganese dissolution and interfacial kinetics. Herein, we synthesized a manganese phosphate material via interfacial polypyrrole chemical binding, with unique structural properties for aqueous supercapacitor application. It exhibited higher specific capacitance, remarkable rate performance and better cycle stability compared to bare manganese phosphate. In contrast with interfacial polypyrrole coating on manganese phosphate nanosheets, the polypyrrole could form a Mn−N bond with the manganese phosphate, indicating stable chemical binding. Thus, the appropriate interfacial chemical binding is an efficient strategy to improve the nanostructure stability and electrochemical kinetics of manganese-based materials for aqueous electrochemical energy storage.
✓ 已验证
产品关联
DOI
高影响因子
Sustainable Energy & Fuels
·
2022
·Vol. 6
·期 4
·1084-1093
·
IF 6.813
Meilian Gao,Pingping Gao,Ting Lei,Chun Ouyang,Xiaobo Wu,Anru Wu
A novel porous iron phosphide (p-FeP) loading on nitrogen-doped carbon fiber/carbon paper (p-FeP/NCF/CP) as highly effective self-supporting catalysts for the hydrogen evolution reaction (HER) is synthesized by a three-step approach, including N-doped carbon fiber network preparation, porous FeOOH/NCF/CP precursor by selectively etching, and subsequent phosphorization process. The as-obtained p-FeP/NCF/CP composite exhibits a higher specific surface area and larger porosity in comparison to FeP/CP composite due to the rich porous structure and 3D network of the N-doped carbon fiber matrix (NCF). Electrochemical measurements demonstrate that p-FeP/NCF/CP composite exhibits an excellent electrocatalytic activity for HER with small overpotentials of 63 mV and 96 mV at 10 mA cm−2 current density in 0.5 M H2SO4 and 1.0 M KOH, respectively. The p-FeP/NCF/CP material also exhibits a small Tafel slope and charge transfer resistance as well as good stability and durability in pH 7 and pH 14.
✓ 已验证
产品关联
DOI
高影响因子
Journal of Water Process Engineering
·
2022
·
IF 7.34
Xing Lai,Chun Wang,Liming Wang,Changfa Xiao
In this study, a stable and controllable poly( p -phenylene terephthamide)/polypyrrole (PPTA/PPy) composite organic solvent nanofiltration (OSN) hollow fiber membrane was successfully prepared based on the robust chemical vapor deposition (CVD) method. The structure and properties of the prepared PPTA/PPy OSN membranes were studied in detail. Interestingly, after modifying by PPy, SEM showed that the surface of the membrane formed a layer of “Turing-like” structure and evenly covered the surface of the membrane. It was evident that the prepared PPTA/PPy OSN membranes achieved good dye-removal ability with a molecular weight cut-off range from 200 to1000 Da, and the rejection of negative dyes was higher than 93.4%. Especially at high temperature (80 °C) and organic solvent ( N , N -dimethylacetamide, DMAc), the PPTA/PPy OSN membranes still exhibited excellent permeation and separation performance. Furthermore, at room temperature, the immersion experiment of the fabricated PPTA/PPy OSN membranes in both ethanol and DMAc for one month also proved the stability of long-term organic solvents. Based on the above results, this work offered a novel PPTA based hollow fiber nanofiltration membrane, which was expected to be applied in thermal and organic dye wastewater treatment .
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Energy Materials
·
2023
·
IF 6.4
Lili Luo,Xiaohong Wang,Siyu Yang,Juguo Dai,Dongxu Li,Long Xia,Cheng Chi,Andreu Cabot,Yiting Xu,Lizong Dai
While asymmetric supercapacitors (ASCs) have huge potential as efficient, durable, and cost-effective energy storage devices, they fail to meet expectations because of the unoptimized architecture and composition of their electrode materials. Herein, PPy/PANI@MoS2 (PPMS) ternary composites with a dual-channel structure are obtained by facile hydrothermal and in situ polymerization methods. These dual conductive channels synergistically improve the electrode’s electrical conductivity, facilitate ion diffusion, enlarge the interlayer distance, and increase the accessible surface area. Taking advantage of such a favorable architecture, PPMS composites exhibit outstanding electrochemical properties, including a huge specific capacitance (1171 F g–1 at 1 A g–1) and rate capability (861 F g–1 at 20 A g–1) in three-electrode systems. Based on charge storage mechanism analyses, we demonstrate that the kinetic behavior of PPMS electrodes is dominated by the surface capacitance (95.9% at 100 mV s–1). Besides, PPMS-based ASCs (PPMS//activated carbon) operate in a broad voltage window (1.8 V), delivering an ultrahigh energy density of 93.4 Wh kg–1 at a power density of 884.8 W kg–1. They also show a superior cycling stability of 90.4% and a remarkable Coulombic efficiency of 99.2% for 10,000 cycles. This work affords an inspiration for rational structural optimization of PANI-based electrode materials with great prospects in the development of next-generation high energy density ASCs.
✓ 已验证
产品关联
DOI
高影响因子
SENSORS AND ACTUATORS B-CHEMICAL
·
2023
·
IF 8.4
Yaqi Yang,Jiejun Li,Zhiwang Luo,Xingnian Li,Jiayi Zou,Chunyan Li,Chao Chen,Yixi Xie,Pengcheng Zhao,Junjie Fei
One-dimensional (1D) ordered mesoporous carbon hybrid nanotubes loaded with bimetallic oxide hollow nanospheres are expected to be very attractive electrocatalysts . In this study, through high-temperature pyrolysis , we generated Mo 2 C@C PNTs with outstanding electrical conductivity , a significant surface area , and effective catalytic activity by wrapping ordered mesoporous polypyrroles on the surface of 1D MoO 3 nanotubes using block polymers that self-assembled. FeMnO 3 hollow porous nanospheres have a large specific surface area, many electroactive sites, and excellent molecular/charge diffusion properties, which can be compounded with 1D ordered mesoporous nitride-rich carbon to solve the problem of poor electrical conductivity of metal oxides and to prevent the accumulation of 1D nanotubes. The composite showed excellent electrocatalytic activity towards rutin due to the synergistic interaction between Mo 2 C@C PNTs and FeMnO 3 . In the best case, rutin has a limit of detection (LOD) as low as 0.35 × 10 −9 M and a wide linear range (3 × 10 −9 to 3.1 × 10 −6 M). The sensor displays a remarkable level of selective response to rutin in the presence of other co-interfering species. Furthermore, it has superb repeatability and reproducibility. The sensor has shown outstanding recovery (95.7–104.1 %) in the practical viability of detecting rutin in beverages. This work not only provides a new candidate for the accurate detection of rutin but also provides insight into the exploration of advanced sensing materials.
✓ 已验证
产品关联
DOI
高影响因子
Science Bulletin
·
2023
·
IF 18.9
Weikang Wang,Yan Bai,Pin Yang,Shuai Yuan,Feiyang Li,Weiwei Zhao,Beibei Jin,Xuan Zhang,Shujuan Liu,Daqiang Yuan,Qiang Zhao
Chemical transformation strategy is capable of fabricating nanomaterials with well-defined structures and fascinating performance via controllable crystallization kinetics in the phase transformation. V 2 CT x MXene has been used as precursors to fabricate vanadium porphyrin metal–organic frameworks (V-PMOFs) via the coordination of deprotonated carboxylic acid ligands. However, the rational and in-depth exploration of synthesis mechanism with the aim of enriching the variety of MXene (i.e., Ti 3 C 2 T x ) and organic ligands (i.e., catechol-based) to design new MOFs is rarely reported. Herein, we have first developed a metal ion assistant transformation strategy to synthesize three-dimensional catechol-based TiCu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxytriphenylene) MOFs with a non-interpenetrating SrSi 2 ( srs ) framework using two-dimensional Ti 3 C 2 T x as precursors. The unique synergetic transformation mechanism involves the electron transfer from Ti 3 C 2 T x to electrostatically adsorbed Cu 2+ ion for redox reaction , the subsequent Ti–C bond rupture for Ti 4+ ion release , and the continuous chelation coordination between Ti 4+ /Cu 2+ and HHTP. Ti 3 C 2 T x precursors and auxiliary metal ion could be rationally substituted by V 2 CT x and M n + (e.g., Ni 2+ , Co 2+ , Mn 2+ , and Zn 2+ ), respectively. This strategy lays the foundation for the design and synthesis of innovative and multifarious MOFs derived from MXene or other unconventional metal precursors .
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF HAZARDOUS MATERIALS
·
2023
·
IF 13.6
Peng Wu,Xiaoyu Yin,Yufan Zhao,Feize Li,Yuanyou Yang,Ning Liu,Jiali Liao,Tu Lan
The reduction of soluble U(VI) to insoluble U(IV) precipitates by visible light is an environmentally friendly and highly effective strategy to remove uranium from uranium-containing radioactive wastewater . Herein, a porous hydrogen-bonded organic framework (HOF) of UPC-H4a was self-assembled by intermolecular hydrogen bonds of 5,10,15,20-tetra(4-(2,4-diaminotriazine)phenyl) porphyrin to remove U(VI) from aqueous solution. UPC-H4a has high crystallinity with permanent porosity, excellent photocatalytic property, good chemical stability, and strong photocatalytic reducibility. The experiments showed that UPC-H4a removed 98.18% of U(VI) after illumination for 120 min, with high selectivity , strong ion interference resistance, and good reusability. A real low-level radioactive wastewater was employed to estimate the potential of UPC-H4a for practical application and its removal rate can reach 66.14% in the presence of redox competing metal ions , exhibiting great potential for practical application. The DFT calculations and EPR spectra revealed that a more negative electrostatic potential of DAT-porphyrin and the formed intermolecular hydrogen bonds in UPC-H4a can facilitate the participation of photogenerated electrons in the O 2 /∙O 2 – reaction, and the radical of ∙O 2 – was proved to be the critical participant in U(VI) photoreduction . The discovery of UPC-H4a in this work will help to develop more potential applications of HOFs as photocatalysts in radioactive wastewater treatment .
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ACS Applied Materials & Interfaces
·
2023
·
IF 9.5
Yu Liu,Xiaoming Qi,Xiuyan Deng,Jieke Ye,Yaqin Fu,Shaoyun Fu
The accuracy of data collected by optical instruments can be greatly impacted by radar band electromagnetic waves (EM) and scattered visible light. Traditional electromagnetic-wave-absorbing (EMA) materials face challenges in effectively attenuating electromagnetic waves within the visible light spectrum. To address this issue, a structural engineering-based assembly strategy was developed to construct PVDF/Ti3CNTx@PPyNF composites with multiple heterogeneous interfaces, inspired by snake scales. And through the self-doping of N elements and the coating process, the material finally exhibits excellent microwave and visible light absorption properties. This approach generates multiple polarization losses of electromagnetic waves, enabling the material to exhibit excellent electromagnetic wave absorption performance. Specifically, the PVDF/Ti3CNTx@PPyNF composite, containing 5 wt % Ti3CNTx@PPyNFs, demonstrates exceptional microwave absorption performance, with a minimum reflection loss of −65.5 dB and an effective absorption bandwidth of up to 6.95 GHz. Additionally, the composite coating exhibits 97.4% visible light absorption performance, providing a promising solution to the challenges of protecting against complex electromagnetic environments.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2023
·
IF 8.2
Yu-Xiong Ju,Peng Song,Ping-Yue Wang,Xin-Xin Chen,Tao Chen,Xiao-Hui Yao,Wei-Guo Zhao,Dong-Yang Zhang
Flexible supercapacitors are an important portable energy storage but suffer from low capacitance, inability to stretch, etc. Therefore, flexible supercapacitors must achieve higher capacitance, energy density, and mechanical robustness to expand the applications. Herein, a hydrogel electrode with excellent mechanical strength was created by simulating the collagen fiber network and proteoglycan in cartilage using silk nanofiber (SNF) network and polyvinyl alcohol (PVA). The Young's modulus and breaking strength of the hydrogel electrode increased by 205 % and 91 % compared with PVA hydrogel owing to the enhanced effect of the bionic structure, respectively, which are 1.22 MPa and 1.3 MPa. The fracture energy and fatigue threshold reached 1813.5 J/m 2 and 1585.2 J/m 2 , respectively. The SNF network effectively connected carbon nanotubes (CNTs) and polypyrrole (PPy) in series, affording a capacitance of 13.62 F/cm 2 and energy density of 1.2098 mWh/cm 2 . This capacitance is the highest among currently reported PVA hydrogel capacitors, which can maintain >95.2 % after 3000 charge–discharge cycles. This capacitance Notably, the cartilage-like structure endowed the supercapacitor with high resilience; thus, the capacitance remained >92.1 % under 150 % deformation and >93.35 % after repeated stretching (3000 times), which was far superior to that of other PVA-based supercapacitors. Overall, this effective bionic strategy can endow supercapacitors with ultrahigh capacitance and effectively ensure the mechanical reliability of flexible supercapacitors, which will help expand the applications of supercapacitors.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of Energy Storage
·
2023
·
IF 9.4
Subin Jiang,Xiang Ji,Tengfei Yu,Feng Liu,Meizhen Gao
The suitable proportion of diffusion contribution during the electrochemical process could influence the electrochemical performance of electrode materials. An effective method is that tuning the diffusion reaction contribution via doping heteroatom, introducing defects or surface modification. In this work, a unique core-shell structure material Cu-Mn-Co LDO-C is obtained. Benefitting from Cu pre-doped into Mn Co LDO, large amount of oxygen vacancies is introduced to enhance electrochemical performance; N-6 doped porous carbon shell protects Cu-Mn-Co LDO core and improves electrochemical performance of Cu-Mn-Co LDO-C further. In addition, doping Cu broadens potential window of Cu-Mn-Co LDO-C surprisingly. Cu-Mn-Co LDO-C presents 5028.7 mF cm −2 at a current density of 1 mA cm −2 with a facilely reached potential window of 0–0.65 V finally, and retains 73.4 % diffusion contribution at a scan rate of 1 mV s −1 , 18.3 % at 100 mV s −1 . After 10,000 cycles at 2 mA cm −2 , Cu-Mn-Co LDO-C keeps 90.3 % of initial capacitance. Using Cu-Mn-Co LDO-C as positive and Fe 3 O 4 -C as negative to fabricate a solid flexible asymmetrical supercapacitor (SAS), this SAS presents a considerable energy density that attribute to the high working potential of positive Cu-Mn-Co LDO-C. SAS could working stably at a potential window of 0–2.2 V, and presents the highest energy density 243.1 μWh cm −2 at a power density of 2.8 mW cm −2 , remains 203.0 μWh cm −2 at the highest power density of 55.4 mW cm −2 . A hand ring that was assembled by three SAS which contacted in series could light a highest rated voltage white LED more than 10 min. As a result, Cu-Mn-Co LDO-C is an ideal candidate for flexible positive electrode in the field of smart, portable energy storage.
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Jie Chen,Wan-jun Jiang,Zhu Zeng,De-xiang Sun,Xiao-dong Qi,Jing-hui Yang,Yong Wang
Porous polymer-based conductive composites are highly regarded for their accomplishments of being applied in the field of electromagnetic interference (EMI) shielding, but fabrication of high-performance porous EMI shielding materials with the ability to realize self-fixable shielding effectiveness (SE) adjustment is still challenging. Herein, ethylene–vinyl acetate copolymer (EVA)@polypyrrole (PPy)@Ag (EPA) foam composites are fabricated by modifying EVA foams with PPy and Ag nanoparticles (AgNPs) in succession. In this system, EVA foam serves as shape memory frameworks to endow this composite with shape memory effect (SME), and PPy is employed to reinforce the interaction between the Ag layers and the EVA foam. Profiting from the reinforced conductive network, the EPA foam composites exhibit electro-thermal performance with a heating temperature of 81.1 °C at a voltage of 1 V and EMI shielding performance with a SE of 107.45 dB within the X-band. Importantly, depending on the SME, the SE of the EPA foams can be easily tuned by controlling and fixing the compressive strain. Moreover, the EPA foams can also serve as sensors for monitoring different actions. By virtue of the above merits, the EPA foams are promising to serve as multifunctional electronics, involving smart EM protection devices and wearable sensors.
✓ 已验证
产品关联
DOI
高影响因子
Advanced Sustainable Systems
·
2023
·Vol. 7
·期 8
·2300097
·
IF 7.1
Ke Hu,Jiayi Zhang,Zhuyue Lan,Qingyu Meng,Shitao Shi,Yunfei Zhang,Yu Lei,Qingfeng Sun,Xiaoping Shen
Smart electromagnetic (EM) functional materials that can arbitrarily utilize EM energy and reduce EM pollution are attractive for future EM devices in an information society; however, studies on precise EM interference (EMI) shielding and sensing are rare. In this work, dual-action electrical and EM-responsive mechanoreceptors are prepared from electrically conductive polypyrrole (PPy) nanoparticle (NP)-infiltrated anisotropic wood (PW) aerogels. The prepared PW aerogels are composed of curved stacked layers of aligned cellulose nanofibers, and can be reversibly condensed and reconstructed for conductive network control during cyclic compression. These PW aerogels can withstand up to 74% compressive strain in a tangential direction and exhibit pressing-enhanced electrical conductivity and polarization loss. The piezoresistive gauge factor (GF) and linearity of the PW aerogels can be adjusted by varying the PPy deposition time, leading to varying GF values in the range of 1.87–4.62. During mechanosensing based on EMI shielding effectiveness (SE), rapid off/on switching between the EM wave transmission and shielding is achieved when the SE varies above and below the effective EMI shielding area (>20 dB) through continuous compression. Such dual-action electrical/EM off/on wood aerogel switches provide opportunities for the development of advanced smart devices from biomass resources.
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）