JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
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2021
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IF 8.067
Wenyu Wang,Dejun Ding,Kunpeng Zhou,Man Zhang,Weifen Zhang,Fang Yan,Ni Cheng
Nitric oxide (NO) has emerged as a potential wound therapeutic agent due to its pivotal role in the wound healing processes. Nevertheless, NO-based therapy for clinical applications is still restricted due to its gaseous state and short half-life. Here we exploited a wound dressing by incorporating sodium nitroprusside doped prussian blue nanoparticals and Type I collagen into the chitosan/poly(vinyl alcohol) nanofibers through the electrospinning method. This hybrid nanofibrous scaffold possess the excellent abilities of NIR controlled NO release, photothermal therapy, and imitation of extra-cellular matrix-like architecture. These synergistic effects could enhance their anti-bactericidal effects in vitro and furthermore accelerate wound healing in vivo when compared to control groups. Histological analysis demonstrated the scaffold could promote fibroblast growth and accelerate epithelialization. Moreover, no apparent histological toxicology and negligible damage to major organs were observed, which provided sufficient biosafety for in vivo application. These data indicate the fabricated hybrid nanofibrous scaffold could be used as an ideal candidate for accelerating wound healing and treating chronic wounds.
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CHEMICAL ENGINEERING JOURNAL
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2020
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IF 10.652
Benjun Huo,Jie Yang,Yao Bian,Daofu Wu,Julin Feng,Jiaer Zhou,Qiang Huang,Fan Dong,Xiaosheng Tang
The superior optical properties and adjustable bandgap allows for hybrid halide perovskite quantum dots to be promising photocatalytic materials, but the serious radiative recombination and instability inhibit the improvement of photocatalytic conversion efficiency. Herein, we successfully synthesized the FAPbBr 3 /A-SiO 2 nanocomposites photocatalyst by anchoring formamidinium (FA + , HC(NH 2 ) 2+ ) lead halide perovskite quantum dots on aminated silica spheres to construct the composite photocatalysts via N H chemical bonding. The FAPbBr 3 /A-SiO 2 composites show the significantly enhanced visible-light-driven NO removal activity (70%) compared to the pristine FAPbBr 3 (30%) in half an hour at room temperature, revealing that the increased active sites and efficient charge carrier separation contribute to the absorption and activation of reactant molecules. This work would open the new possibilities for improving the photocatalytic ability of perovskite quantum dots.
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APPLIED CATALYSIS B-ENVIRONMENTAL
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2020
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IF 16.683
Xiaoshu Lv,Jingyuan Zhang,Xingan Dong,Jian Pan,Wendong Zhang,Weilu Wang,Guangming Jiang,Fan Dong
We demonstrated the partial Ni 2+ substitution for Mg 2+ in Mg 2 Al-layered double hydroxide nanosheet (Ni/LDH) significantly improved its photocatalytic performance in removing the ppb-level NO pollutant from air. With 25 % of Mg 2+ substituted, the Ni/LDH delivered the highest NO removal efficiency of 42.10 % (87.2 % of them were mineralized to nitrate) under UV-light irradiation. Such a robust performance with the low energy input (8 W) made Ni/LDH among the top photocatalysts for NO removal. We evidenced the OH − carried by Ni/LDH transformed to · OH radicals by trapping the photoexcited holes. This unique feature was intriguing as the OH − at layer surfaces of LDH were abundant, fully exposed and dynamically supplemented by atmospheric water, which endowed Ni/LDH with superior · OH production capability even under low atmospheric moistures. The positive contribution of Ni 2+ arose from its function in optimizing band structure and activating the OH − of LDH, leading to enhanced reactive oxidative species production.
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JOURNAL OF HAZARDOUS MATERIALS
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2020
·
IF 9.038
Hongyuan Xi,Song Zhou,Jinxi Zhou,Zhao Zhang
The novel combined system using Na 2 S 2 O 8 /urea was used to simultaneously absorb nitric oxide and sulfur dioxide emissions from marine diesel engines as well as inhibit the formation of nitrate in cleaning wastewater to meet the increasingly stringent requirements of regulations. The influences of reaction temperature, Na 2 S 2 O 8 concentration, urea concentration, SO 2 concentration, NO concentration and pH value on SO 2 removal efficiency, NO removal efficiency and nitrate concentration were investigated. The experimental results showed that different reaction temperatures had different influences on SO 2 removal efficiency, NO removal efficiency and nitrate concentration. An increase in Na 2 S 2 O 8 could improve the absorption of NO. The addition of urea could effectively improve the removal efficiency of NO and reduce the nitrate concentration. The removal efficiencies of 1000 ppm NO and 1000 ppm SO 2 achieved 100 % with 0.2 mol/L Na 2 S 2 O 8 and 2 mol/L urea at 70℃, and the nitrate content was 8.56 mg/L which was far lower than the regulatory requirement of 60 mg/L. The acidic condition (pH ≤ 5.5) not only facilitated the absorption of NO but also reduced the generation of nitrate. According to the experimental results, the novel combined system was promising to be applied to the control technology of marine diesel engine exhaust.
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JOURNAL OF HAZARDOUS MATERIALS
·
2020
·
IF 9.038
Fanyu Meng,Lina Guo,Haocheng Zou,Boming Zhu,Fayang Zhou,Yiqing Zeng,Jiayou Han,Jun Yang,Shule Zhang,Qin Zhong
To achieve high NO oxidation efficiency, excessive O 3 must be used, which would lead to the high cost and escape of ozone. Herein, we adopted low cost and environmental-friendly TiO 2 as the catalyst of low concentration O 3 and H 2 O 2 system for high-efficiency NO x oxidation. The Ti sites on TiO 2 were the deprotonation sites of H 2 O 2 and H 2 O into Ti-OOH and Ti-OH species, respectively. We found that the surface of rutile phase TiO 2 had a low concentration Ti-OOH component but a large amount of Ti-OH after contacting with H 2 O 2 solution, thus lots of ·OH and a few O 2 − radicals formed with introducing O 3 molecules. H 2 O 2 solution induced the formation of a large amount of Ti-OOH and Ti-OH species on the anatase phase TiO 2 surface, thus lots of O 2 − generated in the O 3 /H 2 O 2 system. O 2 − and O H radicals could efficiently oxidize NO, in which O 2 − radicals could oxidize NO to NO 3 − in one step with high selectively. Therefore, anatase TiO 2 had better performance in NO x oxidation than rutile phase TiO 2 . The effect of temperature and SO 2 concentration on NO oxidation was also investigated, the results showed that TiO 2 -A/O 3 /H 2 O 2 system promoted NO oxidation at a low temperature and a low concentration of SO 2 .
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2020
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IF 7.489
Runping Wu,Qing Ye,Kai Wu,Shuiyuan Cheng,Tianfang Kang,Hongxing Dai
The alkali metal (M = Na, K, Rb, and Cs)-modified C-FDU-15 (M-C-FDU-15( x ); x was the M/C-FDU-15 M ratio, and equal to 0.01–0.03) samples were prepared through an in situ process, and characterized by means of the TG, XRD, TEM, EDS, N 2 adsorption–desorption, O 2 -TPD, and CO 2 -TPD techniques. The (NO + O 2 ) adsorption mechanism was investigated using the (NO + O 2 )-TPD and DRIFTS techniques. The results show that the sequence of (NO + O 2 ) adsorption performance was Na-C-FDU-15(0.01) (104.1 mg/g) > K-C-FDU-15(0.01) (92.4 mg/g) > C-FDU-15 (76.2 mg/g) > Rb-C-FDU-15(0.01) (65.1 mg/g) > Cs-C-FDU-15(0.01) (62.3 mg/g). The alkali metal was uniformly distributed in C-FDU-15 and its doping enhanced the amount of the basic sites in the sample. Moreover, the optimal Na/C-FDU-15 M ratio was 0.02. (NO + O 2 ) were chemically adsorbed mainly in the forms of nitrite (NO 2 − ) and nitrate (NO 3 − ) on M-C-FDU-15( x ). A more amount of NO was converted to nitrate than to nitrite. There were three key factors of enhancing the (NO + O 2 ) adsorption capacity of C-FDU-15 due to alkali metal doping: the first factor was the increasing of surface area and pore volume of the sample, the second one was the enhancement in amount of the active sites in the sample, and the third one was the smaller alkali metal ionic radius in the sample.
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INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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2020
·
IF 3.573
Meijuan Chen,Xiaoyan Wei,Liaoliao Zhao,Yu Huang,Shun-cheng Lee,Wingkei Ho,Kehao Chen
Highly efficient and stable photocatalysts were synthesized at room temperature by modifying MIL-125(Ti) with N-doped carbon quantum dots (N/CM(Ti)). The N/CM(Ti) with 2.5 vol % N doped carbon quantum dots (N/CQDs) had the best light absorption and visible-light photocatalytic nitrogen oxide (NO) removal efficiency (approximately 49%). It was found through X-ray photoelectron spectroscopy analysis that a N–Ti–O bond was formed in the 2.5 vol % N/CM(Ti), which is more conducive to charge transfer. Photocurrent and electrochemical impedance data also showed that the carrier separation efficiency of 2.5 vol % N/CM(Ti) was significantly superior to that of MIL-125(Ti). In addition, the TiIII–TiIV of MIL-125(Ti) acts as the active center for photocatalytic removal of NO. Two possible electron migration paths were proposed: electron transfer from N/CQDs to TiIII–TiIV center of MIL-125(Ti) due to the photoinduced electron transfer property of N/CQDs, and absorption of UV light generated from the N/CQDs by the terephthalic acid ligand followed by electron transfer to metal active sites for photocatalytic removal of NO.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2020
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IF 7.489
Beibei Wang,Dongyun Chen,Najun Li,Qingfeng Xu,Hua Li,Jinghui He,Jianmei Lu
We report an unique 2D/2D Iodine doped BiOIO 3 /g-C 3 N 4 heterojunction was successfully prepared. The iodine doped BiOIO 3 was prepared by a simple solvent exchange method and combined with g-C 3 N 4 by solvothermal method . The prepared photocatalyst has potential application value in the future due to its excellent stable cycle property. BiOIO 3 nanoplates and g-C 3 N 4 nanosheets form a close interfacial contact directly, so the catalyst has higher charge transport efficiency and wide visible range due to the introduction of iodide ions. Synergistic heterojunction exhibits strong photocatalytic activity for degradation of NO at ppb-level under visible light , of which 30% Iodine doped BiOIO 3 /g-C 3 N 4 can achieve a maximum removal rate of 57% for NO. According to the experimental results of ESR and other experiments, a more complex Z-scheme photocatalytic mechanism is proposed, which has stronger redox ability than the traditional mechanism.
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2019
·Vol. 26
·期 36
·36933-36941
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IF 2.914
Chen Jun,He Jinjia,Wang Xiaoping,Hrynsphan Dzmitry,Wu Jiali,Chen Jianmeng,Yao Jiachao
Conversion of Fe II (EDTA)-NO or Fe III (EDTA) into Fe II (EDTA) is a key process in a wet flue gas denitrification technology with Fe II (EDTA) solution. In this work, the stoichiometry, kinetics, and thermodynamics of Fe II (EDTA)-NO reduction by Mn powder were investigated. We first studied the Fe II (EDTA)-NO reduction and product distribution to speculate a possible stoichiometry of Fe II (EDTA)-NO reduction by Mn powder. Then, the effects of major influencing factors, such as pH value, temperature, and Mn concentration, were studied. The pseudo-second-order model was established to describe the Fe II (EDTA)-NO reduction. Simultaneously, according to Arrhenius and Eyring-Polanyi equations, the reaction activation energy ( E a ), enthalpy of activation (∆ H ‡ ), and entropy of activation (∆ S ‡ ) were calculated as 23.68 kJ/mol, 21.148 kJ/mol, and − 149.728 J/(k mol), respectively. Additionally, simultaneous reduction of Fe III (EDTA) and Fe II (EDTA)-NO was investigated to better study the mechanism of Fe II (EDTA) regeneration, suggesting that there was a competition between the two reduction processes. Finally, a simple schematic mechanism of NO absorption by Fe II (EDTA) combined with regeneration of manganese ion and ammonium was proposed. These fundamental researches could offer a valuable guidance for wet flue gas denitrification technology with Fe II (EDTA) solution.
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Scientific Reports
·
2019
·Vol. 9
·期 1
·1-13
·
IF 4.011
Huang Yifeng,Ma Yongwen,Wan Jinquan,Wang Yan
In this study, the hydrodynamic characteristic of a lab-scale internal circulation (IC) anaerobic reactor was investigated. We found that the gradual Increasing-Size Continuous Stirred-Tank Reactors (ISC) model is desirable to describe the hydraulic character of the reactor. As a generalized anaerobic digestion model, Anaerobic Digestion Model No.1 (ADM1) was combined simultaneously with the ISC model to simulate the effluent of the IC reactor. Both the stable running and overloading shock tests were carried out to validate the simulation. The mathematical simulation results agreed well with the experimental observation. This proposed model may be valuable to simulate the performance of the IC reactor effectively and to supply a useful tool to for designing and operating other anaerobic reactors.
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NANO
·
2019
·
IF 1.293
Qian Sun,Chun Zeng,Meng-Meng Xing,Bo Chen,Dan Zhao,San-Guo Hong,Ning Zhang
Deliberately engineering oxide composites on constructing and manipulating interactive structures particularly in surface layers was highly desirable for heterogeneous catalysis. Herein, upon the redox replacement reaction between Ce(IV) precursor (Ce(NO 3 ) 6 2 − ) and Cu 2 O nano-substrate, an attempt to directly engineer the surface structure of Cu-based substrate was performed by the Ce(IV)–Cu 2 O etching-embedding process, then the obtained powders were thermo-treated to get a series of Ce–O–Cu catalysts with different Ce:Cu molar ratios for NH 3 selective catalytic reduction (NH 3 -SCR) of NO. Characterized by ICP-OES, XRD, Raman, XPS, SEM, BET, H 2 -TPR, NO- and NH 3 -TPD measurements, it was demonstrated that the Cu–O–Ce catalysts were structured as CuO matrix with an interactive surface composed by co-present Cu(I)–Cu(II) and Ce(III)–Ce(IV) species, even the introduction of Ce was confined in a quite low loading range (0.83–2.3 wt.%); such a surface exhibited the distinct synergistic effect with positively manipulated physical-chemistry properties such as active site distributions, redox features and surface reactivity compared to pure CuO and traditional Cu–Ce composite catalyst, leading to attractive catalytic performance such as ≥ 9 0 % NO conversion with ≥ 9 5 % N 2 selectivity and the two-fold TOF enhancement versus traditional catalysts, even SO 2 was present in reactant mixture on well-manipulated catalyst (Ce loading at 1.6 wt.%) These results indicated that the etching-embedding strategy illuminated in this work could be referred as a feasible method to directly engineer and construct interactive oxide composite surface for advanced application as well as current efficient Ce–O–Cu catalytic interface for heterogeneous catalysis.
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ACS Applied Materials & Interfaces
·
2018
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IF 8.097
Lin Hou,Yinling Zhang,Xuemei Yang,Chunyu Tian,Yingshan Yan,Hongling Zhang,Jinjin Shi,Huijuan Zhang,Zhenzhong Zhang
Nitric oxide (NO) is an important biological messenger implicated in tumor therapy. However, current NO release systems suffer from some disadvantages, such as hydrolysis during blood circulation, poor specificity, and robust irradiation for stimuli. Accordingly, we constructed an intracellular enzyme-triggered NO-generator to achieve tumor cytoplasm-specific disruption and localized rapid drug release. Diethylamine NONOate (DEA/NO) was used as a NO donor and conjugated with hyaluronic acid (HA) to form self-assembly micelle (HA-DNB-DEA/NO), and encapsulate chemotherapeutic agent (doxorubicin (DOX)) into its hydrophobic core (DOX@HA-DNB-DEA/NO). After HA receptor mediated internalization into tumor cells, HA shell would undergo digestion into small conjugated pieces by hyaluronidase. Meanwhile, DOX@HA-DNB-DEA/NO also responded to the intratumoral overexpressed glutathion and glutathione S-transferase π, leading to the intracellular NO production and controlled DOX rapid release. In vitro and in vivo results proved the enzyme-dependent and enhanced targeting delivery profile, and demonstrated that NO and DOX could colocate in specific tumor site, which provided a precondition for exerting their synergistic efficacy. Moreover, expression of p53 protein was upregulated in tumor tissue after treatment, indicating that NO induced cell apoptosis mediated by tumor suppressor gene p53. Overall, this intelligent drug loaded NO-generator might perform as an enhancer to realize better clinical outcomes.
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