CERAMICS INTERNATIONAL
·
2025
·Vol. 52
·期 1
·1122-1131
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IF 5.6
Yuyu Chen,Weiliang Li,Jingyu Zhang,Xiaomin Cheng,Jiaojie Xiao,Kaiwen Zhou,Wenwei Wu,Xuehang Wu
The practical application of O3-type layered oxide cathode materials in sodium-ion batteries is limited by their insufficient structural stability and poor interfacial compatibility, especially under high-voltage operation. In this work, a thin Y 2 O 3 coating is applied to the surface of Na 0.9 Cu 0.12 Ni 0.33 Mn 0.42 Ti 0.13 O 2 (CNMT). During high-temperature annealing, partial diffusion of Y 3+ ions into the CNMT lattice results in an expansion of the interlayer spacing within the sodium layer and a reduction in lattice oxygen vacancies. Owing to the stabilized Y 2 O 3 -modified interface and improved structural integrity, the CNMT modified with 2 wt% Y 2 O 3 (CNMT-2Y) demonstrates superior cycling performance in the voltage range of 2.2–4.3 V. Specifically, in a half-cell configuration, CNMT-2Y delivers an initial discharge capacity of 130.9 mAh g −1 and maintains 94.35 % of its capacity after 100 cycles at a current density of 100 mA g −1 . After being exposed to ambient air for 10 days, the material still retains 89.62 % of its capacity over 100 cycles under the same conditions, significantly outperforming the pristine CNMT (83.54 %). In a full-cell setup with hard carbon (HC) as the anode, CNMT-2Y provides an initial discharge capacity of 119.5 mAh g −1 and retains 77.14 % of its capacity after 150 cycles at 100 mA g −1 within 1.5–4.2 V. This facile dual-modification strategy shows promising potential for promoting the commercialization of O3-type layered oxide cathode materials.
研究领域:
材料科学
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电化学
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能源存储
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无机化学
·
固态化学
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高影响因子
INORGANIC CHEMISTRY
·
2016
·
IF 4.82
Hui Yang,Chun-Li Hu,Jiang-Gao Mao
The first examples of mixed-anion lanthanide galloborates, namely, Ln2Ga[B3O6(OH)]2[B7O9(OH)2](CH3CO2)2 [Ln = Y (1), Sm (2), Eu (3), Gd (4), Dy (5)], have been obtained through hydrothermal synthesis. The title compounds are isomorphic and belong to monoclinic space group C2/c (No. 15). Their structures possess [B7O13(OH)2] borate layers further bridged with [B3O7] clusters to give a three-dimensional (3D) borate framework displaying two types of rhombus-like B14O14 14-membered-ring (14-MR) channels along the b axis. The Ga3+ ions are octahedrally coordinated and located at one end of the B14O14 14-MR channels, forming small tunnels of B7Ga 8-MRs, which are filled by the LnIII ions. The Ln ions and Ga cations are further held together by bridging acetate anions. It is worth noting that in these compounds there are two different types of borate clusters and two types of anions that are uncommon in the borates reported. Luminescent studies revealed the characteristic emission bands of Ln ions for compounds 2–5, and the luminescent lifetimes are 3.6, 0.86, and 3.05 ns for compounds 2, 3, and 5, respectively. Magnetic measurements suggest that there are antiferromagnetic interactions between magnetic centers for compounds 2–5.
研究领域:
材料科学
·
无机化学
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高影响因子
FUEL
·
2022
·
IF 8.035
Jun Liu,Yu Zhang,Zhoujie Liang,Guojie Zhang,Ying Wang,Yuqing Zhao,Guoqiang Li,Yongkang Lv
In this paper, a series of bimetallic catalysts with different Ni/Co ratios were prepared by co-impregnation method for application in methane dry reforming reaction. The effects of different Ni/Co ratios on the catalyst performance were investigated. The catalysts were characterized by XRD, BET, H 2 -TPR, TG, TEM and FTIR. The results showed that after the introduction of a certain amount of Co, the synergistic effect between Ni and Co enhanced the active component-carrier interaction, thus improving the dispersion of the active component of the catalyst, reducing the particle size of the metal, and increasing the activity of the catalyst. Meanwhile, the mechanistic study showed that the introduction of Co species with strong oxygen affinity facilitated the formation of oxygen vacancies. It makes the catalysts contain higher lattice oxygen and carbonate species, which was conducive to the elimination of carbon accumulation, thus improving the stability of catalysts. Therefore, the 10Ni-8Co-10Y/WC-AC catalyst exhibited excellent dry reforming of methane (DRM) performance at a Ni/Co ratio of 5:4. The conversions of CO 2 and CH 4 were 95 % and 88 % at 800 °C under atmospheric pressure, respectively.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
·
2022
·
IF 10.319
Liang Xu,Lei Su,Hongjie Wang,Hongfei Gao,Pengfei Guo,Min Niu,Kang Peng,Lei Zhuang,Zhiwei Dai
Materials with ultralow thermal conductivity and good thermal stability are of great interest in numerous applications such as energy storage and conversion devices, and thermal insulation components. In this work, a family of high-entropy Sm 2 B 2 O 7 (B=Ti, Zr, Sn, Hf, Y, Yb, Nb, and Ta) oxides with highly disordered cations on the B-site has been synthesized by introducing large atomic-size mismatch, mass and charge disorder. Through tuning the composition, the high-entropy Sm 2 B 2 O 7 oxides can be engineered from pyrochlore to fluorite structure, accompanied with an order-disorder transition. The pyrochlore Sm 2 (Nb 0.2 Sn 0.2 Ti 0.2 Y 0.2 Zr 0.2 ) 2 O 7 and fluorite Sm 2 (Nb 0.2 Ta 0.2 Y 0.2 Yb 0.2 Zr 0.2 ) 2 O 7 exhibit low thermal conductivities of 1.35 W·m −1 ·K −1 and 1.23 W·m −1 ·K −1 , respectively, indicating their good thermal insulation. In addition, the high-entropy fluorite Sm 2 (Nb 0.2 Ta 0.2 Y 0.2 Yb 0.2 Zr 0.2 ) 2 O 7 also shows average thermal expansion coefficient of 10.2 × 10 −6 °C −1 and high-temperature stability even after thermal exposure at 1600 °C in air for 30 h. These results indicate that the high-entropy Sm 2 B 2 O 7 (B=Ti, Zr, Sn, Hf, Y, Yb, Nb, and Ta) can be promising candidates for thermal barrier coatings and thermally insulators.
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高影响因子
RARE METALS
·
2021
·Vol. 41
·期 2
·650-662
·
IF 4.003
Guo Hua,Li Jun,Zou Xian-Rui,Wang Hong-Shui,Kang An,Zhou Huan,Li Ming-Jun,Zhao Xiao-Yan
Abstract Development of photocatalytic materials able to profit from the whole spectrum of sun for efficient organic pollution removal and bacterial elimination is a fascinating strategy in environmental engineering. In current work, GO-TiO 2 /(Ca,Y)F 2 :Tm,Yb, a full-spectrum composite photocatalyst, was prepared via hydrothermal processing with TiO 2 /(Ca,Y)F 2 :Tm,Yb particles deposited on the surface of graphene oxide (GO). The surface properties of GO-TiO 2 /(Ca,Y)F 2 :Tm,Yb were characterized using various characterization techniques including X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Brunauer–Emmett–Teller (BET) surface area analyzer. Besides, ultraviolet–visible (UV–Vis) diffuse reflectance spectroscopy, electron spin resonance (ESR) and other methods were used to systematically explore the photocatalytic mechanism of GO enhancement of TiO 2 /(Ca,Y)F 2 :Tm,Yb. In photocatalytic degradation study, the degradation rate of methyl orange (MO) was improved by 40% when GO was added into the TiO 2 /(Ca,Y)F 2 :Tm,Yb system. In addition, the presence of GO also improves the antibacterial ability of TiO 2 /(Ca,Y)F 2 :Tm,Yb against Escherichia coli and Staphylococcus aureus . All results reveal high efficacy of GO-TiO 2 /(Ca,Y)F 2 :Tm,Yb under full spectrum light irradiation, in which (Ca,Y)F 2 :Tm,Yb and TiO 2 can improve its utilization of full spectrum sunlight, and GO can enhance adsorption ability of dye and electron–hole pair differentiation ability of TiO 2 /(Ca,Y)F 2 :Tm,Yb. Graphic abstract
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
·
2021
·
IF 5.816
Wenjie Yang,Chao Han,Yuehua Li,Huizhu Zhou,Shan Liu,Ling Wang,Zhangxing He,Lei Dai
BaHf 0.8 Ln 0.2 O 3-δ doped with rare earth elements with different ionic radii (Ln = Yb , Y, Dy and Gd) as candidate materials for solid oxide fuel cells and H 2 separation membrane have been prepared. Their phase composition , sinterability , chemical stability and conductivity were studied systematically. The rare earth elements are successfully incorporated into the main phase crystal lattice of barium hafnate to generate a single perovskite phase. The relative density of all samples sintered at 1600 °C reaches above 90%, and Y-doped BaHfO 3 has the highest relative density (94.7%) and the biggest grain size (about 1 μm) among all samples. The conductivities of the samples firstly increase and then decrease with the increase of the doped ion radius. Among all samples the conductivity of BaHf 0.8 Y 0.2 O 3-δ is the highest and reaches 6.02 × 10 −3 S cm −1 in wet air at 700 °C, which is attributed to the good sinterability and suitable crystal structure (tolerance factor and free volume). All samples also show excellent chemical stability in the test atmospheres, including saturated H 2 O steam, pure H 2 and CO 2 , 200 ppm H 2 S/Ar and boiling water. The Pt/BaHf 0.8 Y 0.2 O 3-δ electrolyte/Pt single cell was fabricated with a 530 μm-thick disk and its electrochemical properties were tested. The peak power density reaches 10.21 mW cm −2 at 700 °C, which is comparable to similar fuel cells reported. These results suggest that BaHf 0.8 Y 0.2 O 3-δ is a promising electrolyte candidate for proton-conducting fuel cells.
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高影响因子
ACS Catalysis
·
2020
·
IF 12.35
Peng Liu,Zhi Li,Xingyu Liu,Weiyu Song,Bowen Peng,Xinyue Zhang,Suofu Nie,Penghui Zeng,Zhongdong Zhang,Xionghou Gao,Baojian Shen
In fluid catalytic cracking (FCC), Brønsted acid plays a very important role. Herein, a zinc-modified ultrastable Y (USY) zeolite containing higher Brønsted acidity was prepared by synergistic treatment with zinc chloride and steaming. The results of characterization showed that selective dealumination and silicon healing due to introduction of zinc ions ([ZnCl]+ and [ZnOH]+) into zeolite could promote the formation of extra-framework silicon (EFS) and different silicon healing of the Al vacancies, which led to the formation of half-sodalite cages connecting with supercages and thus increased the availability of acidic sites in the sodalite cage. Meanwhile, DFT calculations demonstrated that the acidic strength of protons in the sodalite cage was enhanced by [ZnCl]+ and [ZnOH]+, and the synergy of Brønsted/[ZnCl]+ became stronger. As a result, the strong Brønsted acid was increased by 19%. This translated to higher n-octane and heavy oil (VGO) catalytic cracking activity and gasoline yield.
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高影响因子
MICROCHEMICAL JOURNAL
·
2025
·
IF 5.1
Fulin Yang,Hongjie Liu,Hao Fu,Chaoxin Zhang,Changrui Ye,Shaopeng Wang,Man Zhang,Fang Shen,Liwei Wang
As one of the significant algal bloom species, Akashiwo sanguinea has long brought challenges to controlling red tide. Red tide outbreaks are often accompanied by the mass propagation of various algal bloom species, which brings problems to investigating red tides using traditional optical methods. Electrochemical biosensing technology has high sensitivity and specificity, yet its use in detecting A. sanguinea DNA in sea areas is insufficient. Here, the amplification system combining Nt.BbvCI endonuclease-assisted and hybridization chain reaction (HCR) has a detection limit of the same or even lower magnitude than other HCR systems. More importantly, the auxiliary short strands from the Nt.BbvCI system activates HCR, reducing the steric hindrance of long DNA molecules and enhancing HCR’s activity. Thus, the portable electrochemical biosensor based on this system successfully detected simulated A. sanguinea DNA samples, with a limit of detection (LOD) at 1.53 fg/μL and a limit of quantification (LOQ) at 4.27 fg/μL, far better than traditional optical-based methods. Also, the predicted cell density of A. sanguinea generally matches that of optical microscopy. This portable biosensor is expected to conduct an on-site investigation of A. sanguinea ’s cell density. It can provide data support for early warnings of red tide outbreaks and reduce the time needed for investigations.
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高影响因子
ANALYTICAL AND BIOANALYTICAL CHEMISTRY
·
2016
·Vol. 408
·期 19
·5247-5259
·
IF 3.125
Pan Ziyu,Peng Jingdong,Zang Xu,Lei Gang,He Yan,Liu Di
A novel, highly selective, and sensitive resonance light scattering (RLS) detection approach coupled with high performance liquid chromatography (HPLC) was researched and developed for the synchronous analysis of three kinds of benzimidazole anthelmintics, including mebendazole (MBZ), albendazole (ABZ), and fenbendazole (FBZ) for the first time. In the pH range of 3.5–3.7 Britton-Robinson buffer medium, three kinds of anthelmintics, which were separated by HPLC, reacted with eosin Y (EY) to form 1:1 ion-association complexes, resulting in significantly enhanced RLS signals and the maximum peak located at 335 nm. The enhanced RLS intensity was in proportion to the MBZ, ABZ, and FBZ concentration in the range 0.2–25, 0.2–23, and 0.15–20 μg/mL, respectively. The limit of detection was in the range of 0.064–0.16 μg/mL. In addition, human urine was determined to validate the proposed method by spiked samples and real urine samples. Satisfactory results were obtained by HPLC-RLS method.
The diagram mechanism of generating resonance between emitted light and scattered light
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PubMed
高影响因子
Materials Science & Engineering C-Materials for Biological Applications
·
2017
·
IF 4.164
Peizong Deng,Fangfang Teng,Feilong Zhou,Zhimei Song,Ning Meng,Na Liu,Runliang Feng
Ketoconazole is a hydrophobic broad-spectrum antifungal agent for skin infection therapy. In order to develop topical formulation of ketoconazole for improving its selective skin deposition and water-solubility, ketoconazole-loaded Y-shaped monomethoxy poly(ethylene glycol)-block-poly(ɛ-caprolactone) micelles were prepared through thin-film hydration method with high entrapment efficiency (96.1 ± 0.76%) and small particle (about 58.66 nm). The drug-loaded micelles showed comparative in vitro antimicrobial activity with KET cream. In e x in vivo skin deposition and permeation study, ketoconazole-loaded micelles provided skin accumulation higher than marketed ketoconazole cream without obvious permeation in the whole period. Fluorescence microscopy study and histopathological study demonstrated the copolymeric micelles' penetrating into skin in depth due to its capability of weakening the barrier function of stratum corneum. In vivo skin deposition parameters further confirmed high skin deposition of drug-loaded micelles (AUC (0-t) = 396.16 μg·h/cm 2 ) over marketed ketoconazole cream (AUC (0-t) = 250.03 μg·h/cm 2 ). Meanwhile, in vivo pharmacokinetic parameters proved that ketoconazole-loaded micelles reduced ketoconazole's distribution in blood in comparison with the cream (AUC (0-t) = 93,028.00 μg·h/L vs AUC (0-t) = 151,714.00 μg·h/L), meaning lower possibility of its systemic unwanted effects in the skin fungal infection treatment. The results suggested that the copolymeric micelles can be adopted for specific delivering ketoconazole into skin for fungal infection cure.
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PubMed
高影响因子
FUEL
·
2024
·
IF 6.7
Zi-Chun Fan,Zhuang Li,Xiang Bai,Xian-Yong Wei,Yierxiati Dilixiati,Qian-Qian Kong,Ji Zhao,Yong-Hui Feng,Zhi-Min Zong,Jun-Long Wang
The catalytic hydroconversion (CHC) of benzyloxybenzene (BOB) and oxydibenzene (ODB), two typical lignite-related model compounds (LRMCs) representing α-Ο-4 and 4-O-5 model linkages , have been investigated using uniformly dispersed Ni 15 /HY prepared by a three-step method. The cleavage of >CH-O- bridged bonds in BOB and partial hydrogenation of ODB are considered as a crucial first step, and the target reactions in this work are to produce complete hydrodeoxidized ring saturation products. Through the exploration of reaction mechanism, H + /H - and biatomic active hydrogen, as the main hydrogen species involved in the reaction, play an important role in the CHC of BOB and ODB. Herein, the synergic effect between the hydrogenation of nickel nanoparticles and the acidic function of Y -type zeolite improves the CHC performance, resulting in Ni 15 /HY displaying proficient catalytic activity and selectivity for the CHC of BOB and ODB. Under the optimal reaction conditions, BOB and ODB can be completely converted to cyclanes over Ni 15 /HY, and the main products are dicyclohexylmethane (57.6 %) and cyclohexane (92.4 %), respectively. The developed Ni 15 /HY can not only promote the hydroconversion of BOB and ODB to produce ring-saturated products, but also undergo the rearrangement reaction to produce two- or three-ring cyclanes, which is desirable to upgrade LRMCs to high-density hydrocarbon fuels .
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高影响因子
CERAMICS INTERNATIONAL
·
2025
·
IF 5.6
Jun-Min Zhang,Xiao-Wu Chen,Xiao You,Qing-Gang Li,Meng-Meng Wang,Xiang-Yu Zhang,Yan-Mei Kan,Yu-Dong Xue,Shao-Ming Dong
The effect of RE 2 O 3 (RE = La, Y, Er, Lu) on the oxidation behavior of RMI-SiC ceramics in air and wet oxygen atmospheres at 1400 °C were studied. The outward migration of RE 3+ cations reduces the oxidation resistance of SiC-RE ceramics in air, but improves the wet-oxidation resistance of SiC-RE ceramics due to the formation of denser RE 2 Si 2 O 7 layer. The outward migration rates of RE 3+ cations may be influenced jointly by the RE 3+ cation radius and the formation rate of RE 2 Si 2 O 7 . The higher mobility of Er 3+ and Y 3+ cations makes Y 2 O 3 and Er 2 O 3 promising modifier for enhancing the wet-oxidation resistance of RMI-SiC f /SiC composites, although the modified components need to be optimized and further analyzed in a more realistic service environment.
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高影响因子
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