INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2024
·
IF 7.7
Jinsong Wang,Farzad Seidi,Xiaotong Shi,Chengcheng Li,Yang Huang,Huining Xiao
The development of self-healing ecofriendly coatings for anticorrosion applications provides stronger protection than passive coatings and mitigates the environmental pollution resulting from petroleum-derived coatings. Due to its intrinsic anticorrosion characteristics, lignin is a viable precursor for the formulation of self-healing anticorrosion coatings. However, the structural rigidity of lignin and the lack of self-healing functionalities in pristine lignin-based coatings hinder the comprehensive application of lignin in this field. Accordingly, we introduced Diels-Alder (DA)-based self-healing functions in the lignin-based coatings and meanwhile, the coatings were chemically conjugated with corrosion inhibitors to further improve the anticorrosion performance. A thin layer (16 μm) of the coating increased the E corr from −480 mV (for bare steel) to +91 mV and reduced the corrosion rate (CR) >4000 times. The dual self-healing properties of the coating are attributed to the synergistic action of the DA adduct and the conjugated corrosion inhibitor. Practically, in response to the emergence of microcracks in the coating structure, trace amounts of the corrosion inhibitor are released into the microcracks to form a protective layer on the unveiled metal surface. Simultaneously, DA adducts undergo reversible reactions at specific temperatures (50–120 °C) promoting complete restoration of the microcrack.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF MOLECULAR STRUCTURE
·
2025
·
IF 4.7
Yan Jia,Jinyan Liu,Shenghan Zhou,Xiaohui Ren
The depletion of fossil fuel reserves and their environmental impact have driven the adoption of ethanol-gasoline blends (EGBs) as an alternative fuel, with the aim of reducing gasoline consumption and greenhouse gas emissions. However, the introduction of water and pollutant ions during bioethanol production, transportation, and usage has the potential to lead to corrosion in pipelines and storage equipment. This study investigates the corrosion behaviour of T2 copper in EGBs containing a simulated liquid (SL) and evaluates the corrosion inhibition mechanism of Turkish red oil (TRO) as an eco-friendly inhibitor. Surface observation, electrochemical techniques, and surface analysis (SEM, AFM, XPS) were employed to assess corrosion behaviour. The results obtained from this study indicate that an increase in SL concentration results in an intensification of corrosion, as evidenced by a decrease in charge transfer resistance ( R ct ) and an increase in corrosion current density ( I corr ). The addition of TRO has been shown to significantly inhibit corrosion, with optimal efficiency exceeding 90 % at 500 ppm, resulting in a smooth copper surface. Furthermore, XPS analysis has confirmed the adsorption of TRO molecules on T2 copper, while theoretical analysis has revealed that TRO's electron-donating and electron-accepting groups facilitate parallel adsorption, thereby enhancing corrosion inhibition. This study provides experimental and theoretical insights into the corrosion inhibition of green organics in EGBs, supporting their wider application in sustainable energy systems.
研究领域:
材料科学
·
化学工程
·
能源研究
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Jiefu Lang,Ke Ren,Yiguang Wang
As a thermal barrier coating (TBC) material, 8 wt% yttria-stabilized zirconia (8YSZ) exhibits poor resistance against calcium–magnesium–aluminosilicate (CMAS) corrosion. This is caused by the penetration of molten CMAS glass and the depletion of Y 3+ , which limits the lifetime of 8YSZ. In this study, a multi-rare-earth-oxide-doped zirconia (15 wt% (Lu 0.2 Yb 0.2 Dy 0.2 Gd 0.2 Y 0.2 )–ZrO 2 , denoted as 15LYDGY–SZ) ceramic was prepared to examine its interaction with CMAS. The sluggish diffusion effect and the competition between various dopant elements toward reaction with CMAS effectively slow down the atomic diffusion and limit the transformation of tetragonal phase into monoclinic phase in 15LYDGY–SZ ceramic. Compared with the currently used 8YSZ ceramic, the corrosion resistance of 15LYDGY–SZ to CMAS and its retention rate of fracture toughness after CMAS corrosion are improved. The results show that the multi-rare-earth-oxide-doped zirconia ceramic prepared in this study is a promising candidate material for the development of future TBCs.
研究领域:
材料科学
·
航空工程
✓ 已验证
产品关联
DOI
高影响因子
SURFACE & COATINGS TECHNOLOGY
·
2025
·
IF 6.1
Donghui Guo,Runze Jin,Baolu Shi,Xinlei Jia,Shun Wang,Baosheng Xu
Silicate is considered a promising material for environmental barrier coatings on hot-section components of aircraft engines. However, the interaction of lutetium silicate coating in the molten calcium‑magnesium-aluminosilicate exposure has not been reported yet. In this study, the interaction of nanostructured Lu 2 Si 2 O 7 /Lu 2 SiO 5 environmental barrier coatings (EBCs) with CMAS was systematically investigated at 1300–1400 °C for 25–50 h aiming to clarify the corrosion mechanism of the coatings. Results indicated that the Lu 2 Si 2 O 7 /Lu 2 SiO 5 coatings remained intact and the molten CMAS did not penetrate the Lu 2 SiO 5 layer after corroded at 1400 °C for 50 h. In addition, the recession layer and TGO layer thicknesses of the coatings after corroded at 1400 °C for 50 h were 82.5 μm and 2.27 μm, respectively. The CMAS corrosion resistance of nanostructured Lu 2 Si 2 O 7 /Lu 2 SiO 5 coating is superior to that of ytterbium silicate coatings. The results of this work highlight that the Lu 2 Si 2 O 7 /Lu 2 SiO 5 coatings with significantly enhanced CMAS resistance performance might be suitable for advanced EBCs applications.
研究领域:
材料科学
·
航空工程
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2021
·
IF 9.229
Xue Fu,Wenbo Du,Haixu Dou,Yong Fan,Jianing Xu,Limei Tian,Jie Zhao,Luquan Ren
Synergetic self-healing anticorrosion behaviors, by forming a self-assembly protective layer and repairing coating passive barrier, exhibit great potential in handling the notorious metal corrosion phenomenon. Herein, we developed a nanofiber-supported anticorrosion coating with synergistic protection effects of both self-healing and active corrosion inhibition, via a facile electrospinning combined coating technique. Polycaprolactone (PCL) nanofiber integrated with 2-mecapobenzothiazole-loaded halloysite nanotubes (HNTs-MBT) is directly deposited on the surface of metal substrate, forming an interconnected fiber network framework. The encapsulated corrosion inhibitor MBT can be released by a pH-triggered manner to realize instant corrosion protections. Additionally, coating defects could be repeatedly repaired by continuous polymer fiber upon heat treatment and the anticorrosion efficiency effectively remained, even after three cycles of damage–healing. Moreover, the repaired coating also exhibited durable anticorrosion performance, mainly attributed to the synergetic effects of both thermal-triggered bulk healing and active corrosion inhibition. This type of dual-functional coating provides efficient anticorrosive performances and may show great promise in long-term corrosion protection.
研究领域:
材料科学
·
腐蚀与防护
✓ 已验证
产品关联
DOI
PubMed
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2022
·
IF 5.518
Yuqing Li,Daquan Zhang,Jin Li,Jiamin Lu,Xinrui Zhang,Lixin Gao
An anti-corrosion coating is prepared by reaction of alpha-lipoic acid (ALA) with di-isopropenyl benzene (DB), followed by the addition of Cu 2+ ions. This coating can heal its scratching within 2 h in air and 12 h in solution without external intervention. The corrosion inhibition effect of the DB-ALA-Cu 2+ coating was demonstrated by electrochemical measurements. It shows excellent performance against copper corrosion in 3 wt% NaCl solution. The self-healing mechanism is attributed to the formation and exchange of hierarchical non-covalent and covalent bonds . This coating extends significantly its service life and has potential applications in the metal anti-corrosion area.
研究领域:
材料科学
·
腐蚀与防护
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2021
·
IF 4.527
Bin Han,Shigen Zhu,Weiwei Dong,Yunfeng Bai,Hao Ding,Yilan Luo,Ping Di
(85-x)WC–15 wt%Al 2 O 3 –xTiC (x = 0, 1.5, 2.5, 5, 10, and 20 wt%) composites were prepared by vacuum hot-press sintering. The influence of TiC addition on the corrosion behaviour of WC–Al 2 O 3 composites in 0.1 M NaOH solution was revealed. The results suggest that all the samples containing added TiC had the TiC phase and (W, Ti) C solid-solution phase, while the base composite had neither phase. With increasing added TiC content, the average grain size of WC decreased, and the relative density first increased and then decreased. Furthermore, the results suggest that the addition of TiC could noticeably increase the free corrosion potential and impedance and reduce the corrosion current density. However, the composite containing 20 wt% added TiC showed the opposite trend. Therefore, it can be concluded that the corrosion performance of the composites in an alkaline medium can be improved by adding an appropriate amount of TiC. The change in corrosion properties was caused by changes in the solid-solution phase, relative density, and TiO 2 oxide film .
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
MATERIALS AND STRUCTURES
·
2023
·Vol. 56
·期 1
·1-15
·
IF 3.8
Song Yufeng,Zhang Yi,Shen Siyi,Pan Chenyu,Yan Dongming,Wang Zhiguang,Wang Su,Ruan Shaoqin
This study aims to explore the effects of different Ca(OH) 2 contents on the mechanical performance and corrosion behaviors of steel in Calcium sulfoaluminate (CSA) cement, where compressive strength, corrosion potentials of reinforcements, corrosion current density, pH of pore solution as well as mortar resistivity of CSA/Ca(OH) 2 mortar were researched, and the corrosion behaviors were further interpreted by the clarification of hydration phases through microstructural analyses. The initial results highlighted the positive effects of using adequate Ca(OH) 2 (~ 6%) in CSA mortar in terms of strength, yet its excessive addition could delay the subsequent hydration reaction of CSA. Meanwhile, with an increased quantity of Ca(OH) 2 , the amount of some hydration phases, such as Al(OH) 3 reduced, resulting from their reaction with Ca(OH) 2 . Finally, the corrosion current density increased with the reduced mortar resistivity when the reinforcement in CSA/Ca(OH) 2 system was corroded, and their relationship was also provided in this study.
研究领域:
建筑材料学
·
腐蚀科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2022
·
IF 10.383
Zhaowen Tian,Suning Li,Yiqing Chen,Lixiang Li,Zhizheng An,Yanqiu Zhang,Anqi Tong,Han Zhang,Zunfeng Liu,Baigang An
As an intelligent response system, self-healing anticorrosion materials containing nanocontainers have aroused increasing demands. It is highly expected that the nanocontainers can rapidly respond on corrosion signals to efficiently release corrosion inhibitors, meanwhile to avoid an undesirable leakage before the local corrosion happening. Herein, zinc oxide quantum dot (ZnO-QD)-sealed hollow mesoporous TiO2 nanocontainers loading with 14.2% benzotriazole (BTA) inhibitor have been successfully prepared [hollow mesoporous titanium dioxide nanospheres (HMTNs)–BTA@ZnO-QDs]. ZnO-QDs play the multifunctional roles on anticorrosion of the self-healing coating. The corrosion tests of coatings on the carbon steel well demonstrate that ZnO-QDs can not only act as a valve to seal and release BTA on the time but also act as a precursor to produce the protective film of Zn(OH)2 by the reaction of Zn2+ ions with OH– around the cathode region to inhibit the corrosion of carbon steel. After being soaked in 3.5% NaCl solution for 30 days, the |Z|0.01 Hz value of the coating with HMTNs–BTA@ZnO-QDs still maintains at 2.87 × 107 Ω cm2. Once the defects are formed in the coating, the acid-responsive ZnO-QD valves are rapidly decomposed to release BTA inhibitor; meanwhile, the resulted Zn(OH)2 layer prevent the carbon steel substrate from corrosion in the cathode area. Therefore, it could be promising that the present design of the nanocontainers matching with the multifunctional ZnO-QDs can offer a valuable strategy to construct the self-healing and anticorrosion coatings with a multiresponse to the corrosion environment.
研究领域:
材料科学
·
化学工程
·
表面工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ADVANCES IN COLLOID AND INTERFACE SCIENCE
·
2021
·
IF 12.984
Yinghao Wu,Wenjie Zhao,Junfei Ou
Fluid material can recover from damage rapidly with no demand of external triggering in contrast with the traditional self-healing material which presents low healing efficiency and demands external triggering, such as heat, light, moisture, electricity, etc. However, due to its low viscosity, fluid material is easy to flow away from the surface and thus it is difficult to form a stable coating on the surface to provide practical corrosion resistance to the substrate. Herein, a stable and superfast self-healing coating on steel substrate has been obtained by incorporating carbon nanotube (CNT) into the fluid matrix of epoxy resin (EP) or silicone oil (OIL). To further achieve the active corrosion resistance, 1H, 1H, 2H, 2H- perfluorooctyltriethoxysilane (PTES) which can react with the water inside the coating is added. The coating possesses superfast (tens of seconds) self-healing properties against millimeter-scale scratch repeatedly and excellent corrosion resistance in the aqueous solution of HCl (1 M) and NaOH (1 M). In-situ self-healing and electrochemical behavior in scanning vibrating electrode technique (SVET) measurement indicate the fluid coating possesses infinite self-healing capacity theoretically. Due to its excellent durability and infinite self-healing capacity with short responding time, the optimized fluid coating can be a smart corrosion barrier coating for metals.
研究领域:
材料科学
·
腐蚀与防护
✓ 已验证
DOI
高影响因子
CORROSION SCIENCE
·
2018
·
IF 4.862
Jie Qiu,Bin Leng,Huajian Liu,Digby D. Macdonald,Angjian Wu,Yanyan Jia,Wandong Xue,Guojun Yu,Xingtai Zhou
The effect of SO 4 2− on the corrosion behavior of 316 L stainless steel (SS) in molten FLiNaK (LiF-NaF-KF: 46.5–11.5–42 mol.%) salt was studied. Results reveal that the SO 4 2− in the salt remarkably accelerates the corrosion of 316 L SS by promoting the dissolution of Cr, leading to increasing intergranular corrosion of the alloy. On the other hand, the results of structural characterization indicate that the SO 4 2− can react with Mn to form MnS at the grain boundaries of the alloy. The galvanic couple between MnS and steel matrix could further accelerate the intergranular corrosion of 316 L SS in molten fluoride salt environments.
研究领域:
材料科学
·
腐蚀科学
·
无机化学
·
核工程材料
·
高温电化学
✓ 已验证
DOI
高影响因子
CONSTRUCTION AND BUILDING MATERIALS
·
2024
·
IF 7.4
Lin Wang,Hongqiang Chu,Jiaxuan Xie,Mingzhi Guo,Linhua Jiang,Xiang Xi,Yi Fang,Wei Zhao
Concrete corrosion in wastewater pipelines is caused by biogenic sulfuric acid produced locally by sulfur-oxidizing microorganisms. Concrete mixtures are commonly modified to prevent this form of corrosion by adding biocides to inhibit their biological activities. However, using biocides is not always desirable because of their limited lifespan and potential for leaching into the environment. Therefore, there is a need to develop more durable alternatives to prevent microbial-induced corrosion of concrete. In this study, three types of Cu-Ti amorphous alloys (Cu 35 Ti 65 , Cu 50 Ti 50, and Cu 65 Ti 35 ) were prepared by ball milling, and compared with commercially available TiO 2 nanoparticles to assess their effects on the resistance of the microbial-induced corrosion performance of mortar. Detailed investigations were conducted on the appearance, mechanical properties, and corrosion depth of mortars at various exposure durations in an accelerated biocorrosion environment. The results revealed that the mortars mixed with Cu 35 Ti 65 , Cu 50 Ti 50 , Cu 65 Ti 35 , and TiO 2 nanoparticles exhibited significantly better resistance to microbial-induced corrosion than the reference mortars. The resistance to microbial-induced corrosion of the mortar mixed with Cu 50 Ti 50 was the best. The superior antimicrobial corrosion performance of the mortar containing Cu-Ti amorphous alloy is influenced by both smaller particle sizes and higher sterilization performance. These findings can contribute to the development of novel applications of amorphous alloys in functional concrete.
研究领域:
土木工程
·
材料科学
·
微生物学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）