PROGRESS IN ORGANIC COATINGS
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2024
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IF 6.5
Qian Chen,Xixun Shen,Zuogui Zhang,Qunjie Xu
To solve the problem of icing on the wind turbine blades, here an anti-icing coating composed of PDMS and PVDF as organic bonding frameworks, GPE, MWCNTs , and modified SiO 2 nanoparticles as functional doping phases is synthesized through a one-step spraying method. The coating exhibits excellent superhydrophobic properties with a large contact angle of about 167.0° and a low sliding angle of4.0° and excellent photothermal and electrothermal properties. Under light and electric heating conditions, the coating can be rapidly heated to a high temperature level of about 68.4 °C at 81 s and 48.5 °C at <61 s, respectively. The static water droplet icing experiment shows that the coating can effectively delay the freezing time and reduce the adhesion strength of ice. The freezing rain experiment further showed that under the coordination of photothermal and electrothermal, freezing rain droplets will not freeze on the coating, indicating an excellent anti-icing ability. Meanwhile, the coating also exhibits a superior de-icing ability under the coordination of photothermal and electrothermal. In addition, various performance experiments, including acid and alkali immersion, friction and wear, and impact experiment are also performed to demonstrate the excellent stability and durability of the coating.
研究领域:
材料科学
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能源工程
✓ 已验证
产品关联
DOI
高影响因子
Surfaces and Interfaces
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2021
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IF 4.837
Yeming Xian,Linwei Li,Zhixin Kang
Incorporating nano fillers such as multi-walled carbon nanotubes (MWCNTs) into polymeric matrix can generate rough surface and transfer stress directly to improve adhesion of metal-polymer interfaces. However, the interfaces became more complicate to optimize the adhesion. In this work, the effects of MWCNTs with different surface chemical groups and different diameter on surface profile, wettability and adhesion were studied. The results showed that the adhesion was related to surface wettability when using pristine MWCNTs and this relationship was extinct after the MWCNTs were functionalized. Out of the intuition, the functionalization was not with perfect universality in improving adhesion. D peaks were expanded with the I D /I G and FWHM of A 1 and A 4 increased by dual functionalization from 0.33 to 0.62, 92.39 to 105.91 cm −1 and 0.49 to 1.63, 140.47 to 172.24 cm −1 , respectively. We found that the adhesion of functionalized MWCNTs depended on multiple factors including surface roughness , wettability, the intrinsic mechanical property of MWCNTs, and stress distribution on MWCNT surface when combined with the surface enhanced Raman spectroscopy (SERS) results. This work will be inspiring for novel technology of metal-polymer interfacial modification.
研究领域:
材料科学
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纳米技术
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高分子科学
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表面化学
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机械工程
✓ 已验证
产品关联
DOI
高影响因子
VACUUM
·
2021
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IF 3.627
Yin Li,Li Wang,Hui Zhang,Feng Liang,Yaochun Yao,Keyu Zhang
Three-dimensional (3D) LiFePO 4 @MWCNTs composite has been prepared using phytic acid as the phosphorus source by a simple solvothermal method combined with freeze drying under vacuum. The relationships between the phase structures, the morphologies and electrochemical performance characteristics of the as-prepared samples are studied using a series of characterization methods. It is found that the MWCNTs wrap around the LiFePO 4 particles to form a 3D network because of the reactions between the special functional groups of the phytic acid with Fe 2+ and –C O or –COOH on the surface of the functionalized MWCNTs, resulting in the improvement of conductivity and the electron and ion transport. Due to these merits of MWCNTs and phytic acid, the LiFePO 4 @MWCNTs exhibits good electrochemical performance with high initial discharge capacities of 152.7, 149.6 and 138.8 mAh g −1 at 1, 2 and 5C, respectively. Even at 10C, it still delivers a capacity of 117.5 mAh g −1 .
研究领域:
材料科学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2025
·
IF 6.9
Yifan Tong,Minghao Fang,Chaoqi Liu,Xin Min
As technology continues to advance, multifunctional flexible electronic devices for monitoring human health and managing thermal conditions have garnered considerable attention. Nevertheless, achieving a balance between a wide strain sensing range and high sensitivity remains a considerable challenge. Herein, PDA/PEBA/MWCNTs/rGO (PPMr) sensors were fabricated by vacuum-assisted filtration of ultrasonically mixed multi-walled carbon nanotubes (MWCNTs) and reduced graphene oxide (rGO) loaded on polydopamine-modified PEBA nanofiber membranes. This sensor has a broad range of strain detection capabilities (0–127 % strain), high sensitivity (GF = 42), response/recovery times of 600/500 ms, and over 8000 cycles of stability. At the same time, this sensor also exhibits outstanding photothermal conversion capability (reaching 75.6 °C at 100 mW/cm 2 ), electrothermal conversion capability (up to 82.2 °C at 8 V), and excellent photothermal/electrothermal synergistic conversion capability (reaching 78.9 °C at 100 mW/cm 2 and 4 V). This strain sensor is noteworthy for its outstanding performance, as it can detect body movements across a wide range of strain, such as elbow joint movements, as well as subtle physiological signals like pulse waves. This capability highlights its significant potential for applications in human health monitoring and thermal management.
研究领域:
材料科学
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生物医学工程
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电子工程
✓ 已验证
产品关联
DOI
高影响因子
TALANTA
·
2024
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IF 5.6
Feifan Qi,Mengdie Wu,Simin Liu,Wendi Mu,Chunyan Wu,Xinshui Ren,Chuang Rui,Fangfang Wu,Dong Chang,Hongzhi Pan
Carbohydrate antigen 199 (CA199) is the most sensitive marker reported for pancreatic cancer, and it is a difficult task to develop a highly sensitive assay for CA199. During the experiment, a ratiometric electrochemical immunosensor for quantitative analysis of CA199 was prepared for NiCo@Fc-MWCNTs-LDH as the electrode sensing surface and 3D-rGOF@Ag/Au as the label of Ab 2 . NiCo@Fc-MWCNTs-LDH not only provide the required signal for the immunosensor, but also have a layered structure to obtain a large specific surface area, which can provide more sites for the placement of biological molecules. rGOF has the advantages of large specific surface area and high porosity, which can adsorb Ag electrochemical probe through redox reaction. The modification of gold nanoparticles can not only enhance the electrical conductivity of nano-composites, but also immobilize more biomolecules to improve the sensitivity of electrochemical sensors. With the beefing up of CA199 concentration, the oxidation peak current of Ag increases and the oxidation peak current of Fc-COOH decreases. The ratio (y = I Ag /I Fc-COOH ) of two different signals was linear with the logarithm of CA199 concentration in a certain value range. Under optimal conditions, the immunosensor showed excellent performance in the concentration range of 0.0001 U/mL to 10 U/mL, and the detection limit was 5.55 × 10 −4 U/mL. The strategy could clearly discriminate between matched and mismatched targets, demonstrating high specifificity. This approach further detects CA199 in human plasma to differentiate pancreatic cancer patients from healthy individuals with high accuracy. This method also provided a new idea for the ultrasensitive quantitative detection of other biomarkers.
研究领域:
生物医学工程
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肿瘤标志物检测
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纳米材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
MICROCHEMICAL JOURNAL
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2022
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IF 5.304
Zhijuan Wang,Ran Han,Lin Li,Jiaqing Sun,Jingying Yang,Mingfei Pan,Shuo Wang
A facile, ultra-sensitive and cost-effective electrochemical sensor was successfully prepared by combining metal–organic framework ZIF-8 with MWCNTs-COOH, which detecting of tert -butylhydroquinone (TBHQ) in edible oil and fried foods. The hydrothermally synthesized ZIF-8 material with microporous structure was demonstrated to have large specific surface area, and together with the MWCNTs-COOH with high electrical conductivity and catalytic properties, was used as a modified substrate for electrodes. Because of the synergistic effect between ZIF-8 and MWCNTs-COOH, the modified electrode exhibited significant electrocatalytic ability for TBHQ. Under the optimal experimental conditions, the ZIF-8/MWCNTs-COOH modified electrode obtained good linearity when the TBHQ concentration ranged from 0.01 to 25.0 μg mL −1 with the LOD (limit of detection) of 0.009 μg mL −1 (S/N = 3). Moreover, the constructed electrochemical sensor exhibits better anti-interference capability, reproducibility and stability, and can be used to monitor the content of TBHQ in oil and fried foods.
研究领域:
分析化学
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食品科学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
CARBON
·
2020
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IF 8.821
Meng Zhou,Qiming Yan,Qi Fu,Heqing Fu
The combination of microwave absorption performance and self-healing function is of great practical significance. In this paper, first, ZnO@MWCNTs nanoparticle is prepared by loading Zinc oxide (ZnO) on the surface of the multiwalled carbon nanotubes (MWCNTs) as microwave absorbers. Then, the thermoreversible self-healing DA-PDMS is prepared by using polydimethylsiloxane (PDMS) as raw material based on Diels-Alder (DA) reaction. Finally, a kind of novel multifunctional ZnO@MWCNTs/DA-PDMS nanocomposite with self-healing and microwave absorption properties is synthesized with the addition of ZnO@MWCNTs nanoparticle. When the cracked ZnO@MWCNTs/DA-PDMS nanocomposite is maintained at 120 °C for 10 min, it can recover more than 90% of the original mechanical strength . Even after three healing cycles, the ZnO@MWCNTs/DA-PDMS nanocomposite also displays excellent healing efficiency (about 90%). On the other hand, when the content of ZnO@MWCNTs nanoparticle is 10 wt%, ZnO@MWCNTs/DA-PDMS nanocomposite exhibits an effective absorption bandwidth from 8.2 to 12.4 GHz (full X-band) at a thickness of 3 mm and the minimum reflection loss of −20.1 dB. Even after the 3rd healing cycle, the minimum reflection loss of the healed samples can still maintain −20.0 dB at a thickness of 3 mm. ZnO@MWCNTs/DA-PDMS nanocomposite will have good development prospect in the field of intelligence and microwave absorption materials .
研究领域:
材料科学
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化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2021
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IF 5.316
Meng Zhou,Wenjie Zhao,Qiming Yan,Heqing Fu
The design of multiple heterogeneous interfaces has been proven to be a successful strategy to boost microwave absorption performance. However, the synthesis of magnetic microwave absorber with wide absorption bandwidth is still a challenge. In this work, ZnO@MWCNTs@NiFe 2 O 4 nanocomposites are fabricated by introducing ZnO on the surface of MWCNTs and subsequent anchoring of NiFe 2 O 4 . The minimum reflection loss can reach − 45.5 dB at 12.4 GHz with a thickness of 2 mm, while the broadest efficient absorption bandwidth is above 6.4 GHz at only a 3 mm thickness. Furthermore, the microwave absorption performance of ternary nanocomposites can be optimized by tunable the content of ZnO and NiFe 2 O 4 , whose microwave absorption mechanism depends on the synergy of dielectric loss and magnetic loss. The formation of 3D conductive network and heterogeneous interfaces contributes to the enhancement of conductive loss and polarization, respectively. The experimental results demonstrated that the ZnO@MWCNTs@NiFe 2 O 4 nanocomposites can provide a guide for microwave absorbers with wide absorption bandwidth in the future.
研究领域:
材料科学
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电磁学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2025
·
IF 6.3
Zhihua Zhao,Shuhan Chen,Qingsheng Shi,Chao Qiu,Lan Wu,Xinhao Zhang,Peijuan Wu,Longqi Yao
People pay more and more attention to their own health and environmental safety, which makes the monitoring and treatment of harmful amines such as triethylamine (TEA) emitted in the industrial process increasingly critical. In order to address this issue, we focus on the heterostructure construction of two-dimensional rhenium disulfide (ReS 2 ) and acid-functionalized carbon nanotubes (f-MWCNTs), using their unique electronic properties and high specific surface area for triethylamine gas detection. The findings demonstrated that, at room temperature (25°C), the ReS 2 /f-MWCNTs sensor's response to 100 ppm TEA reached 63 %. Under the same environmental conditions (25℃), the response value of the ReS 2 sensor to 100 ppm TEA is 6 %, and the sensing performance is improved by more than 10 times. In addition, the sensor has fast response recovery (73 s/46 s) and good repeatability and stability. Based on this research, we designed a simple detection device, providing a direction for the practical detection application of TEA sensors.
研究领域:
材料科学
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纳米技术
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气体传感
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环境监测
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电子器件
✓ 已验证
产品关联
DOI
高影响因子
International Journal of Electrochemical Science
·
2023
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IF 1.5
Qiutong Xu,Xiaoliang Song,Li Xu
A large effective surface area and a good electrical conductivity are very important characteristics for electrodes used in wastewater treatment. To improve them while lowering the cost, a novel MWCNTs-modified (Ti/ATONPs-MWCNTs) electrode was produced by a screen-printing technique. To test its performance, the electrode was compared to two other electrodes, namely, Ti/SnO2-Sb and Ti/ATONPs. Several important electrochemical measurements including impedance spectroscopy (EIS), cyclic voltammetry (CV), chronocoulometry (CC) and linear sweep voltammetry (LSV), were used in this study. A toxic organic dye (C.I. Acid Red 73) was chosen as the target pollutant to test the degradation by the removal of chroma and chemical oxygen demand (COD). Compared to Ti/SnO2-Sb and Ti/ATONPs, Ti/ATONPs-MWCNTs show the lowest charge transfer resistance (0.24 Ω), the largest effective surface area (61.97 cm2·cm-2) and the highest oxygen evolution potential (2.15 V). It is known that superior values of these performance characteristics are very important for improving the efficiency of wastewater decontamination. After 90 min electrolysis using Ti/ATONPs-MWCNTs, the removal of AR 73 reached 59.4%, while the energy consumption was as low as only 6.2 Wh·L-1. The remnant COD was only 45% after 3 h of degradation, with an instantaneous current efficiency (ICE) over 80% obtained for Ti/ATONPs-MWCNTs. These results demonstrate the promising prospects for the use of the novel Ti/ATONPs-MWCNTs electrodes in wastewater treatment processes.
研究领域:
环境科学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
·
2022
·
IF 4.598
Wei Zhong,Jin Zou,Yanyu Xie,Jing Yang,Mingfang Li,Shuwu Liu,Yansha Gao,Xiaoqiang Wang,Limin Lu
Herein, a highly sensitive and selective electrochemical sensor for the detection of benomyl (BN), a typical benzimidazole fungicide was proposed based on hierarchical nano-Cu x O decorated MWCNTs-COOH/MXene (nano-Cu x O-MWCNTs-COOH /MXene) composite. The ternary heterostructure presents good electrical conductivity, large specific surface area, and high catalytic activity, exhibiting excellent electrocatalytic activity with enhanced electrochemical signals towards the oxidation of BN. Besides, the embedded nano-Cu x O particles possess strong affinity toward benzimidazole molecules, which could promote the preconcentration of BN, further enhancing the sensitivity, as well as ensuring the high selectivity. Benefitting from the synergistic effect of components in the composite, the developed sensor presents a broad linear range from 10.0 nM to 10.0 μM with a low limit of detection of 3.0 nM (S/N = 3). Meanwhile, the nano-Cu x O-MWCNTs-COOH/MXene electrode also displays good long-term stability and repeatability. Furthermore, this method was successfully applied for the detection of BN in apple samples, illustrating its promising practicability.
研究领域:
分析化学
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环境科学
·
食品科学
✓ 已验证
产品关联
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2024
·
IF 4.9
Aijuan Xie,Linghui Cao,Tianyu Shen,Yuanxinyi Zhou,Haoye Wang,Shiping Luo
As para -aminophenol (PAP) is toxic to humans, causing skin irritation, eye damage, and central nervous system depression, and it can form as a degradation product of paracetamol (PAT) under certain conditions, the simultaneous determination of PAP and PAT is crucial. This work presents the fabrication of three-dimensional ZnCo 2 O 4 @Fe 3 O 4 /MWCNTs hybrid for the simultaneous determination of PAP and PAT using ZIF-8/67@Fe 3 O 4 as precursor and MWCNTs as conductive substrate. The ZnCo 2 O 4 @Fe 3 O 4 /MWCNTs/GCE sensor exhibits linear ranges 1.0–150.0 μM with detection limits of 0.033 μM and 0.018 μM for PAP and PAT, respectively. The developed sensor was successfully used for the determination of PAP and PAT in acetaminophen tablets and lake water with satisfactory results.
研究领域:
分析化学
·
材料科学
·
医学检测
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）