CONSTRUCTION AND BUILDING MATERIALS
·
2023
·
IF 7.4
Sanpeng Mao,Shangheng Zeng,Linghuan Li,Xiaobin Han,Jianying Yu
To better enhance the improvement effect of natural bentonite on the comprehensive performance of styrene-butadiene-styrene thermoplastic elastomer modified bitumen (SMB), in this study, 3-(trimethoxysilopropyl) dimethyl octadecyl ammonium chloride (DC5700) was used for synchronous surface grafting and intercalation of bentonite (DC5700-Bentonite). Meanwhile, γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) surface grafting bentonite (KH560-Bentonite) and octadecyldimethylbenzylammonium chloride (ODBA) intercalation bentonite (ODBA-Bentonite) were used as comparison samples. The structure and properties of the bentonite and organic bentonites (DC5700-Bentonite, KH560-Bentonite and ODBA-Bentonite) were tested by X-ray diffractometer (XRD), Fourier transform infrared spectrometer (FTIR), ultraviolet-visible spectrometer and contact angle measurement . The effects of bentonite and organic bentonites on physical, rheological and aging properties of SMB were investigated. FTIR and XRD results showed that KH560 was chemically grafted onto the surface of bentonite, ODBA was organically intercalated into the bentonite, while DC5700 achieved synchronous surface grafting and intercalation on the bentonite. Compared with KH560-Bentonite and ODBA-Bentonite, DC5700-Bentonite had the best lipophilicity and ultraviolet shielding ability. When the bentonite content was 4 wt% , KH560-Bentonite, ODBA-Bentonite and DC5700-Bentonite could increase the rutting factor of SMB by 2.9 ℃, 4.9 ℃ and 6.5 ℃, respectively, and reduce the ductility of SMB by 6.5 cm, 4.2 cm and 3.1 cm. Meanwhile, compared to SMBs containing KH560-Bentonite or ODBA-Bentonite, the SMB containing DC5700-Bentonite had the smallest creep stiffness at − 12 ℃, − 18 ℃, and − 24 ℃. The results indicated that DC5700-Bentonite was more conducive to increasing high-temperature performance of SMB than KH560-Bentonite and ODBA-Bentonite, and its adverse effects on low-temperature ductility and low-temperature cracking resistance of SMB were also significantly reduced. After thermal and ultraviolet aging, the deterioration extent of physical and rheological properties of SMB containing DC5700-Bentonite was significantly smaller than that of SMB containing KH560-Bentonite and ODBA-Bentonite. FTIR revealed that DC5700-Bentonite was more beneficial than KH560-Bentonite and ODBA-Bentonite in inhibiting the increase of carbonyl index and the decrease of butadiene index in SMB during aging. The comprehensive results revealed that compared to KH560 surface grafting bentonite and ODBA intercalation bentonite, DC5700 synchronous surface grafting and intercalation bentonite were more conducive to improving the physical and rheological properties, and aging resistance of SMB.
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高影响因子
CONSTRUCTION AND BUILDING MATERIALS
·
2023
·
IF 7.4
Tianwei Zhang,Shanjun Gao,Jianying Yu,Yanheng He,Xiaobing Han,Ronghua Zhuang
In this study, self-healing SBS (S-SBS) was first synthesized by introducing dynamic disulfide bonds into the molecular structure of SBS. Subsequently, a self-healing SBS modified bitumen (S-SMB) was prepared by blending of S-SBS and bitumen. The chemical structure of S-SBS and S-SMB was charactered by Fourier transform infrared spectrometer (FTIR) and Raman spectrometer. The physical properties, low-temperature rheological properties and self-healing performance of S-SMB were investigated. The results of FTIR and Raman showed that dynamic disulfide bonds were successfully introduced into the molecular structure of SBS. With the increase of dynamic disulfide bonds content in SBS molecular structure, the softening point and ductility of S-SMB enhanced, and the penetration was decreased. Fluorescence microscope showed that the S-SBS in S-SMB formed a complete crosslinking network structure compared to SMB. The bending beam rheometer illustrated that the low-temperature rheological properties and the cracking resistance of SMB were improved by introducing dynamic disulfide bonds. The fluorescence microscopy observation indicated that the crack in S-SBS can self heal. The fracture healing test and fatigue healing test demonstrated that dynamic disulfide bonds endow S-SMB with great self-healing performance. The fracture healing rate of S-SMB reached 58.7% after 4 h of healing, and the fatigue healing index reached 0.93 after 1 h of healing.
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高影响因子
CONSTRUCTION AND BUILDING MATERIALS
·
2023
·
IF 7.4
Youchao Chen,Junxian Huang,Yaseen Muhammad,Zhenxia Zhao,Shencheng Fan,Wenjie Luo,Jing Li
Based on the four-component separation technology of asphalt, the influence mechanism of carbon nanotubes (CNTs), graphene microsheets (GNPs) and graphene oxide (GO) in SBS-modified asphalt four-component was systematically analyzed by combining macroscopic properties and microscopic characteristics, as well as exploring the morphological distribution of SBS in asphalt four-component. According to the results of Fourier transform infrared spectroscopy and field emission scanning electron microscopy, the modification mechanism of asphalt by three types of carbon nanomaterials follows two pathways: chemical reaction and physical blending. The addition of CNTs, GNPs, and GO results in the destruction of long carbon chains of the saturated fraction in SBS-modified asphalt, and promotes the aggregation of SBS in the asphaltene, as well as its dense distribution and crosslinking in the oil fractions. The results of the fluorescence microscopy test and phase separation test showed that the dispersing effect of the three carbon nanomaterials could alleviate the aggregation phenomenon of SBS, improve the mutual integration between SBS and matrix asphalt, and promote the storage stability of SBS-modified asphalt. Therefore, based on the excellent mechanical properties of the three carbon nanomaterials and their promotion of filling and crosslinking of SBS in asphaltene, they have made significant contributions to the mechanical properties of carbon nanomaterials-composite SBS modified asphalt. This can also be demonstrated by DSR testing and conventional physical property testing. This study hopes to provide a viable analytical route for the use of nanomaterials in modulating the four-component structure and improving the properties of asphalt.
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高影响因子
Arabian Journal of Chemistry
·
2021
·
IF 5.165
Youyuan Wang,Zhanxi Zhang,Rongliang Zheng,Yanfang Zhang
Nonpolar/polar block copolymer materials can be used to develop high-performance dielectric elastomer materials. At present, there is no method to accurately predict its dielectric constant, which is not conducive to improving related research and development efficiency. For this, styrene–butadienestyrene triblock copolymer (SBS) block copolymer grafted modified by thioglycolic acid (TGA) is chosen as the research object. We propose a hybrid calculation method combining the group contribution method, the connectivity index method, and the dipole moment fluctuation method. The connectivity index method and the dipole moment fluctuation method calculate the dielectric constants of nonpolar and polar repeat units to provide accurate basic data for the group contribution method. In the calculation process, the Vogel model completes the mutual conversion between dielectric constant and molar polarizability. Both theoretical calculation and experimental verification show that the dielectric constant of SBS-TGA increases with the grafting rate. We found the correlation between theoretical calculations and experimental values and confirmed that the applicable frequency range of this method is 1 kHz–1000 kHz. This method can be extended to predict the dielectric constant of other polymers and improve development efficiency.
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高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2020
·
IF 3.573
Liangfeng Xiao,Weifeng Liu,Jinhao Huang,Hongming Lou,Xueqing Qiu
The technical enzymatic hydrolysis lignin (EHL) and alkali lignin (AKL) were pretreated via alkaline depolymerization and organic solvent extraction process, respectively. The molecular weight of lignin was lowered and the molecular weight distribution was narrowed, while the content of phenolic hydroxyl group increased after the pretreatment of alkaline depolymerization or solvent extraction. The lignin extracted with ethyl acetate got the lowest molecular weight and highest phenolic hydroxyl group content, showing even better free radical scavenging ability than the commercial Irganox1010. Lignin/SBS elastomer composites were prepared with even dispersion of lignin in the SBS matrix with an average particle size close to 40 nm. It was demonstrated that the alkali lignin extracted with ethyl acetate showed the best improvement on the antioxidant performance of SBS and was comparable to that of Irganox1010 in the SBS elastomer, showing great application potential.
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高影响因子
FUEL
·
2024
·
IF 6.7
Yi Zhao,Mengyu Wang,Naixing Liang,Yaru Wang,Zhi Li,Xiao Li
Asphalt pavements are extensively utilized in tunnel pavement owing to comfortable driving, low noise, short-time construction, and simple maintenance. However, asphalt is a flammable material. To enhance fire retardancy of styrene-butadiene-styrene asphalt (SBSA) and its mixture with a preserved pavement performance, a novel hierarchical core-shell architectured fire retardant, cyclic cross-linked polyphosphazene-functionalized magnesium hydroxide (MH@CPZN), was validated via a chemically guilding assembly in this study. The fire retardancy and smoke suppression properties of SBSA containing MH@CPZN were found to be significantly improved.The MH@CPZN (10 wt%)-incorporated SBSA presented a remarkably higher limiting oxygen index (LOI) of 27.4 % relative to 21.5 % of SBSA with MH and 19.8 % of neat SBSA. In parallel, cone calorimeter test results showed that the peak heat release, peak smoke production rate and CO production of SBSA after an inclusion of 10 wt% MH@CPZN were reduced by 40 %, 35 % and 27 %, respectively, with a 20 s delayed ignition time. A large-scale fire test of asphalt mixture revealed a significant suppression of flame propagation after an addition of MH@CPZN. Moreover, the char yield at 800 °C was significantly increased to 24.1 wt% relative to 14.1 wt% of neat SBSA. A comprehensive analysis demonstrated a co-existence of multi-scale optimization of char microstructure in the condensed and radical quenching due to an interface-located polyphosphazene. Additionally, the high-temperature deformation resistance of SBSA was effectively enhanced after the incorporation of MH@CPZN. In perspective, a hierarchical assembly based on polyphosphazene and metal hydroxides exploits a facile yet practical route for multifunctionally reinforcing asphalt and its mixture with well-preserved fire retardant and pavement performance.
研究领域:
材料科学
·
土木工程
·
火灾安全工程
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Wenlu Zhang,Mengzhe Bao,Mengyao Chen,Wenbin Li,Chong He,Weilin Xu
High-performance TiO 2 nanotube materials are highly demanded across various fields spanning thermal insulation, catalyst supports, filtration, and so on. However, the practical applications of hollow nanotubes are constrained by the low efficiency and uncontrollable structural properties. Herein, mass production of flexible and high catalytic hollow Al/Si@TiO 2 nanotubes were realized. Through solution blow spinning and atomic layer deposition processes, TiO 2 coated Al/Si@PAN core–shell nanofiber intermediate product was obtained with high efficiency. Hollow tubular structure of Al/Si@TiO 2 nanotubes with wall thicknesses among 150–350 nm was successfully replicated by sacrificing PAN core fibers template through a high-temperature pyrolysis process. Organic polysiloxane and polyalumina were employed as the internal supports to enhance the toughness and elasticity of the hollow Al/Si@TiO 2 nanotube products. Diameters of hollow Al/Si@TiO 2 nanotubes can be controlled ranging from 0.5-2.5 μm through adjusting the flow rate among 10–30 mL/h and air pressure among 0.2–0.4 MPa. Pyrolyzed hollow Al/Si@TiO 2 nanotubes exhibited remarkable elasticity with the compression strain of over 60 %. Hollow Al/Si@TiO 2 nanotubes demonstrated a methylene blue degradation efficiency of reached 61 % and outstanding reusability over multiple cycles, which held promising potential for utilization in high efficiency purification and remediation of water pollutants.
研究领域:
材料科学
·
环境科学
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高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Yixiang Chen,Xueli Fu,Yu Jiang,Wanqi Feng,Dan Yu,Wei Wang
Recently, the Ti 3 C 2 T x MXene-based flexible electronics have sparked wide attention in artificial health diagnosis, military security and human–machine interaction. High sensitivity, durability and multifunctionality are desired for strain sensors in long-term health detection. However, unevenness and low fastness of MXene and stretchable nanofibers lead to poor sensitivity and durability, building a strong interface to combine the two-dimensional (2D) MXene nanosheets uniformly along the 1D nanofibers and form a 3D connected electrical network benefits to the improvement of sensing performances. Herein, we propose a facile strategy to prepare a breathable and multifunctional all-nanofiber sensor based on MXene and styrene–butadiene–styrene (SBS) nanofibers. Firstly, the molecular chain of SBS introduces quaternary ammonium groups (NSBS) by thiol-ene click chemistry, hydrophilicity and mechanical properties of NSBS nanofibers are significantly improved, then MXene nanosheets can uniformly and firmly adsorb along with NSBS nanofibers by electrostatic interaction. The assembled MXene/NSBS sensor reaches an ultrahigh sensitivity of 62,194 in the wide detection range of 300% and stability over 3000 cycles for human joint motion, pulse and ECG signal wireless detection. Furthermore, the MXene/NSBS electrodes demonstrate temperature response and thermal management performance including Joule heating and photothermal performance. Consequently, this work indicates a promising candidate for real-time health diagnosis and artificial intelligence in next-generation multifunctional devices.
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CONSTRUCTION AND BUILDING MATERIALS
·
2022
·
IF 7.693
Junxian Huang,Yu Liu,Yaseen Muhammad,Jia Qing Li,Yuting Ye,Jing Li,Zhuang Li,Ruinan Pei
Composite material using glutaraldehyde (GA) cross-linked chitosan (CTS) and graphene oxide (GO-CTS-GA) was designed applying electrostatic interaction strategy under strong alkali environment. GO-CTS-GA was in turn applied to prepare styrene butadiene styrene (SBS) GO-CTS-GA/SBS composite modified asphalt (MA)_binder. The effect of GO-CTS-GA on the physical properties of SBS modified asphalt binder was investigated and its mechanism of action was analyzed. Scanning electron microscopy (SEM), transmission electron microscopy (TEM) and atomic force microscopy tests confirmed the retainment of GO flakes microscopic dimensions while compensating for the chemical structural defects and mechanical property damage of GO. The results of dynamic shear rheometer and multi-stress creep recovery tests indicated that the GO-CTS-GA/SBS-MA binder exhibited better viscosity performance and elasticity performance, rutting resistance and high temperature thermal stability. At 64 °C, the loss modulus of 0.10 % GO-CTS-GA/SBS-MA was 29.5 % and 25.2 % higher than that of SBS-MA and GO/SBS-MA, respectively. SEM and TEM analyses of the four components of asphalt binder before and after modification revealed that the change of asphaltene microscopic morphology seriously affects the stability of asphalt colloidal system. Fourier transform infra-red analysis of the MA binder revealed that the change of saturation fraction and colloidal polarity by GO-CTS-GA is responsible for the dispersion and cross-linking of SBS chain segments in the asphalt binder phase. This study provides important reference information for nanomaterials to change the macroscopic mechanical properties by modulating the microstructure, physical and chemical properties of asphalt binder at the micro and nano-scale.
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高影响因子
MATERIALS SCIENCE FORUM
·
2020
·
IF 0
Xing Liu,Hong Yuan Xing,Gang Liu,Wei Fu,Wen Bo Zeng
Based on the rheological property master curve, a new definition of ageing index was proposed for styrene-butadiene-styrene block copolymer (SBS) modified bitumen. The UV ageing resistance of the combined-modifier modified SBS bitumen was evaluated. Twelve different methods of combined modification were designed with three kinds of modifiers: ultraviolet absorber (Tinuvin 770), organic montmorillonite (OMMT) and layered double hydroxide (LDHs). With modified SBS bitumen, short-term ageing (TFOT) and laboratory ultraviolet ageing (UV) were performed. The dynamic shear rheometer (DSR) was used to perform frequency sweep test on the samples before and after ageing. The rheological property master curve was obtained by fitting the constitutive model equation. Based on the rheological property master curve, a new definition ageing index was proposed for SBS bitumen to evaluate the modified bitumen with different combined-modifier. The results show that the ageing index could effectively evaluate the UV ageing resistance of SBS bitumen. The evaluation results show that the combined-modifier bitumen exhibits better anti-ultraviolet ageing effects than a single modifier. Among them, the combined-modifier modes of 0.3%Tinuvin770+5%OMMT and 0.6%Tinuvin770+2.5%LDHs performed.
研究领域:
材料科学
·
土木工程
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DOI
CHEMICAL ENGINEERING JOURNAL
·
2021
·
IF 13.273
Dingkun Tian,Yadong Xu,Yong Wang,Zuomin Lei,Zhiqiang Lin,Tao Zhao,Yougen Hu,Rong Sun,Ching-Ping Wong
The porous conductive polymer composites have received great attention owing to their superiority of being utilized in electromagnetic interference (EMI) shielding applications. Herein, lightweight and highly compressible conductive composite foam composed of poly(styrene- block -butadiene- block -styrene) (SBS) polymer matrix, carbon nanotubes (CNTs) and silver nanoparticles (Ag NPs) is fabricated by freeze-drying technology, silver precursor absorption and in-situ reduction process. Three-dimensional CNTs conductive network and partially embedded Ag NPs synergistically endow the foam with excellent mechanical, electrical and EMI shielding performance. The flexible 8Ag/4CNTs/10SBS composite foam with a low density of 0.42 g/cm 3 exhibits moderate compressive strength of 169.2 kPa at strain of 50%, remarkable conductivity of 753 S/m, and prominent EMI shielding effectiveness (SE) value of around 91 dB in the electromagnetic wave frequency range of 8.2–12.5 GHz. In addition, the 4Ag/4CNTs/10SBS composite foam exhibits robust mechanical–electrical property upon 1000 compression-release cycles at strain of 50%, and its SE value increased by about 33% compared with the initial state after the cyclic compression test. These results suggest that the Ag/CNTs/SBS foams possess promising potential to be used as lightweight, flexible, and high-performance EMI shielding materials in modern electronic devices.
研究领域:
材料科学
·
电子工程
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高影响因子
Polymers
·
2026
·Vol. 18
·期 17
·2078
·
IF 5.8
Liqun He,Wan Zhang,Jianji Wang,Jianxiao Bian
Polylactic acid (PLA) is derived from renewable resources and can be composted under controlled industrial conditions, but its flammability and brittleness limit wider use. This study combined Ti3C2TxMXene with surface terminations and an intumescent flame retardant (IFR) system based on ammonium polyphosphate and pentaerythritol (4:1,w/w). A styrene–butadiene–styrene (SBS) elastomer was then added to improve toughness. At a total flame retardant loading of 10 wt%, PLA/8.5IFR/1.5MXene reached a limiting oxygen index (LOI) of 30.32% and a UL-94 V-0 rating without dripping. Compared with PLA/10IFR, the peak heat release rate (PHRR) and total heat release (THR) decreased by 18.6% and 28.8%, respectively, and the residue at 600 °C increased from 5.88 to 6.75 wt%. The composite containing MXene formed a denser char and showed a slightly lower Raman D/G intensity ratio. Adding 10 wt% SBS increased notched impact strength by 48% for PLA/IFR and 31% for PLA/IFR/MXene, but reduced tensile strength and modulus. MXene therefore improved the barrier in the condensed phase at a lower IFR content, while SBS partly recovered toughness.
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PubMed
高影响因子
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