SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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2025
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IF 4.6
Yi-Xi Chen,Zhenhua Tang,Le-Yan Feng,Liu-Ling Liang,Deng-Hui Shang,Hui-Qing Li,Xiao-Hai Chen,Feng-Ming Li,Xin-Gui Tang,Shang-Xian Chen
Nowadays, heavy metal pollutants have emerged as a significant global environment affecting human health. Herein, in this work, a highly sensitive and selective dual-signal ratiometric fluorescent sensor for heavy metal Pb 2+ ions detection in aquatic environments was developed by employing the combined highly fluorescent nitrogen and sulfur co-doped carbon dots (N,S-CDs) with rhodamine B (RhB) as a new dual-signal fluorescent probe. The nanostructure, optical properties and a self-calibration mechanism based on the intensity ratio of dual emission peaks were discussed, and, the co-doping of nitrogen and sulfur increased the electron transfer rate and enhanced the coordination interaction between the N,S-CDs and Pb 2+ ions were revealed in the dual-signal ratiometric fluorescent sensor. Moreover, the new sensor exhibited a robust linear response to Pb 2+ ions within the 0–180 μM range, achieving a limit of detection (LOD) of 0.45 μM (93 μg/L) in the actual measurement environment, which is observed to be commensurate with the Grade I standard limit for lead as prescribed in China's “Integrated Wastewater Discharge Standard” (100 μg/L). Furthermore, specificity experiments demonstrated the sensor's superior recognition of Pb 2+ ions over other common metal ions (e.g., Cu 2+ , Fe 3+ , Al 3+ ). In practical industrial wastewater analysis, spike recoveries of 94.20–97.53 % were achieved, with relative standard deviations (RSDs) below 1.32 %, thus validating the method's reliability. This work has been recognized to provide significant potential for environmental monitoring applications.
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NEW JOURNAL OF CHEMISTRY
·
2022
·Vol. 47
·期 4
·1935-1944
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IF 3.925
Hancheng Tan,Xiaolan Zhou,Haiyan Zhu,Wenxiu Gu
A micro/nano hierarchical flower-like ZnS/FeS2 direct Z-scheme heterojunction visible-light catalyst was in situ derived from a Prussian blue analogue cube (Zn–Fe PBA) using a facile one-pot hydrothermal sulfidation strategy. The as-prepared ZnS/FeS2 catalyst shows extraordinarily boosted visible-light photocatalytic degradability for Rhodamine B (RhB) with the synergism of peroxydisulfate (PDS). Under visible-light illumination, 98.5% degradation efficiency can be achieved within 15 min and 100% within 20 min with excellent structural stability of ZnS/FeS2. The degradation kinetic constant of ZnS/FeS2 + PDS is 9.33 times that of ZnS/FeS2, 23.02 times that of p-ZnS/FeS2, 24.05 times that of FeS2, and 28.25 times that of ZnS, respectively. The ZnS/FeS2 heterojunction shows significant synergistic benefits in the photocatalytic degradation reaction. More advantageously, ZnS/FeS2 + PDS shows excellent photocatalytic degradation performance in a wide pH range (1–10). A reasonable direct Z-scheme heterojunction mechanism for visible-light responsive photocatalytic degradation of RhB with ˙OH, h+, ˙O2−, and ˙SO4− as the crucial active species is recommended for the ZnS/FeS2 + PDS composite system. The micro/nano hierarchical flower-like structure of ZnS/FeS2 simultaneously combines the high activity of nano-materials with the advantages of easy recycling of micro-sized materials. The in situ transformation characteristics of ZnS/FeS2 from the PBA template contribute to the advantageous high performance and structural stability.
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ENVIRONMENTAL RESEARCH
·
2020
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IF 5.715
Yangqing He,Hongxia Lv,Yuchen Daili,Qian Yang,Lucas Binnah Junior,Dongjie Liu,Haiyang Liu,Zhanying Ma
In this work, a novel cascade system (i.e., SnTCPP/g-C 3 N 4 /Bi 2 WO 6 ) is successfully constructed using stannum (II) meso-tetra (4-carboxyphenyl) porphyrin (SnTCPP) as the key photovoltaic agent for the first time. Visible light driven photocatalytic experiments indicated that wt . 12% SnTCPP and 30% Bi 2 WO 6 codecorated g-C 3 N 4 demonstrates the highest photodecomposition capabilities for levofloxacin and rhodamine B, achieving 85.64% and 93.64% degradation rates, respectively. The dramatically enhanced photocatalytic performance mainly raised from the synergetic co-effects among SnTCPP, g-C 3 N 4 and Bi 2 WO 6 , including: i) the incorporation of SnTCPP extends the visible light response of the binary Bi 2 WO 6 /g-C 3 N 4 heterojunctions , resulting in the highly efficient visible light harvesting; ii) we find that the g-C 3 N 4 not only serves as a promising supporter to trap electrons from Bi 2 WO 6 , but also as an interfacial electron-hole pairs transfer moderator, like “volleyball setter” to facilitate the charges transfer between Bi 2 WO 6 and SnTCPP. The presence of the “setter” endows a cascade system for boosting the photodegradation efficiency of levofloxacin and rhodamine B. This study provides a promising design strategy to construct efficient g-C 3 N 4 based heterojunctions suitable for removing pharmaceutical antibiotics and hazardous dyes from various real wastewaters .
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MICROCHEMICAL JOURNAL
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2024
·
IF 4.9
Yang Yu,Peng Li,Guohai Zheng,Liwei He,Dandan Ge,Zhehui Weng
A magnetic matrix solid phase dispersion (MSPD) method based on magnetic ZIF-8 (SDS@MZIF-8) and a deep eutectic solvent was developed and used to the extraction of crystal violet and rhodamine B in lake sediments. SDS@MZIF-8 was prepared and used as the extraction sorbent and dispersant in MSPD. The magnetic property of MZIF-8 facilitated the recovery of the extraction sorbent after the blending step. Hydrophilic deep eutectic solvents were prepared and used as efficient green dispersing solvents in MSPD. The use of magnetic sorbent in MSPD is simple and fast, eliminating some additional steps commonly used in the classical MSPD and shortening the extraction time. The parameters influencing the extraction efficiency were investigated and optimized. Under the optimized conditions, the intra- and inter-day relative standard deviations were less than 4.9 %. The linearity ranged from 2-400 µg g −1 with coefficients of determination higher than 0.9943. The detection and quantification limits of RB and CV varied between 0.3–0.5 μg g −1 and 1.0–1.8 μg g −1 , respectively. Finally, the developed method was applied to the analysis of RB and CV in the sediment samples. The recoveries ranged from 93.2 to 107.3 % and the relative standard deviations ranged from 0.8 to 4.9 %. The results suggest a high potential use of the proposed method to determine the organic pollutants in solid samples. Compared with the conventional MSPD extraction technique, the developed method considerably reduced the sample and solvent consumption, offering important environmental benefits.
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RSC Advances
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2025
·Vol. 15
·期 58
·49875-49888
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IF 4.6
Yangyi Cai,Xiaocan Liu,Weiye Yang,Hongyan Peng,Lijian Meng,Shihua Zhao
Persistent organic pollutants pose significant long-term risks to environmental and human health due to their carcinogenic, mutagenic, and teratogenic properties. This study focuses on the efficient activation of peroxymonosulfate (PMS) through the rational design of a cobalt-based metal–organic framework (ZIF-67) catalyst, enabling rapid degradation of high-concentration dye pollutants. By optimizing the molar ratio of 2-methylimidazole (2-MeIM) to Co(NO3)2·6H2O and employing a hydrothermal synthesis method, we fabricated ZIF-67 (4 : 1) with high crystallinity, large specific surface area (1656.68 m2 g−1), and stable degradation performance. The ZIF-67 (4 : 1)/PMS system achieved complete degradation of 20 mg L−1 and 100 mg per L Rhodamine B (RhB) within 60 seconds and 6 minutes, respectively, surpassing recent reported efficiencies. The system also maintained high activity over a broad pH range (3–9). Radical quenching experiments and electron paramagnetic resonance (EPR) analysis identified sulfate radicals (˙SO4−4) and singlet oxygen (1O2) as the dominant reactive species. Furthermore, the catalyst exhibited excellent recyclability with no significant loss in activity after five consecutive cycles. This work provides a facile and scalable strategy for preparing highly active cobalt-based catalysts, demonstrating great potential for practical applications in industrial wastewater treatment and environmental remediation.
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ELECTROCHIMICA ACTA
·
2018
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IF 5.116
Kané Rabé,Lifen Liu,Noor Ahmed Nahyoon,Yizhen Zhang,Ahmed Mahmoud Idris
Degradation of pollutants can be integrated with electricity generation in Photocatalytic fuel cell under light irradiation or self-powered fuel cell in the dark. In fuel cell driven by electrode reactions , the electrode reduction and oxidation transforms chemical energy in pollutants into electrical energy. In this work, Rhodamine B and coking wastewater were treated, using an efficient Z-scheme g-C 3 N 4 /Fe 0 (1%)/TiO 2 as an anodic catalyst and WO 3 as a cathodic catalyst. After 100 min of reaction in a single chamber fuel cell with 10 Ω of external resistance, in 0.05 M Na 2 SO 4 electrolyte, the paired stainless-steel electrodes loaded respectively with g-C 3 N 4 /Fe 0 (1%)/TiO 2 and WO 3 , degraded 98% Rhodamine B and generated 0.95 V cell voltage under 50 W visible-light irradiation, while removed 60% RhB and generated 0.5 V without light. To investigate the PFC performance of g-C 3 N 4 /Fe 0 (1%)/TiO 2 in treating real coking wastewater, at optimal pH 2, 91% chemical oxygen demand (COD) and 89% total organic carbon (TOC) were removed and generated 0.3 V cell voltage. The influence of pH on photocatalytic degradation performance and cell voltage are evaluated. The high cell voltage is attributed to the very low impedance of the g-C 3 N 4 /Fe 0 (1%)/TiO 2 loaded anode. The excellent electrochemical properties of paired electrodes help in generating higher current density , due to the increased photocatalyst activity of the tridimensional catalyst as proved by electron spinning resonance spectrum, photoluminescence , and Electric Impedance Spectrum analysis.
研究领域:
环境科学
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光催化
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能量转换
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废水处理
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电化学
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材料科学
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2023
·
IF 5.2
Binxia Zhao,Nan Shao,Xingliang Chen,Jixian Ma,Yijia Gao,Xiaoqian Chen
As a novel photocatalyst with visible light responsiveness, Bi 2 WO 6 has excellent activity in treating wastewater containing organic pollutants and noble metals. However, its photocatalytic action is limited due to the rapid recombination of photogenerated electrons and holes. Based on the study of Bi 2 WO 6 , a type Ⅱ heterojunction photocatalyst (WO 3 /Bi 2 WO 6 ) and a Z-scheme heterojunction photocatalyst (CdS/Bi 2 WO 6 ) were constructed. Composites exhibited higher catalytic activity than pure Bi 2 WO 6 . The degradation efficiency of RhB(50 mg/L) and reduction efficiency of Cr(VI) (50 mg/L) by 5%WO 3 /Bi 2 WO 6 catalyst within 60 min of photocatalytic reaction was 98.82% and 53.82%, respectively. The degradation efficiency of RhB and reduction efficiency of Cr(VI) by 15%CdS/Bi 2 WO 6 catalyst was 99.52% and 69.52%, respectively. By studying the structural composition , microscopic morphology, photoelectrochemical performance, and light absorption performance of the catalysts of the two different systems. These mechanisms may help to explain the reasons for the enhanced activity of the composite photocatalysts. In addition, mixed wastewater containing organic pollutants (RhB) and heavy metal ions (Cr(VI)) was used to simulate real and complex wastewater, which provided more ideas for wastewater treatment problems.
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JOURNAL OF APPLIED POLYMER SCIENCE
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2025
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IF 2.8
Rui Gao,Shen Zhang,Hailong Liu,Zhizhou Yang,Yue Wu,Sheng Gao,Mei Li,Hanlin Shao,Mingjie Wu
Disposal of dye-contaminated wastewater has become an imperative issue. Synthesis of novel materials for larger-capacity removal of those contaminants assisting by special interaction is a significant challenge. In this paper, a series of hyper-crosslinked poly 9-bromophenanthrene hybrids (HCPs) were synthesized by combination of 9-bromophenanthrene (9BP) and octavinylsilsesquioxane (OVS) via Friedel-Crafts alkylation reaction. The synthesized HCPs were well characterized. The results illustrated that HCPs were porous polymer hybrids consisting of micropores and mesopores with the apparent surface areas ( S BET ) in range of 980.0–1010.6 m 2 g −1 , and the micropore and mesopore widths located at 1.42 and 4 nm. Dye adsorption disclosed that the adsorbed amounts of rhodamine B (RB) and Congo red (CR) on HCP-2 respectively arrived at 2646.0 ± 37.4 and 1550.0 ± 38.5 mg g −1 , ascribing to the interactions of pore filling, hydrogen bonds, π π stacking, electrostatic attraction, especially the C Br⋯π interaction between the resulting polymers and the dye molecules of RB and CR. Moreover, HCP-2 exhibited larger adsorbed amount of iodine vapor arriving at 179.9 ± 2.6 wt%. This work provided an innovative strategy to design new adsorbents for larger-amount removal of contaminants from the environment.
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JOURNAL OF CHROMATOGRAPHY A
·
2021
·
IF 4.759
Qili Liu,Qing Xu,Wei Sun
The monomer of two-in-one molecular design strategy (i.e., A 2 B 2 type monomer) 1,6-bis(4-formylphenyl)-3,8-bis((4-aminophenyl) ethynyl)) pyrene (BFBAEPy) was self-polymerized and coated on the modified Fe 3 O 4 surface to synthesize a magnetic covalent organic framework (Fe 3 O 4 @COF) nanocomposite with a core-shell structure. Before high-performance liquid chromatography with ultraviolet detection (HPLC-UV) determination, Fe 3 O 4 @COF was used as a magnetic solid-phase extraction (MSPE) adsorbent to enrich Rhodamine B (RhB) illegally added to Chili powder and Chinese prickly ash. It had a large specific surface area and suitable pore size, which promoted the efficient adsorption of RhB dye and eliminated the interference of the matrix. Several key parameters affecting the extraction recovery rate were investigated, including adsorption capacity, adsorption time, pH, ionic strength, elution solvent, elution volume and elution time. Under the best optimized conditions, within the linear detection range of 0.05–5 µg/mL for RhB with the limit of detection (LOD) was 0.0038 µg/mL, excellent linearity (correlation coefficient R 2 =0.9997), and good repeatability (relative standard deviations RSD%< 3.8%), satisfactory extraction recovery rate (91.7%-97.5%). Therefore, the application of the established method to the detection of RhB in food samples has bright prospects.
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