JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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2020
·
IF 3.807
Feng Hong,Qiqin Wang,Wenhai Wang,Xixue Chen,Yuting Cao,Youren Dong,Ning Gan,Dazhen Wu,Futao Hu
How to eliminate the background signal of the electrochemical aptasensor and improve its signal amplification efficiency is one of the key factors to build a highly sensitive and selective sensor. Herein, we developed a multi-signal amplified, zero background electrochemical aptasensor for rapid detection of tumor markers, with carcinoembryonic antigen (CEA) as a model analyte . A type of dendritic DNA scaffold labeled with a lead-based metal organic framework (HCR-Pb-MOF) was prepared by hybrid chain reaction as signal tags. After one-step replacement of the signal tags into the supernatant by the target, the inner Pb 2+ ions in the replaced tags were detected by square-wave voltammetry (SWV) for qualification. The assay has some distinct advantages. Firstly, one HCR-Pb-MOF can load many Pb-MOFs, with each Pb-MOF containing large amounts of Pb 2+ ; thus, multi-amplified signals from Pb 2+ can be obtained after one-step replacement of the target. Secondly, Pb-MOF can also completely avoid the leakage of Pb 2+ , which is usually observed in the MOF probes electrostatically adsorbing metal ions , to achieve zero background. Thus, the aptasensor with a one-step replacement detection strategy can greatly improve sensitivity, with the detection limit of CEA being 0.333 pg mL −1 . Finally, the stirring bar was employed after introducing the target into the system. Therefore, the whole sample detection time can be reduced to within 10 min. This aptasensor was successfully applied to rapidly and accurately analyze CEA in human serum, with results consistent to those of ELISA . All of these findings prove that this multi-signal amplified, rapid, zero background electrochemical aptasensor can meet the requirements for rapid and highly sensitive detection of tumor markers in human serum.
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高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2021
·
IF 4.539
Yanru Zhang,Mingzhu Xia,Fengyun Wang,Jianzhe Ma
Amino trimethylposphonate(ATMP) functionalized HAP were synthesized with different ATMP addition (0, 5%, 10%, 15%) and the adsorption performance towards Pb 2+ and Cd 2+ were studied in an aqueous solution. Under the optimum condition, HAP with ATMP addition of 10% (10AT-HAP) displayed the most efficient adsorption performance with the adsorption capacity of 1458.79 mg/g and 321.26 mg/g towards Pb 2+ and Cd 2+ , respectively, which improved 76% and 92% than that of the artificially prepared HAP in the laboratory, respectively. For both heavy metal ions , the adsorption mechanism also included ion exchange and surface complexation, in which the surface complexation played a predominant role. In addition, XRD showed that a new crystal phase was formed after Pb 2+ adsorption, while no new phase appeared after Cd 2+ adsorption, indicating that the adsorption mechanism of Pb 2+ involved dissolution-precipitation. The fitting results of adsorption isotherm and kinetics showed that the adsorption of Pb 2+ and Cd 2+ on HAP and 10AT-HAP were well fitted by the Langmuir isotherm model and Pseudo-second model. Moreover, Multiwfn wavefunction program based on density functional theory (DFT) was applied to deeply probe and vividly visualize the interaction sites, interaction types, interaction strength and the essence of interactions between HAP and ATMP or ATMP-HAP composite and heavy metal ions.
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ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
·
2021
·
IF 6.291
Yelin Zhu,Xinzhong Wang,Ping Wang,Jian Zhu,Yingnan He,Xiuxiu Jia,Fengqin Chang,Huaisheng Wang,Guangzhi Hu
In the present work, hematite–boron-carbonitride (Fe 2 O 3 –BCN) nanosheets were synthesized by a simple hydrothermal reaction and the following high temperature treatment. The morphology, structure and chemical composition of the as-prepared material were carefully characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The Fe 2 O 3 –BCN nanosheets were used to modified on the surface of the glassy carbon electrode to fabricate an electrochemical sensor for lead ions (Pb(II)) via differential pulse anodic stripping voltammetry (DPASV). At the same time, the influence of the modification concentration, solution acidity, deposition potential and deposition time on response peak current of Pb(II) at the Fe 2 O 3 –BCN-based electrochemical sensor was well investigated. Under the optimized conditions, the electrochemical signal and concentration of Pb(II) show two-stage linear relationship in the range of 0.5 – 40 μg/L and 40 –140 μg/L, with a limit of detection (LOD) of 0.129 μg/L. The Fe 2 O 3 –BCN-based electrochemical sensor shows excellent selectivity and anti-interference ability in the anti-interference experiments and actual sample analysis experiments, revealing its broad application in environmental monitoring of Pb(II).
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PubMed
高影响因子
SOLAR ENERGY MATERIALS AND SOLAR CELLS
·
2019
·
IF 6.019
Jianbo Pan,Rongzong Zheng,Yi Wang,Xingke Ye,Zhongquan Wan,Chunyang Jia,Xiaolong Weng,Jianliang Xie,Longjiang Deng
Functions of electrochromism and energy exchange can be achieved by redox reactions , which indicate designing a bi-functional electrochromic energy storage device (EESD) is feasible. In this paper, a NiO/PB composite nanosheet electrode was prepared via loading Prussian blue (iron (Ⅲ) hexacyanoferrate (Ⅱ), PB) nanoparticles on the surface of NiO nanosheets, meanwhile, a high-performance WO 3 negative electrode was also prepared via novel erythritol-assisted hydrothermal method with NH 4 Cl used as capping agent. The designed EESD exhibited properties of large optical modulation (67.6% at 630 nm), high coloration efficiency (109.6 cm 2 C -1 ), fast switching speed (2.8/7.9 s for bleaching/coloration) and long cycle life (ΔT remaining was 84.1% after 4000 cycles). Meanwhile, the EESD also obtained attractive energy storage properties at a potential window from 0 to +1.3 V. Impressively, the EESD exhibited a high areal capacitance of 11.50 mF cm -2 at current density of 0.05 mA cm -2 and the process of charging/discharging can be repeated at least 4000 cycles with a little decay. Therefore, the bi-functional EESD exhibits high promising application prospect.
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2019
·
IF 3.131
Qun Jiang,Weiling Xie,Siyue Han,Yifan Wang,Ying Zhang
The corn straw-converted hydrochar (HC), HC modified with H 3 PO 4 (H 3 PO 4 -HC), and HC modified with polyethyleneimine (PEI) (PEI-HC) were prepared in this study for Pb(II) adsorption from an aqueous solution. SEM, TEM , XRD , Raman, FT-IR, BET and XPS analysis were carried out for the characterization of the as-obtained samples, and the Pb(II) adsorption capacities and mechanism onto them were analyzed. The results of SEM show that PEI loading on HC could cover the aggregates of the carbon spheres, altering the microscopic characteristic of HC. The lower I D / I G value of H 3 PO 4 -HC and no residual cellulose provided evidence to H 3 PO 4 -HC suffering a more thoroughly carbonization process than the original HC or PEI-HC. Both H 3 PO 4 -HC and PEI-HC exhibited excellent performance for Pb(II) adsorption with q max of 353.4 mg g −1 and 214.0 mg g −1 , respectively, which are significantly higher than the adsorption capacity (32.67 mg g −1 ) of the original HC. And the dominant Pb(II) adsorption process onto the as-fabricated HCs was attributed to chemical reaction revealed by the results of XPS analysis. After the adsorption process, the binding energies of C O and C O or NH / NH 2 and N in the as-prepared HCs have been shifted, confirming that the surface functional groups had taken part in the Pb(II) adsorption. The main adsorption mechanisms of Pb(II) on H 3 PO 4 -HC are the ions exchange and hydrogen bonding , and that of PEI-HC are the coordination bonding and hydrogen bonding. This study put forward in-depth views on the adsorption mechanism of the modified HCs. This facilitates the development of new and efficient adsorbents for the removal of heavy metals from water.
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ACS Applied Nano Materials
·
2019
·
IF 0
Jiaxing Wei,Mohamed F. Aly Aboud,Imran Shakir,Zhangfa Tong,Yuxi Xu
The application of sorbent in solving the water pollution induced by heavy metals or metalloids is severely hindered by poor sorption performance and high cost, especially in simultaneous removal. Design and synthesis of nanocomposites as effective sorbents has been widely considered as a promising approach to address this problem. Herein, graphene oxide supported organo-montmorillonite composite (GO-OM) was prepared through a facile ultrasonic-assisted method for the first time and exhibited excellent synergetic adsorption behavior for mixed pollutants in aqueous solutions. Unlike previous studies, the simultaneous removal process can be well-described by the Freundlich and pseudo-second-order kinetic models. The sorption capacities of GO-OM are very high for both metal cations and oxyanionic groups, showing excellent potential in the removal of multiple contaminants. Our study also reveals that GO-OM has high recycling efficiency and good performance under a low level concentration. All results suggest that GO-OM can be used as effective and ecofriendly sorbents for the removal of combined pollutants in an aqueous environment. This work contributes to developing high-performance graphene materials with organic minerals and gives deep insight into simultaneous sorption of metal ions, which can be potentially extended to other multiple pollutants.
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ELECTROANALYSIS
·
2019
·Vol. 32
·期 3
·462-469
·
IF 2.691
Xiaomeng Shan,Tao Pan,Yuting Pan,Wenchang Wang,Xiaohui Chen,Xueling Shan,Zhidong Chen
In this study, a novel electrochemiluminescence (ECL) sensor for highly sensitive and selective detection of Pb(II) was developed based on Ru(bpy) 3 2+ encapsulated UiO66 metal-organic-framework (Ru(bpy) 3 2+ −UiO66 MOF) and −NH 2 group functionalized silica (NH 2 −SiO 2 ). The NH 2 −SiO 2 with large surface area provided an excellent platform for the ECL sensor. As numerous exposed carboxyl groups were present on UiO66 backbone, the Ru(bpy) 3 2+ −UiO66 could be steadily immobilized to NH 2 −SiO 2 by forming amide bonds. Meanwhile, the introduced UiO66 MOF which used for the encapsulation of Ru(bpy) 3 2+ , significantly enhanced the ECL efficiency of the proposed sensor, as it possessed a large specific surface area and porosity for the loading of Ru(bpy) 3 2+ . Moreover, a high quenching effect on ECL intensity was obtained in the presence of Pb(II) in the electrolyte. Under the optimal conditions, the quenched ECL intensity showed a good linear relationship within Pb(II) concentration in the range from 1.0×10 −6 to 1.0×10 2 μM, with a detection limit of 1.0×10 −7 μM ( S / N =3). The proposed sensor for Pb(II) detection was simple in operation, rapid in testing, stable in signal, and showed a good anti-interference ability to some other metal ions. Besides, its application for detecting Pb(II) in a real sample was also investigated here. This work provides a potential platform for metal ions detection in environmental monitoring field.
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MICROCHIMICA ACTA
·
2018
·Vol. 185
·期 5
·1-9
·
IF 5.705
Han Xiujuan,Meng Zuchao,Zhang Hongfang,Zheng Jianbin
Various carbon nanomaterials for use in anodic stripping voltammetric analysis of Hg(II), Cu(II), Pb(II) and Cd(II) are screened. Graphene, carbon nanotubes, carbon nanofibers and fullerene (C 60 ), dispersed in chitosan (Chit) aqueous solution, are used to modify a glassy carbon electrode (GCE). The fullerene-chitosan modified GCE (C 60 -Chit/GCE) displays superior performance in terms of simultaneous determination of the above ions. The electrodes and materials are characterized by electrochemical impedance spectroscopy, cyclic voltammetry, scanning electron microscopy, Raman spectroscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The excellent performance of C 60 -Chit/GCE is attributed to the good electrical conductivity, large surface area, strong adsorption affinity and unique crystalline structure of C 60 . Using differential pulse anodic stripping voltammetry, the assay has the following features for Hg(II), Cu(II), Pb(II) and Cd(II), respectively: (a) Peak voltages of +0.14, −0.11, −0.58 and − 0.82 V (vs SCE); (b) linear ranges extending from 0.01–6.0 μM, 0.05–6.0 μM, 0.005–6.0 μM and 0.5–9.0 μM; and (c), detection limits (3σ method) of 3 nM (0.6 ppb), 14 nM (0.9 ppb), 1 nM (0.2 ppb) and 21 nM (2.4 ppb). Moreover, the modified GCE is well reproducible and suitable for long-term usage. The method was successfully applied to the simultaneous determination of these ions in spiked foodstuff.
Compared with graphene, carbon nanotubes and carbon nanofibers, an electrode modified with fullerene in chitosan electrode displays superior performance for the simultaneous anodic stripping voltammetric detection of Hg(II), Cu(II), Pb(II) and Cd(II).
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高影响因子
Polymers
·
2019
·Vol. 11
·期 5
·815
·
IF 3.164
Mihray Abdulla,Ahmat Ali,Ruxangul Jamal,Tursunnisahan Bakri,Wei Wu,Tursun Abdiryim
Heavy metal ions in water, cosmetics, and arable land have become a world-wide issue as they cause a variety of diseases and even death to humans and animals when a certain level is exceeded. Therefore, it is necessary to development a new kind of sensor material for the determination of heavy metal ions. In this paper, we present an electrochemical sensor based on composite material (thiol(–SH) grafted poly(3,4-proplenedioxythiophene) (PProDOT(MeSH)2)/ porous silicon spheres (Si) composite, denoted as PProDOT(MeSH)2@Si) from the incorporation of thiol(–SH) grafted poly(3,4-proplenedioxythiophene) (PProDOT(MeSH)2) with porous silicon spheres (Si) for the electrochemical detection of heavy metal ions (Cd(II), Pb(II), and Hg(II)). The PProDOT(MeSH)2@Si composite was synthesized via a chemical oxidative polymerization method. The structure and morphology of PProDOT(MeSH)2@Si composite were characterized by Fourier transform infrared (FT-IR), Ultraviolet–visible spectroscopy (UV–Vis), X-ray diffraction (XRD), scanning electron microscope (SEM), Transmission electron microscope (TEM), and Brunauer−Emmett−Teller (BET). Furthermore, the electrochemical performance of PProDOT(MeSH)2@Si was evaluated by detecting of Cd(II), Pb(II), and Hg(II) ions using the differential pulse voltammetry (DPV) method. The relationship between structural properties and the electrochemical performance was systematically studied. The results showed that the entry of two thiol-based chains to the monomer unit resulted in an increase in electrochemical sensitivity in PProDOT(MeSH)2,which was related to the interaction between thiol group(-SH) and heavy metal ions. And, the combination of PProDOT(MeSH)2with Si could improve the electrocatalytic efficiency of the electrode material. The PProDOT(MeSH)2@Si/GCE exhibited high selectivity and sensitivity in the rage of 0.04 to 2.8, 0.024 to 2.8, and 0.16 to 3.2 μM with the detection limit of 0.00575, 0.0027, and 0.0017 µM toward Cd(II), Pb(II), and Hg(II), respectively. The interference studies demonstrated that the PProDOT(MeSH)2@Si/GCE possessed a low mutual interference and high selectivity for simultaneous detection of Cd(II), Pb(II), and Hg(II) ions.Keywords:thiol(–SH), poly(3,4-proplenedioxythiophene), porous silicon spheres;electrochemical sensor;heavy metal ions;simultaneous detection
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高影响因子
Science China-Chemistry
·
2013
·Vol. 56
·期 5
·567-575
·
IF 1.327
Xiang Ting,Zhang ZuLei,Liu HaiQing,Yin ZhengZhi,Li Lei,Liu XiaoMing
Nanofiber membranes from the composite of cellulose acetate/polyvinylpyrrolidone were prepared using electrospinning technique. After treated with water and alcoholic KOH to remove partially polyvinylpyrrolidone and deacetylate the cellulose acetate, the membranes were further functionalized with thiol groups using thioglycolic acid. Related materials were characterized using infrared and thermogravimetric analysis. And the results showed that the membranes were success of functionalisation. Then the nanofiber membranes were used in the sorption-desorption process. The effects of pH, contacting time and adsorption capacity of nanofiber membranes were studied against Cu(II), Cd(II) and Pb(II) ions. And the maximum adsorption capacities of Pb (II), Cu (II), and Cd (II) ions were estimated at 30.96, 19.63, 34.70 mg g −1 . Our results suggested that the adsorption behaviour of metal ions could be described using Langmuir model. Their adsorption kinetics was in agreement with the model of pseudo-second order, suggesting chemical adsorption as the rate-limiting step of the adsorption mechanism. The durability of the thiol-functionalized cellulose nanofiber membranes was also evaluated by repetitive adsorption-desorption.
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Scientific Reports
·
2017
·Vol. 7
·期 1
·1-11
·
IF 4.259
Wang Yaoguang,Wu Di,Wei Qin,Wei Dong,Yan Tao,Yan Liangguo,Hu Lihua,Du Bin
In this study, branched polyethylenimine (PEI) enhanced magnetic carboxymethyl chitosan (MCMC-PEI) was synthesized and applied as adsorbent for the rapid removal of Pb(II) from aqueous solution. The successful synthesis of the adsorbent was proved by scanning electron microscope (SEM), Fourier transform infrared spectrum (FTIR) and X-ray powder diffraction (XRD). Simultaneously, the effect of the parameters such as initial concentration, adsorbent mass and pH of the solution on the removal of Pb(II) was studied by using response surface methodology (RSM). And central composite design (CCD), which is a widely used form of RSM, was employed in the experimental design procedure. The adsorption results revealed that the adsorption process could reach equilibrium rapidly within 10 min. Furthermore, the adsorption kinetic data could be well described by pseudo-second order model. The maximum adsorption capacity was 124.0 mg/g according to the Langmuir-Freundlich model, which fitted the adsorption isotherm of Pb(II) better than Langmuir model and Freundlich model, respectively. Thermodynamic studies (Δ G < 0, Δ H < 0, Δ S > 0) implied a spontaneous and exothermic process in nature. Meanwhile, the fabricated adsorbent exhibited excellent reusability. Therefore, the excellent adsorption property of MCMC-PEI made it a promising application in water treatment.
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高影响因子
Journal of Cleaner Production
·
2017
·
IF 5.715
Nan Zhou,Honggang Chen,Qiuju Feng,Denghui Yao,Huanli Chen,Haiyan Wang,Zhi Zhou,Huiyong Li,Yun Tian,Xiangyang Lu
The acidic environment has been confirmed to have significant influence on the biochar products through hydrothermal carbonization . To investigate the effect of H 3 PO 4 on the surface properties and adsorption mechanisms of the biochar, fresh banana peels were used as feedstock and transformed into hydrochars under the catalysis of H 3 PO 4 with concentration ranges from 0% to 50%wt. The addition of H 3 PO 4 greatly impacted the physicochemical properties of the as-obtained hydrochars, such as carbonization degrees, pH values, amount of surface acidic functional groups and then further affected the adsorption mechanisms of lead ions on those hydrochars. Hydrochars catalyzed by H 3 PO 4 with higher concentration showed higher degree of carbonization, lower value of pH and fewer amount of acidic functional groups, while lower content of H 3 PO 4 could not completely catalyze the degradation reactions and resulted in larger quantity of intermolecular locked oxygen containing groups that could not be participated into the adsorption process . Among all six samples, hydrochar generated in 30%wt H 3 PO 4 exhibited the best adsorption property of 241 mg g −1 , possibly due to the largest concentration of the acidic functional groups on the surface rather than in the intermolecular structure of the carbon. It had been confirmed that the adsorption mechanisms were the combination of surface complexation, cationic exchange and part of precipitation. Hydrochars derived from fresh banana peel via hydrothermal carbonization catalyzed by phosphoric acid could be excellent adsorbents for lead removal in aqueous environments .
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危险品化学品经营许可证（带存储）