Micromachines
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2024
·Vol. 15
·期 1
·154
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IF 3
Qingyun Li,Zihua Wang,Xuezhong Wang
The synthesis of multielement composite oxide nanomaterials containing Ce, Zr, Y, and Yb was investigated using a micro confined jet mixer reactor operated in continuous mode under supercritical water conditions. The obtained nanoparticles were characterized using ICP-AES, SEM-EDS, FTIR, Raman spectroscopy, XRD, and TEM. All samples exhibited a uniform particle shape and a narrow particle size distribution. An analysis of the d-spacing results using selected electron area diffraction (SAED) patterns confirmed the production of cubic-phase crystals. A BET test was employed to determine the specific surface area of the prepared nanoparticles. OSC and TPR techniques were utilized to characterize the oxygen storage capacity and reduction performance of the obtained samples, with an analysis conducted to determine how the different proportions of elements affected the performance of multielement mixed oxides. The ionic conductivity of multielement composite oxide was measured using alternating current impedance spectroscopy (EIS), and the impact of Y, Ce, and Yb on the electrolyte material’s ionic conductivity was analyzed.Keywords:confined jet mixer;multielement composite oxide;continuous hydrothermal flow synthesis;oxygen storage capacity;ionic conductivity
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CHEMICAL ENGINEERING JOURNAL
·
2019
·
IF 8.355
Qingfeng Yang,Hui Hong,Yongkang Luo
Discharged tetracycline (TC) seriously threatens human health and environmental safety. Herein, we developed a novel 3D flower-on-sheet structure of Zr-metal organic framework adsorbent with the assistant of N,S co-doped carbon dots as heterogeneous nucleation (UiO-67/NSC) for selective and effective removal of TC residue from contaminated water. Functional groups of UiO-67/NSC acts as a tentacle to identify TC molecules, and TC-adsorbed NSC can be separated easily by incorporating in UiO-67 structure. Hierarchical UiO-67/NSC exhibited excellent recognition performance with a wide sensitive range (0.08–20.0 mg/L) and low detection limit (0.063 mg/L) for TC. Particularly, vertically oriented 2D nanosheets in UiO-67/NSC alleviate the diffusion barrier and enhance mass transfer between adsorption sites and TC molecules, endowing it with an ability that can improve the TC adsorption capacity of parent UiO-67 to 427.35 mg/g. UiO-67/NSC with 0D structure has no significant toxic effect on human cells (HepG2 and Caco-2), which demonstrate the prepared hybrid structure is safety in practical application. Our data indicate the great potential of UiO-67/NSC as an innocuous, bifunctional, smart adsorbent for the effective detection and removal of TC residues, and we not only provide a rational design of advanced metal organic framework-based hierarchical adsorbents, but also shed light on an available method to toxic antibiotic residue recognition and water remediation.
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JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
·
2025
·
IF 6.2
Chunqi Yu,Yingqi Wang,Ke Wang,Shuai Zhang,Xiaopeng Hu,Yiwei Liu,Jiajia Xi
Chlorpyrifos (CPF) poses severe environmental and health risks, driving the need for on-site monitoring tools. This study presents a novel dual-recognition colorimetric sensor for ultrasensitive detection of CPF by coimmobilizing molecularly imprinted polymers (MIPs) and aptamers onto bimetallic Fe,Zr-MOF composites. The resulting Fe,Zr-MOF/Apt/MIP hybrid synergistically merges the structural robustness of MIPs with the conformational specificity of aptamers, while also functioning as both a nanocarrier and a peroxidase mimic. Notably, CPF binding sterically hinders substrate diffusion to catalytic sites, enabling quantitative detection via dose-dependent inhibition of TMB oxidation. The optimized sensor exhibits exceptional performance: a broad linear range (1–120 ng mL–1), ultralow detection limit (0.105 ng mL–1), and high specificity against interferents. When validated with complex matrices (apples, pears, and cabbage), it achieved satisfactory recoveries (91.0–110.0%). This work establishes a field-deployable strategy for on-site pesticide monitoring in food and environmental safety.
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SENSORS AND ACTUATORS B-CHEMICAL
·
2019
·
IF 6.393
Baoshan He,Xiaoze Dong
In this work, the feasibility of a novel sensitive electrochemistry aptasensor for the detection of patulin (PAT) using hierarchically porous metal organic [email protected] blue connection aptamer as signal tags was demonstrated. The substrate electrode of the aptasensor was prepared by electrodeposited gold nanoparticles (AuNPs) on chitosan-zinc oxide nano flower-modified electrode. Subsequently, the complementary single-stranded DNA was attached to the surface of the modified electrode by Au-S bond. Signal tags self-assemble on the surface of modified electrodes by aptamer-cDNA binding, while methylene blue as mediator for electrochemical detection. Thanks to the large specific surface area provided by zinc oxide nano flower, the electrode can load more signal tags and AuNPs to achieve signal amplification. In presence of PAT, Apt preferentially binds to PAT, causing dissociation of some Apt-cDNA and releasing some signal tags leading, resulting in decreased electrical signals. Under optimal conditions, the change in electrochemical signal was proportional to the logarithm of PAT concentration, from 5 × 10 −8 -5 × 10 -1 μg mL −1 , and the detection limit was estimated to be 1.46 × 10 -8 μg mL -1 . The aptasensor exhibited aceptable reproducibility, renewability, long-term stability and specificity. Moreover, aptasensor was reliable in determination of PAT in spiked apple juice samples.
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APPLIED CATALYSIS A-GENERAL
·
2024
·
IF 4.7
Xin-Hao Shen,Feng Liu,Qin-Qin Chen,Ying Gao,Xiao-Wen Wang,Xin Liu
The efficient degradation of emerging pollutants in water, represented by CBZ, is receiving increasing attention from all sectors of society. Although advanced oxidation reactions represented by Fenton reaction can efficiently degrade emerging pollutants, the problem of iron sludge that comes with it is hindering the further promotion of this technology. Herein, UiO-66(Zr)-2OH material was synthesized by hydrothermal method and loaded with Pd 0 NPs on the surface of the material by in situ reduction. The MOFs-H 2 -Accelerated Catalytic Fenton system was constructed by accelerating the regeneration of Fe(II) in the system by activating the [H] produced by H 2 introduced into the system at room temperature and pressure. Within 180 min, the removal of the target pollutant CZB could reach more than 99 % under the condition of only 25 µmol of Fe(II) and 25 mmol of H 2 O 2 .
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Journal of the Taiwan Institute of Chemical Engineers
·
2022
·
IF 5.477
Yong Pan,Feng Liu,Yong Zhou,Chen Zhu,Haixia Pang,Baoming Xu
Background Phosphorus in wastewater is a major environmental concern. Very small phosphorus inputs in the environment can cause algal blooms that can deplete the dissolved oxygen and decrease the water quality, leading to eutrophication. Furthermore, some algal blooms produce toxins and bacterial growth that can cause human illness through exposure to contaminated water. Therefore, It is necessary to remove phosphorus before it is discharged to the environment. Methods adsorbent enhanced adsorptive ultrafiltration (UF) has recently emerged as an advanced ion recovery technology with membrane filtration function and adsorption function, and is very effective in removing cationic bisphosphate and anionic phosphate. Significant findings Herein, a novel defect-rich and covalently-crosslinked octanoic acid (OA)-UiO-66(Zr)-NH 2 /PVC adsorption ultrafiltration membrane are designed for removal of phosphate ions in water. The OA-UiO-66-NH 2 /PVC-33 membrane achieved the adsorption capacity (∼30 mgg −1 ) and higher removal efficiency (∼90%). The OA-UiO-66(Zr)-NH 2 /PVC ultrafiltration membrane exhibited a higher water flux of 266.9 L/(m 2 ·h·bar) compared to those of pristine PVC and UiO-66-NH 2 /PVC. Filtration and cyclic stability experiments reveal that OA-UiO-66(Zr)-NH 2 /PVC membrane can maintain a high retention capacity and exhibit excellent regeneration performance after 5 cycles.
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Acta Metallurgica Sinica-English Letters
·
2021
·Vol. 35
·期 3
·411-424
·
IF 2.755
Xu Rong,Li Ruidi,Yuan Tiechui,Zhu Hongbin,Li Ping
In order to refine the microstructure and improve the performance of direct energy deposited (DED) additively manufactured Al–Mg–Sc–Zr alloy, TiC-modified Al–Mg–Sc–Zr composites were prepared by DED and the effect of TiC content on the microstructure and performance was studied. In the absence of TiC particle, the microstructure of Al–Mg–Sc–Zr alloy prepared by DED consisted of fine grains with average size of 8.36 μm, and well-dispersed nano-Al 3 (Sc,Zr) particles inside the grains and Mg 2 Si phase along the grain boundaries. With the addition of 1 wt% TiC, the microstructure of TiC/Al–Mg–Sc–Zr prepared by DED became finer apparently compared with that without TiC; while the further increase of TiC content to 3 wt%, the microstructure of TiC/Al–Mg–Sc–Zr prepared by DED became coarser with appearance of a new kind of needle-like (Ti,Zr) 5 Si 3 phase. Also, the addition of TiC decreased the porosity of Al–Mg–Sc–Zr prepared by DED. Simultaneously, after the addition of TiC, the tensile strength increased from 283.25 MPa to 344.98–361.51 MPa, and the elongation increased from 3.61% to 9.58–14.10%. The potential mechanism of the microstructure evolution and strength improvement was discussed. This research will provide new insights into the available metal matrix composites by laser additive manufacturing (LAM).
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ACS Applied Materials & Interfaces
·
2025
·
IF 8.2
Huadong Fu,Rui Chen,Yong Xie,Zheng Wei,Yan Qin,Zhixiong Huang
Element-hybrid phenolic aerogel composites are often utilized as lightweight thermal protection materials for aerospace craft. Zr-phenolic (Zr-PR) aerogels have been extensively studied due to their exceptional high-temperature resistance. However, the phase transformation of ZrO2, the pyrolysis product of Zr-PR, caused the volume changes and internal stresses, greatly limiting the application of Zr-PR. In this work, a small amount of nano-Y2O3 particles was directly doped into the Zr-PR aerogel composites to form the nanoscale mosaic structure. This aerogel composite exhibited properties of low density (0.51 g/cm3) and low thermal conductivity (<0.151 W/(m K)); moreover, it showed a significant improvement in oxidative ablation resistance with a 33% reduction in the linear ablation rate. The research indicated that the doping of nano-Y2O3 effectively addressed the adverse effects associated with ZrO2 phase transformation by in situ rapidly forming (<60s) the dense yttria-stabilized zirconia (YSZ) thermal barrier layer on the ablation surface, which significantly delayed the thermal-oxidative ablation of the composites. Additionally, the pyrolytic carbon (PyC) on the ablation surface can form abundant multilayered graphene structures due to the catalytic graphitization effect produced by the solid-solution reaction of YSZ, which further enhanced the oxidation resistance. This work provides a simple and efficient approach to improve the ablation performance of Zr-PR aerogel composites, broadening their application in extreme thermal environments.
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TALANTA
·
2025
·
IF 6.1
Yuling Gao,Hui Xiao,Zhengang Han,Shuying Li,Shengya Zhang,Yaqi Zhao,Lei Zhang,Jing Chen,Xiaoquan Lu
In light of the critical necessity for precise detection of mercaptan in gasoline, due to its potential to induce metal corrosion and catalyst poisoning, this study investigates a novel methodology that employs resonance energy transfer (RET) between upconversion nanoparticles (UCNPs) and zirconium-based porphyrinic metal-organic frameworks (MOFs) to develop a highly sensitive and selective electrochemiluminescence (ECL) sensor. The NaYF 4 : Yb 3+ , Er 3+ @NaYF 4 @MOFs nanocomposite has been thoroughly characterized and exhibits enhanced ECL emission. This enhancement is attributed to the efficient RET between the UV-vis absorption of the Zr-based porphyrinic MOFs and the upconversion luminescence emission of the UCNPs. Upon interaction with mercaptan, the ECL signal experiences a significant decrease due to the interaction between mercaptan and Zr-based porphyrinic MOFs, leading to the quenching of the ECL signal. This phenomenon facilitates the sensitive detection of mercaptan within a linear range of 0.5 mg/L to 200 mg/L, with a low detection limit of 0.054 mg/L. The sensor demonstrates high selectivity and excellent stability, making it a promising tool for the quality control and environmental monitoring of mercaptan in gasoline.
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Journal of Energy Chemistry
·
2020
·
IF 7.216
Wenwen Lin,Siyu Yao,Hao Chen,Shenglai Li,Yang Xia,Yuan Yao,Jing Li,Dangguo Cheng,Jie Fu
Electrochemical nitrogen reduction reaction (NRR) to produce ammonia under ambient conditions is considered as a promising approach to tackle the energy-intensive Haber-Bosch process, but the low Faradaic efficiency and yield of NH 3 are still a challenge. Herein, a carbon-vacancies enriched mesoporous g-C 3 N 4 is developed by an in situ Zr doping strategy. The in situ mesoporous-forming mechanism is deeply understood by TPSR to reveal the functions of Zr dopant that pulls C from the precursor of C 3 N 4 , resulting the formation of homogeneous mesopores with about 57% of the one C-defective s-triazine ring in C 3 N 4 . Due to the defect sites obtained in metal doping synthesis, the RuAu bimetallic supported catalyst (RuAu 3 /0.3Zr-C 3 N 4 ) exhibits effective NRR performance with a Faraday efficiency of 11.54% and an NH 3 yield of 5.28 μg h −1 mg −1 cat. at −0.1 V (RHE), which is nearly 10 times higher than that of RuAu 3 /C 3 N 4 catalyst. This work proposes a simple and template–free preparation method for the high defect density mesoporous C 3 N 4 , and provides new possibilities of a wide application of mesopore g-C 3 N 4 .
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INORGANICA CHIMICA ACTA
·
2022
·
IF 3.118
Yu-Teng Zhang,Juan Zhu,Zhao-Yang Liu,Shuang-Bao Li,He Huang,Bao-Xu Jiang
For the first time, a microwave-assisted synthesis approach was used to prepare an amino-functionalized Zr-based metal–organic polyhedron (denoted as MW-ZrT-1-NH 2 ). The reaction time was shortened from 12 h to 2 min when compared to the traditional solvothermal method, resulting in crystalline products with good yield and purity. Herein, MW-ZrT-1-NH 2 was utilized as a photocatalyst for the catalytic reduction of Cr(VI) under visible-light irradiation. The results revealed that MW-ZrT-1-NH 2 exhibits better photocatalytic performance for Cr(VI) reduction. Furthermore, a plausible photocatalytic mechanism was proposed via electron spin resonance (ESR) measurements and radical trapping tests.
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JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
·
2022
·
IF 10.319
Tao Xiang,Peng Du,Zeyun Cai,Kun Li,Weizong Bao,Xinxin Yang,Guoqiang Xie
The contradiction between the strength and ductility of metallic materials is a major scientific problem that has been researched for a long time. Dual-phase equiatomic and non-equiatomic Ti-Zr-Nb-Ta high-entropy alloys (HEAs) with super-high strength and excellent ductility have been successfully developed via mechanical alloying (MA) combined with spark plasma sintering (SPS) technology. This is adjusted by altering the atomic ratios of the different phases. X-ray diffraction (XRD) and transmission electron microscopy (TEM) were performed to confirm the dual-phase microstructure. After the SPS process, the average grain size of the aforementioned equiatomic Ti 25 Zr 25 Nb 25 Ta 25 HEAs (134 ± 50 nm) evaluated by electron back-scattering diffraction (EBSD) is smaller than that of the Ti-Zr-Nb-Ta HEAs (150 µm), which were fabricated using arc melting. According to the Hall-Petch formula, the grain boundary strengthening contribution in the Ti-Zr-Nb-Ta system is 33-fold higher than those fabricated using the arc-melting process. When the alloy phase comprises the equivalent dual-phase, equiatomic Ti 25 Zr 25 Nb 25 Ta 25 HEAs have good comprehensive performance compared to non-equiatomic Ti-Zr-Nb-Ta HEAs prepared using the same process. The yield strength of equiatomic Ti 25 Zr 25 Nb 25 Ta 25 HEAs (2212 ± 38 MPa) is two-fold higher than that of Ti-Zr-Nb-Ta HEAs (1100 ± 90 MPa) fabricated via arc melting. This can be attributed to the ultra-fine grain size. Notably, the equiatomic Ti 25 Zr 25 Nb 25 Ta 25 HEAs possess approximately the same biocompatibility as commercial pure Ti (CP-Ti), indicating that the equiatomic Ti 25 Zr 25 Nb 25 Ta 25 HEAs are provided with a possibility as an advanced biomaterial for the applications of the medical field.
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