CHEMICAL ENGINEERING JOURNAL
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2023
·
IF 15.1
Girma Sisay Wolde,Dong-Hau Kuo,Merga Hailemariam Urgesa,Tadele Negash Gemeda
Simultaneous oxidation of benzyl alcohol (BA) and reduction of p-dinitrobenzene (p-DNB) over Gd-doped TiO 2 nanorods decorated with poly(o-phenylenediamine, PoPD) nanowires was reported in this work. The doping of TiO 2 with Gd induced surface defects, i.e., oxygen vacancy (OV) and the Ti 3+ –on-Ti 4+ site, while incorporating PoPD highly enhanced the light absorption capability and electron conductivity of TiO 2 nanorods , as confirmed by UV–vis diffuse reflectance spectroscopy (DRS) and electrochemical measurements, respectively. BA was selectively oxidized by photogenerated h + to form benzaldehyde with a yield of 70.5% in water and 90.6% in acetonitrile solvent. Conversely, p-DNB was selectively reduced to p-nitroaniline (p-NA) with a yield of 89.1% in acetonitrile and to p-phenylenediamine (p-PDA) of 85.0% yield in water. This work demonstrates a vital strategy to utilize the full economic potential of photogenerated charge carriers and the decisive role of solvent for product selectivity in the course of selective organic transformations.
研究领域:
化学工程
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环境科学
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材料科学
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产品关联
DOI
高影响因子
CHINESE CHEMICAL LETTERS
·
2014
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IF 1.178
Cheng-Xi Zhang,Yu-Yuan Deng,Yi-Yang Zhang,Po Yang,Yi Gu
To study the synthesis of 3,4-dihydro-2 H -3-phenyl-1,3-benzoxazine (benzoxazine), the reaction paths of phenol, aniline and formaldehyde were investigated by analyzing the synthesis crude products. With the aid of high-performance liquid chromatography (HPLC), chromatographic column and preparative HPLC, seven compounds originated from the crude products were obtained and their chemical structures were elucidated. Possible reaction paths are proposed based on these compounds. Results show that N -hydroxymethyl aniline (HMA) derived from the reaction of formaldehyde and aniline is probably the key intermediate during the reaction. HMA can react with itself or other reactants to form other intermediates, such as 1,3,5-triphenyl-1,3,5-triazinane and 2-((phenylamino)methyl)phenol, and further form benzoxazine and byproducts.
研究领域:
有机化学
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合成化学
✓ 已验证
DOI
高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2025
·
IF 3.9
Zhiming Ding,Danfeng Wang,Gang Wang,Runjuan Du,Chuanting Fan,Yaheng Zhang,Jie Zhang,Zhiyong Tang
Electrophotocatalysis, a burgeoning and sustainable technique in the field of organic synthesis, faces challenges in practical implementation due to technological and equipment limitations. This work introduces the design and engineering of an electrophotocatalytic flow microreactor for efficient synthesis of phenol from benzene in one step. The study explored the effects of microreactor configuration and various parameters, such as applied voltage, light intensity, and the concentrations of oxidant DDQ and electrolyte TBABF4. The innovative microreactor, characterized by a compact electrode gap and an expansive optical window, achieved a high phenol yield of 21.2% within a short residence time of 10 min, a significant improvement over the 14.3% yield obtained by a batch reactor in 6 h. The microreactor delivered a remarkable phenol productivity of 116.8 mmol h–1 L–1, outperforming all previous electrophotocatalytic synthesis records. Furthermore, a techno-economic analysis demonstrated that small-scale electrophotocatalytic synthesis of phenol reduced the per-unit production cost, displaying economic advantages competitive with the traditional cumene method. This work provides valuable insights into the engineering of flow microreactors for electrophotocatalysis and offers guidance for the potential industrial-scale application of electrophotocatalytic flow reactions.
研究领域:
有机合成
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化学工程
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可持续技术
✓ 已验证
产品关联
DOI
高影响因子
Micromachines
·
2022
·Vol. 13
·期 11
·1857
·
IF 3.523
Shisong Yu,Kai Zhang,Xiangcheng Cai,Peng Tu,Yuanming Zhou,Fei Mei
Organic-inorganic perovskite materials are widely used in the preparation of light-emitting diodes due to their low raw material cost, solution preparation, high color purity, high fluorescence quantum yield, continuously tunable spectrum, and excellent charge transport properties. It has become a research hotspot in the field of optoelectronics today. At present, the nonradiative recombination and fluorescence quenching occurring at the interface between the device transport layer and the light-emitting layer are still important factors limiting the performance of perovskite light-emitting diodes (PeLEDs). In this work, based on CH3NH3PbBr3perovskite, the effects of parameters such as precursor solution, anti-solvent chlorobenzene (CB), and small amine molecule phenylmethylamine (PMA) on the performance of perovskite films and devices were investigated. The research results show that adding an appropriate amount of PMA can reduce the grain size of perovskite, improve the coverage of the film, enhance the crystallinity of the film, and increase the fluorescence intensity of the perovskite film. When the PMA content is 0.050 vol.%, the maximum luminance of PeLEDs is 2098 cd/m2and the maximum current efficiency is 1.592 cd/A, which is greatly improved by 30% and 64.8% compared with the reference device without PMA doping. These results suggest that an appropriate amount of PMA can effectively passivate the defects in perovskite films, and inhibit the non-radiative recombination caused by the traps, thereby improving the optoelectronic performance of the device.Keywords:perovskite;phenylmethylamine;chlorobenzene;light-emitting diode
研究领域:
材料科学
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光学工程
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产品关联
DOI
PubMed
高影响因子
Food Analytical Methods
·
2020
·Vol. 13
·期 8
·1673-1680
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IF 2.667
Cheng Zhu,Ran Qin,Liu Jie,Deng Xing,Qiu Huidong,Jia Zhengfu,Su Xiaodong
Preservatives and sweeteners are always added in the food production process, which can extend the life and flavor of food. Benzoic acid and saccharin sodium are commonly used as preservatives and sweeteners respectively. Phenyllactic acid as a natural preservative, mainly produced by phenylalanine fermentation, may exist in fermented food. The objective of the current study is to develop a reverse-phase HPLC-UV method for simultaneous determination of benzoic acid, sorbic acid, phenyllactic, phenylalanine, and saccharin sodium in vinegar. They were separated on Sapphiresil TM (C 18 ) column (250 × 4.6 mm, 5 μm) with a mobile phase consisting of methyl alcohol:ammonium acetate buffer (pH 6.44; 0.02 M) (20:80, v/v) ran in isocratic mode at a flow rate of 1 mL/min. Complete baseline separation of five analytes was achieved in < 12 min, the linear range was 0.25–50 μg/mL with a correlation coefficient R 2 value > 0.9975, the method was validated with recoveries in the 96.93 to 118.42% range, and RSD was 0.39–6.21%. The detection limits of phenylalanine, benzoic acid, saccharin sodium, sorbic acid, and phenyllactic acid were 0.25, 0.01, 0.01, 0.025, and 0.05 mg/L. This method could be used for determining of benzoic acid, sorbic acid, phenyllactic acid, phenylalanine, and saccharin sodium in vinegar.
Graphical abstract
研究领域:
食品科学
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分析化学
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食品安全
✓ 已验证
DOI
高影响因子
Materials Research Express
·
2019
·Vol. 6
·期 12
·125101
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IF 1.449
Kai Huang,Lin Lin Guo,Dong Fang Wu
Different from the traditional aldimine condensation reaction, N-containing ligand: pyridine-2-formaldehyde was selected as the source of aldehyde group, and NH2-MIL-53(Al) containing a large number of amino functional groups was took as the carrier, transition metal Cu2+ coordinated with N-containing ligand to prepare a new and more stable MOFs catalyst named Cu@Al-MIL-53-P21. The catalyst exhibited a cross-linked nanorod morphology. The effect of the morphology on the catalytic oxidation activity of styrene was studied, the results showed that the catalyst could not only promote the production of benzaldehyde, but also inhibit the production of benzoic acid and phenylacetaldehyde. In addition, the optimal reaction conditions and the reaction mechanism were also discussed in this paper.
研究领域:
材料科学
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催化化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF SEPARATION SCIENCE
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2017
·Vol. 40
·期 20
·3938-3945
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IF 2.557
Yuxin Ma,Lingling Liu,Weiyang Tang,Tao Zhu
Sulfonated poly(styrene-divinylbenzene) modified with five kinds of amine functional groups was applied to the determination of carbendazim in apple samples with a pipette-tip solid-phase extraction method. The structures of the polymers were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and thermogravimetric analysis. Five different modifications of the solid-phase extraction sorbent based on sulfonated poly(styrene-divinylbenzene) were tested under static and pipette-tip solid-phase extraction conditions. The polymer modified with p -methoxyaniline showed the best recognition capacity and adsorption amount for carbendazim. Under the optimum conditions, 3.00 mg of the adsorbent, 1.00 mL of ethyl acetate as washing solvent, and 1.00 mL of ammonia/acetonitrile (5:95, v/v) as elution solvent were used in the pretreatment procedure of apple samples. The calibration graphs of carbendazim in methanol were linear over 5.00–200.00 μg/mL, and the limits of detection and quantification were 0.01 and 0.03 μg/mL, respectively. The method recoveries of carbendazim were in the range of 91.31–98.13% with associated intraday relative standard deviations of 0.76–2.13% and interday relative standard deviations of 1.10–1.85%. Sulfonated poly(styrene-divinylbenzene) modified with p -methoxyaniline showed satisfactory results (recovery: 97.96%) and potential for the rapid purification of carbendazim in apple samples combined with the pipette-tip solid-phase extraction.
研究领域:
分析化学
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食品科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
FLUID PHASE EQUILIBRIA
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2021
·
IF 2.775
Zhenxing Cai,Hui Zhao,Xin Zhou,Xiaobo Chen,Chaohe Yang
Solid-liquid equilibria of three binary mixtures consisting of para-xylene, ortho-xylene, meta-xylene and ethylbenzene were investigated in this study using differential scanning calorimetry (DSC) method, the mixtures were cooled to -120 °C and then heated to 20 °C at different heating rates, eutectic phase diagrams were observed for para-xylene/ortho-xylene and para-xylene/meta-xylene binary systems. The freezing point of pure ethylbenzene at atmospheric pressure is around -95 °C, but due to the effect of induction time, the observed freezing temperature is lower than -120 °C, the operation temperature of industrial xylene crystallization separation process is higher than -80 °C traditionally, therefore ethylbenzene will not crystallize in practical process, the phase diagram for para-xylene/ethylbenzene was not achieved. The experimental data were compared with data from other literatures and new features were found. The data were well correlated by Apelblat equation and λ H equation, it is significative to provide important engineering data for the separation and purification of xylene mixtures.
研究领域:
化学工程
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热力学
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产品关联
DOI
高影响因子
ENERGY & FUELS
·
2021
·
IF 3.605
Xuechun Ding,Shengchao Wei,He Bian,Lijun Zhu,Daohong Xia
Despite the studies on asphaltene aggregation throughout few decades, the formation of asphaltene aggregates and subsequent deposition are still the biggest challenges in the oil industry. Especially, the role of porphyrins existing in oil naturally on asphaltene aggregation is not completely understood due to asphaltene’s and porphyrin’s special structures. Herein, we investigated the influence of tetraphenylporphyrin (TPP), nickel tetraphenylporphyrin (NiTPP), and vanadium tetraphenylporphyrin (VOTPP) on asphaltene aggregation by a multiscale approach, which provides an in-depth understanding of the role of porphyrins on asphaltene aggregation. UV–vis spectroscopy and fluorescence spectroscopy were performed to examine the self-aggregation of TPP, NiTPP, and VOTPP and the influence of porphyrins on the aggregation of asphaltene. The changes of stacking structures, microscopic structures, and particle size distributions of co-aggregates of asphaltenes with porphyrins were analyzed in detail via X-ray diffraction, inverted fluorescence microscopy, and granulometric distribution, respectively. The characterization results indicated that the aggregation ability of the porphyrins (TPP, NiTPP, and VOTPP) was stronger than that of asphaltene and porphyrins can promote the aggregation of asphaltene, which leads to the increase of the average aromatic sheet number, aggregation morphology, and particle size of asphaltene aggregates. Based on experimental analysis, the possible mechanism by which porphyrins promoted asphaltene aggregation was elucidated. This research provided new insights into the aggregation and disaggregation of asphaltenes.
研究领域:
石油化学
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材料科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF POLYMER SCIENCE
·
2021
·Vol. 59
·期 13
·1434-1445
·
IF 0
Hongyu Jiang,Hanzhou Jiang,Guofei Chen,Xingzhong Fang
Two isomers of commercial 4,4′-(4,4′-isopropylidenediphenoxy) bis(phthalic anhydride) (4,4′-BPADA), that is, 3,4′-(4,4′-isopropylidenediphenoxy) bis(phthalic anhydride) (3,4′-BPADA) and 3,3′-(4,4′-isopropylidenediphenoxy) bis(phthalic anhydride) (3,3′-BPADA), were synthesized through aromatic nucleophilic substitution from nitrophthalonitrile and bisphenol A. 3,4′-BPADA was first synthesized from two intermediates, that is, 3-(4-[4-hydroxyphenylisopropylidene] phenoxy) phthalonitrile (3-BPADN) and 3,4′-(4,4′-isopropylidenediphenoxy) bis(phthalonitrile) (3,4′-BPATN). The corresponding three series of polyetherimides (PEIs) were prepared with two representative aromatic diamines (4,4′-oxydianiline and m -phenylenediamine ( m -PDA)) via two-step procedure and chemical imidization. Isomeric polyimides showed T g s from 206 to 256°C in nitrogen and T d5% s from 488 to 511°C in argon, good mechanical properties (tensile moduli of 2.3–3.3 GPa, tensile strengths of 70–96 MPa, and elongations at break of 3.2%–5.1%), and good solubility. With the introduction of 3-substituted phthalimide unit, PEIs displayed higher T g values, lower strengths and elongations, better solubility and larger d -spacings. The rheological properties of thermoplastic polyimide resins based on the BPADA isomers were investigated, which showed that polyetherimide PEI-3b derived from 3,3′-BPADA and m -PDA had the lowest melt viscosity among the isomers, indicating that the melt processibility had been greatly improved. Graphical
研究领域:
高分子化学
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材料科学
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高分子工程
✓ 已验证
DOI
JOURNAL OF MICROELECTROMECHANICAL SYSTEMS
·
2025
·
IF 3.1
Zhengrui Hu,Han Wang,Shan Li,Youjiang Liu,Chunjing Xu,Shaomin Liu,Jianhui Wei,Chilai Chen
By introducing the strengths of the vertical interconnection of TGV (Through Glass Via) technology into FAIMS (high-Field Asymmetric waveform Ion Mobility Spectrometry) chip manufacturing, we propose a wafer-level TGV-MS (multi-stack) FAIMS chip manufacturing method and achieve the wafer-level fabrication of 14 chips on a 6-inch glass wafer for the first time. The test results demonstrate that the TGV wafer manufactured based on this method shows excellent airtightness, electrical properties, and consistency with a leakage rate of $3.94\times 10 ^{-11}$ Pa $\cdot $ m3/s, a resistivity of $1.92\times 10 ^{-4}~\Omega \cdot $ cm. A single FAIMS chip volume is $4.8\times 1.6 \times 0.16$ cm3, weight is 2.28 g, the relative thickness error is less than 0.3%, and the parallelism error is less than 0.01°. Meanwhile, typical volatile organic compounds benzene and toluene were selected as samples to test the separation performance of the FAIMS chip, and the detection spectra under different gas concentrations and voltages were obtained. The experimental results show that the wafer-level FAIMS chip has a good resolution for benzene and toluene, and the linear detection range for the two samples is 0.1 ppm to 2 ppm (linear fitting coefficients 98.9%, 99.5%). The detection limit for benzene and toluene is 77 ppb. This paper solves the problem that microfluidic structures with electrodes cannot be manufactured at the wafer level due to side planar electrode leads, greatly simplifies the structure of the chip, realizes the mass production of FAIMS chips, and provides a technical reference for the wafer-level manufacturing of analysis sensors such as microfluidic chips with electrode structures and MEMS mass analyzers. [2024-0229]
研究领域:
微制造技术
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分析化学
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2020
·
IF 4.939
Shenglin Lu,Bin Zhao,Mingxing Chen,Lei Wang,Xian-Zhu Fu,Jing-Li Luo
Hydrogen generation from water electrolysis is attempted to be one of the replacement of sources as a clean fuel with high energy density . However, its application is limited by the high overpotential of oxygen evolution reaction (OER). Herein, hydrogen fuel is obtained from waste water by replacing OER with aniline electrochemical polymerization . Compared to the OER, the potential of aniline electro-polymerization greatly decreases 1240 mV at the current density of 30 mA cm −2 even using carbon paper electrode. Moreover, the Faradaic efficiency of hydrogen production is close to 100%. The as-prepared polyaniline demonstrates good performance as electrochemical capitative materials. This work provides efficient and lower energy consumed access to co-generate hydrogen and polyaniline in a convenient step by starting from the toxic and environmental-unfriendly wastewater.
研究领域:
环境科学
·
能源科学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）