SEPARATION AND PURIFICATION TECHNOLOGY
·
2023
·
IF 8.6
Lan li,Jie Sun,Hao Ling,Feng Ju
NiSO4/ZnO-Al2O3-SiO2 adsorbent, as a novel reactive adsorption desulfurization (RADS)adsorbent, has self-sulfidation ability and high desulfurization performance when treating model fuel. However, the RADS performance of the adsorbent under FCC gasoline feedstock is not well understood. Here, we compare the performance of the adsorbent under FCC gasoline with model fuel to test the effect of the hydrocarbon composition of the feedstock. The complex composition of FCC gasoline makes it sensitive to the nickel loading amount of the adsorbent. Under the influence of specific surface area and pore structure, the adsorbent loaded with 3 wt% nickel shows better desulfurization activity when treating FCC gasoline. As hydrocarbons in FCC gasoline compete with sulfur compounds for active Ni sites, the reaction conditions have been tested and optimized to achieve deep desulfurization while maintaining low olefin loss to ensure the octane number of the product. By experimental tests and characterization, it has been proved that NiSx and NiO acted as active Ni sites of the adsorbent. Based on these observations, the mechanism of RADS of FCC gasoline over NiSO4/ZnO-Al2O3-SiO2 adsorbent has been proposed, which provides theoretical support for the development of new adsorbents and the optimization of RADS process.
研究领域:
化学工程
·
环境科学
·
石油炼制
✓ 已验证
产品关联
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2025
·
IF 9
Weili Shao,Wanli Yue,Libing Ren,Gaohui Fan,Pengqi Shi,Jianxin He,Li Chen
Ceramic nanofiber sponges offer excellent resistance to temperature and corrosion resistance, rendering them suitable for various applications in heat insulation, sound absorption, and high-temperature filtration. However, traditional ceramic nanofibers are difficult to prepare and are inherently brittle at high temperatures, which significantly limits their development. Therefore, this study proposes a method of fabricating SiO 2 /Al 2 O 3 nanofiber (SANF) sponges using sol–gel processing and electrostatically assisted solution blow spinning (E-SBS). The prepared SANF sponges have a low density (10.63 mg cm −3 ), high compressibility, and low thermal conductivity. Moreover, they have excellent flexibility at − 196 ∼ 1300 °C, a strain-independent zero Poisson’s ratio, and good compression resilience without structural damage. Furthermore, with their low thermal conductivity (0.026 W m −1 K −1 ) and has good interception efficiency (> 99.3 %) against particles of different diameters at 1000 ℃. After undergoing electrostatic removal treatment, the SANF sponge demonstrates remarkable performance stability, maintaining filtration efficiency above 98 % while achieving an exceptional dust holding capacity of 101.2 g m −2 through 40 days of continuous operation. This breakthrough performance represents a significant advancement over conventional nanofiber membrane materials, which have historically suffered from limited dust retention capabilities. We prepared SANF sponges are promising candidates to replace existing thermal insulation and high temperature filtration materials, providing new insights for the development of next-generation thermal insulation and high temperature filtration materials.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF NUCLEAR MATERIALS
·
2025
·
IF 3.2
Shaobo Yang,Chenxi Liang,Jiali Li,Yujie Ma,Sijie Kou,Juanli Deng,Bo Chen,Shangwu Fan
The study investigated the corrosion behavior and mechanical performance of SiC/SiC composite joints with Y 2 O 3 -Al 2 O 3 -SiO 2 (YAS) interlayers under high-temperature steam environments at 1200 °C. Under low-flow conditions, partial disruption of Si-O and Al-O bonds in the YAS glass network reduced crosslinking, forming an aluminosilicate protective layer that inhibited further corrosion. Prolonged exposure led to Y 3+ migration and accumulation, resulting in Y 2 Si 2 O 7 precipitation and growth. High-flow conditions caused a thinner glass layer, continuous longitudinal cracks, and more severe erosion and dissolution of the YAS glass due to higher steam velocity. Despite these degradations, the joints exhibited satisfactory performance, maintaining shear strengths of about 40 ± 2 MPa after 15 h of low-flow exposure and about 36 ± 5 MPa after 5 h of high-flow exposure. These findings demonstrate that YAS interlayers provide excellent corrosion resistance and mechanical stability as a sealant for nuclear-grade SiC/SiC.
研究领域:
材料科学
·
工程学
✓ 已验证
DOI
高影响因子
FUEL PROCESSING TECHNOLOGY
·
2022
·
IF 8.129
Jia Wang,Jianchun Jiang,Xianzhi Meng,Su Shiung Lam,Arthur J. Ragauskas,Yanqin Wang
Chemical upcycling rubber wastes into hydrocarbon fuels offers a promising approach toward achieving carbon neutrality . To generate fuel-range cycloalkanes and isoalkanes from natural rubber glove wastes (NRGWs), the depolymerization of NRGWs was performed by integrating hydropyrolysis with vapor-phase hydrogenation over a bifunctional Ni/Al 2 O 3 -SiO 2 catalyst. Isoprene and limonene were the primary alkenes obtained from the non-catalytic hydropyrolysis of NRGWs, and these intermediates were vapor-phase hydrotreated over Ni/Al 2 O 3 -SiO 2 producing C 10 cycloalkane as the dominant fuel-range products. Complete hydrogenation of isoprene and limonene was achieved under a catalyst to feedstock mass ratio of 2.0, giving a maximum gasoline yield of 92 wt% under 225 °C hydrogenation temperature at 0.2 MPa H 2 . A low hydropyrolysis temperature of 450 °C maximized C 10 cycloalkane yield at 72.3 wt% with 80.1% selectivity, while a high temperature of 600 °C yielded 76.6 wt% C 5 isoalkane. A deconstruction mechanism in the catalytic cascade upcycling of NRGWs was proposed by employing limonene hydrogenation as a probe reaction. The results demonstrate that upcycling polymer wastes by cascade hydropyrolysis‑hydrogenation is a promising approach to produce alternative fuels with improved properties.
研究领域:
化学工程
·
环境科学
·
材料科学
·
能源技术
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2026
·
IF 6
Zhuoqing An,Xiaolong Ni,Zhuang Ma,Yuan Gao,Jiajing Chen
To investigate the effects of La 2 O 3 and Fe 2 O 3 on the structure and high viscosity of the CaO-MgO-Al 2 O 3 -SiO 2 (CMAS) glass system, the microstructure was analyzed using in-situ high-temperature Raman spectroscopy, and the viscosity was measured by high temperature hot-stage. A series of cluster models representing aluminosilicate systems modified by La and Fe ions were constructed, followed by geometric optimization and Raman spectral simulation via quantum chemistry ab initio calculations. The results indicates that the effects of La 2 O 3 and Fe 2 O 3 on both vibrational wavenumber and Raman scattering cross-section (RSCS) followed the order: La < (La + Fe) < Fe. The addition of La 2 O 3 and Fe 2 O 3 loose the glass network structure, and led to a progressive rise in the relative content of Q 0 , Q 1 , and Q 2 units, accompanied by a notable decrease in Q 3 and Q 4 units. Consequently, the high viscosity and viscous flow activation energy decrease with the addition of La 2 O 3 and Fe 2 O 3 , but Fe 2 O 3 has a more pronounced effect. Furthermore, based on the NBO/T for characterizing the microstructure, the relationship between viscosity and microstructure is quantitatively analyzed.
✓ 已验证
产品关联
DOI
高影响因子
MATERIALS CHEMISTRY AND PHYSICS
·
2024
·
IF 4.3
Yonghui Yang,Hengwei Yan,Pengchen Yang,Zhanwei Liu,Guang Yang
The segregation of aluminum-silicon alloys directly impacts the mechanical and chemical properties of the alloys, Therefore, homogenization of alloys is of great significance for alloys. This study initially investigated the electrochemical behavior of aluminum (III) and silicon (IV) during the preparation of aluminum-silicon (Al-Si) alloys in NaF-AlF 3 -Al 2 O 3 -SiO 2 molten salts through cyclic voltammetry and steady-state polarization. The results revealed that Al 2 O 3 underwent one-step reduction to Al, whereas SiO 2 underwent a two-step reduction process to Si. In addition, electrolysis experiments were carried out in a NaF-AlF 3 -Al 2 O 3 -SiO 2 -5wt%CaF 2 -1wt%MgF 2 -2wt%LiF molten salt system with molecular ratio of 2.4. These experiments involved variations in current density, electrolysis time, Al 2 O 3 and SiO 2 additions. It is worth noting that under the conditions of current density of 0.7 A/cm 2 , electrolysis time of 2 h, and silica addition of 2 %, the reduction rate of silicon reached a maximum value of 72.57 %, at which time the silicon in the aluminum-silicon alloys showed a dendritic structure, which was uniformly distributed throughout the entire alloy, and the segregation of the alloy was effectively avoided.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）