SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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2025
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IF 4.6
Yan Wu,Junshi Huang,Longwei Shang,Qi Chen,Fang Peng,Tiantian Liu,Zhijuan Luo,Muhua Liu,Jinhui Zhao,Shuanggen Huang
In this investigation, surface-enhanced Raman spectroscopy (SERS) combined with multivariate analysis was investigated for detection and characterization of ofloxacin residues in egg white. Gold nanoparticles (AuNPs) were meticulously synthesized to serve as the substrate for enhancing Raman signals, its average particle size was approximates 50 nm, and a significant absorption peak appears at 536 nm. The SERS characteristic peaks of ofloxacin were conducted using the density functional theory (DFT) calculations. In an effort to optimize the quantitative detection conditions for ofloxacin residues in egg white, the optimal detection parameters were determined via a single-factor experiment. Following a meticulous comparison of seven distinct spectral preprocessing methodologies, the utilization of adaptive iterative re-weighted penalized least squares (air-PLS) combined with savitzky-golay (SG) preprocessing for the spectral datawithin 400 to 1800 cm −1 were finally selected. The principal component analysis (PCA) helped establish an optimal support vector regression (SVR) model, which was subsequently employed to quantitatively detect the concentration of ofloxacin residues in egg white. It is noteworthy that the SVR model demonstrated outstanding performance metrics, with an R-squared prediction (R2 p) value of 0.9896, root mean square error of prediction (RMSEP) of 1.6246, and residual predictive deviation (RPD) of 8.1720. The adopted methods for detecting ofloxacin is feasible even below 0.5 mg/L. the findings indicate that the SERS-based multivariate analysis technique can swiftly and precisely identify the ofloxacin residues in egg white
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Journal of Environmental Sciences
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2020
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IF 4.302
Changsheng Feng,Chen Chen,Yu Zhu,Qi Cao,Chao Chen,Caiyun Jiang,Yuping Wang
Nitrogen-rich graphitized carbon microspheres (NGCs) with hierarchically porous were constructed by self-assembly. Under different heat treatment conditions, the structure, morphology and properties of NGCs were studied by using multiple characterization techniques. The results showed that the chemical microenvironments (e.g. surface chemistry, degree of graphitization and defective, etc.) and microstructures properties (e.g. morphology, specific surface area, particle size, etc.) could be delicately controlled via thermal carbonization processes. The degradation of ofloxacin (OFLX) by NGCs activated peroxymonosulfate (PMS) was studied systematically. It was found that the synergistic coupling effect between optimum N or O bonding species configuration ratio (graphitic N and C=O) and special microstructure was the main reason for the enhanced catalytic activity of NGC-800 (calcination temperature at 800°C). Electron paramagnetic resonance (EPR) experiments and radical quenching experiments indicated that the hydroxyl ( • OH), sulfate (SO 4 •− ) and singlet oxygen ( 1 O 2 ) were contributors in the NGC-800/PMS systems. Further investigation of the durability of chemical structures and surface active sites revealed that undergo N bonding species configuration reconstruction and cannibalistic oxidation during PMS activation reaction. The used NGC-800 physicochemical properties could be recovered by heat treatment to achieve the ideal catalytic performance. The findings proposed a valuable insight for catalytic performance and controllable design of construction.
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CHEMICAL ENGINEERING JOURNAL
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2020
·
IF 10.652
Peng Chen,Yejing Gou,Jiaming Ni,Yumeng Liang,Bingqiao Yang,Feifei Jia,Shaoxian Song
Base on the strong activation activity and affinity of transition metal ions and MoS 2 for peroxymonosulfate (PMS), respectively, Co(Ⅱ)-doped MoS 2 nano-flowers (Co-MoS 2 NFs) with a great photo-response property was facilely synthesized to achieve a more efficient PMS activation for ofloxacian (OFX) degradation. It was found that Co-MoS 2 NFs exhibits superior catalytic activity for OFX degradation under visible-light irradiation, which was attributed to the synergetic effect of doped Co(Ⅱ) and photo-generated carriers to PMS activation. Besides, Co-MoS 2 NFs was able to efficiently degrade OFX within 4 cycles in the presence of PMS while leaked minute amount of Mo and Co ions, implying the excellent cycle stability of Co-MoS 2 NFs. Furthermore, SO 4 •− and 1 O 2 were detected as the primary reactive radicals for OFX degradation in the Co-MoS 2 NFs-PMS system through EPR and quenching tests. This new strategy of coupling doped Co(Ⅱ) and photo-generated carriers for more efficient PMS activation, which will greatly benefit the development of SO 4 •− -based AOPs as well as cater to the demand for environmental remediation in the future.
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MOLECULES
·
2016
·Vol. 21
·期 7
·915
·
IF 2.465
Yan-Fei Wang,Huo-Xi Jin,Yang-Guang Wang,Li-Ye Yang,Xiao-Kun OuYang,Wei-Jian Wu
A new method for the isolation and enrichment of ofloxacin enantiomers from fish samples was developed using magnetic molecularly imprinted polymers (MMIPs). These polymers can be easily collected and rapidly separated using an external magnetic field, and also exhibit a high specific recognition for ofloxacin enantiomers. The preparation of amino-functionalized MMIPs was carried out via suspension polymerization and a ring-opening reaction usingrac-ofloxacin as a template, ethylenediamine as an active group, glycidyl methacrylate and methyl methacrylate as functional monomers, divinylbenzene as a cross-linker, and Fe3O4nanoparticles as magnetic cores. The characteristics of the MMIPs were assessed using transmission electron microscopy (TEM), X-ray powder diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), and vibrating sample magnetometer (VSM) measurements. Furthermore, the adsorption properties were determined using Langmuir and Freundlich isotherm models. The conditions for use of these MMIPs as magnetic solid-phase extraction (MSPE) sorbents, including pH, adsorption time, desorption time, and eluent, were investigated in detail. An extraction method using MMIPs coupled with high performance liquid chromatography (HPLC) was developed for the determination of ofloxacin enantiomers in fish samples. The limits of quantitation (LOQ) for the developed method were 0.059 and 0.067 μg∙mL−1for levofloxacin and dextrofloxacin, respectively. The recovery of ofloxacin enantiomers ranged from 79.2% ± 5.6% to 84.4% ± 4.6% and ofloxacin enantiomers had good linear relationships within the concentration range of 0.25–5.0 μg∙mL−1(R2> 0.999). The obtained results demonstrate that MSPE-HPLC is a promising approach for preconcentration, purification, and simultaneous separation of ofloxacin enantiomers in biomatrix samples.Keywords:magnetic solid-phase extraction;ofloxacin enantiomers;magnetic molecularly imprinted polymers;chiral HPLC
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PHYSICA B-CONDENSED MATTER
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2024
·
IF 2.8
Yongyi Li,Huixing Yang,Wei Li,Zhigang Shao,Yongzhuo Yu,Huixiang Yan,Shichao Jiao,Di Lin,Wenxu Zhang,Chaoyu Lv,Yuxin Huang
In this work, ultrathin lamellar g-C 3 N 4 /In 2 S 3 S-scheme heterojunctions doped with P were synthesized by urea recrystallization and investigated to see which ratio was more favorable for photocatalysis. The P doping formed a new Fermi energy level and reduced the forbidden bandwidth. The ultrathin lamellar structure facilitated rapid charge transfer, and the formation of S-scheme heterojunction, the presence of the interfacial electric field, and band bending effectively separated strong redox-capable electron-hole pairs, thus significantly improving the photocatalytic performance. Among the prepared materials, the 50UP-C 3 N 4 /In 2 S 3 photocatalyst with 50 % UP-C 3 N 4 mass fraction showed optimal photocatalytic H 2 production performance, with a hydrogen production rate of 12,387 μmol h −1 g −1 . Moreover, it showed good performance in photocatalytic degradation, with a degradation efficiency of up to 90.2 % of ofloxacin after 120 min of light exposure. This article provided a new perspective on the synthesis of other photocatalysts with carbazide-based S-scheme heterojunction structures.
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CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Nana Wang,Bing Wang,Xueyang Zhang
The combined contamination of antibiotics and heavy metals usually occurs in aquaculture wastewater and has high ecological toxicity. Currently, most research only focuses on the removal of a single heavy metal or antibiotics, and there is little research on the simultaneous removal of both. Therefore, to effectively treat them, this study prepared TiO 2 -loaded phosphogypsum-modified biochar (TYBC450) for adsorption and photocatalytic removal of ofloxacin (OFL) and copper (Cu 2+ ). The removal performance and mechanisms of OFL and Cu 2+ were explored, and their ecological toxicity was assessed through zebrafish acute toxicity experiments. The results suggested a synergistic effect between OFL and Cu 2+ . The adsorption efficiencies of TYBC450 for OFL and Cu 2+ were 88.16% and 90.87% (the adsorption capacities were 1.75 and 3.65 mg/g, respectively). Bridging, precipitation, and complexation effects were the main co-adsorption mechanisms. The photocatalytic efficiencies of OFL and Cu 2+ were 91.23% and 72.09% (the rate constants were 0.0101 and 0.0045 min - 1 , respectively). OFL acted as a hole-trapping agent, while Cu 2+ acted as an electron acceptor, hindering the combination of e - and h + . There were 12 intermediates in the OFL degradation process, which had lower toxicity than the mother organism. Both the cyclic regeneration and actual aquaculture wastewater application tests indicated that TYBC450 had potential application prospects.
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CHEMICAL ENGINEERING JOURNAL
·
2025
·
IF 13.2
Yixin Peng,Luwen Qian,Xianbo Sun,Long D. Nghiem,Fei Pan,Jing Ji,Yongdi Liu,Zhengqing Cai
This study introduces Cu into the CoFe 2 O 4 structure via a one-step hydrothermal method, creating a polymetallic (Cu/CoFe 2 O 4 ) catalyst with synergistic dual reaction centers. Material characterization reveals that Cu incorporation facilitates the formation and maintenance of low-valent Cu + and Fe 2+ species. Synergistic Cu + /Cu 2+ and Co 2+ /Co 3+ redox couples efficiently shuttle electrons, facilitating the rapid reduction of Fe 3+ (the rate-limiting step) and boosting H 2 O 2 activation efficiency across a wide pH range. The optimized Fenton system achieved complete ofloxacin (OFX) removal within 120 min and high mineralization under neutral conditions (pH 7), exhibiting a reaction rate 19 times higher than pristine CoFe 2 O 4 . The surface-bound •OH was identified as the primary reactive species (56 % contribution) and O 2 •− as secondary contributors. During the reaction, the •OH concentration reached 411 μM within the initial 5 min followed by slower accumulation, with the secondary reaction rate constant between •OH and OFX to be 1.55 × 10 10 M −1 ·s −1 . The O 2 •− generation rate was 1.81 × 10 −8 M·s −1 , and the secondary reaction rate constant between O 2 •− and OFX was 1.08 × 10 7 M −1 ·s −1 . The dominance of surface-bound •OH provides intrinsic tolerance to bulk solution pH fluctuations, explaining the system's high efficiency at neutrality. The material maintained over 95 % efficiency in continuous-flow pilot operation over 75 h, demonstrating exceptional potential for industrial implementation. Toxicity assessment via seed germination and theoretical calculation indicated reduced ecotoxicity of treated effluent. These findings highlight the material's broad pH adaptability, practical efficacy in complex water matrices, and potential for antibiotic wastewater remediation.
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SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2023
·
IF 4.4
Xiaoqi Lu,Yidan Ma,Shangkun Jiang,Zice Wang,Qian Yu,Chengcheng Ji,Jiaqi Guo,Xianming Kong
Ofloxacin is one kind of quinolone antibiotic drugs, the abuse of ofloxacin in livestock and aquaculture may bring bacterial resistance and healthy problem of people. The illegally feeding cattle with ofloxacin will help it keep health, but the sedimentation of ofloxacin could bring problem in food safety. The accurate, simple and instant monitoring ofloxacin from beef by portable sensor was of vital issue in food quality. A simple and reliable method was proposed for instant and quantitative detecting ofloxacin in beef, in which the thin-layer chromatography (TLC) -surface-enhanced Raman scattering (SERS) spectroscopy was in tandem with machine learning analysis base one principal component analysis-back propagation neural network (PCA-BPNN). The TLC plate was composed with diatomite, that was function as the stationary phase to separate ofloxacin from beef. The real beef juice was directly casted onto the diatomite plate for separating and detecting. The directly monitor ofloxacin from beef was achieved and the sensitivity down to 0.01 ppm. The PCA-BPNN was used as reliable model for quantitative predict the concentration of ofloxacin, that shown superior accuracy compared with the traditional model. The results verify that the diatomite plate TLC-SERS combined with machine-learning analysis is an effective, simple and accurate technique for detecting and quantifying antibiotic drug in meat stuff to improve the food safety.
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ACS Applied Nano Materials
·
2023
·
IF 5.9
Hengqiang Zhao,Ran Miao,Lidan Zhang,Rongyu Wang,Wenhua Ji,Xiaobei Ning,Yingchao Lv,Shaojun Zong,Xiao Wang,Zhaoyu Qiao
The effective removal of hydrophilic pollutants is of vital significance for environmental protection mainly because of the low efficiency of traditional sewage treatment methods. In this work, the cyano-vinylene-linked covalent organic polymer was prepared using 2,2′,2′′-(benzene-1,3,5-triyl)triacetonitrile (BTNA) and 2,4,6-tris(4-formylphenyl)-1,3,5-triazine (TFPT) as the Knoevenagel reaction monomers. The cyano group was then hydrolyzed to obtain a carboxyl-functionalized covalent organic polymer (COP-COOH). With good surface area (73.9 m2 g–1) and large channel (∼3.82 nm), TFPT-BTAN-COP-COOH showed fast adsorption equilibrium and high adsorption capacity for tobramycin and ofloxacin via multiple-functional binding sites. Specifically, the electrostatic interaction between the carboxyl group and basic groups (e.g., amino, piperazine, and dihydropyridine) plays a critical role for the selective removal of tobramycin and ofloxacin. The binding energies of TFPT-BTAN-COP-COOH adsorbed tobramycin and ofloxacin calculated using the density functional theory are −59.83 and −35.63 kcal/mol, respectively. For other aminoglycoside and quinolone antibiotics, such as enrofloxacin, norfloxacin, neomycin, and streptomycin, the removal rate can reach over 95% within 30 min using TFPT-BTAN-COP-COOH as the adsorbent. This work explored a promising strategy for the elimination of hydrophilic organic pollutants during environmental remediation.
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POLYCYCLIC AROMATIC COMPOUNDS
·
2019
·
IF 1.237
Chunmiao Zhu,Yinhai Lang,Ben Liu,Huaxuan Zhao
Chitosan/reed biochar composite (CRBC) was synthesized and employed as an adsorbent to remove ofloxacin (OFL) from aqueous solution. The physical and chemical properties of CRBC were characterized by SEM, FTIR, and BET surface area. The initial OFL concentration, solution pH, and ion strength affecting the adsorption process were investigated. Batch adsorption experiments revealed that OFL adsorption amounts on CRBC increased with the increasing of initial OFL concentration. Furthermore, the solution pH and ion strength had significant effects on OFL adsorption. The adsorption was enhanced in neutral pH condition and was inhibited by the presence of NaCl. The adsorption kinetics was fitted by the pseudo-second-order model with higher correlation coefficients. The adsorption isotherms were better described by the Langmuir model, indicating monolayer adsorption process. The aim of current work was to develop a reed biochar and chitosan composite and explore the adsorption behavior of OFL.
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JOURNAL OF MATERIALS SCIENCE
·
2024
·Vol. 59
·期 42
·19811-19824
·
IF 3.5
Liu Weinan,Zhang Haiyang,Yuan Hang,Wang Lidong,Li Zhen
Peroxymonosulfate (PMS) is widely used in advanced oxidation processes. Fe(II) is an excellent catalyst for PMS, and organic pollutants in water can be effectively degraded in the Fe(II)/PMS system. However, the pollutant degradation efficiency is limited by the low conversion efficiency of Fe(II). Natural antioxidants exist in the water environment and have strong electron-donating ability. At present, the research on the introduction of natural antioxidants into the advanced oxidation processes to degrade pollutants focuses on a few polyphenols, and the effects of other natural antioxidants on the removal of pollutants are worth studying. In this study, natural antioxidants, proanthocyanidins (PCs), saponins (SPs), and Lycium barbarum polysaccharides (LBPs), were introduced into the Fe(III)/PMS system. The reduction ability of natural antioxidants was used to improve the conversion efficiency of Fe(III) to Fe(II), and PMS was more effectively activated to produce ROS, which promoted the degradation of ofloxacin (OFL). After the introduction of PC in the Fe(III)/PMS system, 80% of OFL was degraded at 20 min, and 90% of OFL was degraded at 120 min after the introduction of SP. The experimental results showed that the degradation of OFL was affected by the amount of antioxidants, PMS and Fe(III), pH value, and coexisting anions. Free radical quenching experiments showed that 1 O 2 , SO 4 − ·, and ·OH play an important role in the degradation of OFL in the Fe(III)/antioxidant/PMS system. This paper proves that the introduction of proanthocyanidins and saponins into the advanced oxidation processes can remove organic pollutants more efficiently. Graphical
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SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Liusha Cen,Fan Yu,Yunying Luo,Chengcai Li,Guojin Liu,Wangyong Jin,Hailin Zhu,Yuhai Guo
The construction of a novel ofloxacin degradation catalyst coupled with photocatalysis and PMS activation is of great significance for the regeneration of water resources. A ternary metal (Co, Zn and Mo) sulfide heterojunction with biomimetic flower structure was synthesized using the solvent heat method. And then PVDF@CoZnMoSx membranes were synthetised by researched solvent-assisted nanoparticle embedding (SANE) method, which yielded efficient ofloxacian (OFX) degradation (97.1 %) by PMS activation. The effects of actual environment (such as co-exist ions, organic matter, and actual water matrices) on OFX degradation were observed, and PVDF@CoZnMoSx-3 (Zn:Co = 3:1, PCZM3) exhibited good tolerance for these factors and application value in practice. The pathways of OFX degradation were clarified by LC-MS analysis, and T.E.S.T software simulated the toxicity of the intermediates (P1-P20) gained from LC-MS, which substantiated the efficacy and safety of the PCZM3/PMS system in OFX degradation. The reusability and stability analysis displayed that the OFX degradation of PCZM3/PMS system was maintained in 5 consecutive cycles without additional treatment, and a small number of ions (Co, Zn and Mo) were leached during the OFX degradation. Totally, a new strategy was raised to construct multivariate metal sulfide membranes and couple the photocatalysis and PMS activation, which provided new insights for catalyst membranes to optimize performance.
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