COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2023
·
IF 5.2
Aijing Li,Xinpeng Chen,Yurong Sun,Jin Cheng,Ping Yao,Tieling Xing,Guoqiang Chen
An essential factor affecting the photocatalytic efficiency of a catalyst is the efficient separation of photogenerated electrons and holes. In the present study, a novel heterojunction material, PCN@GO/AgNPs, was synthesized with the aim of improving the photocatalytic performance. This achievement was accomplished through the establishment of a heterojunction between graphitic phase carbon nitride (PCN) and nano silver (AgNO 3 ). The PCN was prepared from melamine powder calcined at high temperature under nitrogen environment, and was modified by graphene oxide (GO) to form heterojunction with silver nanoparticles, which resulted in a significant improvement in the photocatalytic efficiency of the catalyst. Under ultraviolet（UV）excitation, the catalytic rate constant of PCN@GO/AgNPs heterojunction on RhB dye can reach 10.594 × 10 −2 min −1 . This research represents a promising strategy to increase the surface area of PCN photocatalysts through simply doping noble metal and thus improving photocatalytic performance, which contributes to understand the reaction mechanism of photocatalytic effect.
✓ 已验证
产品关联
DOI
高影响因子
Sustainability
·
2023
·Vol. 15
·期 17
·13034
·
IF 3.9
Tiantian Ye,Lihong Liu,Yilin Wang,Jianqiang Zhang,Zhenxing Wang,Cong Li,Haoyu Luo
In this study, an innovative method for RhB (Rhodamine B) degradation in a persulfate (PS) and hand warmer heterogeneous activation system was investigated. The hand warmer showed better catalytic performance and excellent reusability in terms of PS activation. The reaction rate constants of RhB removal in the hand warmer/PS process (0.354 min−1) were much faster than those in other PS- and Fe-related processes (0.010–0.233 min−1) at pH 7. The iron in the hand warmer is the main active ingredient to catalyze PS, and activated carbon, salt, and H+/OH−accelerate the activated reaction due to the formation of micro-batteries in the solution. Moreover, the catalyst of the hand warmer showed excellent stability and reusability with a low level of iron leaching. This new, effective, inexpensive, repeatable, and environmentally friendly catalyst combined with PS has promising prospects for the removal of dyes from industrial wastewater.Keywords:heterogeneous activation;persulfate;hand warmer
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Nano Materials
·
2018
·
IF 0
Shining Ni,Tiantian Zhou,Haonan Zhang,Yongqiang Cao,Ping Yang
By virtue of the facile anion-exchange technique, smart BiOI/BiVO4 two-dimensional (2D) heteronanostructure (HNS) photocatalysts targeted for the degradation of organic pollutants have been developed by the in situ growth of BiVO4 on the scaffolds of BiOI nanoplates. The as-obtained BiOI/BiVO4 HNSs exhibited excellent 2D structure as templates of BiOI nanoplates and well structure stability due to the in situ growth pattern of BiVO4 on BiOI. The 2D HNSs exhibited superior photocatalytic activities, especially the V/I8 2D HNSs (V:I = 80%), exhibited the highest Rhodamine B (RhB) and salicylic acid (SA) degradation rates, which are 29.8 times (RhB) and 15.7 times (SA) those of the individual BiVO4 and 6.4 times (RhB) and 10 times (SA) those of BiOI, respectively. Such excellent photocatalytic activities should be attributed to the organic combination of the 2D structure and heterojunction, as verified by the detailed morphology and composition characterizations. The well-known unique advantages of 2D nanostructures such as efficient light harvesting, quick reactant transport, exposure of plenty of surface reactive sites, and significantly reduced perpendicular migration distances of photogenerated carriers from the interior to the surface of materials, coupled with enhanced carrier separation behavior due to the built-in field at the heterointerface endow the 2D HNSs with ultrastrong photocatalytic abilities. It is hoped that our work could offer a paradigm for the development of smart 2D HNS optoelectronic functional materials used in photosynthesis, solar cells, sensors, catalysis, and so on, in the future.
✓ 已验证
产品关联
DOI
APPLIED SURFACE SCIENCE
·
2014
·
IF 2.538
Xiuying Liu,Dan Yu,Yingchao Yu,Shujuan Ji
A novel magnetic molecularly imprinted polymer (MMIP) was developed as an adsorbent to selectively remove rhodamine B from real samples. The polymer was characterized by scanning electron microscopy, Fourier-transform infrared spectroscopy, and thermo-gravimetric analysis. Static adsorption, kinetic adsorption, and selective recognition experiments were also performed to investigate the specific adsorption equilibrium, kinetics, and selective recognition ability of the MMIP. The MMIPs had outstanding thermal stability, large adsorption capacity, and high competitive selectivity. When they were used as dispersed solid-phase extraction adsorbents in real samples, rhodamine B recovery was 79.97–81.88% and 75.56–79.74% in intra-day and inter-day reproducibility experiments with relative standard deviations lower than 2.62% and 4.28%, respectively. Extraction was optimized for yield and efficiency. Precision, accuracy, and linear working range were determined under optimal experimental conditions. The limits of detection and quantification were 1.05 and 3.49 μg L −1 , respectively. These results suggest MMIPs may be used for determination of rhodamine B in real samples.
✓ 已验证
产品关联
DOI
高影响因子
ACS Omega
·
2024
·
IF 3.7
Xin Zhao,Yishuai Jing,Zhonghua Dai,Yuanbo Chu,Zhenyu Liu,Yu Cong,Jiaming Song
As a wide-bandgap rare-earth oxide, Eu2O3 was often utilized as an auxiliary material of other photocatalysts because its photocatalytic performance was limited by the luminescence characteristics of Eu3+ and low light utilization. In this study, we improved the photocatalytic degradation performance of the Eu2O3 nanoparticles by doping with Fe cations. The Eu2O3 nanoparticles with different Fe-doping concentrations (1, 3, and 5%, noted as EF1.0, EF3.0, and EF5.0, respectively) were synthesized via chemical precipitation and calcination methods. It was found that doping could reduce Eu2O3’s bandgap, which probably originated from the introduction of oxygen vacancies with lower energy levels than the conduction band of Eu2O3. Compared with the undoped Eu2O3 nanoparticles with a removal efficiency of 22% for degrading rhodamine B dye within 60 min, the photocatalytic degradation efficiencies of EF1.0, EF3.0, and EF5.0 were demonstrated to be improved to 42, 48, and 33%, respectively, and EF3.0’s performance was the best. The enhanced photocatalytic performance of the doped samples was related to the oxygen vacancies acting as capture centers for electrons, such that the photogenerated electron–hole pairs were efficiently separated and the redox reactions on the surface of the nanoparticles were enhanced accordingly. Additionally, the enhanced light absorption and broadened spectral band further improved EF3.0’s degradation efficiency.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ENVIRONMENTAL RESEARCH
·
2024
·
IF 7.7
Lei Wang,Yang Ruan,Zenghui Diao,Diyun Chen,Lingjun Kong
Supported Co-based catalysts have shown attractive prospects for peroxymonosulfate (PMS) activation. In this work, Co-doped hydroxyapatite (H-Co/HAP) composites were prepared by a simple hydrothermal method. The Co content in H-Co/HAP could reach 71.2 mg/g, while the Co leaching rate remained relatively low. By right of the excellent catalytic performance, the as-prepared H-Co/HAP could achieve 99.02% degradation of Rhodamine B (RhB) within 10 min in the presence of 0.5 mM PMS and a first-order kinetic rate constant of 0.876 min −1 . Even after 8 cycles, the RhB degradation efficiency remained at 81.96%. In addition, the effects of vital reaction parameters, including catalyst dosage, PMS dosage, initial pH, humic acid, and coexisting anions, on the catalytic performance in the H-Co/HAP10/PMS system were systematically investigated and discussed. The degradation mechanism of a non-radical ( 1 O 2 ) as the dominant active specie and a radical (•O 2 − and SO 4 •− ) as the minor active specie was identified through quenching experiments and electron paramagnetic resonance testing. Moreover, possible degradation pathways of RhB were proposed in the H-Co/HAP10/PMS system. Overall, this study offers a meaningful strategy for designing high-content Co-based catalysts to degrade dye molecules in wastewater.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Green Processing and Synthesis
·
2025
·Vol. 14
·期 1
·
IF 3
Fuhua Wei,Yan Wang,Qinhui Ren,Qin Zhang,Hongliang Chen,Zhao Liang
Cr/Co-MOFs were synthesized via a solvothermal method using chromium acetate and cobalt chloride hexahydrate as metal ions, and trimeric acid as the organic ligand. The structures of Cr/Co-MOFs were characterized using Fourier infrared spectroscopy, X-ray diffraction, and scanning electron microscopy techniques. These Cr/Co-MOFs were used for removing organic contaminants in wastewater treatment. Fleroxacin and Rhodamine B (RhB) were specifically selected as target molecules in this study to evaluate the removal efficiency based on the mass of Co/Cr-MOFs, concentrations of organic contaminants, and adsorption time. Experimental findings indicated that at a Co/Cr-MOFs dosage of 100 mg, with initial concentrations of Fleroxacin (30 ppm) and RhB (20 ppm), removal efficiencies achieved were 95% and 99%, respectively. Within a timeframe of 5 h, Co/Cr-MOFs attained adsorption capacities amounting to 269.6 mg·g −1 for fleroxacin and 289.5 mg·g −1 for RhB. The interaction between Co/Cr-MOFs and fleroxacin, as well as RhB, is primarily attributed to factors such as pore size, hydrogen bonding, electrostatic charge, and π–π interactions. Moreover, theoretical analysis corroborated these experimental results by demonstrating conformity between the adsorption process and both second-order kinetic model equations alongside Langmuir isotherm model equations. Collectively, the experimental data combined with theoretical investigations underscore the practical significance associated with employing Co/Cr-MOFs for effective eradication of organic pollutants.
✓ 已验证
产品关联
DOI
高影响因子
Russian Journal of Physical Chemistry A
·
2014
·Vol. 89
·期 2
·291-296
·
IF 0.488
Sun C. H.,Wang M. L.,Feng Q.,Liu W.,Xu C. X.
The SERS signals of Rhodamine B (RhB) adsorbed on Ag, ZnO, and Ag-capped ZnO (ZnO/Ag) substrates were studied. Comparative analysis indicated no significant difference in the positions of the peaks, but the intensities of SERS signals are different. However, abnormal Raman spectrum of RhB (10 −4 M) adsorbed on ZnO was observed, which was different from the normal Raman spectrum distinctly. By assignment of the vibrational bands of abnormal Raman spectrum, it is suggested that the nitrogen atom is primarily adsorbed on the ZnO substrate instead of the xanthene ring.
✓ 已验证
DOI
高影响因子
ADVANCED POWDER TECHNOLOGY
·
2019
·
IF 3.25
Cuiling Ai,Sikai Yang,Fan Zhang,Xiangwen Shao,Junge Xu
Ag/AgCl-GO composite was fabricated by deposition–precipitation method and photoplasmic reduction method at room temperature. The resulting products were characterized by XRD, XPS, SEM, TEM, Zeta potential and UV–Vis DRS. The results indicated that the samples were composed of Ag, AgCl and graphene oxide (GO). During the photoreduction, the crystallinity of Ag 0 particles gradually increased with prolonging the time of UV irradiation, then remained stable after 90 min. The addition of GO had little effect on the crystal structure of Ag/AgCl, however, this reduced the particle size and enhances the dispersibility of the composite. After 100 min of visible light irradiation, the degradation efficiency of rhodamine B (RhB) reached 98.43%. Therefore, the Ag/AgCl-GO photocatalyst exhibited significant photocatalytic activity during the degradation of RhB under visible light.
✓ 已验证
DOI
高影响因子
DIAMOND AND RELATED MATERIALS
·
2023
·
IF 4.1
Xiaoxiao Gao,Yan Zhang,Zheng Fu,Jiashuo Tian,Liuping Zhang,Wanqiong Li,Shuailiang Li,Fengling Cui
In this paper, rhodamine B (RhB) was modified on carbon dots (CDs) by hydrothermal method , and a double emission ratiometric fluorescent probe (RhB-CDs) with red luminescence was successfully constructed. The synthesized RhB-CDs had exceptional optical properties and exhibit two emission peaks (480 nm and 590 nm) at 350 nm excitation. It could be used for ratiometric detection of MnO 4 − and Cr 2 O 7 2− , and the fluorescent color would also change (red to orange) when the pH changed from 6 to 7, showing great application potential in the field of sensing and detection. Moreover, the ratio of the emission peak fluorescence intensity had a linear relationship with the water content of alcohols, which was successfully used to detect actual water samples. In addition, the synthesized RhB-CDs had low cytotoxicity and were successfully used for multicolor cell imaging .
✓ 已验证
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2021
·
IF 6.953
Xianyi Zhu,Lihua Zhang,Guanglong Zou,Qin Chen,Yuanlong Guo,Songmiao Liang,Lijie Hu,Michael North,Haibo Xie
Facile preparation of functional hydrogel materials for environmental catalysis is a hot research topic of soft materials science and green catalysis. In this study, a carboxylcellulose hydrogel confined Fe 3 O 4 nanoparticles composite catalyst (Fe 3 O 4 @CHC) with magnetic recyclability has been synthesized by taking the advantages of the newly developed cellulose solution in tetramethyl guanidine/DMSO/CO 2 through in situ acylation using mixed cyclic anhydrides and ion exchange reaction. The achieved Fe 3 O 4 @CHC hydrogel catalyst was shown to be an more efficient and better Fenton-like catalyst for decomposition of the organic dye rhodamine B (RhB) in the presence of hydrogen peroxide, with almost complete decomposition occurring within 180 min, in comparison with Fe 3 O 4 @cellulose hydrogel (CH) with excellent recyclability. This work provided a facile strategy for the preparation of hydrogel-based functional composite green catalytic materials, which has potential applications in green catalysis.
✓ 已验证
DOI
高影响因子
FIBERS AND POLYMERS
·
2022
·Vol. 23
·期 10
·2809-2819
·
IF 2.347
Yang Yuhui,Chen Hongbin,Zhang Ruquan,Huang Jingjing,Bai Zhikui,Xiao Shili
The ferric ions sludge produced during pollutants degradation was an obstacle for large scale application of Fenton oxidation technology. Herein, we reported a facile method using 2,2,6,6-tetramethylpiperidine-1-oxygen radical (TEMPO)-oxidized cotton fabric as a substrate for anchoring Fe(II) ions to produce Fe(II)-anchored cotton fabric. The formation of Fe(II)-anchored cotton fabric was confirmed using EDS analysis and FTIR measurement. Bath experiments indicated that Fe(II)-anchored cotton fabric could Fenton oxidize rhodamine B (RhB) dye in a high efficient rate (95.9 %) within 60 min without second pollution. Fe(II)-anchored cotton could be reused without any physical/chemical treatment and its decolorization efficiency was retained at 89.9 % even after the third cycle. Moreover, the decolorization behavior of Fe(II)-anchored cotton fabric for the RhB solution was affected by H 2 O 2 dosage, Fe(II) ion content, and inorganic salts. Kinetic study indicated that the RhB decolorization process fits a pseudo-first order well and the sorption isotherm assessment revealed that the reactive sorption of RhB dye on Fe(II)-anchored cotton fabric fits the Freundlich model.
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）