JOURNAL OF MOLECULAR LIQUIDS
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2020
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IF 5.065
Chen Wang,Guo Lin,Yunhao Xi,Xiteng Li,Zhen Huang,Shixing Wang,Jiling Zhao,Libo Zhang
A novel Zr-MOF adsorbent was synthesized by one-step method and was used to selectively adsorb Hg(II) and Pb(II) from wastewater. The adsorbent can reduce the concentration of mercury and lead to less than the national standard (Hg is 50 μg/L and Pb is 1 mg/L). The entire adsorption process conforms to the pseudo second-order kinetic and Hill isotherm models. At pH 4, the adsorbent removed more than 90% of mercury (to 22 μg/L) and lead (to 0.732 mg/L) in 10 min and 960 min, and the maximum adsorption capacity was 1080 mg/g and 510 mg/g, respectively. In addition, the practical application in wastewater proved that the adsorbent can selectively adsorb Hg(II) and Pb(II) from the mixed ion solution and it still meets national standards for wastewater discharge. The research of repeated experiments proves that the adsorbent can be used repeatedly. The adsorption mechanism was clarified by FTIR, XPS spectroscopy before and after adsorption, and density functional theory (DFT) calculation. In summary, the adsorbent is stable in aqueous solution and has great potential for the efficient removal of trace heavy metal ions (mercury and lead) in future treatment of wastewater.
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JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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2020
·Vol. 31
·期 11
·8464-8471
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IF 2.22
Si Shufang,Deng Hongmei,Wang Tiantian,Yang Pingxiong,Chu Junhao
Perovskite compounds Bi 0.7 A 0.3 FeO 3−δ (BAFO) (A = Ca, Sr, Pb, and Ba) with improved optical and magnetic properties have been synthesized by solid-state method. The effect of bivalent ions substitution on the phase transition, microstructure, optical, and magnetic properties are investigated in detail. X-ray diffraction and Raman scattering spectra analyses indicate the phase transition from rhombohedral to cubic in doped samples and the coexistence of the two phases in BBFO, inducing strong lattice distortions. A blue shift observed in d–d transitions energies can reveal the decreased internal chemical pressure, thus leading to the slight increase in bandgaps of BSFO, BPFO, and BBFO. While, narrowed bandgap of 1.96 eV can be found in BCFO for the increased tailing of the conduction band edge into the gap. Besides, room-temperature ferromagnetism has been observed in Sr-, Pb-, and Ba-doped samples which can be resulted from the suppression of spiral structure of BFO. These results lay a solid foundation on further exploring the potential abilities of BFO ceramics as multiferroic photovoltaic materials.
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BIOCONJUGATE CHEMISTRY
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2020
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IF 4.031
Atheer Hameid Odda,Hailiang Li,Naveen Kumar,Naseeb Ullah,Malik Ihsanullah Khan,Gang Wang,Kuang Liang,Tan Liu,Yue-Yin Pan,An-Wu Xu
Exploring a combined phototherapeutic strategy to overcome the limitations of a single mode therapy and inducing high anticancer efficiency is highly promising for precision cancer nanomedicine. However, a single-wavelength laser activates dual photothermal/photodynamic therapy (PTT/PDT) treatment is still a formidable challenge. Herein, we strategically design and fabricate a multifunctional theranostic nanosystem based on chlorin e6-functionalized polydopamine (PDA) coated prussian blue/manganese dioxide nanoparticles (PB-MnO2@PDA-Ce6 NPs). Interestingly, the obtained PB-MnO2@PDA NPs not only offer an effective delivery system for Ce6 but also provide strong optical absorption in the near-infrared range, endowing high antitumor efficacy of PTT. More importantly, the as-prepared PB-MnO2@PDA-Ce6 nanoagents exhibit an effective oxygen generation, superior reactive oxygen species (ROS), and outstanding photothermal conversion ability to greatly improve PTT and PDT treatments. As a result, both in vitro and in vivo treatments guided by MR imaging on liver cancer cells reveal the complete cell/tumor eradication under a single wavelength of 660 nm laser irradiation, implying the simultaneous synergistic PDT/PTT effects triggered by PB-MnO2@PDA-Ce6 nanoplatform, which are much higher than individual treatment. Taken together, our phototherapeutic nanoagents exhibit an excellent therapeutic performance, which may act as a nanoplatform to find safe and clinically translatable routes to accelerate cancer therapeutics.
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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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2020
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IF 5.162
Hongling Zhang,Jianzhe Ma,Fengyun Wang,Yuting Chu,Lei Yang,Mingzhu Xia
The carboxymethyl-chitosan-montmorillonite (CMC-MMT) organic-inorganic hybrid material was applied to adsorb Pb(II) and Congo red (CR) anionic dye from aqueous solution. Molecular dynamics(MD) simulation was carried out to reveal the mechanism of CMC hybrid MMT. The results suggested that CMC has been adsorbed on the interlayer space and surface of MMT, hydrogen bonds had been formed between hydroxyl & carboxyl groups of CMC with the surface of MMT, Van der Waals interaction was also existed, while amino groups of CMC hadn't obvious interaction with the surface of MMT. Batch experiments were executed to investigate the adsorption effect of CMC-MMT was compared with Na-MMT and CMC. The results showed that CMC-MMT exhibited the higher adsorption capacity than Na-MMT and CMC, The OH and COOH or NH 2 groups of CMC chains may serve as electrostatic interaction active sites and coordination sites, which improved the adsorption performance of CMC-MMT on Pb(II)，and the insertion of CMC enlarged the inter-layer space of MMT, resulting in more surface active sites in the CMC-MMT hybrid composite, which increased the adsorption of organic pollutant CR. The kinetic and isotherm studies indicated that the pseudo-second-order and the Langmuir model well described the adsorption equilibrium of Pb(II) and CR on CMC-MMT.
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RSC Advances
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2021
·Vol. 11
·期 47
·29590-29597
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IF 3.361
Chuanen Guo,Chengxiang Wang,Hongyan Sun,Dongmei Dai,Hongtao Gao
High-performance electrode modification materials play a crucial role in improving the sensitivity of sensor detection in electrochemical determination of heavy metals. In this study, a rGO/MoS2/CS nanocomposite modified glassy carbon electrode (GCE) was used to construct a sensitive sensor for detecting lead ions in tobacco leaves. The reduced graphene oxide (rGO) was used to increase the conductivity of the sensor, and the nano-flowered MoS2 could provide a large reaction specific surface area and a certain active site for heavy metal reaction. Chitosan (CS) was used to improve the enrichment ability of heavy metals and increase the electrocatalytic activity of electrode. Thus, an electrochemical sensor with excellent performance in reproducibility, stability and anti-interference ability was established. The stripping behavior of Pb(II) and the application conditions of the sensor were studied by square wave anodic stripping voltammetry (SWASV). The investigation indicated that the sensor exhibited high detection sensitivity in the range of 0.005–0.05–2.0 μM, and the limit of detection (LOD) was 0.0016 μM. This work can provide a fast and effective method for determination of Pb(II) in samples with low content, such as tobacco leaves.
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JOURNAL OF ENVIRONMENTAL MANAGEMENT
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2019
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IF 4.865
Yasir Hamid,Lin Tang,Bilal Hussain,Muhammad Usman,Muhammad Laeeq ur Rehman Hashmi,Muhammad Bilal Khan,Xiaoe Yang,Zhenli He
The present study evaluated the efficiency of pre-selected composite amendments (CA-1: biochar-lime-sepiolite-zeolite and CA-2: manure-lime-sepiolite) for immobilization and sorption of Cd and Pb in field and batch sorption experiments. The field experiment was performed in a co-contaminated clay purple soil (stagnic anthrosols). Along with a control experiment (T1), CA-1 and CA-2 were tested at different rates including 750, 1500, 3000 and 6000 kg ha −1 by growing wheat as the test crop. The obtained results revealed that the highest dose of both composites (T5: 6000 kg ha −1 and T9: 6000 kg ha −1 ) increased the soil pH to 6.85 and 6.81, respectively as compared to the control (5.63). DTPA-extractable Cd and Pb contents decreased with composite treatments (T7 and T4) at harvest stage samples. Metal fractionation depicted that application of amendments decreased the exchangeable fraction at harvesting stage. Application of CA-2 and CA-1 (3000 kg ha −1 ) significantly increased the plant biomass (by 28% and 24%, respectively) and grain yield (by 26% and 22%, respectively) of wheat. Furthermore, batch sorption experiment results revealed that Langmuir adsorption model better fitted the sorption results with R 2 values ranging between 0.99 and 0.91 for Cd and Pb, respectively. CA-1 and CA-2 exhibited the maximum adsorption capacity for Cd with no significant difference among treatments but Pb adsorption capacity was highest in CA-1 followed by CA-2 and control. The results of our experiments revealed that the application of organics combined with inorganic materials enhanced Cd and Pb immobilization and sorption, consequently reducing metals availability in laboratory and field conditions. Moreover, for field trials, application of the composite amendments at 3000 kg ha −1 emerged as the suitable treatment for tested wheat-grown area.
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FOOD CHEMISTRY
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2019
·
IF 5.399
Danyu Zhang,Shiwei Yang,Qingfang Ma,Jiannan Sun,Heyong Cheng,Yuanchao Wang,Jinhua Liu
This work establishes a hyphenated methodology coupling HPLC with ICP-MS for simultaneous speciation analysis of arsenic, mercury and lead for the first time. Four arsenicals (As(III), DMA, MMA and As(V)), four mercurials (Hg(II), MeHg, EtHg and PhHg) and three lead compounds (Pb(II), TML and TEL) were simultaneously analyzed within only 8 min with acceptable resolution (2.0–8.2 for As, 1.6–6.1 for Hg and 2.7–4.0 for Pb). The detection limits were 0.036–0.20 for As-species, 0.023–0.041 for Hg-species, and 0.0076–0.14 μg L −1 for Pb-species. The developed method was applied for the measurement of five lotus seed samples, indicating the presence of DMA (19.6–28.2 μg kg −1 ), TML (1.4–2.9 μg kg −1 ), MeHg (1.2–4.8 μg kg −1 ) and EtHg (0.8–2.2 μg kg −1 ). This method provides a promising tool for studying the toxic, metabolic and bioavailable behaviors of arsenic, mercury and lead.
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INORGANIC CHEMISTRY COMMUNICATIONS
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2019
·
IF 1.795
Yaxiao Zhang,Chao Li,Yingchun Su,Wei Mu,Xiaojun Han
Heavy metal pollution causes serious health threat to humanbeings. Herein we fabricated a novel bismuth oxycarbide (BOC) modified glassy carbon electrode (GCE) for the simultaneous detection of cadmium and lead ions using differential pulse anodic stripping voltammetry (DPASV). The main factors influencing the detection performance, such as solution pH, deposition voltage and deposition time were optimized to be 4.5, −1.3v, and 700s, respectively. The detection limits for lead ions and cadmium ions were 4.30 μg/L and 3.97 μg/L, respectively. These detection limits are both lower than 5 μg/L for cadmium ions and 10 μg/L for lead ions national standards. The BOC modified GCE exhibits good selectivity and reliability for the detection of lead ions and cadmium ions. BOC/GCE may find great potential for heavy metal ions detection in real water sample.
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JOURNAL OF HAZARDOUS MATERIALS
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2019
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IF 7.65
Jiujiang Ji,Guo Chen,Jun Zhao
To explore the effect of coexisted amino and thiol groups on adsorption of heavy metal, a novel magnetic nanoparticle was prepared by sequentially modification with (3-Chloropropyl) trimethoxysilan, polyetherimide, epichlorohydrin and thiourea. Subsequently, it was characterized by TEM, N 2 adsorption/desorption, FTIR Spectroscopy, zeta potential, and VSM. The maximum adsorption capacity for Pb 2+ , Cd 2+ and Cu 2+ reached 110.13 mg·g −1 , 40.23 mg·g −1 and 29.37 mg·g −1 , respectively. The adsorption of the magnetic nanoparticles with different surface group for heavy metals were compared, which indicated that the amino and thiol group played an important role in the adsorption of heavy metals. Especially, the adsorption capacity increased dramatically after modification with the thiol group, which was attributed to the synergistic coordination of −NH 2 and −SH. The adsorption kinetics is consistent with the quasi-second-order kinetics equation, and the adsorption thermodynamic process is consistent with the Langmuir isotherm equation. The effects of experimental conditions, such as pH, the concentration of metals, adsorption time and temperature, on adsorption of Pb 2+ were studied in detail. In addition, over 90% of removal rate was remained after 6 cycles. The magnetic nanoadsorbents was a promising nanoadsorbent with high adsorption speed, simultaneous adsorption of various heavy metals, strong anti-interference ability and reusability.
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CHEMICAL ENGINEERING JOURNAL
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2019
·
IF 8.355
Jingtao Bi,Xin Huang,Jingkang Wang,Ting Wang,Hao Wu,Jinyue Yang,Haijiao Lu,Hongxun Hao
In this work, to simultaneously remove organic dyes and Pb(II) from wastewater, a series of magnetic Fe 3 O 4 @C@TiO 2 -nanotube composites were designed and successfully synthesized via a new facile oil-phase cyclic magnetic adsorption (OCMA) method. The structural properties of the synthesized composites were investigated by different characterization methods systematically. It was found that Fe 3 O 4 was uniformly deposited on the inner walls of TiO 2 nanotubes. Although a Type III band alignment was formed in the catalysts, Fe 3 O 4 @C@TiO 2 -nanotube composites exhibited enhanced light absorbing ability and enlarged absorption edge due to efficient separation of h + and e − , which was verified by UV–Vis (Ultraviolet–visible) and PL (Photoluminescence) spectra. Decontamination experiments of 1FeCTi showed that more than 98% of RhB and about 92% of Pb(II) ions could be removed through adsorptive removal in the dark equilibrium period and further elimination during the illuminating period. The pseudo-first-order model, L-H model and adsorption-reaction model were established to describe the adsorption of Pb(II) in the dark, photodegradation of RhB and further elimination of Pb(II), respectively. A four-step mechanism was proposed to describe the decontamination process of Pb(II) during the illuminating period according to the final forms of Pb (Pb δ1 , Pb δ2 , Pb 0 and PbO). Finally, it was found that the photocatalytic activity would be maintained in the recycle experiments due to the existence of 1FeCTi@PbO heterostructure.
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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
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2019
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IF 4.784
Xue Xue Liang,Xiao-Kun Ouyang,Songyan Wang,Li-Ye Yang,Fangfang Huang,Chao Ji,Xiaohong Chen
The performance of Fe 3 O 4 /attapulgite (APT) nanoparticles in Pb(II) adsorption from aqueous solutions could be improved by modifying the particles with aminopropyltriethoxysilane (APTS) and then combining with chitosan (CS) into beads. After preparing the APTS-Fe 3 O 4 /APT@CS beads, their surface morphology and crystal phases were analyzed by Fourier-transform infrared spectroscopy, scanning electron microscopy, and X-ray diffraction. The magnetic properties of APTS-Fe 3 O 4 /APT@CS were studied by a vibrating sample magnetometer, while their heat resistance and stability were characterized by thermal weight analysis. A recycling test and comparison of adsorption capacities were also carried out. The adsorption capacity of Fe 3 O 4 /APT was improved by the modification with APTS and CS. The adsorption process conforms to the pseudo-second-order kinetic and Langmuir adsorption isotherm models. The adsorption of Pb(II) reaches a maximum of 625.34 mg/g, which compares favorably with other reported adsorbents. The results show that APTS-Fe 3 O 4 /APT@CS is a promising hybrid adsorbent for effective removal of Pb(II) from water.
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JOURNAL OF RAMAN SPECTROSCOPY
·
2019
·Vol. 50
·期 10
·1445-1451
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IF 2.809
Aili Liu,Huile Jin,Jun Li,Liyun Chen,Haoyuan Zheng,Xinnan Mao,Dajie Lin,Jichang Wang,Shun Wang,Weizhong Jiang
A microwave- and ultrasound-assisted reduction and assembly of lead dimethyldithiocarbamate (Pb (DMDC) 2 ) led to the formation of rod-like Pb (DMDC) 2 embedded with PbS quantum dots (QDs). Transmission electron microscopy measurements show the presence of numerous isolated PbS QDs on the Pb (DMDC) 2 microrod surface, which may potentially act as hot spots for enhanced Raman spectroscopy. A case study using mercaptopyridine as the analyte demonstrates that the rod-like hybrids have outstanding performance as a surface-enhanced Raman scattering (SERS) substrate, comparable with that of Au nanorods. The excellent SERS performance of the as-fabricated PbS QDs/Pb (DMDC) 2 hybrids may be attributed to the unique dispersion of PbS QDs as well as the intimate contacts between PbS QDs and Pb (DMDC) 2 . This study therefore presents a new approach for the development of low-cost and highly efficient semiconductor-based SERS substrates.
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