ChemSusChem
·
2013
·Vol. 6
·期 10
·1945-1951
·
IF 7.475
Wenjin Wang,Jie Zhang,Shengchun Yang,Bingjun Ding,Xiaoping Song
Graphical Not just another brick in the wall: Brick-like Au@Pd core–shell nanobricks (CNBs) with a concave surface were synthesized through a one-pot procedure, and show an enhanced performance towards ethanol electrooxidation. The improved performance of the CNBs is a result of the exposed stepped surfaces, high-index facets, and the synergistic effects of the core and shell metals. Au@Pd core–shell nanobricks (CNBs) with concave surfaces and Pd shells with a thickness of approximately 5 nm were synthesized by co-reduction of HAuCl 4 and H 2 PdCl 4 in the presence of Au seeds and Ag ions. These as-synthesized concave CNBs exhibit significantly enhanced catalytic activity for the electrooxidation of ethanol in alkaline media compared to the commercially-used Pd black. The improved performance of the Au@Pd CNBs can be attributed to the exposed stepped surfaces, high-index facets, and the synergistic effects of the core and shell metals.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2017
·Vol. 7
·期 41
·25746-25752
·
IF 3.108
Li Xu,Qin Xu,Xiaoyu Guo,Ye Ying,Yiping Wu,Ying Wen,Haifeng Yang
Alumina is widely recognized as chemically inert, and resistant to oxidation and high temperature. In this study, Au/Al2O3 nanocomposites (NCs) were prepared by a facile method and were used as a surface enhanced Raman scattering (SERS) substrate for detection of adenosine triphosphate (ATP). This Au/Al2O3-based SERS substrate demonstrated good sensitivity with the lowest detectable concentration of 5 × 10−9 M for ATP and a good linear relationship ranging from 5 × 10−5 to 5 × 10−9 M. The strategy of improvement of SERS detection sensitivity for ATP was based on the consideration of ATP captured by such SERS substrate via chelation of aluminum and phosphates, which was validated by X-ray photoelectron spectroscopy. In addition, alumina as a supporting material could be expected to prolong the stability of such a SERS substrate.
✓ 已验证
产品关联
DOI
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
·
2017
·
IF 2.714
Zhihai Cao,Hangnan Chen,Yi Shang,Yushan Zhang,Dongming Qi,Ulrich Ziener
Rice roll-like (RR-like) Au/SiO 2 nanocatalysts (NCs) were synthesized through simultaneous sol–gel process of tetramethoxysilane and 3-aminopropyltriethoxysilane (APTES) and in situ reduction of gold salt in inverse miniemulsions. APTES played an important role in formation of RR-like SiO 2 nano-supports, reduction of gold salts to narrowly size-distributed sub–10 nm Au nanoparticles (NPs), and improved attachment of Au NPs to the SiO 2 nano-supports. The prepared RR-like Au/SiO 2 NCs displayed a pH-dependent, reversible colloidal stability in water, which facilitated to recycle them through tuning the pH value of the dispersion. Most importantly, the catalytic activity of the RR-like Au/SiO 2 NCs towards reduction of p -nitrophenol was about 7–9 times higher than that of the raspberry-like Au/SiO 2 NCs reported in our previous paper (Colloids Surf. A, 489, 2016, 223–233). The formation mechanism of the RR-like Au/SiO 2 NCs was also discussed.
✓ 已验证
产品关联
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2024
·
IF 5.1
Wei Gao,Jinglei Zhang,Lin Shao,Jiaxi Li,Peng Ding,Qingyan Han,Xuewen Yan,Chenyun Zhang,Jun Dong
Enhancing upconversion luminescence in rare-earth materials through the plasmonic effects of precious metals has emerged as a highly effective strategy. In this study, we explore three distinct self-assembly techniques to fabricate alloy nano-film substrates using silver-coated gold (Au@Ag) core-shell nanoparticles, each with unique structural attributes. To enhance the upconversion luminescence of Er 3+ ions, we combine these substrates with NaYF 4 :Yb 3+ /Er 3+ nanoparticles, creating NaYF 4 :Yb 3+ /Er 3+ /Au@Ag composite nanostructures. The upconversion emission of Er 3+ ions is observably boosted when directly combined with Au@Ag nano-films of various structures under a 980 nm laser excitation. Surprisingly, incorporating a NaYF 4 inert shell as an isolating layer results in a remarkable 13.7-fold enhancement of upconversion luminescence in the NaYF 4 :Yb 3+ /Er 3+ @NaYF 4 /Au@Ag composite structure relative to isolated NaYF 4 : Yb 3+ /Er 3+ nanoparticles. The enhancement mechanism was carefully discussed based on spectral characteristics and luminous lifetime. It was found that the enhanced upconversion emission of nanoparticles on differently structured substrates is primarily driven by excitation enhancement. The composite rare-earth and metal nanoparticle structures fabricated in this investigation not only effectively enhance material spectral properties effectively but also streamline the process by employing an inert NaYF 4 shell as an isolation layer. This novel approach offers a promising avenue for developing efficient luminescent material systems.
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2024
·Vol. 14
·期 32
·23011-23022
·
IF 3.9
Ying Xu,Shuili Yu,Cong Huang,Zheng Xu
The photo-reduction of bromate (BrO3−) has attracted much attention due to the carcinogenesis and genotoxicity of BrO3− in drinking water. In this study, a heterojunction photocatalyst was developed by depositing Au nanoparticles (NPs) onto P25 TiO2 NPs through a one-pot, solvent-thermal process. Due to the unique properties of Au, the Au NPs deposited on the TiO2 surface created a Schottky barrier between the metal and the semiconductor, leading to an effective separation of photo-generated charge carriers as the Au nanoparticles served as electron sinks. The Au/TiO2 photocatalyst demonstrated efficient reduction of BrO3− under UV light illumination without the need for sacrificial agents. The effect of different Au loading of Au/TiO2 was systematically investigated for its influence on the generation of electrons and the reduction ability of BrO3−. The results indicate that the 1% Au/TiO2 catalyst exhibited a higher concentration of localized electrons, rendering it more effective in BrO3− removal. The photocatalytic efficiency for BrO3− reduction decreased upon the addition of K2S2O8 as an electron quencher, suggesting that the primary factor in this photo-reduction process was the availability of electrons. These findings hold promise for the potential application of the Au/TiO2 catalyst in the removal of BrO3− from drinking water through photo-reduction.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2025
·
IF 8.5
Chaofan Yao,Qian Wu,Yu Zhao,Hongbin Li,Jinmei He,Li Liu,Yudong Huang,Feng Cheng
Wound bacterial infections not only impede the healing process but can also give rise to a range of serious complications, thereby posing a substantial risk to human health. Developing effective wound dressings incorporating phototherapy functionalities, specifically photothermal therapy (PTT) and photodynamic therapy (PDT), remains a critical area of research in modern wound care. Existing PTT-PDT systems often suffer from challenges such as nanoparticle aggregation and inefficient reactive oxygen species (ROS) generation, which are essential for therapeutic efficacy. This study presents a pioneering approach by combining zeolitic imidazolate framework derivatives (ZIFs) and Au NPs in a silk fibroin (SF) hydrogel for the first time. This combination not only prevents particle aggregation but also significantly enhances photothermal conversion efficiency and ROS generation capacity. The digital light processing (DLP) printability of our hydrogel allows for customized wound dressings tailored to individual patient needs, improving therapeutic efficacy. The hydrogel's effectiveness was evaluated through rigorous in vivo experiments, demonstrating enhanced antibacterial properties and accelerated wound healing. The biocompatibility of our hydrogel ensures its suitability for clinical applications, minimizing adverse reactions while promoting healing. A wound healing rate of 99.06 % represents a substantial improvement over the control groups, indicating markedly enhanced therapeutic efficacy. These findings underscore its multifunctionality in addressing infected wounds, presenting a promising strategy for facilitating the rapid healing of acute complex wounds in clinical applications.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
International Journal of Electrochemical Science
·
2024
·
IF 1.3
Hao Deng,Shangyao Mo,Yong Xie,Rong Chen
This study presents a novel electrochemical biosensor for the detection of Helicobacter pylori VacA protein using a graphene-Au nanocomposite platform. The nanocomposite was synthesized via a one-pot reduction method and characterized using SEM, XRD, and FTIR. The biosensor fabrication process was monitored through cyclic voltammetry and electrochemical impedance spectroscopy. Optimization studies revealed ideal conditions of pH 7.4, 30-minute incubation time, and 100 μg/mL antibody concentration. The biosensor exhibited a linear response range of 0.1–100 ng/mL with a detection limit of 0.03 ng/mL. Selectivity tests against common interfering substances showed minimal cross-reactivity (<5 % signal change). The sensor demonstrated good reproducibility (3.8 % RSD) and stability (95 % signal retention after 30 days). In spiked serum samples, recoveries ranged from 96.5 % to 103.2 % with RSDs below 4.5 %. Compared to traditional methods, this biosensor offers improved sensitivity and shorter analysis time for VacA detection, potentially enhancing early diagnosis of H. pylori infections and monitoring treatment efficacy.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2024
·
IF 9.4
Mengyuan Shen,Anli Wang,Jianlin Chen,Siyao Song,Wenyan Hou,Yunpeng Li,Jiayu Zhang,Jiamin Yuan,Fei Shen,Xiaogang Han
Aqueous Zn-ion batteries (AZIBs) have attracted widespread attention owing to the feature of low cost, inherent safety and eco-friendliness. However, the poor reversibility of Zn anode severely hinders the practical applicability of AZIBs. Separator modification is an effective way to functionalize the electrode/electrolyte interface and improve the cycling performance. Here, we propose a modified glass fiber separator with Au coating (Au@GF), which could realize uniform Zn 2+ distribution at the electrode/electrolyte interface and regulate the plating/stripping behaviors, achieving a dense and homogenous deposition. Zn||Zn symmetric cells assembled with Au@GF separator demonstrate evidently prolonged cycle life over 1600 h at the current density of 5 mA cm −2 and the capacity of 1 mAh cm −2 , while symmetric cells with GF fail in less than 40 h. Even at the condition of 15 mA cm −2 /3 mAh cm −2 , lifespan of Zn||Zn cells with Au@GF is extended to 750 h, which is more than 3 times compared with that of GF. The modified separator with highly conductive coating is capable of a longtime stable Zn plating/stripping. Moreover, an enhanced cycling performance is also detected in a series of full cells with different cathode materials. This work provides an easy and efficient approach to homogenize Zn 2+ deposition.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Surfaces and Interfaces
·
2025
·
IF 6.3
Dan Chen,Ming Zhai,Jing Zhang,Liqi Miao,Kan Li,Zhong Wang,Xiaozhi Wang
Gold-based catalysts are renowned for their exceptional low-temperature oxidation activity and have found widespread application in the thermos catalytic oxidation of formaldehyde (HCHO). In this study, an in-situ hydrothermal synthesis method was employed to prepare Au 0.5 Ni x /ATP catalysts. By altering the doping amount of Ni during the synthesis process, the impact of Ni doping on the catalytic reactivity was investigated. Compared to pure gold-based catalysts, the dispersion and sintering resistance of the Au 0.5 Ni x /ATP catalysts were enhanced. The OH - ions present in the alkaline solution provided by TPAOH disrupted the morphology of ATP, leading to a flocculent appearance for the Au 0.5 /ATP catalyst. With varying doping levels of Ni, the rod-like structure of ATP gradually recovered due to the strong interaction between Ni 2+ and OH-. On the Au 0.5 Ni x /ATP catalysts, NiO, being a p-type semiconductor, was prone to electron loss, with the lost electrons being captured by Au 3+ to form Au 0 and stronger Au and Ni interactions. When Ni species were introduced onto the Au/ATP surface, the synergistic effect between Au and Ni resulted in higher catalytic activity, favoring the catalytic oxidation of HCHO. The catalytic efficiency peaked when the Ni doping level reached 20 wt%.
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2025
·
IF 6.3
Dilong Zhang,Chengting Wang,Mingzhu Xiao,Lu Gan,Xiujie Yang,Yong Xie,Qi Sun
In this study, a novel CoOOH/AuNPs nanozyme was synthesized through a two-step process by integrating gold nanoparticles (AuNPs) with cobalt oxyhydroxide (CoOOH) nanosheets. The CoOOH/AuNPs nanozyme exhibits significant oxidase and peroxidase (POD)-like activities, with a marked enhancement in POD-like activity attributed to the presence of AuNPs. This advancement facilitates the catalytic decomposition of hydrogen peroxide (H 2 O 2 ) into hydroxyl radicals (·OH), which subsequently oxidizes 3,3′,5,5′-tetramethylbenzidine (TMB) to form blue oxidized TMB (ox-TMB) with an absorbance peak at 652 nm. The CoOOH/AuNPs nanozyme's stability was evaluated and was found to be superior to that of natural horseradish peroxidase (HRP), maintaining over 90 % activity after a 30-day period at room temperature. Steady-state kinetic studies confirmed the nanozyme's higher affinity and quicker reaction rate for the TMB substrate compared to HRP. The POD-like catalytic mechanism was investigated, highlighting the essential role of ·OH in the catalytic reaction. A colorimetric sensing platform was then fabricated for H 2 O 2 detection in chicken feet with pickled peppers, demonstrating high sensitivity and selectivity. This study presents a significant advancement in the field of nanozyme-based sensors for food safety applications.
✓ 已验证
产品关联
DOI
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2025
·
IF 4.6
Borong Yu,Jiawei Zhao,Jiayi Zhao,Zhengguo Lin,Chengxiang Zhao,Mengqi Tian,Fangwei Han,Yuanyuan Ma,Zhangang Han
Surface enhanced Raman spectroscopy (SERS) has been a powerful vibrational optical spectroscopic technique for trace determination. And the application and promotion of SERS technology are closely related to plasmonic substrates. To combine the distinct electronic properties of polyoxovanadates with the plasmonic properties of Au NPs, the small cit-Au NPs (reduced by sodium citrate) was modified with decavanadate (V 10 ) via ligand displacement. The structure of V 10 was controlled by pH adjustment. X-ray photoelectron spectroscopy (XPS) and SERS were introduced for studying interactions of V 10 with the surface of Au NPs. Compared with cit-Au NPs, V 10 -Au NPs owned higher absolute value of zeta potential and presented greater stability in CH 3 OH/H 2 O (V/V = 1:10) solvent environment. Even after 60 min of soaking, the V 10 -Au NPs still exhibited a typical coffee ring effect during the evaporation process with SERS enhancement. The stability of V 10 -Au NPs (in a solution with pH 4.8) was tested over a period of 5 days to indicate their ability to maintain SERS activity. Moreover, the V 10 -Au NPs also showed great sensitivity for cationic dye molecules and antibiotics, and the detection levels could be as low as μg⋅L −1 . This study lays the foundation for the screening low-concentration cations in mixed solutions and monitoring the morphological changes of polyoxometalates during their application via SERS technology.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Guobo Chen,Jun Du,Liping Gu,Qian Wang,Qingwen Qi,Xueyu Li,Rui Zhang,Han Yang,Yuqing Miao,Yuhao Li
Sonodynamic tumor therapy is limited by inefficient sonosensitizers and complex tumor microenvironments. Given this, a concept of metal-sensitized sonocatalyst is proposed and defined as a catalyst based on the metal sensitization effect of noble metals to advance semiconductor sonocatalytic activity. We load Au nanorods onto wide-bandgap semiconductor bismuth oxide to favor its sonocatalytic properties for supporting the concept's practicality. In the catalytic nano-system, Au nanorods improve the ability of bismuth oxide to separate electrons and holes under ultrasound, promoting multifarious reactive oxygen species (ROS) generation and enhancing the photothermal effect. Synergistically, bismuth oxide can consume intratumoral overexpressed glutathione, further disrupting the redox balance. Thus, ROS and heat can directly induce immunogenic cell death, reversing tumor immunosuppressive microenvironment in concert and promoting dendritic cell maturation and CD8 + T cell infiltration. The proposed metal-sensitized sonocatalyst will open up new avenues for sonocatalytic therapy.
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）