ANALYTICAL BIOCHEMISTRY
·
2023
·
IF 2.9
Zhangmin Wang,Ze Zhang,Hongzhi Pan,Dong Chang
Exosomes derived from lung cancer typically contain the genetic information of the donor cells. Therefore, exosomes contribute to early diagnosis, treatment effectiveness evaluation, and prognosis assessment of cancer. Based on the biotin-streptavidin system and MXenes nanomaterial , a dual-effect amplification method had been developed to construct an ultrasensitive colorimetric aptasensor for detecting exosomes. MXenes can enhance the loading of aptamer and biotin as the high specific surface area. Biotin-streptavidin system can increase the amount of horseradish peroxidase-linked (HRP-linked) streptavidin , considerably boosting the color signal of the aptasensor. The proposed colorimetric aptasensor exhibited excellent sensitivity, with a detection limit of 42 particles μL −1 and a linear range of 10 2 to 10 7 particles μL −1 . The constructed aptasensor showed satisfactory reproducibility, stability, and selectivity , confirming the promising application of exosomes in clinical cancer detection.
研究领域:
癌症生物学
·
纳米技术
·
生物传感器
·
分子诊断
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Small
·
2024
·
IF 13
Hongliang Fu,Yue Lian,Yongfeng Hu,Jing Zhao,Huaihao Zhang
The development of highly stable and strongly active electrode materials for sodium-ion batteries (SIBs) and overall water splitting (OWS) is critical in sustainable energy storage and conversion systems. Here, a new electrode material N-Fe-C@Nb 2 CT x is introduced, with a layered sandwich structure consisting of N-doping Fe-MOF derived-nanorods (Fe-C) and Nb 2 CT x MXenes. Specifically, Nb 2 CT x obtained by etching Nb 2 AlC with HF acid is used as the main body to construct the layered sandwich structure with Fe-C as the filler. Benefiting from this structure, Fe-MOF grows in situ within Nb 2 CT x , which restrains MXenes aggregation and stacking and also alleviates the bulk effect of sodium-ion embedding/de-embedding, thus improving its stability. Again, the more exposed active sites from the layered sandwich structure and N-doping introduction ensure high reactivity as electrode materials. In addition, Fe-C nanorods strengthen the linkage between the Nb 2 CT x layers and N-doping enhances the ion/electron transport rate, thereby boosting the effective mass transfer and electrical conductivity. Density functional theory (DFT) calculations show that Fe-C and N-doping help increase the density of states (DOS) and material electrical conductivity. Meanwhile, the generated oxygen species (*OH and *O) in OER are captured by in situ FT-IR test. As a result, the N-Fe-C@Nb 2 CT x electrochemical test displays good electrochemical performance in SIBs and OWS.
研究领域:
材料科学
·
能源存储与转换
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ACS Applied Nano Materials
·
2023
·
IF 5.9
Zongwei Guo,Zhao Wang,Jiajun Ma,Lin Jin,Yuhui Ao
Introducing two-dimensional (2D) nanoreinforced materials on the surface of carbon fibers (CFs) is a promising strategy for overcoming the chemical inertness of CFs. However, disordered alignment and uneven dispersion of 2D nanoreinforced materials on the CF surface are the most critical issues that must be addressed. Herein, MXene (M) was functionalized using graphene oxide (G) to produce intercalated 2D reinforcement materials, and robust Ti–O–C covalent bonds were introduced to ensure that M and G have strong binding forces. An interface layer with a more ordered and compact “brick-and-mortar” structure was developed on the CF surface to obtain CF composites with high strength and toughness. Owing to the structure superiority, robust Ti–O–C covalent bonding, and abundant π–π interactions, the optimal CF composites achieved high strength and toughness, with a tensile strength of 1587 MPa and a toughness of 45 MJ m–3. Meanwhile, the interlaminar shear and flexural strengths increased to 82 and 1178 MPa, respectively. The reinforcing mechanisms of the unique interface layer on CF composites were systematically investigated via data analysis and modeling. This study provides a constructive design inspiration for fabricating high-performance CF-reinforced polymer composites, considerably expanding their applications.
研究领域:
材料科学
·
复合材料工程
✓ 已验证
产品关联
DOI
高影响因子
FUEL
·
2024
·
IF 6.7
Xiuzhu Zhang,Zongxue Yu,Junlei Tang,Jiaqiang Huang,Xunwang Tang,Bing Lin,Shuangshuang Xia
The improvement of ionic conductivity and alkali stability of anion exchange membranes(AEMs) has been the focus of research. The abundant functional groups on the surface of inorganic nanomaterials tend to form a rich hydrogen bonding network, which reduces the activation energy and improves the ionic conductivity. In this paper, the prepared HF-Ti 3 C 2 T x was used as a filler in a quaternized poly(aryl piperidinium) (QPAP) matrix to enhance the performance of the membrane electrode assembly of an anion exchange membrane water electrolyzers (AEMWE). With the addition of MXenes, the mechanical properties of the composite membrane improved significantly (from 12.13 MPa to 27.85 MPa). At 80 °C, the ionic conductivity of QPAP-HM-0.7 was as high as 159.4 mS cm −1 . The results showed that the functional groups on the surface of MXenes and the polymer matrix successfully constructed a hydrogen bonding network within the membrane, forming a hydrophilic and hydrophobic microphase separation structure. In addition, the composite membranes prepared by doping HF-Ti 3 C 2 T x obtained good alkali stability (conductivity retention of more than 85 % after 720 h immersion at 80 °C in 1 M NaOH) and dimensional stability, which proved that MXenes is an effective filler to improve the membrane properties.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
BIOSENSORS & BIOELECTRONICS
·
2025
·
IF 10.5
Xiaobo Zhang,Xiuwen Wang,Longjiao Zhu,Jinyan Zhu,Qiuyue Zheng,Jingli Yuan,Wentao Xu,Jijuan Cao
Salmonella typhimurium ( S. typhimurium ), as common and highly pathogenic foodborne pathogen, poses a significant risk to public safety worldwide. The development of highly sensitive, rapid and on-site method for S. typhimurium analysis is urgently needed to prevent bacterial infections. Herein, we introduced a CRISPR/Cas12a-driven electrochemiluminescence (ECL) sensor based on luminol/O 2 binary systems for S. typhimurium detection, employing ultrafine Pt nanoclusters-anchored 2D delaminated-MXenes (Pt NCs/D-MXenes) as the co-reactant accelerator. The ultrathin D-MXenes support regulates the size and dispersibility of Pt NCs and facilitates the full exposure of active sites, and synergistic interactions between D-MXenes and Pt NCs improves electrocatalytic properties toward the reduction of O 2 , which promotes the generation of ROS for boosting ECL emission. Using target responsive-regulated CRISPR/Cas12a system, the ECL sensor for S. typhimurium showed a broad concentration range from 10 1 to 10 6 CFU/mL and limit of detection of 6 CFU/mL, with satisfactory recoveries in spiked-actual samples.
研究领域:
生物技术
·
食品安全
·
分析化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Applied Nanoscience
·
2020
·Vol. 10
·期 6
·1845-1851
·
IF 2.88
Wang Tianxiong,Jiang Tiancai,Meng Xianquan
We found that the morphology of nanowires could be regulated by adding polyvinylpyrrolidone (PVP, K30) in hydrothermal synthesis of antimony sulfide (Sb 2 S 3 ) nanowires. The nanowires with length more than 20 μm were obtained by adding the proper amount of PVP. Three kinds of fully nanostructured photodetector using Sb 2 S 3 nanowires as active regions were fabricated and the first detector used silver nanowires as the electrodes at both ends, the second used silver nanowires as one electrode and MXenes as the another electrode, and the third used MXenes as both electrodes. The light response speed of the photodetector with both MXenes electrodes was improved greatly. The photodetector which used MXenes and silver nanowires as electrodes at two ends, respectively, showed the phenomenon of being self-driven. The mechanism of asymmetric hole migration was put forward to explain the effect of being self-driven.
研究领域:
材料科学
·
纳米技术
·
光电子学
✓ 已验证
产品关联
DOI
高影响因子
TEXTILE RESEARCH JOURNAL
·
2021
·
IF 1.82
Zhe Liu,Sijia He,Haoyu Wang,Xiuchen Wang
Blended electromagnetic shielding (EMS) fabrics of cotton/stainless steel/polyester have been widely applied. The porous structure of the fabric is the guarantee of its good comfort performance, but it also hinders the improvement of shielding efficiency and the endowing of wave absorption performance. To solve the above problems, this paper proposes a mixed resistance field based on fabric pores by the construction of multi-layer MXenes. Ti3AlC2 is etched by hydrochloric acid and lithium fluoride to generate hydrofluoric acid in situ to prepare multi-layer Ti3C2Tx. The finishing experiments are designed to finish the fabric around the pores with Ti3C2Tx impregnation. The enhancement effect and mechanism of the mixed resistance field on the shielding effectiveness and wave absorbing properties of the fabric are analyzed. The result shows that the multi-layer Ti3C2Tx for textile finishing is prepared quickly and effectively using the proposed method. The micro media of the Ti3C2Tx in the dispersion are adsorbed on the surface of various fibers, most of which are cotton fibers. The shielding effectiveness of the finished EMS fabric is improved significantly in the frequency ranges of 6.57–14 GHz and 11.97–18 GHz. The wave absorbing performances in the frequency range of 11.97–18 GHz are excellent. It is proved that the effect of the mixed resistance field of the pores was satisfactory. This paper provides a new way for the application of Ti3C2Tx in EMS fabric, solves the disadvantages caused by pores, and can provide a reference for the design and production of wave absorbing EMS fabric.
研究领域:
材料科学
·
纺织工程
·
电磁学
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry A
·
2017
·Vol. 6
·期 3
·1017-1027
·
IF 8.867
Rutao Wang,Shijie Wang,Yabin Zhang,Dongdong Jin,Xinyong Tao,Li Zhang
Sodium-ion-based capacitors and batteries are considered as a low-cost energy storage technology alternative to their lithium-ion counterparts owing to the abundance of sodium in Earth. Their widespread use is however limited by the lack of high-performance electrode materials. In this work, we report that MXenes-Ti3C2 can be oxidized into a Ti-peroxo complex gel at room temperature by simply adding H2O2, from concentrated to dilute. The highly water-soluble property of this gel allows the synthesis of a graphene-supported TiO2 nanocomposite with highly porous nano-/meso-hybrid architecture via a more facile and environmentally friendly way. The unique hybrid architecture of the produced TiO2–RGO nanocomposite results in pseudocapacitive behavior in Na+ charge storage with high reversibility, fast kinetics, long cyclability, and negligible degradation to the parent structure. By incorporating the TiO2–RGO composite as the anode, a novel sodium-ion capacitor is constructed that is capable of operating at a high voltage of 4.0 V and delivering a maximum energy density of 94.7 W h kg−1, which is comparable to lithium-ion based capacitors. The approach reported here could be potentially extended for fabricating a host of MXenes-derived metal oxide nanomaterials or nanocomposites for numerous applications, particularly in view of the expanding MXenes portfolio.
研究领域:
材料科学
·
能源存储技术
✓ 已验证
产品关联
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Fenglei Liu,Baowei Hu
Recovery of precious metal ions in wastewater could not only improve resource utilization, but also could reduce environmental pollution. Herein, a composite of TpPa@Nb 2 C was constructed by an interfacial self-assembled method and explored the synergistic adsorption effects for precious metals. The structure and morphology of the composites were analyzed by advanced characterization techniques, followed by parametric analysis of Au(III)/Pd(II) adsorption from the simulated wastewater. The results showed that the grafting of COFs with abundant reducing active sites on the MXenes could significantly improve the selectivity and adsorption capacity. Meanwhile, the interaction was found as monolayer way and controlled by chemistry process, and the maximum equilibrium Au(III) and Pd(II) uptake reached up to 910.1 and 386.2 mg/g, respectively. The competitive adsorption study showed that the co-existence of impurities had little effect on the removal rate. The mechanism analysis demonstrated that the precious metal ions were reduced to elemental gold/palladium on the network of TpPa@Nb 2 C, and they got three electrons or two electrons from the hydroxyl groups through redox reaction, respectively. Thus, this study provided an excellent material for enrichment and recovery of precious metals in waste liquid and the treatment of e-waste.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2021
·
IF 8.128
Zhilin Zhao,Xinming Wu,Chunyan Luo,Yan Wang,Weixing Chen
Although electrodes based on two dimensional hybrids with interstratification-assemble have been widely studied for supercapacitors, the performance enhancement still remains challenge mainly due to the random dispersion of surface passivated two dimensional nanosheets. Herein, a new covalent surface functionalization of MXene-based Ti 3 C 2 Cl 2 nanodots-interspersed MXene@NiAl-layered double hydroxides (QD-Ti 3 C 2 Cl 2 @NiAl-LDHs) hybrid electrode with superior pseudocapacitor storage performance has been elaborately designed by electrostatic-assembled. As a result, the QD-Ti 3 C 2 Cl 2 @NiAl-LDHs electrode exhibits a super specific capacitance of 2010.8F g −1 at 1.0 A g −1 and high energy density of 100.5 Wh kg −1 at a power density of 299.8 W kg −1 . In addition, 94.1% capacitance retention is achieved after cycling for 10,000 cycles at 1.0 A g −1 , outperforming previously reported of two dimensional hybrids electrode for supercapacitor. Furthermore, density functional theory (DFT) calculations show that the superior pseudocapacitor storage performance of the QD-Ti 3 C 2 Cl 2 @NiAl-LDHs may be attributed to the creation of numerous electrochemical active sites and the enhancement of electrical conductivity by the QD-Ti 3 C 2 Cl 2 MXene. This work provides new strategy for developing excellent pseudocapacitor supercapacitor based on two dimensional hybrid electrode.
研究领域:
材料科学
·
电化学
·
储能技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Catalysis Science & Technology
·
2022
·Vol. 12
·期 6
·1788-1798
·
IF 6.177
Jing Zhao,Yanzhuo Zhang,Hucheng Zhang,Haiyan Wang,Jianji Wang
Hydrogen spillover is an important theme for hydrogen storage and H-involving catalytic reactions. This work shows that catalytic reactivity and selectivity can be revealed by differentiating the energetic characteristics of spilled H species. With the assistance of Ti, F and C in MXenes, Pd1.8Ni@Ti3C2Tx presents a high capacity for spillover hydrogen storage at ambient temperatures, and the rich oxygenated groups act as the main carriers of hydrogen spillover around metal nanoparticles. Thermodynamic analysis reveals that the catalytic performances are energetically dominated by the adsorption enthalpies of the active spilled H species rather than the amount of spillover hydrogen, and can be tuned by alloying and surface modification. The ideas are verified from the excellent catalysis, chemoselectivity and stereoselectivity of Pd1.8Ni@Ti3C2Tx in semihydrogenations. The strategy of maximizing catalytic performances is applicable to other Pd-based bimetals@Ti3C2Tx, such as Pd2.6Co@Ti3C2Tx and Pd1.5Fe@Ti3C2Tx, and provides new energetics perspectives to understand the catalytic mechanism in spillover-involving chemical procedures.
研究领域:
催化
·
材料科学
·
化学工程
·
纳米技术
✓ 已验证
产品关联
DOI
高影响因子
GREEN CHEMISTRY
·
2020
·Vol. 23
·期 3
·1382-1388
·
IF 9.48
Liang Chen,Yiming Huang,Ren Zou,Jiliang Ma,Yunyi Yang,Tingzhen Li,Mingsai Li,Qi Hao,Haibo Xie,Xinwen Peng
Synthesis of D-xylonic acid, a high value chemical feedstock, from biomass chemicals through a photocatalytic process is of great significance in respect of economical and sustainable concerns, and therefore has aroused considerable attention. Herein, a TiO2/Ti3C2(TT) photocatalyst was designed for the oxidation of xylose to D-xylonic acid under ambient conditions. The photocatalyst is fabricated by in situ growth of TiO2 nano-particles on Ti3C2 nanosheets and exhibits 64.2% of D-xylonic acid yield with excellent stability. The mechanistic study indicates that the electron transfer from TiO2 to Ti3C2 significantly increases the life time of light-induced charge carriers, and hence improved photocatalytic performance.
研究领域:
材料科学
·
化学工程
·
可持续化学
·
光催化
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）