JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2021
·
IF 8.128
Jin Qin,Shangshi Ye,Kai Yan,Jingdong Zhang
A visible light-driven photoelectrocatalytic system was constructed based on Bi/Bi 2 O 3 /TiO 2 nanotubes (NTs) to treat wastewater containing oxytetracycline and Cu 2+ mixed pollutants. The surface morphology , crystal phase, elemental composition , light absorption property and photoelectrochemical activity of the synthesized Bi/Bi 2 O 3 /TiO 2 NTs were investigated. The composite film , Bi/Bi 2 O 3 /TiO 2 NTs was used for the photoelectrochemical removal of oxytetracycline, and it had excellent visible light photoelectrocatalytic performance. Under optimal conditions, the composite film was simultaneously used to remove coexisting oxytetracycline-Cu 2+ . The study results show that the reduction of Cu 2+ on cathode was promoted by oxytetracycline while the degradation of oxytetracycline on photoanode was slightly suppressed by Cu 2+ . Also, possible photoelectrocatalytic degradation pathways for oxytetracycline-Cu 2+ were analyzed by HPLC-MS.
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高影响因子
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
·
2024
·
IF 5.9
Yixuan Zhang,Guo-Qiang Liu,Chang Su,Danlei Qiao,Xiaojing Xu,Jiaguan Chen,Guang-Yin Liu,Qiang Sun,Lei Wen
Layered oxides are the widely investigated cathodes for sodium-ion batteries (SIBs), especially their pure phases (e.g., P2, O3). In this work, we report a series of Mn-Ni-Fe based cathode materials with P2/O3 bi-phase, which possesses advantages of both P2 and O3 structures. At first, the manuscript shows a synthesis phase diagram of Na 0.83 Mn x Ni y Fe 1-x-y O 2 to pre-screen and select the P2/O3 bi-phase material Na 0.83 Mn 1/2 Ni 1/3 Fe 1/6 O 2 . Then, it is found that the cationic ratio has a significant impact on the phase formation. The structure of the materials gradually changes with the various of the Mn/Ni ratio. When the Mn/Ni ratio reaches 3/2, P2/O3 bi-phase is formed. Moreover, Fe content will influence the P2/O3 ratio in the bi-phase material. In particular, the synthesized bi-phase Na 0.83 Mn 3/6 Ni 2/6 Fe 1/6 O 2 has a P2/O3 ratio of 71/29 wt%. It delivers a high specific capacity of 136.6 mA h g −1 (at current density 20 mA g −1 ) between 2.0 and 4.0 V and 94.8% retention (at current density 100 mA g −1 ) after 100 cycles. In addition, an 85.6 mA h g −1 discharge capacity can be maintained at a superior high current density of 2000 mA g −1 . The work offers critical guidance to the rational design of the bi-phase layered cathode materials.
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高影响因子
CARBON
·
2023
·
IF 10.9
Qingyuan Zhao,Wenjie Zhao,Yinghao Wu
The limited interfacial combination between CF and polymer matrix caused by the chemical inertness of CF surface greatly restricts the protective capability of carbon fiber reinforced polymer coatings (CFRPCs), which could not effectively resist the impact of external forces, especially in the severe and complicated ocean environment (like deep-sea area and splash zone). Hence, it is the crux to enhance the interface compatibility and interface strength between fiber and resin. Based on the reliable compatibility between imidazole and epoxy as well as the corrosion inhibition effects of cerium-based compounds, a kind of bi-functional metal-organic framework (MOF) called the cerium-imidazole framework (Ce-MI) was constructed on the CFs surface via in-situ growth method to improve the interface compatibility and interface strength of fiber and resin and further increase protective performance of epoxy (EP) coating under the simulated deep-sea area and splash zone . After 168 h immersion under alternating hydrostatic pressure, CF@Ce-MI/EP coating displayed impressive impermeability and anti-corrosion performance, and the interfaces of fiber/epoxy adhered firmly. After the erosion wear test, the volume loss and mass loss of CF@Ce-MI/EP were decreased by 23.77% and 14.80%, respectively, compared with CF/EP. Finally, we discussed the protective mechanism of composite coating to reveal the different processes of interface failure caused by the high pressure and the impact of solid particles , respectively.
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高影响因子
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
·
2022
·
IF 10.319
Yuzhen Wang,Xuanyi Yuan,Yongge Cao,Chaoyang Ma
With the rapid development of science and technology, the high-security-level anti-counterfeiting technique is essential for ensuring property or information security. In this work, we prepared micron NaYTiO 4 : Bi/Er (NYT: Bi/Er) phosphors with integrating up-conversion (UC) photoluminescence, down-shifting (DS) emission, phosphorescence and photochromism (PC) performances for advanced multiple anti-counterfeiting application. Owing to the abundant energy levels of Er 3+ ions, the UC and DS luminescence behaviors are anticipated. Specifically, the yellow-green emission of Er 3+ ions can be observed upon 980 nm excitation, and the bright green emission is demonstrated under 281 or 254 nm excitation due to the energy transitions of Er 3+ ions and the energy transfer process from Bi 3+ to Er 3+ ions. Besides, the introduction of Bi 3+ ions generates defect levels in the matrix and thus leads to phosphorescence. Furthermore, the repeatable PC performance could be triggered by the 365 nm irradiation and vanished with 450 nm illumination or thermal stimulation. To verify the practical usability of NYT: Bi/Er phosphors on anti-counterfeiting applications, some experiments are designed and successfully executed. It is believed that the NYT: Bi/Er phosphors can be a promising candidate for high-security-level multiple anti-counterfeiting.
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高影响因子
JOURNAL OF POWER SOURCES
·
2024
·
IF 8.1
Aiying Lei,Guangchang Yang,Kai Pan,Wentao Liu,Chengqing Deng,Ming Fang,Xiaohui Zhang,Chunlei Tan,Huilong Dong,Feiyan Lai
Bismuth (Bi) is a promising anode material for lithium-ion batteries due to its high capacity. However, challenges such as low conductivity and significant volume expansion during charge cycles restrict its practical application. Metal-organic frameworks (MOFs), known for their controllable structure, hybrid inorganic-organic nature, large surface area, and high porosity, offer a solution to fix up above challenges. This study designs three-dimensional porous hollow spherical nanostructured bismuth-based MOF (Bi-MOF) by coordinating Bi 3+ with terephthalic acid. The material features a functional spherical shell and internal pore structure that maintain open ion transport channels, abundant electrochemical sites, and a large contact area between electrolyte and electrode. This design accelerates ion/electron transport within the cavity, mitigating volume expansion during charge-discharge cycles and ensuring structural stability. As an anode material, Bi-MOF exhibits great electrochemical performance: retaining discharge capacities of 617.6 mAh g −1 after 1000 cycles at 1 A g −1 and 579.1 mAh g −1 after 200 cycles at 0.1 A g −1 . Coupled with LiFePO 4 cathodes, the full-battery maintains 93.1 mAh g −1 after 110 cycles at 1C. This work provides a train of thought to develop high-performance anode materials for enhanced lithium storage in lithium-ion batteries (LIBs) and validated the lithium storage mechanism of Bi-MOF.
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高影响因子
ACS Applied Materials & Interfaces
·
2021
·
IF 9.229
Xiangyang Zhang,Xiaolin Ye,Shaopei Huang,Xuelong Zhou
Elaborate nanoarchitectured solid/liquid interface design of felt electrodes is arguably the most effective pathway to promote the pore-level transport-reaction processes of redox flow batteries. Herein, we conceive a new type of nanocatalytic-layer-architectured graphite felt via introducing the vertically standing carbon nanosheet-confined Bi nanodots onto carbon fiber surfaces. The vertically standing carbon nanosheets construct a nanoporous layer with straight channels for vanadium ion shuttling, where highly dispersed Bi nanodots are stiffly confined to afford abundant active sites. The vanadium redox flow battery utilizing the rationally designed electrodes achieves an energy efficiency of 89% at 150 mA cm–2, which is substantially higher than those of raw felt (61%) and oxidized felt (77%). Also, the battery with the present electrode maintains an energy efficiency of over 73% even at 400 mA cm–2, showing the excellent capability of withstanding fast charging and discharging. The multiphysics simulation shows that the vertically standing architecture optimizes the vanadium ion accessibility to the solid/liquid interfaces and thus maximizes the catalytic activity. Moreover, the battery can sustain more than 1000 cycles without obvious efficiency decay, confirming the superb stability of the present electrode. These encouraging results indicate that engineering vertically standing structures with tailored compositions may open up new avenues for advancing the flow battery technology.
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高影响因子
JOURNAL OF POWER SOURCES
·
2024
·
IF 8.1
Wenhui Tu,Zewei Chen,Yuanpeng Cao,Jianguo Duan,Jingjing He,Runlin Li,Peng Dong,Xianshu Wang,Yingjie Zhang,Ding Wang
Olivine-structured LiMnPO 4 -based cathodes have generated enormous development prospects due to their high energy density , good structural stability , and low cost. However, their scale of application is limited by high electronic and ionic insulativity. In this study, we designed and synthesized a bi-functional interfacial modified composite, 0.9LiMnPO 4 @0.1LiFePO 4 /C ( [email protected] /C ), using mechanochemical activation-assisted hydrothermal technology. The innovative Li-storage structure consists of a high-energy density LiMnPO 4 (LMP) core, a uniformly coated LiFePO 4 (LFP) layer with improved ionic conductivity as the secondary outer shell, and an in-situ coated carbon film with high conductivity as the outermost functional skin. As anticipated, the [email protected] /C composite exhibits outstanding Li-storage properties, demonstrating discharge capacities as high as 157.1 mAh g −1 and 146.7 mAh g −1 at 0.1 C and 1 C rates, respectively. Moreover, it exhibits an ultrahigh capacity retention of 92.5 % after 500 charge and discharge cycles.
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高影响因子
Catalysts
·
2024
·Vol. 14
·期 10
·735
·
IF 3.8
Lu Qiu,Hanliang Li,Wenyi Xu,Rongshu Zhu,Feng Ouyang
The organic pollutants discharged from industrial wastewater have caused serious harm to human health. The efficient photocatalytic degradation of organic pollutants under sunlight shows promise for industrial applications and energy utilization. In this study, a modified TiO2photocatalyst doped with bismuth (Bi) and fluorine (F) and composited with SnO2and SiO2was prepared, and its performance for the degradation of Rhodamine B (RhB) under simulated sunlight was evaluated. Through the optimization of the doping levels of Bi and F, as well as the ratio of SnO2and SiO2to TiO2, the optimal catalyst reached degradation efficiency of 100% for RhB within 20 min under simulated sunlight, with a first-order reaction rate constant of 0.291 min−1. This value was 15, 41, 6.5, and 3.3 times higher than those of TiO2/SnO2, Bi/TiO2, Bi-TiO2/SnO2, and F/Bi-TiO2/SnO2, respectively. The active species detection showed that h+was the most crucial active species in the process. The role of Bi and F addition and SnO2-SiO2compositing was investigated by characterization. Bi formed a chemical bonding with TiO2by doping into TiO2. The absorbance intensity in the UV and visible light regions was improved by SnO2and F modification. Composite with SiO2led to a larger surface area that allowed for more RhB adsorption sites. These beneficial modifications greatly enhanced the photocatalytic activity of the catalyst.
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高影响因子
Journal of Cleaner Production
·
2022
·
IF 11.072
Sihan Ma,Xian Luo,Guang Ran,Zonglang Zhou,Jun Xie,Yipeng Li,Xingyong Li,Jianghua Yan,Wangyu Cai,Lin Wang
The release of pollutants from bacterial pathogens in air or water, which causes a serious threat to human health and well-being. Traditional antibiotics have exhibited insufficient ability in combating bacteria owing to the emergence of drug-resistant bacteria. Hence, effective antibacterial candidates urgently need to be explored as an alternative for overcoming the antibiotic barrier. It is highly necessary to find an effective stable disinfection system with the nature of environmental-friendly, high activity and stability, convenient synthesis procedure, low energy, cleaner, and low economic consumption. Considering these aspects, optical strategy and chemical treatment bring convenience and advantages in bacterial inactivation. In this work, the bimetallic Cu–Bi alloy was explored using a simple one-pot solvothermal strategy. On the one hand, the bimetallic structure can prevent copper from oxidation to decrease potential secondary pollution activity caused by excessive release of copper ions , and maintain copper's highly biological activity . On the other hand, the as-prepared Cu–Bi alloy was employed to perform antibacterial applications. Hyperthermia is driven by near-infrared light and the introduction of ROS from Cu Fenton-like reaction that can effectively promote the death of bacteria, and perform a better antibacterial ability than that of single Ag + or Cu 2+ release, resulting in the significant growth inhibition of E. coli . Overall, the combination of the multiple disinfection ability of the Cu–Bi alloy, involving highly efficient ROS generation and effective photothermal performance, not only shows the potential in fighting against pathogenic bacteria but also provides an important insight for the exploration of antibacterial platforms based on the bimetallic materials.
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高影响因子
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
·
2019
·
IF 4.029
Bo-Wei Xun,Yu-Cheng Tang,Jian-Yin Chen,Bo-Ping Zhang
We reported a facile analysis and reduction of oxygen vacancy ( V O • • ) in 0.7Bi(Fe 1- x Sc x )O 3 -0.3BaTiO 3 (0≤ x ≤0.08) ceramics. The leakage current mechanism was investigated intensively. Our results indicated that oxygen vacancies are the main cause for the high conductivity in BF-BT ceramics, and their concentration was quantitatively estimated from the Bi 3+ content and the average oxidation state of iron. The V O • • concentration was effectively suppressed and the insulation resistance was enhanced by almost two orders of magnitude after doping 2%mol Sc 3+ . The enhanced insulation resistance contributed to excellent piezoelectric properties with d 33 = 165 pC/N, T C = 505 °C, and k p = 26%. The proposed analysis method used to quantify the V O • • concentration provides valuable indications to reduce the leakage current density and improve the piezoelectric properties of BF-BT based ceramic.
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高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2024
·Vol. 35
·期 6
·1-12
·
IF 2.8
Tang Lanxin,Li Shuangchi,Wang Fang,Chen Yu
The binary perovskite-type compound (1 − x )BiFeO 3 – x BaTiO 3 (BF-BT) is considered as a promising high-temperature lead-free piezoelectric material due to its high Curie temperature ( T C > 400 °C) and better electromechanical properties. In this work, ternary lead-free piezoelectric ceramics with a chemical formula of (0.67 − x )BiFeO3–0.33BaTiO3– x Bi(Zn0.5Ti0.5)O 3 + 1 mol% MnO 2 (where x = 0–0.05) were prepared by the conventional solid-state reaction route. The effects of Bi(Zn 0.5 Ti 0.5 )O 3 introduction on the phase structures and microstructures, piezoelectric and dielectric properties, as well as impedance characteristics of BF-BT ceramics were investigated in detail. Firstly, all the samples synthesized exhibit a pure perovskite structure with the coexistence of rhombohedral ( R ) and tetragonal ( T ) phases, and the T phase content increases with increase in x . A small amount of Bi(Zn 0.5 Ti 0.5 )O 3 ( x ≤ 0.03) that were incorporated into the perovskite lattice of BF-BT can promote the grain growth of ceramics. Secondly, all samples were found with a notable relaxed phase transition behavior, T C of the system decreases with increase in x . The AC impedance spectra of the samples were fitted and analyzed according to the R-CPE equivalent circuit model, the electric impedance of the ceramics at high temperatures was mainly contributed by grain boundaries. Moreover, the dielectric relaxation activation energy of the samples firstly decreases and then increases with increase in x . Finally, the composition with x = 0.02 shows the optimized electrical properties among these samples, including T C = 454 °C, d 33 = 117 pC/N, k p = 23%, tan δ = 0.11, which are mainly benefited from the bismuth content compensation and the substitution of (Zn 0.5 Ti 0.5 ) 3+ for Fe 3+ at B-site reducing the valence change of Fe 3+ in BF-BT.
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高影响因子
Reaction Chemistry & Engineering
·
2024
·Vol. 9
·期 6
·1521-1531
·
IF 3.4
Yuxing Sun,Zilong Zhang,Juan Yang,Xiang Wang,Huanjun Peng,Jingdong Peng
Generally, a Bi-doped TiO2 nanocomposite was synthesized by a microwave-assisted hydrothermal method to introduce Bi4Ti3O12 and an oxygen vacancy onto the pristine TiO2. The optimized composite 6Bi–TiO2 exhibits a good photocatalytic ability for degradation of rhodamine B (RhB), and the calculated reaction rate constant is about 13.7 times higher than that of pristine TiO2. After 60 minutes of light irradiation, the 6Bi–TiO2 sample achieved a degradation rate of 95% and that of the pristine TiO2 was 21%. Furthermore, the catalyst retains a good photocatalytic ability after recycling five times. The enhanced photocatalytic ability can be credited to the improved charge separation efficiency, caused by the altered band structure after the anchoring of Bi4Ti3O12, and the oxygen vacancy also plays a crucial role in the degradation process. This study offers insights into the application of a microwave-assisted hydrothermal method in the effective synthesis of Bi4Ti3O12 on TiO2 by a Bi-doping strategy.
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高影响因子
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