ACS Applied Materials & Interfaces
·
2019
·
IF 8.456
Yanni Yu,Biyu Jin,Muhammad Imran Jamil,Dangguo Cheng,Qinghua Zhang,Xiaoli Zhan,Fengqiu Chen
Various organogel materials with either a liquid or solid surface layer have recently been designed and prepared. In this work, amphiphilic organogels (AmOG) are innovatively developed from copolymer P(PDMS-r-PEG-r-GMA) and 2,2′-diaminodiphenyldisulfide via epoxy group addition reaction and then infiltrated with amphiphilic lubricants instead of traditional hydrophilic or hydrophobic lubricants. Because of synergistic effects of hydrophilic and hydrophobic segments of amphiphilic lubricants, the AmOG surfaces showed high stability and excellent anti-icing performance. The delay in the freezing point of water was 1000 s on AmOG surfaces, which is 40 times longer as compared to the untreated hydrophilic glass surface. More importantly, low ice adhesion strength (15.1 kPa) was observed on AmOG which remained about 40 kPa even after 20 icing–deicing cycles. The novel amphiphilic organogels provide a new idea to prepare long-term anti-icing materials for practical applications.
研究领域:
材料科学
·
化学工程
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产品关联
DOI
PubMed
高影响因子
Nanoscale Advances
·
2022
·Vol. 4
·期 13
·2884-2892
·
IF 5.598
Wei Guo,Cui Liu,Nian Li,Min Xi,Yamin Che,Changlong Jiang,Shudong Zhang,Zhenyang Wang
Anti-/de-icing of glass surfaces is of great importance in present daily life. The long-standing challenge in this field is largely due to the lack of stable multifunctional coatings that can be conveniently and economically constructed on the glass surface, and more importantly, are capable of retaining the original transparency of glass ranging from the visible to the near infrared spectrum. Herein, a direct spraying sol method on the glass surface to prepare a highly transparent and photothermal composite coating is reported. Such multifunctional coating of Cu7S4 nanoparticles/organo-silicone sols has displayed a good photothermal conversion property and hydrophobic property and therefore yields excellent anti-icing and self-melting ice properties. The condensation time of water droplets can be extended to 86 s even at −10 °C, which is 3.42 times delayed relative to ordinary blank glass. And the adhesion strength of ice is largely reduced to 72 KPa, which is as low as ∼1/3 that of ordinary glass. Meanwhile, the subcooling of adhering droplets is reduced to −12 °C under one solar illumination condition and exhibits a rapid de-icing capability. More impressively, the prepared functional coating glass shows an outstanding transmittance of more than 75% in the visible region, while it is over the minimum glass transmittance limit allowed by Safety Standards for Glass (GB9656-2016, China). In addition, the multifunctional photothermal glass coating exhibits good physical/chemical stability, which facilitates the long-term application of the coating in different environments.
研究领域:
材料科学
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能源科学
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产品关联
DOI
PubMed
高影响因子
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2022
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IF 5.518
Yubo Wang,Yongyang Sun,Yiqing Xue,Xin Sui,Fangxin Wang,Wenyan Liang,Qianqian Dong
Shape memory polymer (SMP) surfaces can achieve wettability transition by controlling microstructure have attracted great attention. However, attempts at achieving in situ reversible switching capability remain largely challenging. This paper aims to elaborate on the preparation of a shape memory superhydrophobic surface with switchable wettability and electrothermal performance. The surface microstructure array is regulated by the shape memory effect based on the electrothermal response, and the reversible switching of the wetting state is realized under the action of voltage and external force. Different microstructural morphologies exhibit different solid-liquid contact states, as well as large/small contact angles and low/high adhesion. In addition, the rapid thermal response, excellent thermal conductivity , and satisfactory durability provide the possibility for anti-icing/deicing. The structure can prevent droplet aggregation, greatly delay the nucleation of droplet crystallization, and remove ice by Joule heat. In short, this work successfully realized the in-situ control of surface wettability which also provided a significant application potential in droplet manipulation, droplet writing, anti-icing/deicing, and other fields.
研究领域:
材料科学
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表面工程
✓ 已验证
产品关联
DOI
高影响因子
MATERIALS CHEMISTRY AND PHYSICS
·
2023
·
IF 4.6
Yiqing Xue,Yubo Wang,Yanhua Wang,Wenyan Liang,Fangxin Wang,Dongyu Zhu,Huanyu Zhao
Ice accumulation often threatens the safety of human life and property. How to effectively solve the problem of solid surface icing has been the research work of many researchers. However, how to prepare superhydrophobic and anti-icing film with multi-strategy collaborative deicing is still facing great challenges. In this paper, a design strategy of photothermal and electrothermal superhydrophobic nanocomposite film based on polyetherimide (PEI) was proposed. Multi-walled carbon nanotubes (MWCNT) were dispersed in PEI matrix by solution blending method, and a lotus leaf like rectangular micropillar array was constructed on the surface of the film by laser etching technology. Then, the surface was fluorinated to further reduce the surface energy. Finally, a kind of MWCNT/PEI nanocomposite film with passive anti-icing and active deicing with photothermal and electrothermal collaboration was successfully prepared. The freezing time of droplets on MWCNT/PEI nanocomposite film is about 6.7 times longer than that of pure PEI film. This film exhibits excellent superhydrophobicity (CA = 156.6°), while also having excellent photothermal and electrothermal conversion properties. In addition, we also conducted various tests on MWCNT/PEI nanocomposite film to verify its reliability in the actual application environment. The MWCNT/PEI nanocomposite film with the function of anti-icing and photothermal and electrothermal active deicing is expected to solve the problem of solid surface icing in daily life, and also provides a new idea for the development of a new generation of anti-icing/deicing film.
研究领域:
材料科学
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表面工程
✓ 已验证
产品关联
DOI
高影响因子
Coatings
·
2023
·Vol. 13
·期 4
·732
·
IF 3.4
Bo Li,Jie Bai,Lei Fan,Xianyin Mao,Zhimin Ding,Hao Mu,Guoyong Liu,Yuan Yuan
Slippery liquid-infused porous surfaces (SLIPS) have received growing attention as promising icephobic materials. In this study, SLIPS were prepared on aluminum alloys by combining anodization and infusion of common silicone oil. An SLIPS with low ice-adhesion strength (6 kPa) was obtained by optimizing the anodizing time parameters (10 min). In addition, the frosting process and freezing of water droplets on the as-prepared SLIPS at −10 °C were delayed for 2000 s and 4800 s, respectively. Simultaneously, the as-prepared SLIPS also exhibited excellent anti-icing performance in glaze ice, since the supercooled water drips/ice slipped from the surface. The ice weight of the as-prepared SLIPS was significantly lower than that of the bare aluminum surface and the anti-icing-fluid-coated aluminum surface, which was reduced by 38.2%–63.6% compared with the bare aluminum surface. The ice weight increased with decreased temperature and inclination angle. This work proposes a method suitable for large-area preparation of SLIPS that achieves excellent anti-icing performance and significantly reduces the weight of glaze ice.Keywords:slippery liquid-infused porous surfaces;anti-icing;glaze ice;ice-adhesion strength
研究领域:
材料科学
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表面工程
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2023
·
IF 6.7
Xinghua Wu,Yutong Pan,Zhaokang Han,Yizhou Shen
To address the issues caused by ice accretion, researchers have made various attempts to obtain anti-icing surfaces, among which superhydrophobic surfaces have been approved to be an ideal candidate for anti-icing applications. Although extensive research has been conducted to date, the relationship between the anti-icing performance and the anti-condensation performance of superhydrophobic surfaces has yet to be investigated. In this study, superhydrophobic coatings with different surface microstructures were prepared. Tuning of surface morphology was conducted by controlling molar ratio of SiO 2 nanoparticles and polyester powders. The superhydrophobic coatings with uniform surface microstructures exhibit anti-condensation performance. Superhydrophobic coatings with cavities-pore combined surface structures demonstrated superior anti-icing performance to other coatings. The relationship between the anti-icing and anti-condensation performance was investigated. It is verified that the anti-condensation performance of the superhydrophobic surface do not have a simple correlation with the anti-icing performance. Furthermore, the coatings present oil repellency, durable superhydrophobicity and anti-fouling properties.
研究领域:
材料科学
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表面工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2023
·
IF 9.9
Jun Ma,Jinlong Song
Slippery liquid-infused porous surface (SLIPS) has shown significant application values in various areas and has been commonly obtained by injecting the water-immiscible lubricant into a low-surface-energy modified micro/nano-structured surface. Constrained by the availability of desirable structured substrates or simple preparation schemes, the exploration of SLIPS with multifunctionality and universality that is facile to fabricate and robust in realistic applications remains challenging. Herein, we propose a one-step, fluoride-free and unconventional protocol based on a one-pot reaction of polysilazane (PSZ), silicone oils and multiwalled carbon nanotubes (MWCNT), which creates not only the favorable micro/nano-scale physical structures and surface chemistry for the excellent slippery property (sliding angle < 3°) and robust lubricant retention, but also the superior photothermal responsiveness for the potential multifunctional applications. It has been demonstrated that the proposed multifunctional slippery photothermal coating (MSPC) displayed outstanding potential in corrosion resistance , droplet manipulation and anti/de-icing. We envision that the proposed strategy could be realized in the real-life applications.
研究领域:
材料科学
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表面工程
·
纳米技术
✓ 已验证
DOI
PubMed
高影响因子
NANOTECHNOLOGY
·
2022
·Vol. 33
·期 32
·325703
·
IF 3.953
Jing Xu,Xiaojing Gong,Seeram Ramakrishna
Photothermal anti-icing/deicing technology is an environmentally friendly surface technology that can be applied to the surface of aircraft, vehicles or ships. However, it is still a huge challenge to develop a strong and stable flexible film that can efficiently convert light to heat. Here, based on a simple electrochemical method to construct a zinc oxide (ZnO) nanoneedles structure on the surface of the carbon nanotube film, a film with the function of condensed micro-droplet self-propelling (CMDSP) was successfully prepared. The prepared film has excellent light absorption capacity and high energy transfer efficiency (76.71%). The film has strong photothermal anti-icing/deicing performance. Under 4406 Lux light irradiation, even under low temperature conditions of −5 °C, the icing delay time exceeds 4 h. This novel characteristic is attributed to the CMDSP function on the surface and the ultra-fast evaporation mechanism, which can remove water droplets on the surface as quickly as possible. This function helps to design energy-saving equipment that requires high-power heating and deicing.
研究领域:
材料科学
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能源技术
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表面工程
✓ 已验证
DOI
PubMed
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Qingqing Zhang,Yaxin Chen,Ren Liu,Jing Luo
Photothermal superhydrophobic coatings are one of the most promising anti-icing/de-icing materials. However, the intermittence of light energy limits the application of photothermal energy conversion technologies when continuous de-icing is required. Herein, an innovative solution for the integration of photothermal effect and phase change thermal storage was proposed. In this work, an efficient anti-icing/de-icing coating was successfully fabricated based on multifunctional polyaniline microcapsule encapsulating butyl stearate (BS). Benefiting from the heat storage capacity of BS in the microcapsule, the coating could achieve all-weather anti-icing capability. Under the condition of −20 °C, the freezing time of water droplets on the coating with only 10 wt% microcapsules was delayed by about 12.6 times compared to the blank coating. At the same time, under simulated dark conditions, the freezing time of water droplets could be delayed by about 14.1 times. Moreover, owing to the thermal conductivity and high solar energy exploitation, polyaniline endowed the coating with outstanding photothermal de-icing performance, presenting the superiority of outdoor applications. Under NIR (200 mW/cm 2 ) illumination, the melting time of water droplets was reduced to 18 s, which was nearly 10 times faster than that on the blank coating. Moreover, the polyaniline microcapsules also possessed outstanding anticorrosion property, which was particularly attractive for mental coating applications. The combined properties of this all-weather anti-icing and de-icing coating could render it a promising contender for challenging outdoor applications.
研究领域:
材料科学
·
能源技术
✓ 已验证
DOI
高影响因子
APPLIED SURFACE SCIENCE
·
2025
·
IF 6.9
Pengao Yu,Zongxue Yu,Kexi Liao,Shuangshuang Xia,Kun Li,Jiao Chen,Xiuzhu Zhang
In this study, a self-healing superhydrophobic bilayer coating with dual photothermal and pH response was developed by combining a smart self-healing bottom layer with a superhydrophobic top layer. The composite material (MZT) obtained by combining zeolitic imidazolate framework-8 (ZIF-8) loaded with corrosion inhibitor AMT (2-amino-5-mercapto-1,3,4-thiadiazole) and Ti 3 C 2 T X nanosheets (MXene) was embedded with a shape memory coating (SMP) as the bottom coating. The bottom coating is photo-thermal as well as pH dual-responsive, enabling smart self-healing. Under near-infrared (NIR) light irradiation, the MXene can effectively heal scratches in the coating by utilizing the photothermal effect. Even after the coating is subjected to severe corrosion, a change in pH will cause ZIF-8 to dissociate and release corrosion inhibitors to further protect the metal. In addition, the stearic acid-modified ZIF-8 combined with MXene to form a top layer coating (MZSA), and a superhydrophobic surface with a photothermal effect was prepared, with a contact angle of 159.3°. Under the irradiation of near-infrared light, it has good anti-icing/de-icing performance. The Electrochemical impedance spectroscopy (EIS) results showed that |Z| f=0.01 Hz of the composite coating was as high as 4.47 × 10 9 Ω⋅cm 2 after 40 days of immersion in 3.5 wt% NaCl solution, which was four orders of magnitude higher than that of the SMP coating.
研究领域:
材料科学
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表面工程
·
腐蚀与防护
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2024
·
IF 13.3
Xiaoyu Xu,Shaoze Shi,Baohong Sun,Shuying Di,Juyang Zhang,Yuxin Xie,Ninglin Zhou
Agricultural coatings play a crucial role in addressing the global food crisis by significantly improving the plant growth environment, accelerating plant development, and enhancing the biological quality of plants. Nevertheless, there exist constraints in the form of limited sunlight utilization, decreased light transmission caused by surface icing leading to diminished plant photosynthesis, and high cost. In this study, a cost-effective and readily scalable superhydrophobic photothermal light-conversion coating is suggested as a means to improve the light conditions necessary for optimal plant growth. By employing in situ growth of carbon dots (CDs) on the surface and interlayers of montmorillonite (MMT) and hydrolytic polymerization of fluorinated alkyl silane (FAS) on the surface of MMT, light-converting superhydrophobic materials (CDs/MMT) with a micro-nano structure were synthesized. These materials demonstrated broad-spectrum fluorescence emission suitable for utilization by plant photosynthesis. They were dispersed into an epoxy resin (ER) matrix to obtain an agricultural superhydrophobic coating (ER-CDs/MMT). The “light absorption-capture-conversion” effect confers exceptional passive anti-icing and active de-icing properties upon the coating. Furthermore, outdoor planting experiments have demonstrated its capacity to substantially enhance the light environment and enhance the biological quality of soybean and morning glory by leveraging light scattering and conversion characteristics. This underscores its considerable potential for application in the next generation of facility agriculture.
研究领域:
农业科学
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材料科学
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植物生理学
✓ 已验证
DOI
高影响因子
Materials
·
2025
·Vol. 18
·期 11
·2540
·
IF 3.2
Yingcheng Zhao,Pei Tian,Xinlin Li,Di Gai,Wei Tong
Icing on power lines and wings can cause serious economic damage and safety hazards. While superhydrophobic materials show promise for anti-icing applications, their passive anti-icing mechanisms require external energy activation, highlighting the need for the development of active de-icing materials with energy-to-heat conversion capabilities. Here, we developed three photothermal superhydrophobic shape-memory polymers with anti-icing performance (PSSPs), with 3%, 5%, and 7% CNT doping ratios, through a two-step process: resin preparation and laser-processing modification. The results showed that all samples presented good superhydrophobic properties. In addition, the tested materials demonstrated good shape-memory performance (recovery rates were close to 100%). They also showed excellent de-icing performance. Owing to the simplicity of the fabrication process, the material is suitable for mass production. The synergistic interplay between superhydrophobicity and photothermal activation endows the material with dual-functional icephobic performance, demonstrating practical applicability in industrial cryogenic environments.
研究领域:
材料科学
·
能源转换
·
表面工程
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）